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1. 发明授权

US06183558B2 Method and apparatus for producing molecular film 有权
标题翻译：生产分子膜的方法和装置
公开(公告)号：US06183558B2
公开(公告)日：2001-02-06
申请号：US09294297
申请日：1999-04-19
申请人： Tadashi Otake , Norihisa Mino , Tohru Nakagawa , Mamoru Soga , Kazufumi Ogawa , Takaiki Nomura , Yasuo Takebe
发明人： Tadashi Otake , Norihisa Mino , Tohru Nakagawa , Mamoru Soga , Kazufumi Ogawa , Takaiki Nomura , Yasuo Takebe
IPC分类号： B05C108
CPC分类号： B82Y30/00 , B05D1/283 , B05D3/0486 , B82Y40/00
摘要： A method for forming a molecular film includes the steps of: coating a surface of a substrate having active hydrogen atoms on its surface with a coating solution containing a silane-based compound having at least one reactive group selected from the group consisting of a chloro group, an alkoxy group and an isocyanate group; and effecting an elimination reaction between the active hydrogen atoms on the surface of the substrate and reactive groups of the silane-based compound, thereby covalently bonding the silane-based compounds to the surface of the substrate. The substrate is supplied to a chamber in which an atmosphere is maintained at a low water vapor density. The surface of the substrate is coated with a coating solution containing the silane-based compound and a solvent by using a transfer element. A dehydrochlorination reaction is effected between the active hydrogen atoms and the chloro groups of the silane-based compounds. Thereafter, any coating solution containing unreacted silane-based compounds after coating is removed inside or outside the chamber.
摘要翻译：形成分子膜的方法包括以下步骤：用包含具有至少一个选自氯基团的反应性基团的硅烷基化合物的涂布溶液在其表面上涂覆具有活性氢原子的基材的表面，烷氧基和异氰酸酯基; 并且进行基板表面上的活性氢原子与硅烷类化合物的反应性基团之间的消除反应，从而将硅烷类化合物共价键合到基板的表面。将基板供给到气氛保持在低水蒸汽密度的室中。通过使用转印元件，将含有硅烷系化合物和溶剂的涂布液涂布在基材的表面上。在活性氢原子和硅烷基化合物的氯基之间进行脱氯化氢反应。此后，在室内或室外除去涂布后含有未反应的硅烷类化合物的任何涂布溶液。

2. 发明授权

US5948476A Method and apparatus for producing molecular film 失效
标题翻译：生产分子膜的方法和装置
公开(公告)号：US5948476A
公开(公告)日：1999-09-07
申请号：US964471
申请日：1997-11-04
申请人： Tadashi Otake , Norihisa Mino , Tohru Nakagawa , Mamoru Soga , Kazufumi Ogawa , Takaiki Nomura , Yasuo Takebe
发明人： Tadashi Otake , Norihisa Mino , Tohru Nakagawa , Mamoru Soga , Kazufumi Ogawa , Takaiki Nomura , Yasuo Takebe
IPC分类号： B05D1/28 , B05D3/04
CPC分类号： B82Y30/00 , B05D1/283 , B05D3/0486 , B82Y40/00
摘要： A method for forming a molecular film includes the steps of: coating a surface of a substrate having active hydrogen atoms on its surface with a coating solution containing a silane-based compound having at least one reactive group selected from the group consisting of a chloro group, an alkoxy group and an isocyanate group; and effecting an elimination reaction between the active hydrogen atoms on the surface of the substrate and reactive groups of the silane-based compound, thereby covalently bonding the silane-based compounds to the surface of the substrate. The substrate is supplied to a chamber in which an atmosphere is maintained at a low water vapor density. The surface of the substrate is coated with a coating solution containing the silane-based compound and a solvent by using a transfer element. A dehydrochlorination reaction is effected between the active hydrogen atoms and the chloro groups of the silane-based compounds. Thereafter, any coating solution containing unreacted silane-based compounds after coating is removed inside or outside the chamber.
摘要翻译：形成分子膜的方法包括以下步骤：用包含具有至少一个选自氯基团的反应性基团的硅烷基化合物的涂布溶液在其表面上涂覆具有活性氢原子的基材的表面，烷氧基和异氰酸酯基; 并且进行基板表面上的活性氢原子与硅烷类化合物的反应性基团之间的消除反应，从而将硅烷类化合物共价键合到基板的表面。将基板供给到气氛保持在低水蒸汽密度的室中。通过使用转印元件，将含有硅烷系化合物和溶剂的涂布液涂布在基材的表面上。在活性氢原子和硅烷基化合物的氯基之间进行脱氯化氢反应。此后，在室内或室外除去涂布后含有未反应的硅烷类化合物的任何涂布溶液。

3. 发明授权

US5868827A Chemically bonding material and method for manufacturing the same 失效
标题翻译：化学结合材料及其制造方法
公开(公告)号：US5868827A
公开(公告)日：1999-02-09
申请号：US988645
申请日：1997-12-11
申请人： Norihisa Mino , Kazufumi Ogawa , Yasuo Takebe , Tadashi Otake
发明人： Norihisa Mino , Kazufumi Ogawa , Yasuo Takebe , Tadashi Otake
IPC分类号： C07F7/10 , C07F7/12 , C07F7/18 , C09D183/04 , C09D183/06 , C09D183/07
CPC分类号： C07F7/12 , C07F7/10 , C07F7/1836 , C07F7/184
摘要： A method for manufacturing a chemically bonding material comprising the steps of: mixing a compound expressed by a general formula ABX.sub.n (Formula 1), wherein A shows a group including carbon, B indicates Si, Ge, Sn, Ti or Zr, X is a hydrolyzable group and n indicates 1, 2 or 3, and at least one kind of compound not including active hydrogen groups in a dry atmosphere having a water vapor density of 0.0076 kg/m.sup.3 or less; and storing the same in a dry atmosphere having a water vapor density of 0.0076 kg/m.sup.3 or less. A coating solution including compounds that are easily hydrolyzed is stored in a dry state so that the material is not deactivated before reacting with a substrate.
摘要翻译：一种化学键合材料的制造方法，包括以下步骤：将由通式ABXn（式1）表示的化合物混合，其中A表示包含碳的基团，B表示Si，Ge，Sn，Ti或Zr，X为水解性基团，n表示1,2或3，并且在水蒸汽密度为0.0076kg / m 3以下的干燥气氛中含有至少一种不包括活性氢基团的化合物; 并将其储存在水蒸汽密度为0.0076kg / m 3以下的干燥气氛中。包含容易水解的化合物的涂布溶液以干燥状态储存，使得材料在与基材反应之前不失活。

4. 发明授权

US06333074B1 Water repellent coating film, method and apparatus for manufacturing the same, and water repellent coating material composition 失效
标题翻译：防水涂膜，其制造方法和装置以及防水涂料组合物
公开(公告)号：US06333074B1
公开(公告)日：2001-12-25
申请号：US09480252
申请日：2000-01-11
申请人： Kazufumi Ogawa , Yasuo Takebe , Norihisa Mino
发明人： Kazufumi Ogawa , Yasuo Takebe , Norihisa Mino
IPC分类号： B05D300
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , F28F17/005 , F28F2245/02 , Y10T428/2936 , Y10T428/2995 , Y10T428/31663 , Y10T428/31678
摘要： By forming a film that comprises a microcrystalline polymer having at least a fluorocarbon group and has a rough surface on a surface of a base material, super-water-repellency is provided, the dew condensation water of an air conditioner, for example, can be easily removed, and the freezing of the fin of the heat exchanger can be prevented. A fin that is made of aluminium is coated with a solution for forming a coating film, in which CF3(CF2)7—(CH2)2—SiCl3 is diluted with nonaqueous cyclohexamethyl trisiloxane at a concentration of 10 vol. % for preparation, to a thickness of 1 to 10 &mgr;m by a brush, and then the cyclohexamethyl trisiloxane is vaporized in an atmosphere having a relative humidity of about 75% at room temperature. CF3(CF2)7—(CH2)2—SiCl3 that remained on the fin is rapidly hydrolyzed with the moisture in the atmosphere, and the moisture in air and a —SiCl3 group dehydrochlorinated to form a microcrystalline polymer on the fin. As a result, a coating film having a surface roughness in the range of 1 to 40 &mgr;m and a contact angle of about 171° to water can be formed.
摘要翻译：通过形成包含至少具有碳氟化合物基团并且在基材表面上具有粗糙表面的微晶聚合物的膜，提供超疏水性，例如空调的结露水可以是容易地除去，并且可以防止热交换器的翅片的冻结。用铝制成的翅片涂覆有形成涂膜的溶液，其中CF 3（CF 2）7 - （CH 2）2 -SiCl 3用10体积浓度的非水性环己甲基三硅氧烷稀释。制备时，用刷子将其厚度设定为1〜10μm，然后在室温下在相对湿度为约75％的气氛中将环己甲基三硅氧烷蒸发。残留在翅片上的CF 3（CF 2）7 - （CH 2）2 -SiCl 3随着大气中的水分，空气中的水分和-SiCl 3基团脱氯化氢而迅速水解，从而在翅片上形成微晶聚合物。结果，可以形成表面粗糙度为1〜40μm，与水接触角为约171°的涂膜。

5. 发明授权

US6042948A Water repellent coating film, method and apparatus for manufacturing the same, and water repellent coating material composition 失效
标题翻译：防水涂膜，其制造方法和装置以及防水涂料组合物
公开(公告)号：US6042948A
公开(公告)日：2000-03-28
申请号：US792133
申请日：1997-01-31
申请人： Kazufumi Ogawa , Yasuo Takebe , Norihisa Mino
发明人： Kazufumi Ogawa , Yasuo Takebe , Norihisa Mino
IPC分类号： B05D1/18 , F28F17/00 , B32B9/04
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , F28F17/005 , F28F2245/02 , Y10T428/2936 , Y10T428/2995
摘要： By forming a film that comprises a microcrystalline polymer having at least a fluorocarbon group and has a rough surface on a surface of a base material, super-water-repellency is provided, the dew condensation water of an air conditioner, for example, can be easily removed, and the freezing of the fin of the heat exchanger can be prevented. A fin that is made of aluminium is coated with a solution for forming a coating film, in which CF.sub.3 (CF.sub.2).sub.7 --(CH.sub.2).sub.2 --SiCl.sub.3 is diluted with nonaqueous cyclohexamethyl trisiloxane at a concentration of 10 vol. % for preparation, to a thickness of 1 to 10 .mu.m by a brush, and then the cyclohexamethyl trisiloxane is vaporized in an atmosphere having a relative humidity of about 75% at room temperature. CF.sub.3 (CF.sub.2).sub.7 --(CH.sub.2).sub.2 --SiCl.sub.3 that remained on the fin is rapidly hydrolyzed with the moisture in the atmosphere, and the moisture in air and a --SiCl.sub.3 group dehydrochlorinated to form a microcrystalline polymer on the fin. As a result, a coating film having a surface roughness in the range of 1 to 40 .mu.m and a contact angle of about 171.degree. to water can be formed.
摘要翻译：通过形成包含至少具有碳氟化合物基团并且在基材表面上具有粗糙表面的微晶聚合物的膜，提供超疏水性，例如空调的结露水可以是容易地除去，并且可以防止热交换器的翅片的冻结。用铝制成的翅片涂覆有形成涂膜的溶液，其中CF 3（CF 2）7 - （CH 2）2 -SiCl 3用10体积浓度的非水性环己甲基三硅氧烷稀释。用于制备，通过刷子至1至10μm的厚度，然后环己基三硅氧烷在室温下在相对湿度为约75％的气氛中蒸发。残留在翅片上的CF 3（CF 2）7 - （CH 2）2 -SiCl 3随着大气中的水分，空气中的水分和-SiCl 3基团脱氯化氢而迅速水解，从而在翅片上形成微晶聚合物。结果，可以形成表面粗糙度为1〜40μm，接触角为171度左右的涂膜。

6. 发明授权

US07220468B2 Conductive organic thin film, method for manufacturing the same, and electronic device, electric cable, electrode, pyrrolyl compound, and thienyl compound using the same 有权
标题翻译：导电性有机薄膜及其制造方法以及电子器件，电缆，电极，吡咯基化合物及使用其的噻吩基化合物
公开(公告)号：US07220468B2
公开(公告)日：2007-05-22
申请号：US11488994
申请日：2006-07-19
申请人： Kazufumi Ogawa , Norihisa Mino , Shinichi Yamamoto
发明人： Kazufumi Ogawa , Norihisa Mino , Shinichi Yamamoto
IPC分类号： C09K19/06
CPC分类号： H01L51/0545 , B82Y10/00 , G02F1/133711 , G02F1/133719 , G02F1/13378 , G02F1/133784 , G02F1/133788 , G02F2001/133796 , G02F2202/027 , H01B1/12 , H01B1/125 , H01B1/127 , H01L51/0012 , H01L51/0075 , H01L51/0508 , H01L51/0595 , H01L51/42 , H01L51/428 , Y02E10/549 , Y02P70/521 , Y10S428/91 , Y10T428/10 , Y10T428/1005 , Y10T428/1014 , Y10T428/31663
摘要： It is an object to provide a conductive organic thin film having organic molecules that include at one end a terminal bonding group that is covalently bonded to a substrate surface, a conjugate bonding group that is located at any portion of the organic molecules and that is polymerized with other molecules, and a polar functional group that does not include active hydrogen and that is located at any portion between the terminal bonding group and the conjugate bonding group, wherein the organic molecules are oriented and their conjugate bonding groups are polymerized, forming a conduction network. The conductivity (ρ) of the conductive organic thin film at room temperature (25° C.) is at least 5.5×105 S/cm, and preferably at least 1×107 S/cm, without dopants, having significantly higher conductivity than metals such as gold and silver. In particular, a film of polypyrrole or polythienylene conjugate bonds that is polymerized through polymerization through electrolytic oxidation has high conductivity.
摘要翻译：本发明的目的是提供一种具有有机分子的导电有机薄膜，该有机分子的一端包含共价结合到基材表面的端键合基团，位于有机分子的任何部分并且被聚合的共轭键合基团与其它分子，以及不包括活性氢并且位于末端键合基团和共轭键合基团之间的任何部分的极性官能团，其中有机分子取向并且它们的共轭键合基团聚合，形成导电网络。导电有机薄膜在室温（25℃）下的电导率（rho）至少为5.5×10 -5 S / cm，优选至少为1×10 7 / S / cm，没有掺杂剂，具有比诸如金和银的金属显着更高的导电率。特别地，通过电解氧化聚合而聚合的聚吡咯或聚噻吩键共轭键具有高导电性。

7. 发明授权

US06593000B2 Chemically adsorbed film and method of manufacturing the same 失效
公开(公告)号：US06593000B2
公开(公告)日：2003-07-15
申请号：US10058220
申请日：2002-01-29
申请人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
发明人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B32B904
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , Y10T428/261 , Y10T428/31504 , Y10T428/31663
摘要： A highly dense chemically adsorbed film is formed by repeating the alternate process of adsorption reaction and washing. Adsorption reaction is directed by contacting the substrate surface, which has or is given an alkali metal or a functional group, with a chemical adsorbent, having halosilyl or alkoxysilyl groups at the end of molecules. An unreacted chemical adsorbent is then washed away from the substrate surface. The alternate treatment of adsorption reaction and washing is repeated, thereby covalently bonding a chemically adsorbed film to the substrate surface. As a result, a chemically adsorbed film is formed in which stem molecules are directly or indirectly covalently bonded to the substrate surface via at least one element chosen from the group consisting of Si, Ge, Sn, Ti, Zr, S or C and graft molecules are covalently bonded to at least one element chosen from Si, Ge, Sn, Ti, Zr, S or C via at least one bond chosen from —SiO—, —GeO—, SnO—, —TiO—, ZrO—, —SO2—, —SO— and —C—.

8. 发明授权

US5869136A Method of manufacturing a chemically adsorbed multilayer film 失效
标题翻译：制造化学吸附多层膜的方法
公开(公告)号：US5869136A
公开(公告)日：1999-02-09
申请号：US12753
申请日：1993-02-03
申请人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
发明人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B05D1/18 , C03C23/00 , B05D1/36
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C03C23/00
摘要： A chemically adsorbed multilayer film is formed through the process of replacing a halogen atom on the surface of a chemically adsorbed film with an alkaline metal or changing the halogen atom to a Grignard group by Grignard reaction. This manufacturing method does not disrupt the molecules of the chemically adsorbed film, is easy to perform, low in cost and is safe. After replacing the halogen (for example, Br) on the surface of the film with an alkaline metal such as Li, a condensation reaction including a dealkalihalide reaction is promoted by contacting the chemically adsorbed film with an adsorbent, such as a chemical adsorbent--containing a halosilane group at one end of a molecule--dissolved in a nonaqueous solvent. A chemically adsorbed multilayer film is then formed by reacting the chemically adsorbed film with chemical absorption composition and with water after removing unreacted adsorbents using a nonaqueous solution.
摘要翻译：通过用碱金属代替化学吸附膜表面上的卤素原子或通过格利雅反应将卤素原子改变成格利雅特基团的方法形成化学吸附的多层膜。该制造方法不会破坏化学吸附膜的分子，容易实施，成本低，安全。用Li等碱性金属取代膜表面的卤素（例如Br）后，通过使化学吸附膜与吸附剂（如含化学吸附剂）接触来促进包括脱卤化物反应的缩合反应分子一端的卤代硅烷基溶解在非水溶剂中。然后通过使用非水溶液除去未反应的吸附剂，使化学吸附膜与化学吸收组合物和水反应形成化学吸附的多层膜。

9. 发明授权

US5455360A 1-pyrrolyl silicon compounds, chemically adsorbed ultrathin film formed therefrom and method of manufacturing the same 失效
标题翻译： 1-吡咯基硅化合物，由其形成的化学吸附的超薄膜及其制造方法
公开(公告)号：US5455360A
公开(公告)日：1995-10-03
申请号：US107886
申请日：1993-08-18
申请人： Norihisa Mino , Kazufumi Ogawa , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Katsuya Takemura
发明人： Norihisa Mino , Kazufumi Ogawa , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Katsuya Takemura
IPC分类号： C08G77/26 , B05D1/18 , C07F7/12 , C07F7/18 , C08G77/28 , C08J5/18 , C09K3/16 , H01B1/12 , C07F7/10 , C07D207/323
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , C07F7/12 , C07F7/182 , C07F7/1836 , C07F7/1868
摘要： Disclosed are a conductive pyrrole derivative monomolecular film covalently bonded to a substrate surface and method of manufacturing the same, and a monomer used for forming the conductive pyrrole derivative monomolecular film and method of manufacturing the same. The invention relates to a monomolecular ultrathin film comprising 1-pyrrolyl groups and silicon groups. The monomer used for forming the film is provided by reacting .omega.-(1-pyrrolyl)-1-alkene compound to a monosilane derivative compound, in which three out of four hydrogen atoms of monosilane are replaced with halogen or alkoxy groups, in the presence of a transition metal catalyst. A substrate is dipped and held in a nonaqueous solution of the above-noted monomer, thus chemically bonding a monomolecular film to a substrate surface. Furthermore, a polypyrrole derivative ultrathin film is formed by the electrolytic or catalytic polymerization of the monomolecular film.
摘要翻译：公开了共价键合到基材表面的导电吡咯衍生物单分子膜及其制备方法，以及用于形成导电吡咯衍生物单分子膜的单体及其制造方法。本发明涉及包含1-吡咯基和硅基团的单分子超薄膜。用于形成膜的单体是通过使ω-（1-吡咯基）-1-烯烃化合物与甲硅烷衍生物化合物反应而得到的，其中甲硅烷的四个氢原子中的三个被卤素或烷氧基取代，的过渡金属催化剂。将基材浸渍并保持在上述单体的非水溶液中，从而将单分子膜化学键合到基材表面。此外，通过单分子膜的电解或催化聚合形成聚吡咯衍生物超薄膜。

10. 发明授权

US5451459A Chemically absorbed film comprising fluorocarbon chains 失效
标题翻译：含氟碳链的化学吸收膜
公开(公告)号：US5451459A
公开(公告)日：1995-09-19
申请号：US281681
申请日：1994-07-28
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D1/18 , C09D4/00 , B32B7/04 , B32B17/06
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C09D4/00 , Y10T428/261 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： According to the invention, a fluorine-based or siloxane -based chemical adsorbed film containing a fluorocarbon compound can be formed on a given substrate surface in a laminated state and through chemical bonds (i.e., covalent bonds) with the substrate, it is possible to obtain a laminated film which has satisfactory adhesion to the substrate, is substantially pin-hole free and is very thin. Further, since the outermost layer may be substituted by fluorocarbon groups or hydroxyl groups, it is possible to obtain a film which has excellent water- and oil-repelling properties or hydrophilic and oil-repelling properties and can replace fluorine-based coating films, thus improving the performance of products requiring a coating having a water- and oil-repelling resistant property, weather-resistant property, wear-resistant property and so forth which are desirable in electric products, vehicles, industrial devices and so forth.
摘要翻译：根据本发明，可以在给定的基板表面上以层压状态和通过与基板的化学键（即共价键）形成含氟碳化合物的基于氟或硅氧烷的化学吸附膜，获得对基材具有令人满意的粘合性的层压膜，其基本上无针孔，并且非常薄。此外，由于最外层可以被碳氟基或羟基取代，所以可以获得具有优异的防水疏斥性或亲水性和拒油性能，并且可以代替氟基涂膜的膜提高了在电气产品，车辆，工业装置等中需要具有耐斥油性，耐油污性，耐候性，耐磨性等的涂层的产品的性能。

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