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1. 发明授权

US09969958B2 Concentrated detergent composition for the improved removal of starch in warewashing applications 有权
公开(公告)号：US09969958B2
公开(公告)日：2018-05-15
申请号：US14888537
申请日：2013-05-02
申请人： Ecolab USA, Inc.
发明人： David Dotzauer , Tobias Foster , David W. Gohl , Dirk Kullwitz , John Mansergh
IPC分类号： C11D3/10 , C11D3/16 , C11D3/39
CPC分类号： C11D3/10 , C11D3/168 , C11D3/3932 , C11D3/3942 , C11D3/3947
摘要： The invention provides a concentrated detergent composition comprising alkali metal carbonate, alkali metal percarbonate, and a peroxidation catalyst according to formula (I) [(LpMq)nXr]Ys, wherein each L independently is an organic ligand containing at least three nitrogen atoms that coordinate with the metal M; M is Mn or Fe; each X independently is a coordinating or bridging group selected from the group consisting of H2O, OH−, SH−, HO2−, O2−, O22−, S2−, F−, Cl−, Br−, I−, NO3−, NO2−, SO42−, SO32−, PO43−, N3−, CN−, NR3, NCS−, RCN, RS−, RCO2−, RO−, and with R being hydrogen or a C1 to C6 alkyl group; p is an integer from 1 to 4; q is an integer from 1 to 2; r is an integer from 0 to 6; Y is a counter ion; and s is the number of counter ions. The invention also relates to the use of said concentrated detergent composition as a warewashing detergent for the removal of starch soil.

2. 发明申请

US20170321164A1 DISHWASHER DETERGENT CONTAINING METAL COMPLEXES 审中-公开
公开(公告)号：US20170321164A1
公开(公告)日：2017-11-09
申请号：US15520124
申请日：2015-10-21
申请人： Henkel AG & Co. KGaA
发明人： Christian Kropf , Nadine Bluhm , Inga Kerstin Vockenroth , Noelle Wrubbel
IPC分类号： C11D3/39 , C11D17/00 , C11D3/28 , C11D3/20 , C11D3/00
CPC分类号： C11D3/3907 , C11D3/0073 , C11D3/168 , C11D3/2068 , C11D3/28 , C11D3/3935 , C11D11/0023 , C11D17/0039 , C11D17/0091 , C11D17/043
摘要： The present disclosure relates to an automatic dishwasher detergent which comprises metal complex of formula Mn+L(Amm−)n/m, wherein M is a metal cation, A is an arbitrary anion, n and m are integers selected from 1 to 6, and L is a neutral ligand of formula (II), wherein each X is as defined herein, and which exhibits improved cleaning performance in the removal of burnt-on soiling, to the use of this dishwasher detergent, and to a method for automatically washing dishes using this dishwasher detergent.

3. 发明授权

US09752106B2 Cleansing compositions containing stable silver 有权
公开(公告)号：US09752106B2
公开(公告)日：2017-09-05
申请号：US15114092
申请日：2015-01-06
申请人： Conopco, Inc.
发明人： Ajit Manohar Agarkhed , Nitish Kumar
IPC分类号： C11D3/48 , C11D3/22 , C11D1/02 , C11D3/12 , C11D3/16 , C11D1/14
CPC分类号： C11D3/48 , C11D1/02 , C11D1/143 , C11D3/1213 , C11D3/122 , C11D3/1226 , C11D3/168 , C11D3/22
摘要： Disclosed is a cleansing composition having pH of at least 9, said composition comprising: (i) 20 to 85 wt % anionic surfactant; and, (ii) a silver(I) compound having silver ion solubility (in water at 25° C.) of at least 1×10−4 mol/L, at a level equivalent to silver content of 0.01 to 100 ppm, wherein the free alkali content of said composition is less than 0.01%. The composition is a robust and improved cleansing composition with a stable colour.

4. 发明申请

US20170127679A1 OPHTHALMIC CONTACT LENS SOLUTIONS CONTAINING FORMS OF VITAMIN B 审中-公开
公开(公告)号：US20170127679A1
公开(公告)日：2017-05-11
申请号：US15412496
申请日：2017-01-23
申请人： FXS Ventures, LLC
发明人： Francis X. Smith
IPC分类号： A01N47/44 , A01N25/00 , A01N25/02 , C11D3/00 , C11D3/48 , C11D3/36 , C11D3/37 , C11D3/28 , C11D3/20 , C11D3/22 , C11D3/33 , A01N33/12 , C11D3/32
CPC分类号： A01N47/44 , A01N25/00 , A01N25/02 , A01N33/12 , A61K47/18 , A61K47/22 , A61K47/26 , A61L12/142 , A61L12/145 , A61L12/147 , C11D3/0078 , C11D3/168 , C11D3/2065 , C11D3/222 , C11D3/28 , C11D3/30 , C11D3/32 , C11D3/323 , C11D3/33 , C11D3/3481 , C11D3/361 , C11D3/362 , C11D3/37 , C11D3/3703 , C11D3/3707 , C11D3/3773 , C11D3/48
摘要： The present invention relates to improved ophthalmic solutions that employ select B vitamins; pyridoxine and its salts; and thiamine and its salts in order to more effectively preserve solutions and to reduce the degree to which cationic preservatives will deposit on contact lenses. Ophthalmic solutions are here understood to include contact lens treatment solutions, such as cleaners, soaking solutions, conditioning solutions and lens storage solutions, as well as wetting solutions and in-eye solutions for treatment of eye conditions.

5. 发明申请

US20160348039A1 CLEANSING COMPOSITIONS CONTAINING STABLE SILVER 有权
标题翻译：含有稳定银的清洁组合物
公开(公告)号：US20160348039A1
公开(公告)日：2016-12-01
申请号：US15114092
申请日：2015-01-06
申请人： CONOPCO, INC., D/B/A/ UNILEVER
发明人： Ajit Manohar AGARKHED , Nitish KUMAR
IPC分类号： C11D3/48 , C11D3/12 , C11D3/16 , C11D1/14
CPC分类号： C11D3/48 , C11D1/02 , C11D1/143 , C11D3/1213 , C11D3/122 , C11D3/1226 , C11D3/168 , C11D3/22
摘要： Disclosed is a cleansing composition having pH of at least 9, said composition comprising: (i) 20 to 85 wt % anionic surfactant; and, (ii) a silver(I) compound having silver ion solubility (in water at 25° C.) of at least 1×10−4 mol/L, at a level equivalent to silver content of 0.01 to 100 ppm, wherein the free alkali content of said composition is less than 0.01%. The composition is a robust and improved cleansing composition with a stable colour.
摘要翻译：公开了一种pH至少为9的清洁组合物，所述组合物包含：（i）20至85重量％的阴离子表面活性剂; 和（ii）具有至少1×10 -4 mol / L的银离子溶解度（在25℃的水中）的银（I）化合物，其含量相当于银含量为0.01〜100ppm，其中所述组合物的游离碱含量小于0.01％。该组合物是稳定且改进的具有稳定颜色的清洁组合物。

6. 发明申请

US20160075973A1 CONCENTRATED DETERGENT COMPOSITION FOR THE IMPROVED REMOVAL OF STARCH IN WAREWASHING APPLICATIONS 有权
标题翻译：用于改进清洗应用中淀粉的浓缩洗涤剂组合物
公开(公告)号：US20160075973A1
公开(公告)日：2016-03-17
申请号：US14888537
申请日：2013-05-02
申请人： Ecolab USA, Inc.
发明人： DAVID DOTZAUER , TOBIAS FOSTER , DAVID W. GOHL , DIRK KULLWITZ , JOHN MANSERGH
IPC分类号： C11D3/10 , C11D3/16 , C11D3/39
CPC分类号： C11D3/10 , C11D3/168 , C11D3/3932 , C11D3/3942 , C11D3/3947
摘要： The invention provides a concentrated detergent composition comprisingalkali metal carbonate, alkali metal percarbonate, and a peroxidation catalyst according to formula (I) [(LpMq)nXr]Ys, wherein each L independently is an organic ligand containing at least three nitrogen atoms that coordinate with the metal M; M is Mn or Fe; each X independently is a coordinating or bridging group selected from the group consisting of H2O, OH−, SH−, HO2−, O2−, O22−, S2−, F−, Cl−, Br−, I−, NO3−, NO2−, SO42−, SO32−, PO43−, N3−, CN−, NR3, NCS−, RCN, RS−, RCO2−, RO−, and with R being hydrogen or a C1 to C6 alkyl group; p is an integer from 1 to 4; q is an integer from 1 to 2; r is an integer from 0 to 6; Y is a counter ion; and s is the number of counter ions. The invention also relates to the use of said concentrated detergent composition as a warewashing detergent for the removal of starch soil.
摘要翻译：本发明提供了含有碱金属碳酸盐，碱金属过碳酸盐和根据式（I）[（LpMq）n Xr] Ys的过氧化催化剂的浓缩洗涤剂组合物，其中每个L独立地是含有至少三个氮原子的有机配体，与金属M; M是Mn或Fe; 每个X独立地是选自H 2 O，OH-，SH-，HO 2 - ，O 2 - ，O 22 - ，S 2 - ，F-，Cl-，Br-，I-，NO 3 - 的配位或桥接基团， NO2-，SO42-，SO32-，PO43-，N3-，CN-，NR3，NCS-，RCN，RS-，RCO2-，RO-，且R为氢或C1至C6烷基; p是1至4的整数; q是1至2的整数; r为0〜6的整数; Y是抗衡离子; s是抗衡离子的数量。本发明还涉及将所述浓缩洗涤剂组合物用作去除淀粉土壤的器皿洗涤剂。

7. 发明授权

US08961822B2 Metallocarbene complex peroxide activators 有权
标题翻译：金属络合物复合过氧化物活化剂
公开(公告)号：US08961822B2
公开(公告)日：2015-02-24
申请号：US13792749
申请日：2013-03-11
申请人： Arkema Inc.
发明人： Michael B. Abrams , Xiawei Zhang
IPC分类号： C07D295/15 , C11D3/395 , C11D3/16 , C11D3/39
CPC分类号： C11D3/3951 , C11D3/168 , C11D3/3932
摘要： A bleaching composition comprising a peroxy compound and one or more activator present in an effective amount to activate the peroxy compound, present in an amount effective to accomplish bleaching or cleaning or oxidation. The activator is a metallocarbene of the general structure (XX′C)yMLn′ where M represents a metal center, C represents the carbene carbon bound to the metal center, X and X′ may be the same or different and may furthermore be part of a cyclic structure, Ln′ represents one or more other ligands which may or may not include one or more metal centers, and where y≧1.
摘要翻译：一种漂白组合物，其包含有效量的过氧化合物和一种或多种活化剂以活化过氧化合物，以有效实现漂白或清洁或氧化的量存在。活化剂是一般结构（XX'C）yMLn'的金属苝，其中M表示金属中心，C表示与金属中心结合的碳烯碳，X和X'可以相同或不同，并且还可以是环状结构，Ln'表示一个或多个其它配体，其可以或可以不包括一个或多个金属中心，并且其中y≥1。

8. 发明申请

US20130281353A1 Use of Metal Hydrazide Complex Compounds as Oxidation Catalysts 有权
标题翻译：金属酰肼配合物作为氧化催化剂的应用
公开(公告)号：US20130281353A1
公开(公告)日：2013-10-24
申请号：US13920381
申请日：2013-06-18
申请人： BASF SE
发明人： Barbara Winkler , Hauke Rohwer , Marie-Josee Dubs , Menno Hazenkamp , Kai Eichin , Albert Schneider
IPC分类号： C11D3/39
CPC分类号： C11D3/28 , A01N47/34 , A61L2/18 , A61L12/128 , B01J27/20 , B01J27/24 , B01J31/1805 , B01J31/2208 , B01J2231/70 , B01J2531/0238 , B01J2531/72 , C11D3/168 , C11D3/32 , C11D3/323 , C11D3/3917 , C11D3/3927 , C11D3/3932 , C11D7/3209 , C11D7/3263 , C11D7/3281 , D06L4/12
摘要： The present invention relates to the use of selected metal complex compounds and ligands as oxidation catalysts as well as to a process for removing stains and soil on textiles and hard surfaces. The metal complex compounds have hydrazide ligands, preferably with electron withdrawing groups in the phenyl ring adjacent to the acyl group. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands.
摘要翻译：本发明涉及选择的金属络合物和配体作为氧化催化剂的用途以及去除织物和硬表面上的污渍和污垢的方法。金属络合物具有酰肼配体，优选在与酰基相邻的苯环中具有吸电子基团。本发明的其它方面是包含这种金属络合物，新型金属络合物和新型配体的制剂。

9. 发明申请

US20110147654A1 METALLOCARBENE COMPLEX PEROXIDE ACTIVATORS 有权
标题翻译： METALLOCARBENE复合过氧化物活化剂
公开(公告)号：US20110147654A1
公开(公告)日：2011-06-23
申请号：US12990317
申请日：2009-05-12
申请人： Michael B. Abrams , Xiawei Zhang
发明人： Michael B. Abrams , Xiawei Zhang
IPC分类号： C11D3/395
CPC分类号： C11D3/3951 , C11D3/168 , C11D3/3932
摘要： A bleaching composition comprising a peroxy compound and one or more activator present in an effective amount to activate the peroxy compound, present in an amount effective to accomplish bleaching or cleaning or oxidation. The activator is a metallocarbene of the general structure (XX′C)yMLn′ where M represents a metal center, C represents the carbene carbon bound to the metal center, X and X′ may be the same or different and may furthermore be part of a cyclic structure, Ln′ represents one or more other ligands which may or may not include one or more metal centers, and where y>1.
摘要翻译：一种漂白组合物，其包含有效量的过氧化合物和一种或多种活化剂以活化过氧化合物，以有效实现漂白或清洁或氧化的量存在。活化剂是一般结构（XX'C）yMLn'的金属苝，其中M表示金属中心，C表示与金属中心结合的碳烯碳，X和X'可以相同或不同，并且还可以是环状结构，Ln'表示一个或多个其它配体，其可以或可以不包括一个或多个金属中心，并且其中y> 1。

10. 发明申请

US20110071066A1 USE OF METAL HYDRAZIDE COMPLEX COMPOUNDS AS OXIDATION CATALYSTS 有权
标题翻译：使用金属氢化物复合化合物作为氧化催化剂
公开(公告)号：US20110071066A1
公开(公告)日：2011-03-24
申请号：US12936699
申请日：2009-03-30
申请人： Barbara Wagner , Hauke Rohwer , Marie-Josee Dubs , Menno Hazenkamp , Kai Eichin , Albert Schneider
发明人： Barbara Wagner , Hauke Rohwer , Marie-Josee Dubs , Menno Hazenkamp , Kai Eichin , Albert Schneider
IPC分类号： C11D3/395 , C07C243/18 , C07D295/155 , C07F13/00 , C11D3/60
CPC分类号： C11D3/28 , A01N47/34 , A61L2/18 , A61L12/128 , B01J27/20 , B01J27/24 , B01J31/1805 , B01J31/2208 , B01J2231/70 , B01J2531/0238 , B01J2531/72 , C11D3/168 , C11D3/32 , C11D3/323 , C11D3/3917 , C11D3/3927 , C11D3/3932 , C11D7/3209 , C11D7/3263 , C11D7/3281 , D06L4/12
摘要： The present invention relates to the use of selected metal complex compounds and ligands as oxidation catalysts as well as to a process for removing stains and soil on textiles and hard surfaces. The metal complex compounds have hydrazide ligands preferably with electron withdrawing groups in the phenyl ring adjacent to the acyl group. Further aspects of the invention are formulations comprising such metal complex compounds, novel metal complex compounds and novel ligands.
摘要翻译：本发明涉及选择的金属络合物和配体作为氧化催化剂的用途以及去除织物和硬表面上的污渍和污垢的方法。金属配位化合物优选在与酰基相邻的苯环中具有吸电子基团的酰肼配体。本发明的其它方面是包含这种金属络合物，新型金属络合物和新型配体的制剂。

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