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1. 发明授权

US09441054B2 Vinylidene fluoride copolymers 有权
标题翻译：偏二氟乙烯共聚物
公开(公告)号：US09441054B2
公开(公告)日：2016-09-13
申请号：US13995275
申请日：2011-12-13
申请人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
发明人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
IPC分类号： H01M4/00 , C08F14/22 , C08F214/22 , C08J5/22 , C08L27/16 , H01M4/02 , H01M4/86 , H01M8/02 , H01M8/10 , H01M10/0565 , C08K5/06 , C08L33/02
CPC分类号： C08F14/22 , C08F214/22 , C08F214/225 , C08J5/2237 , C08J2327/16 , C08K5/06 , C08L27/16 , C08L33/02 , C08L2205/02 , C08L2205/025 , H01M4/02 , H01M4/8605 , H01M8/0289 , H01M8/1023 , H01M10/0565 , Y02E60/521 , Y02P70/56 , C08F2/16 , C08F220/06 , C08F214/182 , C08F214/24
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF), and from 0.01% to 5% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (F) comprising end groups having formula —CF2H and/or —CF2CH3 in an amount of at least 30 mmoles per Kg of vinylidene fluoride (VDF) recurring units. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as binders for the manufacture of electrodes or for the manufacture of membranes.
摘要翻译：本发明还涉及制备所述聚合物（F）的方法和所述聚合物（F）用作制备电极或制造膜的粘合剂。

2. 发明申请

US20130264522A1 Vinylidene fluoride copolymers 有权
标题翻译：偏二氟乙烯共聚物
公开(公告)号：US20130264522A1
公开(公告)日：2013-10-10
申请号：US13995275
申请日：2011-12-13
申请人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
发明人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
IPC分类号： C08F14/22 , C08L33/02 , C08K5/06
CPC分类号： C08F14/22 , C08F214/22 , C08F214/225 , C08J5/2237 , C08J2327/16 , C08K5/06 , C08L27/16 , C08L33/02 , C08L2205/02 , C08L2205/025 , H01M4/02 , H01M4/8605 , H01M8/0289 , H01M8/1023 , H01M10/0565 , Y02E60/521 , Y02P70/56 , C08F2/16 , C08F220/06 , C08F214/182 , C08F214/24
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF), and from 0.01% to 5% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (F) comprising end groups having formula —CF2H and/or —CF2CH3 in an amount of at least 30 mmoles per Kg of vinylidene fluoride (VDF) recurring units. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as binders for the manufacture of electrodes or for the manufacture of membranes.
摘要翻译：本发明涉及含氟聚合物[聚合物（F）]，其包含：衍生自偏二氟乙烯（VDF）的重复单元和0.01％至5％（摩尔）来源于至少一种（甲基）丙烯酸单体的重复单元[单体（ MA）]，其中：R 1，R 2和R 3彼此相同或不同，独立地选自氢原子和C1-C3烃基，ROH表示氢原子或包含至少一个羟基的C 1 -C 5烃部分，所述聚合物（F）包含具有式-CF 2 H和/或-CF 2 CH 3的端基，其量为至少30mmol / Kg偏二氟乙烯（VDF）重复单元。本发明还涉及制备所述聚合物（F）的方法和所述聚合物（F）用作制备电极或制造膜的粘合剂。

3. 发明授权

US09751967B2 Vinylidene fluoride and trifluoroethylene polymers 有权
公开(公告)号：US09751967B2
公开(公告)日：2017-09-05
申请号：US13996018
申请日：2011-12-13
申请人： Alessio Marrani , Giulio Brinati
发明人： Alessio Marrani , Giulio Brinati
IPC分类号： C08F214/22
CPC分类号： C08F214/225 , C08F214/22
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF); from 10% to 50% by moles of recurring units derived from trifluoroethylene (TrFE); and from 0.01% to 10% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as ferroelectric, piezoelectric, pyroelectric or dielectric material in electrical and electronic devices.

4. 发明授权

US08575286B2 Vinylidene fluoride and trifluoroethylene containing polymers 有权
标题翻译：偏二氟乙烯和含三氟乙烯的聚合物
公开(公告)号：US08575286B2
公开(公告)日：2013-11-05
申请号：US12995214
申请日：2009-05-26
申请人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
发明人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
IPC分类号： C08F114/22
CPC分类号： H01L41/193 , C08F214/182 , C08F214/22 , H01L37/025 , C08F2/26 , C08F2/20
摘要： A polymer comprising recurring units derived from vinylidene fluoride (VDF) and trifluoroethylene (TrFE), such polymer comprising end groups of formula —CF2H and/or —CF2CH3 in an amount of at least 60 mmoles per kg of VDF recurring units [polymer (F)], a process for its manufacture and the use thereof as ferroelectric, piezoelectric, dielectric or pyroelectric material in electric/electronic devices.
摘要翻译：包含衍生自偏氟乙烯（VDF）和三氟乙烯（TrFE）的重复单元的聚合物，包含至少60mmol / kg VDF重复单元的量的式-CF 2 H和/或-CF 2 CH 3的端基的聚合物[聚合物（F ）]，其制造方法及其在电气/电子设备中的铁电，压电，电介质或热电材料的使用。

5. 发明申请

US20130296512A1 Vinylidene fluoride and trifluoroethylene polymers 有权
标题翻译：偏二氟乙烯和三氟乙烯聚合物
公开(公告)号：US20130296512A1
公开(公告)日：2013-11-07
申请号：US13996018
申请日：2011-12-13
申请人： Alessio Marrani , Giulio Brinati
发明人： Alessio Marrani , Giulio Brinati
IPC分类号： C08F214/22
CPC分类号： C08F214/225 , C08F214/22
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF); from 10% to 50% by moles of recurring units derived from trifluoroethylene (TrFE); and from 0.01% to 10% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as ferroelectric, piezoelectric, pyroelectric or dielectric material in electrical and electronic devices.
摘要翻译：本发明涉及含氟聚合物[聚合物（F）]，其包含：衍生自偏二氟乙烯（VDF）的重复单元; 来自三氟乙烯（TrFE）的10％至50％摩尔的重复单元; 和0.01％至10％摩尔的衍生自具有式（I）的至少一种（甲基）丙烯酸单体[单体（MA）]的重复单元：其中：R1，R2和R3等于或不同于另一个独立地选自氢原子和C 1 -C 3烃基，ROH表示氢原子或包含至少一个羟基的C 1 -C 5烃部分。本发明还涉及制造所述聚合物（F）的方法以及所述聚合物（F）在电气和电子设备中用作铁电，压电，热电或介电材料的方法。

6. 发明申请

US20110082271A1 Vinylidene fluoride and trifluoroethylene containing polymers 有权
标题翻译：偏二氟乙烯和含三氟乙烯的聚合物
公开(公告)号：US20110082271A1
公开(公告)日：2011-04-07
申请号：US12995214
申请日：2009-05-26
申请人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
发明人： Giulio Brinati , Alessio Marrani , Bernard Goffaux
IPC分类号： C08F214/22 , C08F214/18 , C08F2/00 , C08F4/32
CPC分类号： H01L41/193 , C08F214/182 , C08F214/22 , H01L37/025 , C08F2/26 , C08F2/20
摘要： A polymer comprising recurring units derived from vinylidene fluoride (VDF) and trifluoroethylene (TrFE), such polymer comprising end groups of formula —CF2H and/or —CF2CH3 in an amount of at least 60 mmoles per kg of VDF recurring units [polymer (F)], a process for its manufacture and the use thereof as ferroelectric, piezoelectric, dielectric or pyroelectric material in electric/electronic devices.
摘要翻译：包含衍生自偏氟乙烯（VDF）和三氟乙烯（TrFE）的重复单元的聚合物，包含至少60mmol / kg VDF重复单元的量的式-CF 2 H和/或-CF 2 CH 3的端基的聚合物[聚合物（F ）]，其制造方法及其在电气/电子设备中的铁电，压电，电介质或热电材料的使用。

7. 发明授权

US08461448B2 Solar cell module 有权
标题翻译：太阳能电池组件
公开(公告)号：US08461448B2
公开(公告)日：2013-06-11
申请号：US12594525
申请日：2008-04-04
申请人： Paolo Toniolo , Padmanabhan Srinivasan , Alessio Marrani , Giambattista Besana , Vincenzo Arcella
发明人： Paolo Toniolo , Padmanabhan Srinivasan , Alessio Marrani , Giambattista Besana , Vincenzo Arcella
IPC分类号： H01L31/042
CPC分类号： H02S50/15 , B32B27/322 , H01L31/048 , H01L31/0481 , Y02E10/50
摘要： The present invention pertains to a solar cell module comprising at least one photovoltaic element encapsulated between a front layer on its light receiving surface side and a back layer, said front layer comprising at least one layer comprising a tetrafluoroethylene (TFE) polymer [polymer (F)], said polymer (F) comprising: recurring units derived from TFE; and from 15 to 25% wt of recurring units derived from at least one perfluoromonomer [monomer (CM)] chosen among: (i) perfluoroalkylvinylethers complying with formula CF2═CFORf1, in which Rf1 is a C1-C6 perfluoroalkyl, e.g. —CF3, —C2F5, —C3F7; and/or (ii) perfluoro-oxyalkylvinylethers complying with formula CF2═CFOX0, in which X0 is a C1-C12 perfluorooxyalkyl having one or more ether groups, like perfluoro-2-propoxy-propyl; and (iii) mixtures thereof. Still objects of the invention are a process for the manufacture of the solar cell module as above defined and its use for producing current to external sources, e.g. for powering a fixed-wing aircraft.
摘要翻译：本发明涉及太阳能电池模块，其包括封装在其光接收表面侧的前层和背层之间的至少一个光伏元件，所述前层包括至少一层包含四氟乙烯（TFE）聚合物[聚合物（F ）]，所述聚合物（F）包含：衍生自TFE的重复单元; 和15至25重量％的衍生自至少一种全氟单体[单体（CM）]的重复单元，其选自：（i）符合式CF2 = CFORf1的全氟烷基乙烯基醚，其中Rf1为C1-C6全氟烷基，例如 -CF 3，-C 2 F 5，-C 3 F 7; 和/或（ii）符合式CF 2 = CFOX 0的全氟烷氧基乙烯基醚，其中X 0是具有一个或多个醚基的C 1 -C 12全氟氧烷基，如全氟-2-丙氧基丙基; 和（iii）它们的混合物。本发明的另一目的是制造如上所述的太阳能电池组件的方法及其用于产生电流至外部源的用途，例如，为固定翼飞机提供动力。

8. 发明申请

US20090105420A1 Thermoplastic Fluoropolymer Composition 有权
标题翻译：热塑性氟聚合物组合物
公开(公告)号：US20090105420A1
公开(公告)日：2009-04-23
申请号：US12297888
申请日：2007-04-23
申请人： Julio Abusleme , Alessio Marrani
发明人： Julio Abusleme , Alessio Marrani
IPC分类号： C08L27/12 , C08L27/18 , C08L27/16 , C08L27/04 , C08L27/10
CPC分类号： C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , C08L2205/03 , C08L2666/04
摘要： This invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic hydrogen-containing fluoropolymer [polymer (A)]; and from 0.1 to 10% by weight of (A) of at least one per(halo)fluoropolymer chosen among tetrafluoroethylene (TFE) copolymers having a dynamic viscosity at a shear rate of 1 rad sec−1 of less than 10 Pa sec at a temperature of 280° C. [polymer (B)]. The addition of a TFE copolymer [polymer (B)] of low melt viscosity advantageously enables improvement of rheological behavior of thermoplastic hydrogen-containing fluoropolymer (A), making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency.Still objects of the invention are a process for manufacturing said thermoplastic fluoropolymer composition and the articles, such as shaped articles, films, cable sheathing, pipes, flexible pipes, hollow bodies comprising said thermoplastic fluoropolymer composition.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种含热塑性氢的含氟聚合物[聚合物（A）]; 和（A）至少一种选自四氟乙烯（TFE）共聚物中的至少一种每（卤代）含氟聚合物，其在剪切速率为1radsec-1时的动态粘度小于10Pa·sec，温度280℃[聚合物（B）]。加入低熔体粘度的TFE共聚物[聚合物（B）]有利于改善热塑性含氢含氟聚合物（A）的流变行为，使得在不太严格的条件下可能的加工，并产生具有优异表面面积和良好均匀性的最终部件和一致性。本发明的另一目的是制造所述热塑性含氟聚合物组合物和制品的方法，例如成型制品，薄膜，电缆护套，管，柔性管，包含所述热塑性含氟聚合物组合物的中空体。

9. 发明授权

US08710149B2 Thermoplastic fluoropolymer composition 有权
标题翻译：热塑性氟聚合物组合物
公开(公告)号：US08710149B2
公开(公告)日：2014-04-29
申请号：US12297888
申请日：2007-04-23
申请人： Julio Abusleme , Alessio Marrani
发明人： Julio Abusleme , Alessio Marrani
IPC分类号： C08L27/12 , C08F214/26
CPC分类号： C08L27/12 , C08L27/16 , C08L27/18 , C08L2205/02 , C08L2205/03 , C08L2666/04
摘要： This invention pertains to a thermoplastic fluoropolymer composition comprising: at least one thermoplastic hydrogen-containing fluoropolymer [polymer (A)]; and from 0.1 to 10% by weight of (A) of at least one per(halo)fluoropolymer chosen among tetrafluoroethylene (TFE) copolymers having a dynamic viscosity at a shear rate of 1 rad sec−1 of less than 10 Pa sec at a temperature of 280° C. [polymer (B)]. The addition of a TFE copolymer [polymer (B)] of low melt viscosity advantageously enables improvement of rheological behavior of thermoplastic hydrogen-containing fluoropolymer (A), making possible processing in less severe conditions and yielding final parts with outstanding surface aspect and good homogeneity and coherency.Still objects of the invention are a process for manufacturing said thermoplastic fluoropolymer composition and the articles, such as shaped articles, films, cable sheathing, pipes, flexible pipes, hollow bodies comprising said thermoplastic fluoropolymer composition.
摘要翻译：本发明涉及一种热塑性含氟聚合物组合物，其包含：至少一种含热塑性氢的含氟聚合物[聚合物（A）]; 和（A）至少一种选自四氟乙烯（TFE）共聚物中的至少一种每（卤代）含氟聚合物，其在剪切速率为1radsec-1时的动态粘度小于10Pa·sec，温度280℃[聚合物（B）]。加入低熔体粘度的TFE共聚物[聚合物（B）]有利于改善热塑性含氢含氟聚合物（A）的流变行为，使得在不太严格的条件下可能的加工，并产生具有优异表面面积和良好均匀性的最终部件和一致性。本发明的另一目的是制造所述热塑性含氟聚合物组合物和制品的方法，例如成型制品，薄膜，电缆护套，管，柔性管，包含所述热塑性含氟聚合物组合物的中空体。

10. 发明申请

US20140009937A1 Led lighting device with an adjustable spatial distribution of the emitted light 审中-公开
标题翻译： LED照明装置具有可调节的发射光的空间分布
公开(公告)号：US20140009937A1
公开(公告)日：2014-01-09
申请号：US14006528
申请日：2012-03-22
申请人： Stefano Bonora , Enrico Zanoni , Matteo Meneghini , Giovanna Brusatin , Alessio Marrani , Mattia Bassi , Ivan Falco
发明人： Stefano Bonora , Enrico Zanoni , Matteo Meneghini , Giovanna Brusatin , Alessio Marrani , Mattia Bassi , Ivan Falco
IPC分类号： F21K99/00
CPC分类号： F21K9/65 , F21V7/16 , F21V7/22 , F21Y2115/10 , G02B19/0061 , G02B26/0825
摘要： The present invention relates to a lighting device (1) that comprises a first light source (2) comprising one or more LED devices (21).At least a deformable reflective element (3) is optically coupled to said first light source, so as to receive light from said first light source, said reflective structure comprising at least a first portion (31) having a reflective surface (310) that reflects at least partially the light (L1) received from said first light source, and a second portion (32) that is solidly coupled to said first portion.Driving means (4) are operatively coupled to said second portion (32), which induce a deformation of said second portion that in turn causes a deformation of the reflective surface (310) of said first portion.The position of the focus point (F) of the light (L2) reflected by said reflective surface can thus be varied in a controlled manner.
摘要翻译：本发明涉及一种照明装置（1），其包括包括一个或多个LED装置（21）的第一光源（2）。至少可变形的反射元件（3）被光学耦合到所述第一光源，以便接收来自所述第一光源的光，所述反射结构包括至少第一部分（31），所述第一部分具有反射表面（310）至少部分地从所述第一光源接收的光（L1）和与所述第一部分牢固耦合的第二部分（32）。驱动装置（4）可操作地联接到所述第二部分（32），这引起所述第二部分的变形，这又导致所述第一部分的反射表面（310）的变形。因此，可以以受控的方式改变由所述反射表面反射的光（L2）的焦点（F）的位置。

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