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1. 发明授权

US08889760B2 Photoactivatable crosslinker 有权
标题翻译：可光活化交联剂
公开(公告)号：US08889760B2
公开(公告)日：2014-11-18
申请号：US13074537
申请日：2011-03-29
申请人： Aleksey V. Kurdyumov , Dale G. Swan
发明人： Aleksey V. Kurdyumov , Dale G. Swan
IPC分类号： C07F9/08 , C07F9/12 , C07C49/786 , C07F9/145 , C07F9/40 , A61L17/14 , A61L27/34 , A61L29/08 , A61L31/10 , C07F7/10 , C07F7/18 , C08F2/48
CPC分类号： C09D7/63 , A61L17/145 , A61L27/34 , A61L29/085 , A61L31/10 , A61L2400/18 , A61L2420/02 , C07F7/10 , C07F7/1804 , C07F7/184 , C07F9/06 , C07F9/12 , C07F9/145 , C07F9/4025 , C07F9/4084 , C08F2/48 , C08K5/51 , C08K5/5419 , C08K5/544 , C09D7/1233
摘要： Described herein is a degradable linking agent of formula Photo1-LG-Photo2, wherein Photo1 and Photo2 independently represent at least one photoreactive group and LG represents a linking group comprising one or more silicon atoms or one or more phosphorous atoms. The degradable linking agent includes a covalent linkage between at least one photoreactive group and the linking group, wherein the covalent linkage between at least one photoreactive group and the linking group is interrupted by at least one heteroatom. A method for coating a support surface with the degradable linking agent, coated support surfaces and medical devices are also described.
摘要翻译：本文描述了分子式为Photo1-LG-Photo2的可降解连接剂，其中Photo1和Photo2独立地表示至少一个光反应性基团，LG代表包含一个或多个硅原子或一个或多个磷原子的连接基团。可降解交联剂包括至少一个光反应基团和连接基团之间的共价键，其中至少一个光反应基团和连接基团之间的共价键被至少一个杂原子中断。还描述了用可降解的连接剂，涂覆的支撑表面和医疗装置涂覆支撑表面的方法。

2. 发明授权

US6114562A Organosilicon compounds and method of making 失效
标题翻译：有机硅化合物及其制备方法
公开(公告)号：US6114562A
公开(公告)日：2000-09-05
申请号：US366788
申请日：1999-08-04
申请人： Kenichi Fukuda , Hirofumi Kishita
发明人： Kenichi Fukuda , Hirofumi Kishita
IPC分类号： C07F7/18 , C02F7/08 , C02F7/18
CPC分类号： C07F7/1844 , C07F7/184
摘要： Novel organosilicon compounds having a perfluoroalkyl or perfluoropolyether group and at least one ethynyl group are useful as an agent for controlling hydrosilylation reaction between a --SiH group-bearing compound and a --CH.dbd.CH.sub.2 group-bearing compound.
摘要翻译：具有全氟烷基或全氟聚醚基团和至少一个乙炔基的新型有机硅化合物可用作控制含-SiH基的化合物和含-CH-CH2基团的化合物之间的氢化硅烷化反应的试剂。

3. 发明授权

US5919886A Room temperature curable fluoropolymer composition; and fluorine-containing organosilicon compounds, a method of producing the same, and room temperature curable silicone composition containing the same 失效
公开(公告)号：US5919886A
公开(公告)日：1999-07-06
申请号：US934085
申请日：1997-09-19
申请人： Takashi Matsuda , Takafumi Sakamoto , Shinichi Sato , Noriyuki Koike , Yasuo Tarumi , Tsuneo Kimura , Yasushi Yamamoto , Masatoshi Arai
发明人： Takashi Matsuda , Takafumi Sakamoto , Shinichi Sato , Noriyuki Koike , Yasuo Tarumi , Tsuneo Kimura , Yasushi Yamamoto , Masatoshi Arai
IPC分类号： C07F7/18 , C07F7/21 , C08G65/00 , C08G65/336 , C08G77/48
CPC分类号： C08G65/007 , C07F7/1836 , C07F7/184 , C07F7/1896 , C07F7/21 , C08G65/336
摘要： A room temperature curable fluoropolymer composition is provided which comprises (A) a straight chain fluoropolymer compound containing, in its backbone chain, at least one structure selected from a perfluoroalkylene structure and a perfluoropolyether structure and having a hydrolyzable silyl group at both ends of its molecular chain, (B) an organic compound having at least one carbonyl group per molecule, and (C) one compound selected from (C-1) an organic compound having at least one primary amino group per molecule and (C-2) a compound having at least one proton per molecule and having an acid dissociation constant (pKa) in water of 2 or less. Another room temperature curable composition is also provided which comprises said (A) component, (B') an organosilicon compound having at least two silanol groups per molecule, and (C') a condensation accelerator. These compositions are not only excellent in heat resistance, weatherability, electrical properties, processability, chemical resistance, solvent resistance and oil repellant properties, but also excellent in fast curability and deep-portion curability. A novel compound which is suitable as said fluoropolymer compound (A) is further provided.

4. 发明授权

US5908868A Retinol derivatives useful for enhancing immune response 失效
标题翻译：视黄醇衍生物可用于增强免疫反应
公开(公告)号：US5908868A
公开(公告)日：1999-06-01
申请号：US331627
申请日：1995-06-05
申请人： Jochen Buck , Ulrich Hammerling , Fadila Derguini , Koji Nakanishi
发明人： Jochen Buck , Ulrich Hammerling , Fadila Derguini , Koji Nakanishi
IPC分类号： A61K31/07 , C07D303/14 , C07F7/18 , C12N5/078 , C12N5/0783 , C12N15/67 , C12P23/00 , A61K31/045 , A61K31/075
CPC分类号： C12P23/00 , A61K31/045 , A61K31/07 , A61K31/075 , C07C403/08 , C07C403/10 , C07C403/12 , C07C403/20 , C07D303/14 , C07F7/184 , C12N15/67 , C12N5/0636 , C12N5/065 , C07B2200/07 , C07B2200/09 , C07C2101/16 , C12N2501/385
摘要： The present invention provides a purified retinoid compound characterized by a molecular mass of about 320 daltons and an atomic composition of C.sub.20 H.sub.32 O.sub.3. The present invention also provides a purified retinoid compound having the following structure: ##STR1## wherein the configuration of C7, C9, and C11 double bond independently is Z or E and the absolute configuration at C13 and C14 is independently R or S; wherein R1 is hydroxyl, alkyl, alkyl halide, alcohol, ester, ether, aldehyde, ketone, carboxylic acid, carboxylic ester, acyl halide, amide, nitrile, or amine; wherein R2 and R3 are independently hydroxyl, halide, alkoxy, ester, alkyl, alcohol, ether, aldehyde, ketone, carboxylic acid, carboxylic ester, nitrile, amine, azide, alkyl halide, acid halide, acid azide, or amide; or wherein R2 and R3, or R1 and R2 are replaced by a 13,14-oxirane or a 14,15-oxirane group, respectively. Also provided by this invention is a pharmaceutical composition which comprises the compound above and a pharmaceutically acceptable carrier. This invention further provides a growth medium comprising the compound above at a concentration effective to enhance cell growth. Additionally, the present invention provides a method of enhancing the growth of a cell, a method for enhancing an immune response in a subject, and a method for enhancing transcription of a gene regulated by a retinoid in a cell.
摘要翻译： PCT No.PCT / US93 / 04323 Sec。 371日期：1995年5月6日 102（e）日期1995年5月6日PCT提交1993年5月6日PCT公布。公开号WO93 / 22267 日期：1993年11月11日本发明提供一种纯化的类视黄醇化合物，其特征在于分子量为约320道尔顿，原子组成为C20H32O3。本发明还提供具有以下结构的纯化类视黄醇化合物：其中C7，C9和C11双键独立的构型是Z或E，C13和C14的绝对构型独立地是R或S; 其中R1是羟基，烷基，烷基卤，醇，酯，醚，醛，酮，羧酸，羧酸酯，酰基卤，酰胺，腈或胺; 其中R2和R3独立地是羟基，卤素，烷氧基，酯，烷基，醇，醚，醛，酮，羧酸，羧酸酯，腈，胺，叠氮化物，烷基卤，酰卤，叠氮化物或酰胺; 或其中R2和R3，或R1和R2分别被13,14-环氧乙烷或14,15-环氧乙烷基团取代。本发明还提供了包含上述化合物和药学上可接受的载体的药物组合物。本发明进一步提供包含上述化合物的生物培养基，其浓度有效地增强细胞生长。此外，本发明提供增强细胞生长的方法，增强受试者的免疫应答的方法，以及增强细胞中类视黄醇调节基因转录的方法。

5. 发明授权

US5868827A Chemically bonding material and method for manufacturing the same 失效
标题翻译：化学结合材料及其制造方法
公开(公告)号：US5868827A
公开(公告)日：1999-02-09
申请号：US988645
申请日：1997-12-11
申请人： Norihisa Mino , Kazufumi Ogawa , Yasuo Takebe , Tadashi Otake
发明人： Norihisa Mino , Kazufumi Ogawa , Yasuo Takebe , Tadashi Otake
IPC分类号： C07F7/10 , C07F7/12 , C07F7/18 , C09D183/04 , C09D183/06 , C09D183/07
CPC分类号： C07F7/12 , C07F7/10 , C07F7/1836 , C07F7/184
摘要： A method for manufacturing a chemically bonding material comprising the steps of: mixing a compound expressed by a general formula ABX.sub.n (Formula 1), wherein A shows a group including carbon, B indicates Si, Ge, Sn, Ti or Zr, X is a hydrolyzable group and n indicates 1, 2 or 3, and at least one kind of compound not including active hydrogen groups in a dry atmosphere having a water vapor density of 0.0076 kg/m.sup.3 or less; and storing the same in a dry atmosphere having a water vapor density of 0.0076 kg/m.sup.3 or less. A coating solution including compounds that are easily hydrolyzed is stored in a dry state so that the material is not deactivated before reacting with a substrate.
摘要翻译：一种化学键合材料的制造方法，包括以下步骤：将由通式ABXn（式1）表示的化合物混合，其中A表示包含碳的基团，B表示Si，Ge，Sn，Ti或Zr，X为水解性基团，n表示1,2或3，并且在水蒸汽密度为0.0076kg / m 3以下的干燥气氛中含有至少一种不包括活性氢基团的化合物; 并将其储存在水蒸汽密度为0.0076kg / m 3以下的干燥气氛中。包含容易水解的化合物的涂布溶液以干燥状态储存，使得材料在与基材反应之前不失活。

6. 发明授权

US5814612A Retinol derivatives and uses thereof 失效
标题翻译：视黄醇衍生物及其用途
公开(公告)号：US5814612A
公开(公告)日：1998-09-29
申请号：US880041
申请日：1992-05-06
申请人： Jochen Buck , Ulrich Hammerling , Fadila Derguini , Koji Nakanishi
发明人： Jochen Buck , Ulrich Hammerling , Fadila Derguini , Koji Nakanishi
IPC分类号： A01N37/18 , A01N37/34 , A61K31/07 , A61K31/16 , A61K31/23 , A61K31/70 , C07C43/15 , C07C47/21 , C07C49/203 , C07C233/09 , C07C235/28 , C07C403/00 , C07C403/08 , C07D303/12 , C07D303/14 , C07D317/20 , C07F7/18 , C07F9/06 , C12N1/38 , C12N5/078 , C12N5/0783 , C12N15/67 , C12P17/02 , C12P23/00 , A61K37/22 , C07D317/74
CPC分类号： C07F7/184 , C07C403/08 , C07C403/10 , C07C403/12 , C07C403/20 , C07D303/14 , C12N15/67 , C12N5/065 , C12P23/00 , C07B2200/09 , C07C2101/14 , C07C2101/16 , C12N2501/385
摘要： The present invention provides a purified retinoid compound characterized by a molecular mass of about 320 daltons and an atomic composition of C.sub.20 H.sub.32 O.sub.3. The present invention also provides a purified retinoid compound having the structure: ##STR1## wherein the configuration of the C7, C9, and C11 double bond independently is Z or E and the absolute configuration at C13 and C14 is independently R or S; wherein R1 is alkyl, alkyl halide, alcohol, ester, ether, aldehyde, ketone, carboxylic acid, carboxylic ester, acyl halide, amide, nitrile, or amine; R2 and R3 are independently hydroxyl, halide, alkoxy, ester, alkyl, alcohol, ether, aldehyde, ketone, carboxylic acid, carboxylic ester, nitrile, amine, azide, alkyl halide, acid halide, acid azide, or amide; or wherein R2 and R3, or R1 and R2 are replaced by a 13,14-oxirane or a 14,15-oxirane group, respectively.
摘要翻译：本发明提供一种纯化的类视色素化合物，其特征在于分子量为约320道尔顿，原子组成为C20H32O3。本发明还提供了具有以下结构的纯化的类视黄醇化合物：单独的独立地为Z或E，且C13和C14的绝对构型独立地为R或S; 其中R1是烷基，烷基卤，醇，酯，醚，醛，酮，羧酸，羧酸酯，酰卤，酰胺，腈或胺; R2和R3独立地是羟基，卤素，烷氧基，酯，烷基，醇，醚，醛，酮，羧酸，羧酸酯，腈，胺，叠氮化物，烷基卤，酰卤，酸叠氮化物或酰胺; 或其中R2和R3，或R1和R2分别被13,14-环氧乙烷或14,15-环氧乙烷基团取代。

7. 发明授权

US5741922A Fluorine-containing aromatic compounds 失效
标题翻译：含氟芳香族化合物
公开(公告)号：US5741922A
公开(公告)日：1998-04-21
申请号：US525702
申请日：1995-09-12
申请人： Norio Yoshino
发明人： Norio Yoshino
IPC分类号： C07C17/35 , C07C22/08 , C07C25/24 , C07C33/46 , C07C43/225 , C07C45/68 , C07C49/80 , C07C49/84 , C07C67/343 , C07C69/76 , C07C69/78 , C07C69/92 , C07F7/08 , C07F7/12 , C07F7/18 , C09K3/18 , H01F1/44
CPC分类号： C07F7/1836 , C07C17/35 , C07C22/08 , C07C25/24 , C07C33/46 , C07C43/225 , C07C45/68 , C07C49/80 , C07C49/84 , C07C67/343 , C07C69/76 , C07F7/12 , C07F7/182 , C07F7/184 , H01F1/44 , Y10T428/2991 , Y10T428/31663 , Y10T428/31678
摘要： A fluorine-containing aromatic compound represented by the formula (1) is effectively usable to obtain a magnetic fluid or the like having a wide heat-resistant temperature range and high water resistance ##STR1## wherein X is H, F, Cl, C.sub.1.about.20 alkyl or C.sub.1.about.20 alkoxyl, p is an integer of 1 to 4, Y is --COCH.sub.3, --COOC.sub.2 H.sub.5, --CH(OH)CH.sub.3, --C(CH.sub.3).sub.2 OH, --CH.dbd.CH.sub.2, --C(CH.sub.3).dbd.CH.sub.2, --CAB(CH.sub.2).sub.m Si(CH.sub.3).sub.n Z.sub.3-n, A and B are each H or CH.sub.3, Z is Cl, OCH.sub.3 or OC.sub.2 H.sub.5, and m and n are each 0 or 1, and Rf is C.sub.1.about.20 fluoroalkyl or C.sub.1.about.100 fluoropolyether group.
摘要翻译： PCT No.PCT / JP94 / 00374 Sec。 371 1995年9月12日第 102（e）日期1995年9月12日PCT 1994年3月9日PCT公布。公开号WO94 / 20442 日期1994年9月15日由式（1）表示的含氟芳香族化合物可有效地用于获得耐热温度范围宽，耐水性高的磁性液体等。（1）其中，X为 H，F，Cl，C1差异20烷基或C1差异20烷氧基，p是1至4的整数，Y是-COCH 3，-COOC 2 H 5，-CH（OH）CH 3，-C（CH 3）2 OH，-CH = CH2，-C（CH3）= CH2，-CAB（CH2）mSi（CH3）nZ3-n，A和B各自为H或CH3，Z为Cl，OCH3或OC2H5，m和n各自为0或1，并且Rf是C1 DIFFERENCE 20氟代烷基或C1 DIFFERENCE 100氟代聚醚基团。

8. 发明授权

US5679820A Silylated ultraviolet light absorbers having resistance to humidity 失效
标题翻译：具有耐湿性的甲硅烷基化紫外线吸收剂
公开(公告)号：US5679820A
公开(公告)日：1997-10-21
申请号：US766655
申请日：1996-12-16
申请人： James Edward Pickett , Gregory Ronald Gillette
发明人： James Edward Pickett , Gregory Ronald Gillette
IPC分类号： C09K3/00 , C07F7/08 , C07F7/18 , C09D7/12 , C09D133/00 , C09D161/28 , C09D175/04 , C09D183/06
CPC分类号： C09D183/06 , C07F7/0818 , C07F7/1836 , C07F7/184 , C07F7/1844 , Y10T428/31507 , Y10T428/31663
摘要： The instant invention is directed to novel silylated agents having the formula ##STR1## where Ar and Ar' are independently substituted or unsubstituted aromatic rings, R is a branched or unbranched chain of 1 to 6 carbons, R' and R" are independently C1 to C12 alkyl or mixtures of C1 to C12 alkyl, and n is 1 or 2. The novel dibenzoylresorcinol silylated agents are capable of absorbing ultraviolet light.
摘要翻译：本发明涉及具有式（II）的新型甲硅烷基化剂，其中Ar和Ar'独立地是取代或未取代的芳环，R是1至6个碳的支链或非支链，R'和R“ 独立地为C1至C12烷基或C1至C12烷基的混合物，n为1或2.新型二苯甲酰间苯二酚甲硅烷基化剂能够吸收紫外光。

9. 发明授权

US5498770A Catalyst for the polymerization of olefins and process for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂和烯烃聚合方法
公开(公告)号：US5498770A
公开(公告)日：1996-03-12
申请号：US309885
申请日：1994-09-20
申请人： Motoki Hosaka , Kenji Goto , Masahiko Matsuo
发明人： Motoki Hosaka , Kenji Goto , Masahiko Matsuo
IPC分类号： C08F4/658 , C07F7/18 , C08F10/00 , C08F110/06 , C08F4/656
CPC分类号： C08F10/00 , C07F7/184 , C08F110/06
摘要： A catalyst for the polymerization of olefins comprising (A) a solid catalyst component essentially containing magnesium, titanium, an electron donor compound, and a halogen which is prepared by contacting a magnesium compound, a titanium halide compound, and an electron donor compound, (B) an organoaluminum compound, and (C) an organosilicon compound and a process for polymerizing an olefin using the same are disclosed, the organosilicon compound (C) being represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, each represents an alkyl group having from 1 to 3 carbon atoms; R.sup.3 and R.sup.4, which may be the same or different, each represents an alkyl group having from 1 to 3 carbon atoms, or a halogen atom; and m and n each represents 0 or an integer of 1 or 2. A polyolefin having high stereoregularity and broad molecular weight distribution can be obtained in high yield.
摘要翻译：一种用于烯烃聚合的催化剂，包括（A）基本上含有镁，钛，电子给体化合物和卤素的固体催化剂组分，其通过使镁化合物，卤化钛化合物和电子给体化合物接触而制备（ B）有机铝化合物和（C）有机硅化合物和使用其的使烯烃聚合的方法，有机硅化合物（C）由式（I）表示：其中R1和R2 其可以相同或不同，各自表示具有1至3个碳原子的烷基; R 3和R 4可以相同或不同，各自表示具有1至3个碳原子的烷基或卤素原子; m和n各自表示0或1或2的整数。可以高产率获得具有高立构规整性和宽分子量分布的聚烯烃。

10. 发明授权

US5486633A Photochemically-removable silyl protecting groups 失效
标题翻译：光化学拆除甲硅烷基保护基
公开(公告)号：US5486633A
公开(公告)日：1996-01-23
申请号：US339216
申请日：1994-11-10
申请人： Michael C. Pirrung , Yong Rok Lee
发明人： Michael C. Pirrung , Yong Rok Lee
IPC分类号： C07F7/10 , C07F7/12 , C07F7/18 , C07F7/08
CPC分类号： C07F7/1852 , C07F7/10 , C07F7/12 , C07F7/184 , Y02P20/55
摘要： The present invention relates, in general, to photochemically removable protecting groups, and, in particular, to the use of styrylsilyl groups to protect reactive functional groups, such as, hydroxyl, amino and thiol groups.
摘要翻译：本发明一般涉及光化学去除的保护基团，特别是涉及使用苯乙烯基甲硅烷基保护反应性官能团如羟基，氨基和巯基的用途。

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