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1. 发明授权

US5573889A Process for adjusting the sensitivity to radiation of photopolymerizable compositions 失效
标题翻译：调整可光聚合组合物对辐射敏感度的方法
公开(公告)号：US5573889A
公开(公告)日：1996-11-12
申请号：US437737
申请日：1995-05-09
申请人： Manfred Hofmann , Bernd Klingert , Max Hunziker , Rolf Wiesendanger , Adrian Schulthess , Paul Bernhard
发明人： Manfred Hofmann , Bernd Klingert , Max Hunziker , Rolf Wiesendanger , Adrian Schulthess , Paul Bernhard
IPC分类号： B29C67/00 , C08F2/48 , C08F4/00 , C08F4/32 , C08F4/42 , C08F20/10 , C08F20/20 , C08F299/02 , G03F7/00 , G03F7/028 , G03F7/029 , G03F7/031 , C08F2/50
CPC分类号： B29C67/0066 , B29C67/0055 , C08F2/48 , G03F7/0037 , G03F7/029 , G03F7/031
摘要： A process is described for the preparation of photopolymerizable compositions, wherein the photopolymerizable compositions can be photopolymerized by the irradiation of emission lines of differing wavelength from a UV/VIS laser light source, and contain a photopolymerizable compound and at least two photoinitiators, by adjusting the sensitivity to radiation. The ratio between the concentrations of the individual photoinitiators is so adjusted that the composition has virtually the same optical density for the radiation of the different emission lines at which the photoinitiators are effective.
摘要翻译：描述了用于制备可光聚合组合物的方法，其中可光聚合组合物可以通过从UV / VIS激光光源照射不同波长的发射线而被光聚合，并且通过调节光聚合性组合物，通过调节光聚合性组合物和至少两种光引发剂，对辐射敏感。调整各个光引发剂的浓度之间的比例，使得组合物对于光引发剂有效的不同发射线的辐射具有几乎相同的光密度。

2. 发明授权

US5645973A Process for adjusting the sensitivity to radiation of photopolymerizable compositions 失效
标题翻译：调整可光聚合组合物对辐射敏感度的方法
公开(公告)号：US5645973A
公开(公告)日：1997-07-08
申请号：US592899
申请日：1996-01-29
申请人： Manfred Hofmann , Bernd Klingert , Max Hunziker , Rolf Wiesendanger , Adrian Schulthess , Paul Bernhard
发明人： Manfred Hofmann , Bernd Klingert , Max Hunziker , Rolf Wiesendanger , Adrian Schulthess , Paul Bernhard
IPC分类号： B29C67/00 , C08F2/48 , C08F4/00 , C08F4/32 , C08F4/42 , C08F20/10 , C08F20/20 , C08F299/02 , G03F7/00 , G03F7/028 , G03F7/029 , G03F7/031 , G03F7/20 , B29C35/08 , B29C67/24 , G03F7/095
CPC分类号： B29C67/0066 , B29C67/0055 , C08F2/48 , G03F7/0037 , G03F7/029 , G03F7/031
摘要： A process is described for the preparation of photopolymerizable compositions, wherein the photopolymerizable compositions can be photopolymerized by the irradiation of emission lines of differing wavelength from a UV/VIS laser light source, and contain a photopolymerizable compound and at least two photoinitiators, by adjusting the sensitivity to radiation. The ratio between the concentrations of the individual photoinitiators is so adjusted that the composition has virtually the same optical density for the radiation of the different emission lines at which the photoinitiators are effective.
摘要翻译：描述了用于制备可光聚合组合物的方法，其中可光聚合组合物可以通过从UV / VIS激光光源照射不同波长的发射线而被光聚合，并且通过调节光聚合性组合物，通过调节光聚合性组合物和至少两种光引发剂，对辐射敏感。调整各个光引发剂的浓度之间的比例，使得组合物对于光引发剂有效的不同发射线的辐射具有几乎相同的光密度。

3. 发明授权

US5476749A Photosensitive compositions based on acrylates 失效
标题翻译：基于丙烯酸酯的感光组合物
公开(公告)号：US5476749A
公开(公告)日：1995-12-19
申请号：US303563
申请日：1994-09-09
申请人： Bettina Steinmann , Rolf Wiesendanger , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Rolf Wiesendanger , Adrian Schulthess , Max Hunziker
IPC分类号： C08F2/50 , C08F2/48 , C08F290/00 , C08F299/06 , C09D4/00 , C09D4/02 , G03F7/00 , G03F7/027 , G03C5/00
CPC分类号： G03F7/027 , B29C67/0066 , G03F7/0037
摘要： A liquid photosensitive composition comprising(1) 40 to 80% by weight of a urethane (meth)acrylate having a functionality of 2 to 4 and a molecular weight (Mw) of 500 to 10,000,(2) 5 to 40% by weight of a hydroxyl group containing aliphatic or cycloaliphatic di(meth)acrylate,(3) 0 to 40% by weight of a mono(meth)acrylate or of a mono-N-vinyl compound having a Mw of not more than 500,(4) 0.1 to 10% by weight of a photoinitiator,(5) 0 to 30% by weight of an aliphatic or cycloaliphatic di(meth)acrylate which differs from (2), of an aliphatic tri(meth)acrylate or of an aromatic di- or tri(meth)acrylate, and(6) 0 to 5% by weight of customary additives, such that the proportion of components (1) to (6) together is 100% by weight.The composition is a photosensitive composition which can be polymerised by irradiation with actinic light and which is suitable for the production preferably of three-dimensional objects by the stereolithographic technique.
摘要翻译：一种液体光敏组合物，其包含（1）40至80重量％的官能度为2至4，分子量（Mw）为500至10,000的聚氨酯（甲基）丙烯酸酯，（2）5至40重量％含有脂肪族或脂环族二（甲基）丙烯酸酯的羟基，（3）0〜40重量％的单（甲基）丙烯酸酯或Mw不大于500的单-N-乙烯基化合物，（4） 0.1〜10重量％的光引发剂，（5）0〜30重量％脂肪族或（脂）三（甲基）丙烯酸酯或芳香族二（甲基）丙烯酸酯的脂肪族或脂环族二（甲基）丙烯酸酯与（2）或三（甲基）丙烯酸酯，和（6）0-5重量％的常规添加剂，使得组分（1）至（6）的比例在一起为100重量％。该组合物是可以通过用光化光照射而聚合的光敏组合物，其适用于通过立体光刻技术优选生产三维物体。

4. 发明授权

US4957988A Process and polymers for the production of images 失效
标题翻译：用于生产图像的工艺和聚合物
公开(公告)号：US4957988A
公开(公告)日：1990-09-18
申请号：US178810
申请日：1988-03-28
申请人： Edward Irving , Beat Muller , Adrian Schulthess , Max Hunziker
发明人： Edward Irving , Beat Muller , Adrian Schulthess , Max Hunziker
IPC分类号： C08G8/00 , C08F20/00 , C08F20/34 , C08F20/36 , C08G8/28 , C08G85/00 , G03C1/72 , G03F7/004 , G03F7/039
CPC分类号： G03F7/039 , C08G85/004
摘要： A polymer having a molecular weight of at least 500 and containing at least one residue of formula I(--L.sup.1 --).sub.m Ar.sup.1 [X]--OSO.sub.2 --Ar.sup.2 (--L.sup.2 --).sub.n (I)whereone of m and n denotes 1 and the other denotes 0 or 1,X denotes either a group of formula II ##STR1## linked through the carbonyl group to an aromatic carbon atom in Ar.sup.1, ora group of formula III ##STR2## linked through the carbonyl groups to aromatic carbon atoms in Ar.sup.1, p denotes zero or 1,when p denotes zero, R.sup.1 denotes a hydrogen atom or a monovalent aliphatic, araliphatic or aromatic group,when p denotes 1, R.sup.1 denotes a hydrogen atom, a hydroxyl group, an etherified hydroxyl group, an acyloxy group, an alkyl group or a phenyl-substituted alkyl group,r.sup.2 denotes a hydrogen atom or a monovalent aliphatic, cycloaliphatic, heterocyclic, aromatic or araliphatic group,Ar.sup.1 denotes a monovalent, divalent or trivalent aromatic group,Ar.sup.2 denotes a monovalent or divalent aromatic group, andAr.sup.3 denotes a monovalent aromatic group, andL.sup.1 and L.sup.2 each denote --CO--, --COO--, --CONH--, --OCOO--, --NHCONH--, --OCONH--, --CSS--, OCSS--, --OSO.sub.2 --, --CH.sub.2 --, --CH.dbd., --O--, --S-- or --N.dbd..These polymers, which can be prepared in known manner from intermediates, some of which intermediates are novel, are suitable for the production of images which are obtained by exposure to actinic radiation and subsequent development with aqueous bases.
摘要翻译：分子量为至少500且含有至少一个式I（-L1-）mAr1 [X] -OSO 2 -Ar 2（-L 2 - ）n（I）的残基的聚合物，其中m和n之一表示1和另一个表示0或1，X表示在Ar 1中通过羰基连接到芳族碳原子的式II（II）的基团，或通过羰基连接的式III（III）的基团在Ar 1中的芳族碳原子的基团，p表示0或1，当p表示0时，R 1表示氢原子或一价脂族，芳脂族或芳族基团，当p表示1时，R 1表示氢原子，羟基，醚化的羟基，酰氧基，烷基或苯基取代的烷基，r2表示氢原子或一价脂族，脂环族，杂环，芳族或芳脂族基团，Ar1表示一价，二价或三价芳基，Ar 2 表示一价或二价芳香族基团，Ar 3表示1价芳香族基团，L1表示1价芳香族基团和L2各自表示-CO - ， - COO - ， - CONH - ， - OOO-， - NHCONH-， - OCONH-，-CSS-，OCSS-，-OSO 2 - ， - CH 2 - ， - CH = ，-S-或-N =。这些可以以已知方式从中间体制备的聚合物，其中一些中间体是新的，适用于生产通过暴露于光化辐射获得的图像，随后用含水碱显影。

5. 发明授权

US5487966A Photosensitive compositions 失效
标题翻译：感光组合物
公开(公告)号：US5487966A
公开(公告)日：1996-01-30
申请号：US231953
申请日：1994-04-21
申请人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
IPC分类号： C08G63/00 , B29C67/00 , C08G63/52 , C08G63/58 , C08J5/00 , G03F7/00 , G03F7/027 , G03F7/029 , G03F7/032 , G03C5/00 , G03C1/492 , G03C1/725
CPC分类号： C08G63/52 , C08G63/58 , G03F7/0037 , G03F7/032
摘要： Photosensitive compositions comprisinga) 5-95% by weight of a polyester of formula I, II or III ##STR1## wherein R.sub.1 is the radical of a cyclic anhydride of a dicarboxylic acid after removal of the --O--CO--O-- grouping, which radical may be substituted by C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.6 -C.sub.10 aryl, halogen or C.sub.1 -C.sub.22 alkyl which is interrupted by --O-- or --CO--O--,R.sub.2 is hydrogen, unsubstituted or halogen-substituted C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.7 -C.sub.22 aralkyl, C.sub.6 -C.sub.10 aryl or a radical --CH.sub.2 --O--R.sub.5 or --CH.sub.2 --O--CO--R.sub.5, wherein R.sub.5 is C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.6 cycloalkyl or C.sub.6 -C.sub.10 aryl,R.sub.3 is hydrogen, orR.sub.2 and R.sub.3, together with the linking carbon atoms, are a cyclopentylene or cyclohexylene radical,R.sub.4 is a radical of 4 to 12 carbon atoms which carries an unsaturated end group and carboxyl or ether groups,A is a mono- or polyfunctional low molecular or high molecular carboxylate or alcoholate,x is an integer from 0-100,n is an integer from 2-150, andz is an integer from 1-4,b) 10-90% by weight of a liquid polyfunctional aliphatic, cycloaliphatic or aromatic (meth)acrylate,c) 0-70% of a mono(meth)acrylate or mono-N-vinyl compound with a molecular weight of not more than 500,d) 0.1-10% by weight of a photoinitiator, ande) 0-10% by weight of optional customary additives.
摘要翻译：包含a）5-95重量％的式I，II或III的聚酯的方法，其中R 1是基团（R 1）的C 1 -C 22烷基，C 5 -C 10环烷基，C 3 -C 6烯基，C 6 -C 10芳基，卤素或C 1 -C 22烷基取代的-O-CO-O-基团后的二羧酸的环状酸酐，其为被-O-或-CO-O-中断，R 2是氢，未取代的或被卤素取代的C 1 -C 22烷基，C 5 -C 10环烷基，C 7 -C 22烷基，C 6 -C 10芳基或基团-CH 2 -O-R 5或-CH 2 -O -CO-R 5，其中R 5是C 1 -C 22烷基，C 5 -C 6环烷基或C 6 -C 10芳基，R 3是氢，或者R 2和R 3与连接碳原子一起是亚环戊基或亚环己基，R4是4- 带有不饱和端基和羧基或醚基团的12个碳原子，A是单官能或多官能低分子或高分子量羧酸盐或醇化物，x是0-100的整数，n是2-150的整数， dz是1-4的整数，b）10-90重量％的液体多官能脂族，脂环族或芳族（甲基）丙烯酸酯，c）0-70％的单（甲基）丙烯酸酯或单-N-乙烯基分子量不超过500的化合物，d）0.1-10重量％的光引发剂，和e）0-10重量％的任选的常规添加剂。

6. 发明授权

US5461088A Liquid radiation-curable formulation, in particular for use in stereolithography 失效
标题翻译：液体可辐射固化制剂，特别用于立体光刻
公开(公告)号：US5461088A
公开(公告)日：1995-10-24
申请号：US292654
申请日：1994-08-18
申请人： Jean-Pierre Wolf , Adrian Schulthess , Bettina Steinmann , Max Hunziker
发明人： Jean-Pierre Wolf , Adrian Schulthess , Bettina Steinmann , Max Hunziker
IPC分类号： C08F2/44 , C08F2/48 , C08F2/50 , C08F20/10 , C08F20/22 , C08F20/26 , C08F20/34 , C08F20/38 , C08F26/10 , C08F220/18 , C08F220/20 , C08F220/22 , C08F220/26 , C08F220/34 , C08F220/38 , C08F226/10 , C08F283/00 , C08G77/46 , C09D183/12 , G03C9/08 , G03F7/00 , G03F7/032 , G03F7/038 , G03F7/075 , C08F283/06 , G03F7/028
CPC分类号： G03F7/0757 , G03F7/0037
摘要： Liquid radiation-curable formulation, in particular for stereolithography, based on at least one compound that contains free radically polymerisable groups, and at least one photoinitiator suitable for the polymerisation, which formulation additionally contains a polyoxyalkylene-polysiloxane block copolymer that is selected from copolymers of the chemical formulaeR.sup.1 --(OC.sub.c H.sub.2c).sub.d --{[T]--(C.sub.c H.sub.2c O).sub.d-1 --(C.sub.c H.sub.2c)}.sub.g --OR.sup.1 (I) ##STR1## wherein: R.sup.1 is a hydrogen atom or a C.sub.1 -C.sub.8 alkyl group;R.sup.2 is a methyl or phenyl group;[T] is a polysiloxane group [PS] terminated as described in the specification in more detail;[PS] is the group of formula ##STR2## and [Alk] is an alkylene group of 3 to 10 carbon atoms, as well as novel block copolymers of formulae (I) and (II). The cured formulations have, inter alia, superior impact strength.
摘要翻译：基于至少一种含有自由基可聚合基团的化合物，以及至少一种适用于聚合的光引发剂的液体可辐射固化制剂，特别是用于立体光刻法，该制剂还含有聚氧化烯 - 聚硅氧烷嵌段共聚物，该聚氧化烯 - 聚硅氧烷嵌段共聚物选自化学式R1-（OCcH2c）d - {[T] - （CcH2cO）d-1-（CcH2c）} g-OR1（I）（Ⅱ）：其中：R1 是氢原子或C1-C8烷基; R2是甲基或苯基; [T]是如本说明书中更详细地终止的聚硅氧烷基团[PS] [PS]是式[IMAGE]的基团，[Alk]是3至10个碳原子的亚烷基，以及式（I）和（II）的新的嵌段共聚物。固化的制剂尤其具有优异的冲击强度。

7. 发明授权

US06783809B2 Photosensitive diacrylate and dimethacrylate compositions 失效
标题翻译：感光二丙烯酸酯和二甲基丙烯酸酯组合物
公开(公告)号：US06783809B2
公开(公告)日：2004-08-31
申请号：US09953250
申请日：2001-09-17
申请人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
IPC分类号： B05D506
CPC分类号： C07C69/54 , B33Y10/00 , B33Y70/00 , G03F7/027 , Y10S525/922
摘要： A photosensitive composition of (a) a compound of formula (Ia) or (Ib) and (b) a bifunctional acrylate or methacrylate.
摘要翻译：（a）式（Ia）或（Ib）化合物和（b）双官能丙烯酸酯或甲基丙烯酸酯的光敏组合物。

8. 发明授权

US5495029A (Meth)acrylates containing urethane groups 失效
标题翻译：（甲基）丙烯酸酯
公开(公告)号：US5495029A
公开(公告)日：1996-02-27
申请号：US286061
申请日：1994-08-04
申请人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
IPC分类号： C07C271/06 , C07C271/12 , C07C271/24 , C07C271/28 , C07C271/34 , C07C271/36 , C07C271/38 , C07D207/452 , C07D303/16 , C07D303/22 , C08F20/34 , C08F20/36 , C08F222/10 , C08G18/67 , C08G59/02 , C08G59/14 , C09D4/00 , C09D175/14 , C09J175/00 , C09J175/14 , G03F7/00 , G03F7/027
CPC分类号： G03F7/027 , C07C271/12 , C07C271/24 , C07C271/28 , C07C271/34 , C07C271/36 , C07C271/38 , C07D303/16 , C08F20/36 , C08F222/1006 , C08G18/675 , C08G59/1494 , C09D4/00 , G03F7/0037 , C07C2101/14 , C07C2101/16 , C07C2103/70
摘要： Novel (meth)acrylates containing urethane groups Novel (meth)acrylates which also contain urethane groups and other polymerizable groups in one and the same molecule and can be polymerized either by means of free radicals and/or cationically are used for the production of coatings, adhesives, photoresists, solder masks or in stereolithography. The mouldings produced therefrom contain a coherent, homogeneous network and have high strength properties, in particular mechanical properties.
摘要翻译：含有氨基甲酸酯基团的新型（甲基）丙烯酸酯在同一分子中也含有氨基甲酸酯基和其它可聚合基团的新型（甲基）丙烯酸酯可以通过自由基和/或阳离子聚合，用于制备涂料，粘合剂，光致抗蚀剂，焊接掩模或立体光刻。由此产生的模塑制品含有一种连贯的均质网络，并具有高强度特性，特别是机械性能。

9. 发明授权

US5476748A Photosensitive compositions 失效
标题翻译：感光组合物
公开(公告)号：US5476748A
公开(公告)日：1995-12-19
申请号：US166767
申请日：1993-12-14
申请人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
IPC分类号： C08G59/18 , C08F283/00 , C08F283/10 , C08G59/00 , C08G59/14 , C08G59/40 , C08G59/62 , C08G59/68 , C08L63/00 , G03F7/00 , G03F7/027 , G03F7/029 , G03F7/038 , G03C5/00
CPC分类号： G03F7/0037 , C08F283/00 , C08F283/10 , G03F7/038
摘要： The invention relates to photosensitive compositions comprisingA) from 40 to 80% by weight of at least one liquid epoxy resin having an epoxy functionality of equal to or greater than 2,B) from 0.1 to 10% by weight of at least one cationic photoinitiator for component A),C) from 5 to 40% by weight of at least one liquid cycloaliphatic or aromatic diacrylate,D) from 0 to 15% by weight of at least one liquid poly(meth-)acrylate having a (meth-)acrylate functionality of greater than 2, the proportion of component D) constituting a maximum of 50% by weight of the total (meth-)acrylate content,E) from 0.1 to 10% by weight of at least one radical photoinitiator for component C) and, where appropriate, D) andF) from 5 to 40% by weight of at least one OH-terminated polyether, polyester or polyurethane,which are especially suitable, for example, for the manufacture of photopolymerized layers, especially of three-dimensional objects.
摘要翻译：本发明涉及光敏组合物，其包含A）40至80重量％的至少一种环氧官能度等于或大于2的液体环氧树脂，B）0.1至10重量％的至少一种阳离子光引发剂对于组分A），C）5至40重量％的至少一种液体脂环族或芳族二丙烯酸酯，D）0至15重量％的至少一种具有（甲基）丙烯酸酯的液体聚（甲基）丙烯酸酯，丙烯酸酯官能度大于2，组分D）的比例构成最大为总（甲基）丙烯酸酯含量的50重量％，E）0.1至10重量％的至少一种用于组分C的基团光引发剂）以及在适当的情况下，D）和F）5至40重量％的至少一种OH封端的聚醚，聚酯或聚氨酯，其特别适用于制备光聚合层，特别是三维对象

10. 发明授权

US06043323A Diacrylates and dimethacrylates 失效
标题翻译：二丙烯酸酯和二甲基丙烯酸酯
公开(公告)号：US06043323A
公开(公告)日：2000-03-28
申请号：US342955
申请日：1994-11-21
申请人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
IPC分类号： C07B61/00 , C07C69/54 , C08F2/48 , C08F20/30 , G03C1/73 , G03F7/027 , C08F283/10
CPC分类号： C07C69/54 , G03F7/027 , Y10S525/922
摘要： Compounds of formulae (Ia) and (Ib) ##STR1## wherein the substituents R.sub.1 are each independently of the other hydrogen or methyl, R.sub.2 is an unsubstituted C.sub.1 -C.sub.20 alkyl group or a C.sub.1 -C.sub.20 alkyl group which is substituted by one or more than one substituent selected from the group consisting of hydroxy, C.sub.6 -C.sub.14 aryl and halogen, an unsubstituted phenyl group or a phenyl group which is substituted by one or more than one substituent selected from the group consisting of C.sub.1 -C.sub.6 alkyl, hydroxy or halogen, or is a radical of formula --CH.sub.2 --OR.sub.3, wherein R.sub.3 is an unsubstituted C.sub.1 -C.sub.20 alkyl group or a C.sub.1 -C.sub.20 alkyl group which is substituted by one or more than one substituent selected from the group consisting of hydroxy, C.sub.6 -C.sub.14 aryl and halogen, an unsubstituted phenyl group or a phenyl group which is substituted by one or more than one substituent selected from the group consisting of C.sub.1 -C.sub.6 alkyl, hydroxy and halogen, or is a C.sub.2 -C.sub.6 alkenyl group, a C.sub.2 -C.sub.20 acyl group or an unsubstituted cyclohexylcarbonyl group or a cyclohexylcarbonyl group which is substituted by one or more than one substituent selected from the group consisting of C.sub.1 -C.sub.6 alkyl, hydroxy and halogen, Z is a group of formulae (IIa)-(IIe) ##STR2## wherein Y is a direct bond, C.sub.1 -C.sub.6 alkylene, --S--, --O--, --SO--, --SO.sub.2 -- or --CO--, and R.sub.1 is hydrogen or methyl, and wherein the aromatic and cycloaliphatic rings of formulae (IIa)-(IIe) are unsubstituted or substituted by one or more than one substituent selected from the group consisting of C.sub.1 -C.sub.6 alkyl, chloro and bromo, form, in conjunction with other acrylates or methacrylates, low viscosity photocurable compositions which, when fully cured, give moulded articles of excellent flexibility.
摘要翻译：式（Ia）和（Ib）的化合物，其中取代基R 1各自独立地为氢或甲基，R 2为未取代的C 1 -C 20烷基或被一个或多于一个选自以下的取代基取代的C 1 -C 20烷基由羟基，C 6 -C 14芳基和卤素组成的基团，未取代的苯基或被一个或多于一个选自C 1 -C 6烷基，羟基或卤素的取代基取代的苯基，或者是式 -CH2-OR3，其中R3是未取代的C1-C20烷基或被一个或多于一个选自羟基，C 6 -C 14芳基和卤素的取代基取代的C 1 -C 20烷基，未取代的苯基或被一个或多于一个选自C 1 -C 6烷基，羟基和卤素的取代基取代的苯基，或者是C 2 -C 6烯基，C 2 -C 20酰基或未取代的环己基羰基或环由一个或多于一个选自C1-C6烷基，羟基和卤素的取代基取代的环己基羰基，Z是其中Y是直接键的式（IIa） - （IIe）基团，C1-C6亚烷基， -S - ， - O - ， - SO - ， - SO 2 - 或-CO-，并且R 1是氢或甲基，其中式（IIa） - （IIe）的芳族和脂环族环是未取代的或被一个或选自C 1 -C 6烷基，氯和溴的多于一个取代基与其它丙烯酸酯或甲基丙烯酸酯结合形成低粘度可光固化组合物，其在完全固化时得到优异柔性的模制品。

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