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1. 发明授权

US09441054B2 Vinylidene fluoride copolymers 有权
标题翻译：偏二氟乙烯共聚物
公开(公告)号：US09441054B2
公开(公告)日：2016-09-13
申请号：US13995275
申请日：2011-12-13
申请人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
发明人： Milena Stanga , Bradley Lane Kent , Alessio Marrani , Giulio Brinati
IPC分类号： H01M4/00 , C08F14/22 , C08F214/22 , C08J5/22 , C08L27/16 , H01M4/02 , H01M4/86 , H01M8/02 , H01M8/10 , H01M10/0565 , C08K5/06 , C08L33/02
CPC分类号： C08F14/22 , C08F214/22 , C08F214/225 , C08J5/2237 , C08J2327/16 , C08K5/06 , C08L27/16 , C08L33/02 , C08L2205/02 , C08L2205/025 , H01M4/02 , H01M4/8605 , H01M8/0289 , H01M8/1023 , H01M10/0565 , Y02E60/521 , Y02P70/56 , C08F2/16 , C08F220/06 , C08F214/182 , C08F214/24
摘要： The present invention pertains to a fluoropolymer [polymer (F)] comprising: recurring units derived from vinylidene fluoride (VDF), and from 0.01% to 5% by moles of recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] having formula (I) here below: wherein: R1, R2 and R3, equal to or different from each other, are independently selected from a hydrogen atom and a C1-C3 hydrocarbon group, and ROH represents a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group, said polymer (F) comprising end groups having formula —CF2H and/or —CF2CH3 in an amount of at least 30 mmoles per Kg of vinylidene fluoride (VDF) recurring units. The invention also pertains to a process for the manufacture of said polymer (F) and to use of said polymer (F) as binders for the manufacture of electrodes or for the manufacture of membranes.
摘要翻译：本发明还涉及制备所述聚合物（F）的方法和所述聚合物（F）用作制备电极或制造膜的粘合剂。

2. 发明授权

US09410005B2 Polymer, preparation method thereof, composition and film comprising the same 有权
标题翻译：聚合物，其制备方法，组合物和包含其的膜
公开(公告)号：US09410005B2
公开(公告)日：2016-08-09
申请号：US14554426
申请日：2014-11-26
申请人： LG Chem, Ltd.
发明人： Jeong Ae Yoon , No Ma Kim , Su Jeong Kim , In Ho Hwang
IPC分类号： C08F220/18 , C09D133/12 , C08F214/18 , C08J5/18 , C08F212/08 , C08F220/14 , C08F293/00 , C08L53/00 , C09D127/12
CPC分类号： C08F220/18 , C08F212/08 , C08F214/18 , C08F220/14 , C08F293/005 , C08F2438/01 , C08J5/18 , C08J2300/102 , C08J2327/22 , C08J2333/12 , C08L53/00 , C09D127/12 , C09D133/12 , C08F214/24 , C08L33/12 , C08L27/04 , C08L101/00
摘要： Provided is a polymer, a composition and film comprising the polymer, and a preparation method of the polymer. The polymer includes a compound having a hydrophobic property at its terminal, and thus a film capable of having a hydrophobic surface can be provided at the same time when the film is formed without a separate surface treatment. Further, an effect capable of permanently hydrophobically modifying a film surface is obtained at a low cost and a composition that does not occur a phase separation phenomenon in a polymer solution state is provided. For example, the film is used as a water repellent coating film, an anti-contamination film, or the like.
摘要翻译：提供聚合物，包含聚合物的组合物和膜以及聚合物的制备方法。聚合物包括在其末端具有疏水性的化合物，因此可以在没有单独的表面处理形成膜的同时提供能够具有疏水性表面的膜。此外，可以低成本获得能够永久地疏水改性膜表面的效果，并且提供在聚合物溶液状态下不发生相分离现象的组合物。例如，该膜用作防水涂膜，防污染膜等。

3. 发明申请

US20160194512A1 FLUORINE-CONTAINING THERMOPLASTIC ELASTOMER COMPOSITION 审中-公开
标题翻译：含氟的热塑性弹性体组合物
公开(公告)号：US20160194512A1
公开(公告)日：2016-07-07
申请号：US14909339
申请日：2014-07-24
申请人： SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
发明人： Suneel BANDI , Kun LI , Philip SCHILD , Edwin FIGUEROA , Bradley Lane KENT
IPC分类号： C09D127/20 , C09D127/16
CPC分类号： C09D127/20 , C08F210/02 , C08F214/242 , C08L27/12 , C09D127/16 , H01B3/28 , H01B3/441 , H01B3/445 , C08L23/08 , C08F214/24 , C08F216/1408
摘要： The invention pertains to a thermoplastic vulcanizate fluorine-containing composition [vulcanizate (C)], comprising a continuous thermoplastic fluoropolymer phase and a dispersed vulcanized fluoroelastomer phase, said composition comprising: —at least one thermoplastic fluoropolymer [polymer (F)], said polymer (F) comprising (j) from 40 to 60% by moles of recurring units derived from ethylene (E); (jj) from 60 to 40% by moles of recurring units derived from at least one of chlorotrifluoroethylene (CTFE) and tetrafluoroethylene (TFE); and (jjj) from 0.5 to 10% by moles of recurring units derived from of at least one (per)fluoroalkylvinylether of formula CX2═CX—ORf, wherein each of X, equal to or different from each other, is independently H or F (preferably F); and Rf is a C1-C12 (per)fluoroalkyl group or a C1-C12 (per)fluoro-oxy-alkyl group comprising one or more than one catenary oxygen atoms [monomer (V)], with % by moles being referred to the total moles of recurring units of the polymer (F); and —at least one (per)fluoroelastomer [elastomer (A)].
摘要翻译：本发明涉及包含连续的热塑性含氟聚合物相和分散的硫化含氟弹性体相的热塑性硫化橡胶含氟组合物[硫化橡胶（C）]，所述组合物包含： - 至少一种热塑性含氟聚合物[聚合物（F）]，所述聚合物（F）包含（j）40-60％（摩尔）衍生自乙烯（E）的重复单元; （jj）60至40摩尔％的由三氟氯乙烯（CTFE）和四氟乙烯（TFE）中的至少一种衍生的重复单元; 和（jjj）0.5至10摩尔％的衍生自式CX2 = CX-ORf的至少一个（全）氟烷基乙烯基醚的重复单元，其中X彼此相同或不同的独立地为H或F （优选F）; 并且R f是包含一个或多于一个链状氧原子的C1-C12（全）氟代烷基或C1-C12（全）氟 - 氧基 - 烷基[单体（Ⅴ）]，其摩尔数相对于聚合物（F）的重复单元的总摩尔数; 和至少一种（全）氟弹性体[弹性体（A）]。

4. 发明申请

US20160130379A1 PROCESS, PROPERTIES, AND APPLICATIONS OF GRAFT COPOLYMERS 有权
标题翻译： GRAFT共聚物的工艺，性能和应用
公开(公告)号：US20160130379A1
公开(公告)日：2016-05-12
申请号：US14971487
申请日：2015-12-16
申请人： Honeywell International Inc. , Universite de Montpellier , Centre National de la Recherche Scientifique
发明人： Alagappan Thenappan , Eric Rainal , Bruno Ameduri , Frederic Boschet , Noureddine Ajellal , Gerald Lopez
IPC分类号： C08F214/24
CPC分类号： C08F214/24 , C08F259/00 , C08J5/18 , C08J2327/12
摘要： A polymeric molecule having the formula: X—[C(A)2C(B)(B′)]n-Q[CY═C(Z)(Z′)] or [C(A)2=C(B)]n-Q[C(Y)(Y′)—C(Z)(Z′)]—X′, wherein A is either H or F; B and B′ are either H, F, or Cl, and are not necessarily the same; X and X′ are Br, Cl or I (and are not necessarily the same); Y and Y′ are F, Br, Cl or I (and are not necessarily the same); and wherein Z and Z′ are F, Br, Cl or I (and are not necessarily the same); Q is optional and is either oxygen (O) or sulfur (S); and n is at least 1.
摘要翻译：具有下式的聚合物分子：X- [C（A）2C（B）（B'）] nQ [CY = C（Z）（Z'）]或[C（A）2 = C（B） [C（Y）（Y'）-C（Z）（Z'）] - X'，其中A为H或F; B和B'是H，F或Cl，并不一定相同; X和X'是Br，Cl或I（并不一定相同）; Y和Y'是F，Br，Cl或I（并不一定相同）; 并且其中Z和Z'是F，Br，Cl或I（并且不一定相同）; Q是任选的，并且是氧（O）或硫（S）; 且n至少为1。

5. 发明申请

US20160108159A1 FLUOROPOLYMER PRODUCTION METHOD 有权
标题翻译：氟聚合物生产方法
公开(公告)号：US20160108159A1
公开(公告)日：2016-04-21
申请号：US14892844
申请日：2014-04-30
申请人： DAIKIN INDUSTRIES, LTD.
发明人： Takashi SEKIGUCHI , Manabu FUJISAWA , Ryouichi FUKAGAWA , Takeshi SHIMONO
IPC分类号： C08F214/26 , C08F214/28
CPC分类号： C08F214/26 , C08F4/34 , C08F14/18 , C08F14/24 , C08F14/26 , C08F214/24 , C08F214/242 , C08F214/245 , C08F214/262 , C08F214/265 , C08F214/28
摘要： The present invention aims to provide a method of producing a fluoropolymer, especially a fluoropolymer essentially including a tetrafluoroethylene or chlorotrifluoroethylene unit, at a higher polymerization rate with improved efficiency, the method being capable of improving the moldability in extrusion molding and suppressing discoloration. The method of producing a fluoropolymer of the present invention includes producing a fluoropolymer by polymerizing tetrafluoroethylene or chlorotrifluoroethylene in the presence of a peroxydicarbonate. The peroxydicarbonate is represented by the formula: R—O—C(═O)—O—O—C(═O)—O—R wherein R's may be the same as or different from each other and individually represent a C4 alkyl group or alkoxy alkyl group.
摘要翻译：本发明的目的在于提供一种以更高的聚合速率生产含氟聚合物，特别是基本上包含四氟乙烯或氯三氟乙烯单元的含氟聚合物的方法，该方法能够提高挤出成型中的成型性和抑制变色。本发明的含氟聚合物的制造方法包括在过氧化二碳酸酯的存在下聚合四氟乙烯或氯三氟乙烯来制造含氟聚合物。过氧化二碳酸酯由下式表示：R-O-C（= O）-O-O-C（= O）-O-R，其中R可以彼此相同或不同，并且各自表示C4烷基或烷氧基烷基。

6. 发明申请

US20150240012A1 METHOD FOR PRODUCING FLUORINE-CONTAINING COPOLYMER 审中-公开
标题翻译：生产含氟聚合物的方法
公开(公告)号：US20150240012A1
公开(公告)日：2015-08-27
申请号：US14008617
申请日：2012-03-28
申请人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe
发明人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe
IPC分类号： C08F218/08
CPC分类号： C08F218/08 , C08F2/26 , C08F14/18 , C08F214/00 , C08F214/182 , C08F214/186 , C08F214/188 , C08F214/24 , C08F214/245 , C08F214/26 , C08F214/265 , C08F14/26
摘要： The present invention provides a method for producing a copolymer containing a perhaloolefin and vinyl acetate by a novel emulsion polymerization method. The present invention relates to a method for producing a perhaloolefin-vinyl acetate copolymer by emulsion polymerization of at least a perhaloolefin having two carbon atoms and vinyl acetate in the presence of a hydrocarbon emulsifier or in the absence of an emulsifier, provided that the hydrocarbon emulsifier excludes a compound (1) represented by the formula (1): wherein R1 and R2 are the same as or different from each other and each represent a C4 to 12 unfluorinated saturated hydrocarbon group; M represents an alkali metal, an ammonium salt, or an amine salt.
摘要翻译：本发明提供一种通过新的乳液聚合法制备含有全卤代烯烃和乙酸乙烯酯的共聚物的方法。本发明涉及一种通过在烃类乳化剂的存在下或不存在乳化剂的情况下通过至少具有两个碳原子的全卤代烯烃和乙酸乙烯酯的乳液聚合制备全卤代烯烃 - 乙酸乙烯酯共聚物的方法，条件是烃类乳化剂不包括由式（1）表示的化合物（1）：其中R1和R2彼此相同或不同，并且各自表示C4至12个未氟饱和烃基; M表示碱金属，铵盐或胺盐。

7. 发明申请

US20150094428A1 SYNTHESIS OF CHLOROTRIFLUOROETHYLENE-BASED BLOCK COPOLYMERS BY IODINE TRANSFER POLYMERIZATION 有权
标题翻译：通过碘转移聚合合成基于氯代三氟乙烯的嵌段共聚物
公开(公告)号：US20150094428A1
公开(公告)日：2015-04-02
申请号：US14448062
申请日：2014-07-31
申请人： Honeywell International Inc.
发明人： Alagappan Thenappan , Bruno Ameduri , Gerald Lopez
IPC分类号： C08F299/00
CPC分类号： C08F214/242 , C08F2/38 , C08F214/24 , C08F293/005 , C08F2438/00
摘要： Methods for the synthesis of CTFE-based block copolymers through iodine transfer polymerization are disclosed. In an exemplary embodiment, a method includes reacting a fluoromonomer “M” with a chain transfer agent of the formula X—Y or Y—X—Y, wherein X represents a C1-C3 hydrocarbon, a C1-C6 hydrofluorocarbon, C1-C6 hydrochlorofluorocarbon, or C1-C6 fluorocarbon and Y represents iodine or bromine, in the presence of a radical initiator, to form a macro-initiator of the formula: X-poly(M)-Y or Y-poly(M)-X-poly(M)-Y, wherein poly(M) represents a polymer of the fluoromonomer. The method further includes reacting the macro-initiator with chlorotrifluoroethylene (CTFE) in the presence of a radical initiator to form a diblock or a triblock CTFE-based block copolymer of the formula: X-poly(M)-block-poly(CTFE) or PCTFE-block-poly(M)-X-poly(M)-block-PCTFE.
摘要翻译：公开了通过碘转移聚合合成CTFE基嵌段共聚物的方法。在一个示例性实施方案中，一种方法包括使含氟单体“M”与式X-Y或Y-X-Y的链转移剂反应，其中X表示C1-C3烃，C1-C6氢氟烃，C1-C6 氯代氟代烃或C1-C6碳氟化合物，Y代表碘或溴，在自由基引发剂的存在下形成下式的大分子引发剂：X-聚（M）-Y或Y-聚（M）-X- 聚（M）-Y，其中聚（M）表示所述含氟单体的聚合物。该方法还包括在自由基引发剂的存在下使大分子引发剂与氯三氟乙烯（CTFE）反应以形成下式的二嵌段或三嵌段CTFE基嵌段共聚物：X-聚（M） - 嵌段 - 聚（CTFE）或PCTFE-嵌段 - 聚（M）-X-聚（M） - 嵌段-PCFEFE。

8. 发明申请

US20150080524A1 POLYMER, PREPARATION METHOD THEREOF, COMPOSITION AND FILM COMPRISING THE SAME 有权
标题翻译：聚合物，其制备方法，组合物和包含其的膜
公开(公告)号：US20150080524A1
公开(公告)日：2015-03-19
申请号：US14554426
申请日：2014-11-26
申请人： LG Chem, Ltd.
发明人： Jeong Ae Yoon , No Ma Kim , Su Jeong Kim , In Ho Hwang
IPC分类号： C08F220/18 , C09D133/12
CPC分类号： C08F220/18 , C08F212/08 , C08F214/18 , C08F220/14 , C08F293/005 , C08F2438/01 , C08J5/18 , C08J2300/102 , C08J2327/22 , C08J2333/12 , C08L53/00 , C09D127/12 , C09D133/12 , C08F214/24 , C08L33/12 , C08L27/04 , C08L101/00
摘要： Provided is a polymer, a composition and film comprising the polymer, and a preparation method of the polymer. The polymer includes a compound having a hydrophobic property at its terminal, and thus a film capable of having a hydrophobic surface can be provided at the same time when the film is formed without a separate surface treatment. Further, an effect capable of permanently hydrophobically modifying a film surface is obtained at a low cost and a composition that does not occur a phase separation phenomenon in a polymer solution state is provided. For example, the film is used as a water repellent coating film, an anti-contamination film, or the like.
摘要翻译：提供聚合物，包含聚合物的组合物和膜以及聚合物的制备方法。聚合物包括在其末端具有疏水性的化合物，因此可以在没有单独的表面处理形成膜的同时提供能够具有疏水性表面的膜。此外，可以低成本获得能够永久地疏水改性膜表面的效果，并且提供在聚合物溶液状态下不发生相分离现象的组合物。例如，该膜用作防水涂膜，防污染膜等。

9. 发明授权

US07879962B2 Powders or manufactured articles having a surface hydrophilicity 有权
标题翻译：具有表面亲水性的粉末或制品
公开(公告)号：US07879962B2
公开(公告)日：2011-02-01
申请号：US11384823
申请日：2006-03-21
申请人： Julio A. Abusleme , Gabriella Carignano
发明人： Julio A. Abusleme , Gabriella Carignano
IPC分类号： C08F214/18
CPC分类号： B01D71/32 , B01D67/0009 , B01D67/0018 , B01D67/003 , B01D67/0093 , B01D71/36 , B01D71/38 , B01D71/40 , B01D2323/20 , B01D2325/24 , B01D2325/30 , B01D2325/36 , C08F214/24 , C08F214/26
摘要： Powders or hydrophilic manufactured articles of E/CTFE and/or E/TFE thermoprocessable polymers, or of CTFE copolymers, wherein, on the surface of the powder or the manufactured article, one or more of the following hydrophilic units are present: —C(COOH)H—CH2—; —C(COOM)H—CH2—; —C(OCOOH)H—CH2—; —C(OCOOM)H—CH2—; with M=alkaline ion.
摘要翻译： E / CTFE和/或E / TFE热可加工聚合物或CTFE共聚物的粉末或亲水制品，其中在粉末或制品的表面上存在一种或多种下列亲水单元：-C（ COOH）H-CH 2 - ; -C（COOM）H-CH 2 - ; -C（OCOOH）H-CH 2 - ; -C（OCOOM）H-CH 2 - ; M =碱性离子。

10. 发明授权

US07335705B2 Thermosetting coating compositions comprising a copolymer formed from chlorotrifluoroethylene and methods of making copolymers formed from chlorotrifluoroethylene 失效
标题翻译：包含由三氟氯乙烯形成的共聚物的热固性涂料组合物和由氯三氟乙烯形成的共聚物的方法
公开(公告)号：US07335705B2
公开(公告)日：2008-02-26
申请号：US11241344
申请日：2005-09-30
申请人： Simion Coca , Edward R. Coleridge , James B. O'Dwyer , Brian E. Woodworth
发明人： Simion Coca , Edward R. Coleridge , James B. O'Dwyer , Brian E. Woodworth
IPC分类号： C08F114/18
CPC分类号： C08F8/00 , C08F214/18 , C08F214/24 , C08K5/0025 , C09D127/12 , D06M15/277 , C08L27/12
摘要： Fluoropolymers are disclosed. The fluoropolymers include (i) units derived from a fluoromonomer composition comprising chlorotrifluoroethylene, and (ii) units derived from at least one donor monomer composition. In the disclosed fluoropolymers, units (i) and (ii) are distributed along the fluoropolymer chain in a substantially alternating fashion. Also disclosed are thermosetting compositions containing such fluoropolymers, substrates coated with such compositions, methods for making such compositions, and methods for coating substrates with such compositions.
摘要翻译：披露了含氟聚合物。含氟聚合物包括（i）衍生自包含氯三氟乙烯的含氟单体组合物的单元，和（ii）衍生自至少一种供体单体组合物的单元。在所公开的含氟聚合物中，单元（i）和（ii）以基本交替的方式沿着含氟聚合物链分布。还公开了含有这样的含氟聚合物的热固性组合物，用这种组合物涂覆的基材，制备这种组合物的方法，以及用这种组合物涂覆基材的方法。

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