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    • 2. 发明授权
    • Solvent systems for polymeric dielectric materials
    • 高分子电介质材料溶剂体系
    • US06413202B1
    • 2002-07-02
    • US09340976
    • 1999-06-28
    • Oana M. LeonteTadashi NakanoKelly M. BeresKreisler Lau
    • Oana M. LeonteTadashi NakanoKelly M. BeresKreisler Lau
    • C08G7902
    • H01L21/02118C08J3/095H01L21/02126H01L21/02216H01L21/02222H01L21/02282H01L21/312Y10T428/31504
    • Aromatic aliphatic ether solvents, such as anisole, methylanisole, and phenetole, have been found useful in formulating coating solutions of polymeric dielectric materials and as a clean up solvent in the coating process. A process for forming a dielectric film on a substrate includes depositing a coating solution of a dielectric material in a formulation solvent onto a surface of the substrate and depositing an aromatic aliphatic ether solvent onto an edge portion of the surface of the substrate. The process is used to form films of dielectric materials including arylene ether dielectric polymers, hydridosiloxane resins, organohydridosiloxane resins, spin-on-glass materials, partially hydrolyzed and partially condensed alkoxysilane compositions which are cured to form a nanoporous dielectric silica material, and poly(perhydrido)silazanes.
    • 已经发现芳族脂族醚溶剂如苯甲醚,甲基苯甲醚和苯乙醚可用于配制聚合物电介质材料的涂料溶液和作为涂布过程中的清洁溶剂。 在衬底上形成电介质膜的方法包括将介电材料的涂布溶液在配方溶剂中沉积到衬底的表面上,并将芳族脂族醚溶剂沉积在衬底表面的边缘部分上。 该方法用于形成包括亚芳基醚介电聚合物,氢化硅氧烷树脂,有机氢硅氧烷树脂,旋涂玻璃材料,固化以形成纳米多孔介电二氧化硅材料的部分水解和部分缩合的烷氧基硅烷组合物的介电材料的膜,以及聚( perhydrido)硅氮烷。
    • 4. 发明申请
    • Organic compositions
    • 有机成分
    • US20070155997A1
    • 2007-07-05
    • US10536884
    • 2003-12-31
    • Bo LiKreisler LauPaul Apen
    • Bo LiKreisler LauPaul Apen
    • C07C13/615
    • C07C17/10C07C13/615C07C13/64C07C17/269C07C2603/74C07C2603/90C08G61/06C07C23/46C07C25/22
    • Compositions and methods of forming and using those compositions are provided herein where the composition comprises at least one oligomer or polymer of Formula I wherein E is a cage compound; each Q is the same or different and selected from aryl, branched aryl, and substituted aryl wherein the substituents include hydrogen, halogen, alkyl, aryl, substituted aryl, heteroaryl, aryl ether, alkenyl, alkynyl, alkoxyl, hydroxyalkyl, hydroxyaryl, hydroxyalkenyl, hydroxyalkynyl, hydroxyl, or carboxyl; A is substituted or unsubstituted aryl with substituted or unsubstituted arylalkynyl group (substituents include hydrogen, halogen, alkyl, phenyl or substituted aryl; and aryl includes phenyl, biphenyl, naphthyl, terphenyl, anthracenyl, polyphenylene, polyphenylene ether, or substituted aryl); h is from 0 to 10; i is from 0 to 10; j is from 0 to 10; and w is 0 or 1.
    • 本文提供了组合物和形成和使用这些组合物的方法,其中组合物包含至少一种式I的低聚物或聚合物,其中E是笼形化合物; 每个Q相同或不同,选自芳基,支链芳基和取代芳基,其中取代基包括氢,卤素,烷基,芳基,取代的芳基,杂芳基,芳基醚,烯基,炔基,烷氧基,羟基烷基,羟基芳基,羟基烯基, 羟基炔基,羟基或羧基; A是取代或未取代的具有取代或未取代的芳基炔基的芳基(取代基包括氢,卤素,烷基,苯基或取代的芳基;芳基包括苯基,联苯基,萘基,三联苯基,蒽基,聚亚苯基,聚苯醚或取代的芳基)。 h为0〜10; 我是从0到10; j为0〜10; w为0或1。
    • 10. 发明授权
    • Compositions and methods for thermosetting molecules in organic compositions
    • 有机组合物中热固性分子的组成和方法
    • US06803441B2
    • 2004-10-12
    • US10267380
    • 2002-10-08
    • Kreisler LauFeng Quan LiuBoris KorolevEmma BroukRuslan ZherebinDavid Nalewajek
    • Kreisler LauFeng Quan LiuBoris KorolevEmma BroukRuslan ZherebinDavid Nalewajek
    • C08G6378
    • C08G61/12C08G61/02C08G2650/60
    • In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
    • 在制造低介电常数聚合物的方法中,提供了一种热固性单体,其中该热固性单体具有笼形化合物或芳基核心结构,以及共价结合笼形化合物或核心结构的多个臂。 在随后的步骤中,将热固性单体引入聚合物中以形成低介电常数聚合物,其中掺入聚合物中包含位于至少一个臂中的三键的化学反应。 考虑的笼状化合物和核心结构包括金刚烷,二金刚烷,硅,苯基和亚噻吩基,而优选的臂包括亚芳基,支链亚芳基和亚芳基醚。 热固性单体可以有利地用于在电子器件中产生低k介电材料,并且聚合物的介电常数可以通过改变臂的整个长度来控制。