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1. 发明授权

US06596386B1 Formaldehyde-free binders for shaped articles 有权
标题翻译：成型制品不含甲醛的粘合剂
公开(公告)号：US06596386B1
公开(公告)日：2003-07-22
申请号：US09527583
申请日：2000-03-17
申请人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
发明人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
IPC分类号： B32B2102
CPC分类号： C08K5/17 , B27N3/00 , C08L35/00 , C08L97/00 , Y10T428/249925 , C08L2666/26
摘要： A formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl groups can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, is useful as binder for renewable raw materials in the form of fibers or chips to produce shaped articles.
摘要翻译：一种不含甲醛的水性粘合剂，其包含：A）含有5-100重量％衍生自烯属不饱和酸酐或羧基可形成酸酐基团的烯属不饱和二羧酸的单元的自由基聚合聚合物，和B）具有至少两个羟基的链烷醇胺可用作纤维或碎片形式的可再生原料的粘合剂，以生产成型制品。

2. 发明授权

US06200640B1 Polymer composition and process for treating leather and fur skins 有权
标题翻译：用于处理皮革和毛皮的聚合物组合物和方法
公开(公告)号：US06200640B1
公开(公告)日：2001-03-13
申请号：US09147078
申请日：1998-11-09
申请人： Michael Kneip , Axel Kistenmacher , Peter Danisch , Gerhard Wolf
发明人： Michael Kneip , Axel Kistenmacher , Peter Danisch , Gerhard Wolf
IPC分类号： C14C900
CPC分类号： C09D123/08 , C14C9/00
摘要： Aqueous solutions or dispersions of copolymers obtainable by free-radical copolymerization of (a) from 20 to 90% by weight of at least one monoethylenically unsaturated C4-6-dicarboxylic acid or the anhydride thereof, as component A, (b) from 5 to 50% by weight of at least one olefin having 2 to 6 carbon atoms, as component B, (c) from 5 to 50% by weight of at least one hydrophobic comonomer from the group consisting of long-chain olefins, esters of long-chain alcohols with acrylic acid or methacrylic acid, long-chain amides of acrylic acid or methacrylic acid, and long-chain alkyl vinyl ethers, as component C, (d) from 0 to 40% by weight of further comonomers which can be copolymerized with the above monomers, as component D, where the sum of the amounts of components A, B, C and, if used, D is 100% by weight, followed by at least partial esterification or hydrolysis and neutralization and/or reaction of the carboxyl groups formed during the hydrolysis with bases, for treating leather and/or fur skins.
摘要翻译：通过（a）20至90重量％的至少一种单烯属不饱和C4-6二羧酸或其酸酐作为组分A，（b）的自由基共聚获得的共聚物的水溶液或分散体，从5至 50重量％的至少一种具有2至6个碳原子的烯烃作为组分B，（c）5至50重量％的至少一种疏水性共聚单体，其由长链烯烃，长链烯烃，具有丙烯酸或甲基丙烯酸的链醇，丙烯酸或甲基丙烯酸的长链酰胺和作为组分C的长链烷基乙烯基醚，（d）0至40重量％的可共聚合的另外的共聚单体上述单体作为组分D，其中组分A，B，C和（如果使用的话）D的量的总和为100重量％，然后至少部分酯化或水解和中和和/或羧基的反应在用碱水解过程中形成的基团，用于处理皮革和/ 或毛皮。

3. 发明授权

US06586534B1 Agglomerated particles of finely divided polymers which are water-soluble or capable of swelling in water and contain ammonium carboxylate groups 失效
标题翻译：精细分散的聚合物的聚集颗粒，其水溶性或能够在水中溶胀并含有羧酸铵基团
公开(公告)号：US06586534B1
公开(公告)日：2003-07-01
申请号：US08809710
申请日：1997-04-04
申请人： Martin Rübenacker , Reinhard Schneider , Jürgen Nieberle , Heinrich Hartmann , Walter Denzinger , Axel Kistenmacher
发明人： Martin Rübenacker , Reinhard Schneider , Jürgen Nieberle , Heinrich Hartmann , Walter Denzinger , Axel Kistenmacher
IPC分类号： C08F800
CPC分类号： C08F220/04 , C08F6/18
摘要： Agglomerated polymer particles of finely divided, water-soluble or water-swellable polymers containing ammonium carboxylate groups are prepared by azeotropic removal of water from water-in-oil emulsions of the water-soluble or water-swellable polymers which contain ammonium carboxylate groups in the presence of from 0.1 to 40% by weight, based on the polymers, of polyalkylene glycols which have an agglomerating effect and which are obtainable by an addition reaction of C2-C4-alkylene oxides with alcohols, phenols, amines or carboxylic acids and contain at least two polymerized alkylene oxide units and additionally of from 0.1 to 20% by weight, based on the polymers, of protective colloids which are obtainable by free radical copolymerization of C8-C40-monoolefins with monoethylenically unsaturated C4-C6-dicarboxylic anhydrides by a mass polymerization method at from 80 to 300° C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, and said agglomerated polymer particles are used as thickeners for textile pigment print pastes.
摘要翻译：通过共沸除去含有羧酸铵基团的水溶性或水溶胀性聚合物的水，从而将含有羧酸铵基团的细分散的水溶性或水溶胀性聚合物的聚集的聚合物颗粒共沸去除，基于聚合物，存在具有附聚效应的聚亚烷基二醇的0.1至40重量％，其可通过C 2 -C 4 - 烯化氧与醇，酚，胺或羧酸的加成反应获得并含有至少两个聚合的烯化氧单元，另外为基于聚合物的0.1至20重量％的保护胶体，其通过C8-C40-单烯烃与单烯属不饱和C4-C6-二羧酸酐通过质量自由基共聚获得在80〜300℃下进行聚合，得到分子量为500〜20,000g / mol的共聚物，所述聚集体聚合物颗粒用作纺织品颜料印刷浆料的增稠剂。

4. 发明授权

US6114464A Thermosetting aqueous compostions 有权
标题翻译：热固性水性组合物
公开(公告)号：US6114464A
公开(公告)日：2000-09-05
申请号：US147310
申请日：1998-11-25
申请人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Jurgen Mohr , Axel Kistenmacher , Joachim Roser
发明人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Jurgen Mohr , Axel Kistenmacher , Joachim Roser
IPC分类号： C08J5/04 , B27N3/00 , C08F8/30 , C08G73/00 , C08G81/02 , C08K5/17 , C08L33/02 , C08L35/00 , C09J133/00 , C09J177/00 , D04H1/4218 , D04H1/4266 , D04H1/559 , D04H1/587 , D04H1/593 , D04H1/645 , C08F20/00
CPC分类号： D04H1/645 , B27N3/002 , C08F8/32 , C08K5/17 , D04H1/4218 , D04H1/4266 , D04H1/559 , D04H1/587 , D04H1/593 , B27N3/02 , C08F2800/20 , Y10T428/2933 , Y10T428/31993
摘要： Thermally curable mixtures of hydroxyalkylated polyamines and polycarboxylic acids are formaldehyde-free and particularly useful as binders for shaped articles.
摘要翻译： PCT No.PCT / EP97 / 02796 Sec。 371日期：1998年11月25日 102（e）1998年11月25日日期PCT提交1997年5月28日PCT公布。公开号WO97 / 45461 日期1997年12月4日羟基烷基化多胺和多元羧酸的可固化混合物是无甲醛的，特别适用于成型制品的粘合剂。

5. 发明授权

US06946004B2 Use of grafted polyalkylene oxides as greying inhibitors when washing 失效
标题翻译：在洗涤时使用接枝聚环氧烷作为灰化抑制剂
公开(公告)号：US06946004B2
公开(公告)日：2005-09-20
申请号：US10362360
申请日：2001-08-30
申请人： Jürgen Huff , Bernhard Mohr , Axel Kistenmacher , Sebastian Koltzenburg , Christine Müller
发明人： Jürgen Huff , Bernhard Mohr , Axel Kistenmacher , Sebastian Koltzenburg , Christine Müller
IPC分类号： D06L1/12 , C08F283/06 , C08L51/08 , C11D3/37 , D06M11/00 , D06M11/58 , D06M14/00
CPC分类号： C11D3/3788 , C08F283/06 , C08L51/08
摘要： The invention relates to the use of grafted polymers as greying inhibitors during the washing and aftertreatment of textile goods. Said polymers are obtained by polymerising A) 10 to 95 wt. % of grafted monomers containing, in relation to A), a) 1 to 99 wt. % of at least one vinyl ester, b) 1 to 99 wt. % of at least one N-vinyl lactam, c) 0 to 90 wt. % of at least one other monoethylenically unsaturated monomer which can be copolymerized with monomers a) and b), and d) 0 to 5 wt. % of at least one monomer having at least two ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of A) 5 to 90 wt. % of at least one polymer B), chosen from polyalkylene oxides containing at least 3 units of a C2 to C4 alkylene oxide, and polytetrahydrofuranes containing at least 3 units of tetramethyl oxide units, and the mixtures thereof.
摘要翻译：本发明涉及在纺织品的洗涤和后处理中使用接枝聚合物作为防灰白剂。所述聚合物通过聚合A）10至95wt。含有相对于A）的接枝单体的％，a）1〜99wt。％的至少一种乙烯基酯，b）1至99wt。％的至少一种N-乙烯基内酰胺，c）0-90wt。％的至少一种可与单体a）和b）共聚的其它单烯属不饱和单体，和d）0-5重量％％的至少一种在分子中具有至少两个烯属不饱和的非共轭双键的单体，A）5-90wt。至少一种聚合物B）的％，选自含有至少3个C 2至C 4 O 3环氧烷单元的聚环氧烷，以及含有至少3个单元的至少3个单元的聚四氢呋喃四甲基氧化物单元及其混合物。

6. 发明授权

US06384111B1 Polymers containing carboxyl groups and polyalkylene ether side- chains as additives in mineral building materials 有权
标题翻译：含有羧基和聚亚烷基醚侧链作为矿物建筑材料添加剂的聚合物
公开(公告)号：US06384111B1
公开(公告)日：2002-05-07
申请号：US09331167
申请日：1999-06-21
申请人： Axel Kistenmacher , Paul Klingelhofer , Johannes Perner , Markus Hartmann , Alfred Ruland
发明人： Axel Kistenmacher , Paul Klingelhofer , Johannes Perner , Markus Hartmann , Alfred Ruland
IPC分类号： C08F22004
CPC分类号： C04B24/2647 , C08F220/04 , C08F220/28
摘要： Additives for mineral building materials made of water-soluble or water-dispersible polymers containing a carboxyl group, optionally in latent form, and at least one side chain of formula I: —X—Y—[O—(Alk—O)n—R]k (I) wherein k is 1, 2, 3 or 4; Y is a C1-C4-alkylene unit, or a single bond if X is a carbonyl group, or when k≠1, can also be X is wherein R′ is hydrogen, C1-C20-alkyl, C5-C10-cycloalkyl, C6-C20-aryl, C1-C20-alkanoyl, C7-C21-aroyl, (Alk-O)n—R or -Alk′-O(Alk-O)n—R; Alk is C2-C4-alkylene; Alk′ is C1-C4-alkylene optionally having an OH group; n is a number in the range from 15 to 300; and R is hydrogen, C1-C20-alkyl, C5-C8-cycloalkyl, C6-C20-aryl, C1-C20-alkanoyl or C7-C21-aroyl; are obtained by polymerization of ethylenically unsaturated monomers in the presence of phosphorus-containing compounds and, if appropriate, subsequent polymer-analogous conversion.
摘要翻译：含有任选潜伏的羧基的水溶性或水分散性聚合物和至少一种式I侧链的矿物建筑材料用添加剂：其中为1,2,3或4; Y为C1- C4-亚烷基单元，如果X是羰基，则为单键，或者当k <1时，也可以是X，其中R'是氢，C 1 -C 20 - 烷基，C 5 -C 10 - 环烷基，C 6 -C 20 - 芳基，C 1 -C 20烷酰基，C 7 -C 21 - 芳酰基，（Alk-O）nR或-Alk'-O（Alk-O）nR; Alk是C 2 -C 4亚烷基; Alk' 具有OH基团; n为15至300的数值; 和R为氢，C 1 -C 20烷基，C 5 -C 8 - 环烷基，C 6 -C 20 - 芳基，C 1 -C 20烷酰基或C 7 -C 21 - 芳酰基; 是通过在含磷化合物存在下烯属不饱和单体的聚合获得的，并且如果合适的话，则随后进行聚合物 - 类似转化。

7. 发明授权

US06071994A Formaldehyde-free aqueous binders 有权
标题翻译：不含甲醛的含水粘合剂
公开(公告)号：US06071994A
公开(公告)日：2000-06-06
申请号：US125113
申请日：1998-08-18
申请人： Rainer Hummerich , Axel Kistenmacher , Walter Denzinger , Gunnar Schornick , Bernd Reck , Manfred Weber
发明人： Rainer Hummerich , Axel Kistenmacher , Walter Denzinger , Gunnar Schornick , Bernd Reck , Manfred Weber
IPC分类号： D06N7/06 , C08F8/30 , C08K5/17 , C08K7/04 , C08L33/02 , C08L35/00 , D04H1/42 , D04H1/58 , D04H1/64 , D06M13/02 , D06M13/325 , D06M15/263 , D06N3/04 , C08K3/00
CPC分类号： C08K5/17
摘要： Formaldehyde-free aqueous binders compriseA) a polymer containing from 5 to [lacuna]% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl groups can form an anhydride group, andB) an alkanolamine having at least two hydroxyl groups.
摘要翻译： PCT No.PCT / EP97 / 00770 Sec。 371日期1998年8月18日 102（e）1998年8月18日PCT PCT 1997年2月19日PCT公布。公开号WO97 / 31036 日期1997年8月28日无甲醛水性粘合剂包含A）含有5至[空白]％（重量）衍生自烯属不饱和酸酐的单元或由羧基可形成酸酐基团的烯键式不饱和二羧酸的聚合物，和B）具有至少两个羟基的链烷醇胺。

8. 发明授权

US5714560A Water-soluble or water-dispersible graft polymers of proteins as leather tanning agents 失效
标题翻译：作为皮革鞣剂的蛋白质的水溶性或水分散性接枝聚合物
公开(公告)号：US5714560A
公开(公告)日：1998-02-03
申请号：US737329
申请日：1996-11-13
申请人： Walter Denzinger , Axel Kistenmacher , Heinrich Hartmann , Gunter Bernhardt , Gerhard Wolf
发明人： Walter Denzinger , Axel Kistenmacher , Heinrich Hartmann , Gunter Bernhardt , Gerhard Wolf
IPC分类号： C08F289/00 , C14C3/22
CPC分类号： C08F289/00 , C14C3/22
摘要： Water-soluble or water-dispersible graft polymers which are obtainable by free-radical-initiated polymerization of (A) a monomer or monomer mixture comprising (a) from 20 to 100% by weight of acrylic acid or methacrylic acid or a mixture thereof or alkali metal, alkaline earth metal or ammonium salts thereof, (b) from 0 to 80% by weight of other monoethylenically unsaturated monomers which can be copolymerized with the monomers (a), and (c) from 0 to 5% by weight of monomers containing at least 2 ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of proteins (B) in an A:B weight ratio of from (95 to 10):(5 to 90), are used as tanning agents for self-tanning, pretanning and assist tanning of pelts and skin pelts and for the retanning of leather and skin.
摘要翻译： PCT No.PCT / EP95 / 01720 Sec。 371日期：1996年11月13日 102（e）日期1996年11月13日PCT提交1995年5月6日PCT公布。公开号WO95 / 31576 日期1995年11月23日可通过（A）单体或单体混合物的自由基引发聚合获得的水溶性或水分散性接枝聚合物，其包含（a）20至100重量％的丙烯酸或甲基丙烯酸或其混合物或其碱金属，碱土金属或铵盐，（b）0至80重量％的其它单烯属不饱和单体，其可与单体（a）和（c）共聚0至5 （B）重量比为（95〜10）：（5〜90）的蛋白质（B）存在下，分子中含有至少2个烯属不饱和的非共轭双键的单体重量％用作鞣制剂，用于自动鞣制，预处理和辅助皮肤和皮肤鞣制以及皮革和皮肤的复鞣。

9. 发明授权

US6146746A Formaldehyde-free coating composition for shaped articles 有权
标题翻译：用于成型制品的无甲醛涂料组合物
公开(公告)号：US6146746A
公开(公告)日：2000-11-14
申请号：US101797
申请日：1998-08-19
申请人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
发明人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
IPC分类号： B05D7/24 , B05D1/00 , C08F8/30 , C08J7/04 , C08K5/17 , C08L23/26 , C08L35/00 , C08L57/00 , C08L57/10 , C09D135/00 , B05D3/02 , E04B1/82 , E04B1/84
CPC分类号： C08K5/17
摘要： The use of a formaldehyde-free aqueous binder comprisingA) a polymer obtained by free-radical polymerization comprising 5-100% by weight of an ethylenically unsaturated acid anhydride or of an ethylenically unsaturated dicarboxylic acid whose carboxyl groups may form an anhydride group, andB) an alkanolamine having at least two hydroxyl groupsas a coating composition for shaped articles.
摘要翻译： PCT No.PCT / EP97 / 00773 Sec。 371日期1998年8月19日 102（e）1998年8月19日PCT PCT 1997年2月19日PCT公布。公开号WO97 / 31060 PCT 日期1997年8月28日使用不含甲醛的水性粘合剂，其包含A）通过自由基聚合获得的聚合物，其包含5-100重量％的烯键式不饱和酸酐或其羧基可形成的烯属不饱和二羧酸酸酐基，B）具有至少两个羟基的链烷醇胺作为成型制品的涂料组合物。

10. 发明授权

US6099773A Formaldehyde-free binder for mouldings 有权
标题翻译：用于模塑的无甲醛粘合剂
公开(公告)号：US6099773A
公开(公告)日：2000-08-08
申请号：US101805
申请日：1998-08-21
申请人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
发明人： Bernd Reck , Eckehardt Wistuba , Wilhelm Friedrich Beckerle , Axel Kistenmacher , Robert Rupaner , Rainer Hummerich
IPC分类号： B05D1/00 , B27N1/02 , B27N3/00 , C08F8/30 , C08K5/17 , C08L33/02 , C08L35/00 , C08L57/00 , C08L97/02 , B32B21/02
CPC分类号： C08K5/17 , B27N3/00 , C08L35/00 , C08L97/00 , Y10T428/249925
摘要： A method for forming shaped products by mixing a formaldehyde-free aqueous binder comprising A) a free-radically polymerized polymer containing from 5 to 100% by weight of units derived from an ethylenically unsaturated acid anhydride or from an ethylenically unsaturated dicarboxylic acid whose carboxyl group can form an anhydride group, and B) an alkanolamine having at least two hydroxyl groups, with fibers or chips to form a shaped article, wherein said binder has a property of drying at 50.degree. C. in 72 hours to a film from 0.3 to 1 mm in thickness and, following a subsequent 15 minute cure at 130.degree. C. in air, has a gel content of above 50% by weight, wherein the binder includes less than 0.1% by weight, based on A)+B), of a phosphorus-containing reaction accelerant with fibers or chips.
摘要翻译： PCT No.PCT / EP97 / 00768 Sec。 371日期1998年8月21日 102（e）1998年8月21日PCT PCT 1997年2月19日PCT公布。公开号WO97 / 31059 日本1997年8月28日一种通过混合不含甲醛的水性粘合剂形成成形制品的方法，其包括A）含有5至100重量％衍生自烯属不饱和酸酐或烯属不饱和酸酐的单元的自由基聚合的聚合物羧酸可以形成酸酐基的二羧酸，以及B）具有至少两个羟基的链烷醇胺与纤维或碎片形成成型制品，其中所述粘合剂具有在72℃下在72℃下干燥的性质，厚度为0.3〜1mm的薄膜，然后在130℃下在空气中固化15分钟后，凝胶含量在50％（重量）以上，其中粘合剂的含量小于0.1％（重量），基于A ）+ B），含有纤维或芯片的含磷反应促进剂。

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