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    • 2. 发明授权
    • Aqueous solutions or dispersions of copolymers
    • 共聚物的水溶液或分散体
    • US5914442A
    • 1999-06-22
    • US676233
    • 1996-07-25
    • Hermann BirkhoferMichael KneipPeter DanischWalter DenzingerAxel KistenmacherHeinrich Hartmann
    • Hermann BirkhoferMichael KneipPeter DanischWalter DenzingerAxel KistenmacherHeinrich Hartmann
    • C14C9/00B01F17/22B01F17/42C08F220/18C08F222/06C08J3/03C14C9/02C14C11/00
    • C08J3/03C08F220/18C08F222/06C14C9/02
    • Aqueous solution or aqueous dispersion of copolymers suitable for the fatliquoring and filling of leather and fur skins are obtained by free-radical copolymerization ofA.sup.1) C.sub.6 -C.sub.40 -monoolefins or C.sub.6 -C.sub.40 -alkyl vinyl ethers or mixtures thereof withB.sup.1) monoethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides or by free-radical copolymerization ofA.sup.2) C.sub.6 -C.sub.40 -alkyl acrylates or methacrylates or vinyl esters of C.sub.6 -C.sub.40 -carboxylic acids or mixtures thereof withB.sup.2) monoethylenically unsaturated C.sub.3 -C.sub.12 -carboxylic acids, monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids, amides of monoethylenically unsaturated C.sub.3 -C.sub.12 -carboxylic acids or mixtures thereofto give copolymers with molecular weights of 500 to 30,000, where the carboxyl groups which are present in aqueous medium are at least partially neutralized, and some of the carboxylic groups can be in amidated form,containing 0.5-40% by weight, based on the amount of copolymer, of defined emulsifiers.
    • PCT No.PCT / EP95 / 00144 Sec。 371日期:1996年7月25日 102(e)日期1996年7月25日PCT提交1995年1月16日PCT公布。 WO95 / 20056 PCT公开号 日期1995年7月27日适用于加脂和填充皮革和毛皮的共聚物的水溶液或水分散体通过A1)C6-C40-单烯烃或C6-C40-烷基乙烯基醚或其混合物与 B1)单烯键式不饱和C 4 -C 8二羧酸酐或通过A2)C6-C40烷基丙烯酸酯或甲基丙烯酸酯或C6-C40-羧酸的乙烯酯或其混合物与B2)单烯属不饱和C 3 -C 12羧酸的自由基共聚合 酸,单烯属不饱和C 4 -C 12二羧酸酐,单烯属不饱和C 4 -C 12二羧酸的单酯或单酰胺,单烯属不饱和C 3 -C 12羧酸的酰胺或其混合物,得到分子量为500至30,000的共聚物,其中 存在于水性介质中的羧基至少部分中和,并且一些羧基可以是酰胺化形式,其含有0.5 -40重量%,基于共聚物的量,定义的乳化剂。
    • 5. 发明授权
    • Use of graft polymers for fatliquoring and filling leather and fur skins
    • 使用接枝聚合物来加脂和填充皮革和毛皮
    • US5620748A
    • 1997-04-15
    • US193135
    • 1994-03-03
    • Hermann BirkhoferPeter DanischWalter DenzingerHeinrich HartmannMichael Kneip
    • Hermann BirkhoferPeter DanischWalter DenzingerHeinrich HartmannMichael Kneip
    • C14C9/00B05D3/02
    • C14C9/00
    • Soft leathers with a pleasant hand are obtained on fatliquoring and filling leather and fur skins with water-soluble or water-dispersible graft polymers of vegetable and animal oils, obtainable by radically initiated polymerizationA) of a monomer or monomer mixture comprising(a) from 20 to 100% by weight of monoethylenically unsaturated carboxylic acids and/or monoethylenically unsaturated sulfonic acids and/or monoethylenically unsaturated phosphonic acids or their alkali metal, alkaline earth metal or ammonium salts,(b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which are copolymerizable with the monomers (a), and(c) from 0 to 5% by weight of at least doubly ethylenically unconjugatedly unsaturated monomers in the presence ofB) vegetable and/or animal oils in a weight ratio of A:B of (80-1):(20-99).
    • PCT No.PCT / EP93 / 01831 Sec。 371日期1994年3月3日 102(e)1994年3月3日PCT提交1993年7月13日PCT公布。 出版物WO94 / 02650 日期1994年2月3日柔软的手皮是通过加脂和填充皮革和毛皮皮肤与水溶性或水分散性植物和动物油的接枝聚合物获得的,可通过自由基引发聚合A)单体或单体混合物 包含(a)20至100重量%的单烯属不饱和羧酸和/或单烯属不饱和磺酸和/或单烯属不饱和膦酸或其碱金属,碱土金属或铵盐,(b)0至80% 重量的其它单烯属不饱和单体,它们可与单体(a)和(c)共聚,0至5%重量的至少双烯键式非共轭不饱和单体在B)存在下的植物油和/或动物油 (80-1):( 20-99)的A:B的重量比。
    • 8. 发明授权
    • Vinyl formate copolymers, preparation thereof, and use thereof in
detergents and cleaners
    • 甲酸乙烯酯共聚物,其制备方法及其在洗涤剂和清洁剂中的应用
    • US5739241A
    • 1998-04-14
    • US750472
    • 1996-12-16
    • Dieter BoeckhAxel KistenmacherWalter DenzingerThomas RuhlAngelika FunhoffRichard BaurAlexander KudVolker Schwendemann
    • Dieter BoeckhAxel KistenmacherWalter DenzingerThomas RuhlAngelika FunhoffRichard BaurAlexander KudVolker Schwendemann
    • C08F218/06C08F220/04C08F222/02C11D3/37C08F22/02C08F20/10
    • C11D3/3757C08F218/06C08F220/04
    • Copolymers containing (a) from 5 to 90 mol % of vinyl formate units, (b) from 10 to 95 mol % of units of monoethylenically unsaturated carboxylic acids, (c) from 0 to 70 mol % of units of monoethylenically unsaturated dicarboxylic acids, and (d) from 0 to 30 mol % of units of other monoethylenically unsaturated monomers in copolymerized form and having K values of at least 8 (determined by the method of H. Fikentscher in 1% strength by weight aqueous solution on the sodium salt of the copolymers at pH 7 and 25.degree. C.), processes for their preparation by copolymerizing monomer mixtures of (a) from 5 to 90 mol % of vinyl formate, (b) from 10 to 95 mol % of monoethylenically unsaturated carboxylic acids, (c) from 0 to 70 mol % of monoethylenically unsaturated dicarboxylic acids, and (d) from 0 to 30 mol % of other monoethylenically unsaturated monomers in an aqueous medium or in an organic solvent in the presence of free-radical polymerization initiators and use of the vinyl formate copolymers and of the vinyl alcohol copolymers obtainable therefrom by hydrolysis and/or oxidation as detergent and cleaner additives.
    • PCT No.PCT / EP95 / 02053 Sec。 371日期1996年12月16日第 102(e)日期1996年12月16日PCT提交1995年5月31日PCT公布。 公开号WO95 / 34587 日期:1995年12月21日含有(a)5〜90摩尔%甲酸乙烯酯单元的聚合物,(b)10〜95摩尔%的单烯属不饱和羧酸单元,(c)0〜70摩尔% 单烯属不饱和二羧酸,和(d)0至30摩尔%的共聚形式的其它单烯属不饱和单体的单元,并且K值至少为8(通过H.Fikentscher在1%重量比浓度的水溶液中测定) 在共聚物的钠盐上,在pH7和25℃下),其制备方法是通过使(a)5-90mol%的甲酸乙烯酯,(b)10至95mol%的单烯属的单体混合物 不饱和羧酸,(c)0-70摩尔%的单烯属不饱和二羧酸,和(d)0-30摩尔%的其它单烯属不饱和单体在水性介质或有机溶剂中,在自由基存在下 聚合引发剂和使用v 甲酸丁酯共聚物和通过水解和/或氧化作为洗涤剂和清洁剂添加剂得到的乙烯醇共聚物。