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    • 4. 发明授权
    • Phthalocyanines
    • 酞菁
    • US5629417A
    • 1997-05-13
    • US594412
    • 1996-01-31
    • James S. CampbellPeter GregoryDean Thetford
    • James S. CampbellPeter GregoryDean Thetford
    • C07D487/22C09B47/20C09B47/22
    • C09B47/20C09B47/22
    • A phthalocyanine of Formula (1): ##STR1## wherein: M.sub.k PC is a phthalocyanine nucleus of Formula (2): ##STR2## M is a metal atom, a chloro-metal group, and oxy-metal group or hydrogen; k is inverse of 1/2 valency of M; R and R.sup.1 each independently is an organic radical;R.sup.2 is H or optionally substituted alkyl;a is an average value from 15 to 8;b is an average value from 1 to 8; anda+b is from 15 to 16; and sulphonated derivatives thereof and process for their preparation.The phthalocyanines of the present invention are useful for absorbing electro-magnetic radiation from for example a laser source and may be used in a coating for optical data storage disks, or in security applications such as printing banknotes or cheques, or in the preparation of lithographic printing plates or in washing powders to assist in bleaching.
    • 式(1)的酞菁:式(1)其中:MkPC是式(2)的酞菁核:式(2)M是金属原子,氯 - 金属基和氧 - 金属基团或氢; k为+ E的倒数,为M的1/2 + EE化合价; R和R 1各自独立地为有机基团; R2是H或任选取代的烷基; a是从15到8的平均值; b为1〜8的平均值; a + b为15〜16; 及其磺化衍生物及其制备方法。 本发明的酞菁可用于从例如激光源吸收电磁辐射,并且可用于光学数据存储盘的涂层中,或用于诸如印刷纸币或支票的安全应用中,或用于制备光刻 印刷板或洗涤粉以帮助漂白。
    • 5. 发明授权
    • Poly(oxyalkylene) modified phthalocyanine colorants
    • 聚(氧化烯)改性酞菁着色剂
    • US5270363A
    • 1993-12-14
    • US935567
    • 1992-08-24
    • Edward W. KlugerJohn W. RekersDavid J. Moody
    • Edward W. KlugerJohn W. RekersDavid J. Moody
    • C08K5/43C09B47/18C09B47/20C09B47/22C09B47/26C09B69/00C08K5/3417C08K5/04C08K5/41
    • C09B47/22C08K5/43C09B47/18C09B47/20C09B47/26C09B69/00
    • A colorant for natural or synthetic resinous or polymeric materials, having the formula A--[SO.sub.2 --N(R.sub.2)--Y].sub.1-4 ; wherein: R.sub.2 is selected for example from hydrogen, methyl, cyclohexyl, phenyl or Y; A is a nonionic metallophthalocyanine chromophore which can be substituted for example with halogen, alkyl. alkoxy, alkylthio, or aryloxy; Y is a poly(oxyalkylene) moiety containing at least three monomeric units or mixtures thereof of the formula (--RO--) wherein each R is straight or branched alkylene of 1-4 carbons or mixtures thereof, up to about 20 mole percent of said monomeric units may be connected by one or more linking groups such as alkyleneoxy, --NH--, or --NHCONH--, and wherein Y can be terminated by hydrogen, or by at branch substituents, containing 1--3 groups or moieties selected from alkyl, cycloalkyl, acyl, or aryl; wherein any of the above recited hydrocarbon groups, moieties or substitutents may themselves be substituted with up to four substitutents selected, for example, from alkyl, halogen, mercapto, alkoxycarbonyl, hydroxy, alkoxy, or the like; and wherein each aliphatic hydrocarbon portion or moiety of the groups, moieties or substituents recited above contains from 1-20 carbons.
    • 具有式A- [SO 2 -N(R 2)-Y] 1-4的天然或合成树脂或聚合物材料的着色剂; 其中:R2选自例如氢,甲基,环己基,苯基或Y; A是非离子金属酞菁发色团,其可以被卤素,烷基取代。 烷氧基,烷硫基或芳氧基; Y是包含式(-RO-)的至少三个单体单元或其混合物的聚(氧化烯)部分,其中每个R是1-4个碳的直链或支链亚烷基或其混合物,最多约20摩尔% 单体单元可以通过一个或多个连接基团例如亚烷基氧基,-NH-或-NHCONH-连接,并且其中Y可以被氢封端,或者通过分支取代基连接,所述分支取代基包含1-3个选自烷基, 环烷基,酰基或芳基; 其中任何上述烃基,部分或取代基本身可以被至多四个选自例如烷基,卤素,巯基,烷氧基羰基,羟基,烷氧基等的取代基取代; 并且其中上述基团,部分或取代基的每个脂族烃部分或部分含有1-20个碳。
    • 10. 发明授权
    • Phthalocyanine compounds, process for producing the same, and near infrared absorbent comprising the same
    • 酞菁化合物,其制造方法和包含该酞菁化合物的近红外吸收剂
    • US06468713B1
    • 2002-10-22
    • US09673029
    • 2000-10-10
    • Hiroshi TeraoShigeo FujitaYojiro Kumagae
    • Hiroshi TeraoShigeo FujitaYojiro Kumagae
    • G03F7038
    • C07D487/22C09B47/00C09B47/063C09B47/064C09B47/08C09B47/18C09B47/20C09B47/22C09K3/00
    • The invention relates to a novel phthalocyanine compound which absorbs in a near-infrared region of 700˜1000 nm with little absorption in the visible region of the spectrum and can be applied with advantage to a near-infrared light-absorbing filter for plasma display, a secret ink and other applications and to a process for producing the phthalocyanine compound. The above phthalocyanine compound has the following general formula (I). A near-infrared light-absorbing material containing the same is also provided. wherein R1˜R8 represents alkyl or alkoxyalkyl; X1˜X8 represents sulfur or >NR9; X1=(either X3 or X4)=(either X5 or X6)=(either X7 or X8)=sulfur and X2=(the other one of X3 and X4)=(the other one of X5 and X6)=(the other one of X7 and X8)=>NR9; R9 represents an acyl group which may optionally be substituted or an aroyl group which may optionally be substituted; M represents a couple of hydrogen atoms, a divalent metal, a trivalent metal derivative or a tetravalent metal derivative).
    • 本发明涉及一种新颖的酞菁化合物,其在700〜1000nm的近红外区域吸收,在光谱的可见光区域吸收少,可用于等离子显示器的近红外光吸收滤光片, 秘密油墨和其它用途以及制备酞菁化合物的方法。上述酞菁化合物具有以下通式(I)。 还提供了含有它的近红外光吸收材料。其中R1〜R8代表烷基或烷氧基烷基; X1〜X8表示硫或> NR9; X1 =(X3或X4)=(X5或X6)=(X7或X8)=硫,X2 =(X3和X4中的另一个)=(X5和X6中的另一个)=(另一个 X7和X8之一)=> NR9; R9表示可任选被取代的酰基或可任选被取代的芳酰基; M表示氢原子,二价金属,三价金属衍生物或四价金属衍生物)。