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1. 发明授权

US5461088A Liquid radiation-curable formulation, in particular for use in stereolithography 失效
标题翻译：液体可辐射固化制剂，特别用于立体光刻
公开(公告)号：US5461088A
公开(公告)日：1995-10-24
申请号：US292654
申请日：1994-08-18
申请人： Jean-Pierre Wolf , Adrian Schulthess , Bettina Steinmann , Max Hunziker
发明人： Jean-Pierre Wolf , Adrian Schulthess , Bettina Steinmann , Max Hunziker
IPC分类号： C08F2/44 , C08F2/48 , C08F2/50 , C08F20/10 , C08F20/22 , C08F20/26 , C08F20/34 , C08F20/38 , C08F26/10 , C08F220/18 , C08F220/20 , C08F220/22 , C08F220/26 , C08F220/34 , C08F220/38 , C08F226/10 , C08F283/00 , C08G77/46 , C09D183/12 , G03C9/08 , G03F7/00 , G03F7/032 , G03F7/038 , G03F7/075 , C08F283/06 , G03F7/028
CPC分类号： G03F7/0757 , G03F7/0037
摘要： Liquid radiation-curable formulation, in particular for stereolithography, based on at least one compound that contains free radically polymerisable groups, and at least one photoinitiator suitable for the polymerisation, which formulation additionally contains a polyoxyalkylene-polysiloxane block copolymer that is selected from copolymers of the chemical formulaeR.sup.1 --(OC.sub.c H.sub.2c).sub.d --{[T]--(C.sub.c H.sub.2c O).sub.d-1 --(C.sub.c H.sub.2c)}.sub.g --OR.sup.1 (I) ##STR1## wherein: R.sup.1 is a hydrogen atom or a C.sub.1 -C.sub.8 alkyl group;R.sup.2 is a methyl or phenyl group;[T] is a polysiloxane group [PS] terminated as described in the specification in more detail;[PS] is the group of formula ##STR2## and [Alk] is an alkylene group of 3 to 10 carbon atoms, as well as novel block copolymers of formulae (I) and (II). The cured formulations have, inter alia, superior impact strength.
摘要翻译：基于至少一种含有自由基可聚合基团的化合物，以及至少一种适用于聚合的光引发剂的液体可辐射固化制剂，特别是用于立体光刻法，该制剂还含有聚氧化烯 - 聚硅氧烷嵌段共聚物，该聚氧化烯 - 聚硅氧烷嵌段共聚物选自化学式R1-（OCcH2c）d - {[T] - （CcH2cO）d-1-（CcH2c）} g-OR1（I）（Ⅱ）：其中：R1 是氢原子或C1-C8烷基; R2是甲基或苯基; [T]是如本说明书中更详细地终止的聚硅氧烷基团[PS] [PS]是式[IMAGE]的基团，[Alk]是3至10个碳原子的亚烷基，以及式（I）和（II）的新的嵌段共聚物。固化的制剂尤其具有优异的冲击强度。

2. 发明授权

US5495029A (Meth)acrylates containing urethane groups 失效
标题翻译：（甲基）丙烯酸酯
公开(公告)号：US5495029A
公开(公告)日：1996-02-27
申请号：US286061
申请日：1994-08-04
申请人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
IPC分类号： C07C271/06 , C07C271/12 , C07C271/24 , C07C271/28 , C07C271/34 , C07C271/36 , C07C271/38 , C07D207/452 , C07D303/16 , C07D303/22 , C08F20/34 , C08F20/36 , C08F222/10 , C08G18/67 , C08G59/02 , C08G59/14 , C09D4/00 , C09D175/14 , C09J175/00 , C09J175/14 , G03F7/00 , G03F7/027
CPC分类号： G03F7/027 , C07C271/12 , C07C271/24 , C07C271/28 , C07C271/34 , C07C271/36 , C07C271/38 , C07D303/16 , C08F20/36 , C08F222/1006 , C08G18/675 , C08G59/1494 , C09D4/00 , G03F7/0037 , C07C2101/14 , C07C2101/16 , C07C2103/70
摘要： Novel (meth)acrylates containing urethane groups Novel (meth)acrylates which also contain urethane groups and other polymerizable groups in one and the same molecule and can be polymerized either by means of free radicals and/or cationically are used for the production of coatings, adhesives, photoresists, solder masks or in stereolithography. The mouldings produced therefrom contain a coherent, homogeneous network and have high strength properties, in particular mechanical properties.
摘要翻译：含有氨基甲酸酯基团的新型（甲基）丙烯酸酯在同一分子中也含有氨基甲酸酯基和其它可聚合基团的新型（甲基）丙烯酸酯可以通过自由基和/或阳离子聚合，用于制备涂料，粘合剂，光致抗蚀剂，焊接掩模或立体光刻。由此产生的模塑制品含有一种连贯的均质网络，并具有高强度特性，特别是机械性能。

3. 发明授权

US5476748A Photosensitive compositions 失效
标题翻译：感光组合物
公开(公告)号：US5476748A
公开(公告)日：1995-12-19
申请号：US166767
申请日：1993-12-14
申请人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
IPC分类号： C08G59/18 , C08F283/00 , C08F283/10 , C08G59/00 , C08G59/14 , C08G59/40 , C08G59/62 , C08G59/68 , C08L63/00 , G03F7/00 , G03F7/027 , G03F7/029 , G03F7/038 , G03C5/00
CPC分类号： G03F7/0037 , C08F283/00 , C08F283/10 , G03F7/038
摘要： The invention relates to photosensitive compositions comprisingA) from 40 to 80% by weight of at least one liquid epoxy resin having an epoxy functionality of equal to or greater than 2,B) from 0.1 to 10% by weight of at least one cationic photoinitiator for component A),C) from 5 to 40% by weight of at least one liquid cycloaliphatic or aromatic diacrylate,D) from 0 to 15% by weight of at least one liquid poly(meth-)acrylate having a (meth-)acrylate functionality of greater than 2, the proportion of component D) constituting a maximum of 50% by weight of the total (meth-)acrylate content,E) from 0.1 to 10% by weight of at least one radical photoinitiator for component C) and, where appropriate, D) andF) from 5 to 40% by weight of at least one OH-terminated polyether, polyester or polyurethane,which are especially suitable, for example, for the manufacture of photopolymerized layers, especially of three-dimensional objects.
摘要翻译：本发明涉及光敏组合物，其包含A）40至80重量％的至少一种环氧官能度等于或大于2的液体环氧树脂，B）0.1至10重量％的至少一种阳离子光引发剂对于组分A），C）5至40重量％的至少一种液体脂环族或芳族二丙烯酸酯，D）0至15重量％的至少一种具有（甲基）丙烯酸酯的液体聚（甲基）丙烯酸酯，丙烯酸酯官能度大于2，组分D）的比例构成最大为总（甲基）丙烯酸酯含量的50重量％，E）0.1至10重量％的至少一种用于组分C的基团光引发剂）以及在适当的情况下，D）和F）5至40重量％的至少一种OH封端的聚醚，聚酯或聚氨酯，其特别适用于制备光聚合层，特别是三维对象

4. 发明授权

US5629133A Liquid radiation-curable formulation, in particular for use in stereolithography 失效
标题翻译：液体可辐射固化制剂，特别用于立体光刻
公开(公告)号：US5629133A
公开(公告)日：1997-05-13
申请号：US449172
申请日：1995-05-24
申请人： Jean-Pierre Wolf , Adrian Schulthess , Bettina Steinmann , Max Hunziker
发明人： Jean-Pierre Wolf , Adrian Schulthess , Bettina Steinmann , Max Hunziker
IPC分类号： C08F2/44 , C08F2/48 , C08F2/50 , C08F20/10 , C08F20/22 , C08F20/26 , C08F20/34 , C08F20/38 , C08F26/10 , C08F220/18 , C08F220/20 , C08F220/22 , C08F220/26 , C08F220/34 , C08F220/38 , C08F226/10 , C08F283/00 , C08G77/46 , C09D183/12 , G03C9/08 , G03F7/00 , G03F7/032 , G03F7/038 , G03F7/075 , G03C5/00 , C08L83/10
CPC分类号： G03F7/0757 , G03F7/0037
摘要： Liquid radiation-curable formulation, in particular for stereolithography, based on at least one compound that contains radically polymerizable groups, and at least one photoinitiator suitable for the polymerization, which formulation additionally contains a polyoxyalkylene-polysiloxane block copolymer that is selected from copolymers of the chemical formulae ##STR1## wherein: R.sup.1 is a hydrogen atom or a C.sub.1 -C.sub.8 alkyl group;R.sup.2 is a methyl or phenyl group;[T] is a polysiloxane group [PS] terminated as described in the specification in more detail;[PS] is the group of formula ##STR2## and [Alk] is an alkylene group of 3 to 10 carbon atoms, as well as novel block copolymers of formulae (I) and (II). The cured formulations have, inter alia, superior impact strength.
摘要翻译：液体可辐射固化制剂，特别是用于立体光刻法，基于至少一种含可自由基聚合基团的化合物，以及至少一种适用于聚合的光引发剂，该制剂还含有聚氧化烯 - 聚硅氧烷嵌段共聚物，该聚氧化烯 - 聚硅氧烷嵌段共聚物选自化学式和其中：R1是氢原子或C1-C8烷基; R2是甲基或苯基; [T]是如本说明书中更详细地终止的聚硅氧烷基团[PS] [PS]是式[IMAGE]的基团，[Alk]是3至10个碳原子的亚烷基，以及式（I）和（II）的新的嵌段共聚物。固化的制剂尤其具有优异的冲击强度。

5. 发明授权

US5470689A Polymerisable compositions containing tetraacrylates 失效
标题翻译：含有四丙烯酸酯的可聚合组合物
公开(公告)号：US5470689A
公开(公告)日：1995-11-28
申请号：US200982
申请日：1994-02-24
申请人： Jean-Pierre Wolf , Adrian Schulthess , Bettina Steinmann , Max Hunziker
发明人： Jean-Pierre Wolf , Adrian Schulthess , Bettina Steinmann , Max Hunziker
IPC分类号： C08F20/34 , C08F20/10 , C08F290/00 , C08F299/02 , C08G18/67 , C09D4/00 , G03F7/00 , G03F7/027 , G03C5/00
CPC分类号： C08G18/6795 , C08G18/672 , C08G18/6735 , C09D4/00 , G03F7/0037 , G03F7/027
摘要： Photopolymerisable compositions comprising(a) a tetraacrylate of formula I or II ##STR1## wherein R.sub.1 is a hydrogen atom or methyl,X.sub.1 and X.sub.2 are each independently of the other --O-- or --CO--O--,R.sub.2 is a divalent aliphatic, cycloaliphatic or aromatic radical of a diglycidyl compound that contains no more glycidyl ether or ester groups,A is a divalent aliphatic, cycloaliphatic or aromatic radical of a diisocyanate compound that contains no more isocyanate groups,n is an integer from 1 to 8, andR.sub.3 is a tetravalent cycloaliphatic radical of a diepoxide compound that contains no more 1,2-epoxide groups at the cycloaliphatischen ring,(b) at least one liquid radically polymerisable compound that differs from component a), and(c) a radical photoinitiator, are suitable preferably for the production of three-dimensional objects by the stereolithographic technique.
摘要翻译：包含（a）式I或II的四丙烯酸酯的可光聚合组合物其中R 1是氢原子或甲基，X 1和X 2各自独立地是其它的-O-或-CO- O-，R2是不包含缩水甘油醚或酯基的二缩水甘油基化合物的二价脂族，脂环族或芳族基团，A是不含异氰酸酯基团的二异氰酸酯化合物的二价脂族，脂环族或芳族基团，n是 1〜8的整数，R3是在环状环上不含1,2-环氧基的二环氧化合物的四价脂环族基团，（b）与成分a）不同的至少一种液体可自由基聚合的化合物，和（c）自由基光引发剂，优选用于通过立体光刻技术生产三维物体。

6. 发明授权

US5658712A (Meth)acrylates containing urethane groups 失效
标题翻译：（甲基）丙烯酸酯
公开(公告)号：US5658712A
公开(公告)日：1997-08-19
申请号：US552643
申请日：1995-11-03
申请人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
IPC分类号： C07C271/06 , C07C271/12 , C07C271/24 , C07C271/28 , C07C271/34 , C07C271/36 , C07C271/38 , C07D207/452 , C07D303/16 , C07D303/22 , C08F20/34 , C08F20/36 , C08F222/10 , C08G18/67 , C08G59/02 , C08G59/14 , C09D4/00 , C09D175/14 , C09J175/00 , C09J175/14 , G03F7/00 , G03F7/027 , C07C271/00
CPC分类号： G03F7/027 , C07C271/12 , C07C271/24 , C07C271/28 , C07C271/34 , C07C271/36 , C07C271/38 , C07D303/16 , C08F20/36 , C08F222/1006 , C08G18/675 , C08G59/1494 , C09D4/00 , G03F7/0037 , C07C2101/14 , C07C2101/16 , C07C2103/70
摘要： Novel (meth)acrylates which also contain urethane groups and other polymerizable groups in one and the same molecule and can be polymerized either by means of free radicals and/or cationically are used for the production of coatings, adhesives, photoresists, solder masks or in stereolithography. The mouldings produced therefrom contain a coherent, homogeneous network and have high strength properties, in particular mechanical properties.
摘要翻译：在同一分子中也含有氨基甲酸酯基团和其它可聚合基团的新型（甲基）丙烯酸酯可以通过自由基和/或阳离子聚合，用于制备涂料，粘合剂，光致抗蚀剂，防焊剂或在立体光刻。由此产生的模塑制品含有一种连贯的均质网络，并具有高强度特性，特别是机械性能。

7. 发明授权

US5599651A (Cyclo)aliphatic epoxy compounds 失效
标题翻译：（Cyclo）脂肪族环氧化合物
公开(公告)号：US5599651A
公开(公告)日：1997-02-04
申请号：US517888
申请日：1995-08-21
申请人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
IPC分类号： C07D303/40 , C08G59/20 , C08G59/24 , C08G59/32 , G03F7/027 , G03L5/00 , C07D303/38
CPC分类号： G03F7/027 , C07D303/40 , C08G59/24 , C08G59/3218
摘要： Novel (cyclo)aliphatic epoxy compounds that contain at least one acrylate group in the molecule and at least one cycloaliphatic epoxy group can be used for the production of coating formulations, adhesives, photoresists or in stereolithography. As they contain a cohesive homogeneous network, the three-dimensional objects produced have very good green strength and very good strength properties.
摘要翻译：在分子中含有至少一个丙烯酸酯基团和至少一个环脂族环氧基团的新型（环状）脂族环氧化合物可用于制备涂料配方，粘合剂，光致抗蚀剂或立体光刻。由于它们含有内聚的均匀网络，所生产的三维物体具有非常好的生坯强度和非常好的强度性能。

8. 发明授权

US5468886A (Cyclo)aliphatic epoxy compounds 失效
标题翻译：（Cyclo）脂肪族环氧化合物
公开(公告)号：US5468886A
公开(公告)日：1995-11-21
申请号：US169938
申请日：1993-12-20
申请人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Jean-Pierre Wolf , Adrian Schulthess , Max Hunziker
IPC分类号： C07D303/40 , C08G59/20 , C08G59/24 , C08G59/32 , G03F7/027 , C07D303/38 , G03C5/00
CPC分类号： G03F7/027 , C07D303/40 , C08G59/24 , C08G59/3218
摘要： Novel (cyclo)aliphatic epoxy compounds that contain at least one acrylate group in the molecule and at least one cycloaliphatic epoxy group can be used for the production of coating formulations, adhesives, photoresists or in stereolithography. As they contain a cohesive homogeneous network, the three-dimensional objects produced have very good green strength and very good strength properties.
摘要翻译：在分子中含有至少一个丙烯酸酯基团和至少一个环脂族环氧基团的新型（环状）脂族环氧化合物可用于制备涂料配方，粘合剂，光致抗蚀剂或立体光刻。由于它们含有内聚的均匀网络，所生产的三维物体具有非常好的生坯强度和非常好的强度性能。

9. 发明授权

US5487966A Photosensitive compositions 失效
标题翻译：感光组合物
公开(公告)号：US5487966A
公开(公告)日：1996-01-30
申请号：US231953
申请日：1994-04-21
申请人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
IPC分类号： C08G63/00 , B29C67/00 , C08G63/52 , C08G63/58 , C08J5/00 , G03F7/00 , G03F7/027 , G03F7/029 , G03F7/032 , G03C5/00 , G03C1/492 , G03C1/725
CPC分类号： C08G63/52 , C08G63/58 , G03F7/0037 , G03F7/032
摘要： Photosensitive compositions comprisinga) 5-95% by weight of a polyester of formula I, II or III ##STR1## wherein R.sub.1 is the radical of a cyclic anhydride of a dicarboxylic acid after removal of the --O--CO--O-- grouping, which radical may be substituted by C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.6 -C.sub.10 aryl, halogen or C.sub.1 -C.sub.22 alkyl which is interrupted by --O-- or --CO--O--,R.sub.2 is hydrogen, unsubstituted or halogen-substituted C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.10 cycloalkyl, C.sub.7 -C.sub.22 aralkyl, C.sub.6 -C.sub.10 aryl or a radical --CH.sub.2 --O--R.sub.5 or --CH.sub.2 --O--CO--R.sub.5, wherein R.sub.5 is C.sub.1 -C.sub.22 alkyl, C.sub.5 -C.sub.6 cycloalkyl or C.sub.6 -C.sub.10 aryl,R.sub.3 is hydrogen, orR.sub.2 and R.sub.3, together with the linking carbon atoms, are a cyclopentylene or cyclohexylene radical,R.sub.4 is a radical of 4 to 12 carbon atoms which carries an unsaturated end group and carboxyl or ether groups,A is a mono- or polyfunctional low molecular or high molecular carboxylate or alcoholate,x is an integer from 0-100,n is an integer from 2-150, andz is an integer from 1-4,b) 10-90% by weight of a liquid polyfunctional aliphatic, cycloaliphatic or aromatic (meth)acrylate,c) 0-70% of a mono(meth)acrylate or mono-N-vinyl compound with a molecular weight of not more than 500,d) 0.1-10% by weight of a photoinitiator, ande) 0-10% by weight of optional customary additives.
摘要翻译：包含a）5-95重量％的式I，II或III的聚酯的方法，其中R 1是基团（R 1）的C 1 -C 22烷基，C 5 -C 10环烷基，C 3 -C 6烯基，C 6 -C 10芳基，卤素或C 1 -C 22烷基取代的-O-CO-O-基团后的二羧酸的环状酸酐，其为被-O-或-CO-O-中断，R 2是氢，未取代的或被卤素取代的C 1 -C 22烷基，C 5 -C 10环烷基，C 7 -C 22烷基，C 6 -C 10芳基或基团-CH 2 -O-R 5或-CH 2 -O -CO-R 5，其中R 5是C 1 -C 22烷基，C 5 -C 6环烷基或C 6 -C 10芳基，R 3是氢，或者R 2和R 3与连接碳原子一起是亚环戊基或亚环己基，R4是4- 带有不饱和端基和羧基或醚基团的12个碳原子，A是单官能或多官能低分子或高分子量羧酸盐或醇化物，x是0-100的整数，n是2-150的整数， dz是1-4的整数，b）10-90重量％的液体多官能脂族，脂环族或芳族（甲基）丙烯酸酯，c）0-70％的单（甲基）丙烯酸酯或单-N-乙烯基分子量不超过500的化合物，d）0.1-10重量％的光引发剂，和e）0-10重量％的任选的常规添加剂。

10. 发明授权

US06043323A Diacrylates and dimethacrylates 失效
标题翻译：二丙烯酸酯和二甲基丙烯酸酯
公开(公告)号：US06043323A
公开(公告)日：2000-03-28
申请号：US342955
申请日：1994-11-21
申请人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
发明人： Bettina Steinmann , Adrian Schulthess , Max Hunziker
IPC分类号： C07B61/00 , C07C69/54 , C08F2/48 , C08F20/30 , G03C1/73 , G03F7/027 , C08F283/10
CPC分类号： C07C69/54 , G03F7/027 , Y10S525/922
摘要： Compounds of formulae (Ia) and (Ib) ##STR1## wherein the substituents R.sub.1 are each independently of the other hydrogen or methyl, R.sub.2 is an unsubstituted C.sub.1 -C.sub.20 alkyl group or a C.sub.1 -C.sub.20 alkyl group which is substituted by one or more than one substituent selected from the group consisting of hydroxy, C.sub.6 -C.sub.14 aryl and halogen, an unsubstituted phenyl group or a phenyl group which is substituted by one or more than one substituent selected from the group consisting of C.sub.1 -C.sub.6 alkyl, hydroxy or halogen, or is a radical of formula --CH.sub.2 --OR.sub.3, wherein R.sub.3 is an unsubstituted C.sub.1 -C.sub.20 alkyl group or a C.sub.1 -C.sub.20 alkyl group which is substituted by one or more than one substituent selected from the group consisting of hydroxy, C.sub.6 -C.sub.14 aryl and halogen, an unsubstituted phenyl group or a phenyl group which is substituted by one or more than one substituent selected from the group consisting of C.sub.1 -C.sub.6 alkyl, hydroxy and halogen, or is a C.sub.2 -C.sub.6 alkenyl group, a C.sub.2 -C.sub.20 acyl group or an unsubstituted cyclohexylcarbonyl group or a cyclohexylcarbonyl group which is substituted by one or more than one substituent selected from the group consisting of C.sub.1 -C.sub.6 alkyl, hydroxy and halogen, Z is a group of formulae (IIa)-(IIe) ##STR2## wherein Y is a direct bond, C.sub.1 -C.sub.6 alkylene, --S--, --O--, --SO--, --SO.sub.2 -- or --CO--, and R.sub.1 is hydrogen or methyl, and wherein the aromatic and cycloaliphatic rings of formulae (IIa)-(IIe) are unsubstituted or substituted by one or more than one substituent selected from the group consisting of C.sub.1 -C.sub.6 alkyl, chloro and bromo, form, in conjunction with other acrylates or methacrylates, low viscosity photocurable compositions which, when fully cured, give moulded articles of excellent flexibility.
摘要翻译：式（Ia）和（Ib）的化合物，其中取代基R 1各自独立地为氢或甲基，R 2为未取代的C 1 -C 20烷基或被一个或多于一个选自以下的取代基取代的C 1 -C 20烷基由羟基，C 6 -C 14芳基和卤素组成的基团，未取代的苯基或被一个或多于一个选自C 1 -C 6烷基，羟基或卤素的取代基取代的苯基，或者是式 -CH2-OR3，其中R3是未取代的C1-C20烷基或被一个或多于一个选自羟基，C 6 -C 14芳基和卤素的取代基取代的C 1 -C 20烷基，未取代的苯基或被一个或多于一个选自C 1 -C 6烷基，羟基和卤素的取代基取代的苯基，或者是C 2 -C 6烯基，C 2 -C 20酰基或未取代的环己基羰基或环由一个或多于一个选自C1-C6烷基，羟基和卤素的取代基取代的环己基羰基，Z是其中Y是直接键的式（IIa） - （IIe）基团，C1-C6亚烷基， -S - ， - O - ， - SO - ， - SO 2 - 或-CO-，并且R 1是氢或甲基，其中式（IIa） - （IIe）的芳族和脂环族环是未取代的或被一个或选自C 1 -C 6烷基，氯和溴的多于一个取代基与其它丙烯酸酯或甲基丙烯酸酯结合形成低粘度可光固化组合物，其在完全固化时得到优异柔性的模制品。

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