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    • 3. 发明授权
    • Silver halide photographic material containing selenium compound
    • 含硒化合物的卤化银照相材料
    • US5306613A
    • 1994-04-26
    • US110988
    • 1993-08-24
    • Morio YagiharaHiroyuki MifuneHirotomo SasakiShinji Kato
    • Morio YagiharaHiroyuki MifuneHirotomo SasakiShinji Kato
    • G03C1/09G03C1/34
    • G03C1/09
    • A silver halide photographic material comprises a silver halide emulsion layer and a non-light-sensitive hydrophilic colloidal layer provided on a support. The silver halide emulsion layer or the hydrophilic colloidal layer contains a selenium compound represented by the formula (I), (II) or (III): ##STR1## in which R.sup.11 is an aliphatic, aromatic or heterocyclic group, --OR.sup.13 or --NR.sup.14 R.sup.15 ; each of R.sup.13, R.sup.14 and R.sup.15 is hydrogen or an aliphatic or aromatic group; Ch is S, Se or Te; R.sup.12 is an aliphatic, aromatic or heterocyclic group or --COR.sup.16 ; each of R.sup.16, R.sup.21 and R.sup.31 has the same meaning as that of R.sup.11 ; M.sup.1 is Ge, Sn or Pb; M.sup.2 is Ni, Pd or Pt; each of R.sup.22 and R.sup.32 is an aliphatic or aromatic group; and each of n and m is 1 or 2.
    • 卤化银照相材料包括卤化银乳剂层和设置在载体上的非光敏亲水性胶体层。 卤化银乳剂层或亲水胶体层含有由式(I),(II)或(III)表示的硒化合物:(*化学结构*)(I)(*化学结构*)(II)(* 化学结构*)(III)其中R11是脂族,芳族或杂环基团,-OR13或-NR14R15; R 13,R 14和R 15各自为氢或脂族或芳族基团; Ch是S,Se或Te; R12是脂族,芳族或杂环基或-COR16; R16,R21和R31各自与R11具有相同的含义; M1是Ge,Sn或Pb; M2是Ni,Pd或Pt; R 22和R 32中的每一个是脂族或芳族基团; n和m各自为1或2。
    • 6. 发明授权
    • Silver halide color photographic light-sensitive material
    • 卤化银彩色摄影感光材料
    • US4607004A
    • 1986-08-19
    • US682452
    • 1984-12-17
    • Shinpei IkenoueHaruhiko IwanoHiroyuki MifuneMorio Yagihara
    • Shinpei IkenoueHaruhiko IwanoHiroyuki MifuneMorio Yagihara
    • G03C7/26G03C7/392G03C1/34
    • G03C7/3926Y10S430/162
    • A silver halide color photographic light-sensitive material is disclosed, comprising a support having provided thereon light-sensitive silver halide emulsion layers, wherein on the outside of the light-sensitive silver halide emulsion layer positioned farthest from the support, a layer containing silver halide fine grains of about 0.2.mu. or less in average grain size is provided, and in the silver halide color photographic light-sensitive material at least one compound represented by the following general formula (I) is present: ##STR1## wherein M represents a hydrogen atom, an alkali metal or a quaternary ammonium group, X represents COOM' or SO.sub.3 M' (wherein M' represents a hydrogen atom, an alkali metal or a quaternary ammonium group), n represents 1 or 2, R.sub.1 represents a group capable of substituting on the phenyl group, and m represents 0, 1 or 2.
    • 公开了一种卤化银彩色照相感光材料,其包括在其上提供有感光卤化银乳剂层的载体,其中位于离支持体最远的感光卤化银乳剂层的外侧含有卤化银 提供平均粒径约0.2μm以下的细晶粒,并且在卤化银彩色照相感光材料中存在至少一种由以下通式(I)表示的化合物:其中M(M) 表示氢原子,碱金属或季铵基,X表示COOM'或SO3M'(其中M'表示氢原子,碱金属或季铵基),n表示1或2,R1表示 能够在苯基上取代,m表示0,1或2。
    • 8. 发明授权
    • Silver halide photographic material containing a tellurium compound
    • 含有碲化合物的卤化银照相材料
    • US5342750A
    • 1994-08-30
    • US51691
    • 1993-04-23
    • Hirotomo SasakiToru FujimoriHiroyuki MifuneKimiyasu Morimura
    • Hirotomo SasakiToru FujimoriHiroyuki MifuneKimiyasu Morimura
    • G03C1/09G03C1/06G03C1/005G03C1/494
    • G03C1/09
    • A silver halide photographic material comprises a silver halide emulsion layer provided on a support. In the photographic material of the present invention, the silver halide emulsion layer contains a tellurium compound represented by the formula (I) or (II): ##STR1## in which each of R.sup.11 and R.sup.12 is --OR.sup.13, --NR.sup.14 R.sup.15, --SR.sup.16 or hydrogen; R.sup.11 and R.sup.12 may be combined with each other to form a heterocyclic ring; each of R.sup.21 and R.sup.22 is an alkyl, alkenyl, alkynyl, aralkyl, aryl or heterocyclic group, --OR.sup.23, --NR.sup.24 R.sup.25, --SR.sup.26 or hydrogen; R.sup.21 and R.sup.22 may be combined with each other to form a heterocyclic ring; each of X.sup.1 and X.sup.2 is oxygen, sulfur or .dbd.NR.sup.17 ; each of X.sup.3 and X.sup.4 is oxygen, sulfur or .dbd.NR.sup.27 ; each of R.sup.13, R.sup.14, R.sup.15, R.sup.16, R.sup.17, R.sup.23, R.sup.24, R.sup.25, R.sup.26 and R.sup.27 is an alkyl, alkenyl, alkynyl, aralkyl, aryl or heterocyclic group or hydrogen; R.sup.14 and R.sup.15 may be combined with each other to form a heterocyclic ring; and R.sup. 24 and R.sup.25 may be combined with each other to form a heterocyclic ring.
    • 卤化银照相材料包括设置在载体上的卤化银乳剂层。 在本发明的照相材料中,卤化银乳剂层含有由式(I)或(II)表示的碲化合物:其中R11和R12各自为-OR13,-NR14R15,-SR16或 氢; R 11和R 12可以相互结合形成杂环; R 21和R 22各自为烷基,烯基,炔基,芳烷基,芳基或杂环基,-OR 23,-NR 24 R 25,-SR 26或氢; R 21和R 22可以相互结合形成杂环; X1和X2各自为氧,硫或= NR17; X3和X4各自为氧,硫或= NR27; R 13,R 14,R 15,R 16,R 17,R 23,R 24,R 25,R 26和R 27中的每一个是烷基,烯基,炔基,芳烷基,芳基或杂环基或氢; R 14和R 15可以相互结合形成杂环; 并且R 24和R 25可以彼此结合形成杂环。