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    • 1. 发明授权
    • Ceramic shell-and-tube type heat exchanger, and method for manufacturing
it
    • 陶瓷管壳型热交换器及其制造方法
    • US6006824A
    • 1999-12-28
    • US260550
    • 1999-03-02
    • Mitsuru HattoriKeiichiro WatanabeToshihiro Yoshida
    • Mitsuru HattoriKeiichiro WatanabeToshihiro Yoshida
    • C04B37/00F28F9/00
    • F28D7/16C04B37/003F28F21/04C04B2235/5244C04B2235/5427C04B2235/6581C04B2237/08C04B2237/083C04B2237/345F28F2225/04F28F2255/18F28F2265/30
    • A method for manufacturing a ceramic shell-and-tube type heat exchanger having a plurality of heat transfer tubes and tubular plates joined to both the end portions of these heat transfer tubes which has the steps of inserting the heat transfer tubes of sintered tubular ceramics into through-holes of the tubular plates of unsintered plate-like ceramics having a plurality of the through-holes, standing the heat transfer tubes vertically to a floor surface, and then firing them in a condition where the tubular plates are positioned at both the upper and lower end portions of the heat transfer tubes, thereby integrally joining the tubular plates to both the end portions of the plurality of heat transfer tubes by the utilization of a difference between firing shrinkage ratios of both the members, the method having the steps of interposing at least one tubular plate between the tubular plate positioned at the upper end portions and the tubular plate positioned at the lower end portions of the heat transfer tubes, and then firing them to integrally join them. The ceramic shell-and-tube type heat exchanger can be obtained in which the deformation of the heat transfer tubes can be remarkably inhibited and which is free from the deterioration of joining strength due to the deformation of the heat transfer tubes in the firing join step and the occurrence of gas leakage due to a joining failure.
    • 一种陶瓷管壳型热交换器的制造方法,其具有多个传热管和连接到这些传热管的两端的管状板,其具有将烧结管状陶瓷的传热管插入 具有多个通孔的未烧结板状陶瓷的管状板的通孔,将传热管垂直地放置在地板表面上,然后在管状板位于两者的上部 和传热管的下端部,从而通过利用两个部件的烧成收缩率之间的差异将管状板整体地接合到多个传热管的两个端部,该方法具有插入步骤 在位于上端部的管状板和位于t的下端部的管状板之间的至少一个管状板 他传热管,然后点燃它们以一体加入。 可以获得陶瓷壳管型热交换器,其中可以显着抑制传热管的变形,并且不会由于在烧结接合步骤中的传热管的变形而导致的接合强度的劣化 并且由于接合故障而发生气体泄漏。
    • 3. 发明授权
    • Process for production of joined ceramic body
    • 接合陶瓷体的生产工艺
    • US5529651A
    • 1996-06-25
    • US341074
    • 1994-11-17
    • Toshihiro YoshidaKeiichiro Watanabe
    • Toshihiro YoshidaKeiichiro Watanabe
    • C04B35/64C04B37/00
    • C04B35/64C04B37/001C04B2235/6567C04B2235/658C04B2237/365C04B2237/368C04B2237/62C04B2237/704C04B2237/765C04B2237/80C04B2237/84
    • A process for producing a joined ceramic component having a plurality of parallel ceramic tubes and two perforated ceramic plates joined to the both ends of said ceramic tubes, which process comprises: arranging two unsintered ceramic plates each having a plurality of holes, in parallel to each other and also to the floor surface with a given distance provided between the upper plate and the lower plate; inserting a plurality of sintered ceramic tubes into the holes of the upper and lower plates so that the tubes are arranged vertically to the floor surface and in parallel to each other; and sintering the resulting material to join the tubes and the plates into one piece by utilizing the difference in sintering shrinkage factor between them, in which process the sintering is conducted in a state that each tube is hanged from the upper plate and that the lower end of each tube is in one hole of the lower plate placed on or above a setter, with a certain distance provided between the lower end of each tube and the setter so that they do not come in contact with each other during the sintering.
    • 一种用于生产具有多个平行陶瓷管和两个穿孔陶瓷板的接合陶瓷部件的方法,所述多个陶瓷管连接到所述陶瓷管的两端,所述方法包括:将每个具有多个孔的两个未烧结陶瓷板排列成平行于每个 另一个并且还具有设置在上板和下板之间的给定距离的地板表面; 将多个烧结陶瓷管插入上板和下板的孔中,使得管垂直于地板表面布置并且彼此平行; 并且通过利用它们之间的烧结收缩率的差异来烧结所得材料以将管和板连接成一体,其中在每个管从上板悬挂的状态下进行烧结,并且下端 每个管的下部板在位于设置器上或上方的下板的一个孔中,在每个管的下端和固定器之间设置一定距离,使得它们在烧结期间彼此不接触。
    • 9. 发明授权
    • Process for production of a silicon nitride ceramic
    • 氮化硅陶瓷的制造方法
    • US5804521A
    • 1998-09-08
    • US905025
    • 1997-08-01
    • Akira TakahashiMasaaki MasudaKeiichiro Watanabe
    • Akira TakahashiMasaaki MasudaKeiichiro Watanabe
    • C04B35/626C04B35/593C04B35/587
    • C04B35/5935
    • A silicon nitride ceramic of the present invention possesses excellent strength of the surface, including a silicon nitride and a rare earth oxide compound and being characterized in that the ratio of the transverse rupture strength, at a room temperature, of the fired surface used as a tensile surface to the transverse rupture strength, at a room temperature, of the worked surface used as a tensile surface subjected to the working so as to have the surface roughness of R.sub.MAX 0.8 .mu.m or less is 0.7 or more, and the strength ratio is satisfied even when any portion besides the fired surface is utilized as the tensile surface to be worked to have the surface roughness of R.sub.MAX 0.8 .mu.m or less. The present invention also provides a process for producing a silicon nitride ceramic including the steps of: (1) mixing .alpha.-Si.sub.3 N.sub.4 powder and .beta.-Si.sub.3 N.sub.4 powder to obtain a raw material powder so as to satisfy the formula indicated by 0.05.ltoreq..beta./.alpha.+.beta..ltoreq.0.50, in which a refers to the weight of .alpha.-Si.sub.3 N.sub.4 powder and .beta. refers to the weight of .beta.-Si.sub.3 N.sub.4 powder; (2) mixing at least one sintering aid to the raw material powder; (3) forming the powder mixture to give a compact; and (4) firing the compact at a temperature ranging from 1800.degree. to 2000.degree. C. under a nitrogen atmosphere having an atmospheric pressure of at least 1 atm.
    • 本发明的氮化硅陶瓷具有优异的表面强度,包括氮化硅和稀土氧化物,其特征在于,在室温下,作为烧结表面的烧结表面的横向断裂强度的比例 作为经受加工的拉伸面的加工面的拉伸面与横向断裂强度在室温下的表面粗糙度为0.8μm以下,强度比为 即使将烧成的表面以外的任何部分用作待加工的拉伸面,其表面粗糙度为0.8μm以下。 本发明还提供一种制造氮化硅陶瓷的方法,包括以下步骤:(1)将α-Si 3 N 4粉末和β-Si 3 N 4粉末混合以获得原料粉末,以满足0.05≤β /α+β<0.50,其中a表示α-Si 3 N 4粉末的重量,β表示β-Si 3 N 4粉末的重量; (2)将至少一种烧结助剂与原料粉末混合; (3)形成粉末混合物以产生致密的; 和(4)在大气压至少为1个大气压的氮气气氛下,在1800〜2000℃的温度下烧成。