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1. 发明授权

US4020037A Process for the spin-dyeing of polymers or copolymers of acrylonitrile 失效
标题翻译：丙烯腈聚合物或共聚物的纺丝染色方法
公开(公告)号：US4020037A
公开(公告)日：1977-04-26
申请号：US527414
申请日：1974-11-26
申请人： Manfred Hahnke , Theodor Papenfuhs , Wolfgang Teige
发明人： Manfred Hahnke , Theodor Papenfuhs , Wolfgang Teige
IPC分类号： C08L33/00 , C08J3/20 , C08K5/00 , C08L33/02 , C08L33/04 , C08L33/18 , D01F6/18 , D01F6/54 , D06P3/76 , C08L33/20 , D01F1/06
CPC分类号： D01F6/18 , C08K5/0041 , D01F1/06 , D01F6/38
摘要： The novel improved process of the invention for spin-dyeing of acid-modified polymers or copolymers of acrylonitrile with basic dyestuffs wherein the spinning solutions of the polymers contain the basic dyestuffs in form of their free dyestuff bases as anhydro or carbinol bases is conducted with completely transparent spinning solutions avoiding clogging and mechanical abrasion of the spinning nozzles and yields filaments and fibers which do not show matting effects but have a high tinctorial strength and good and improved fastnesses to rubbing, to light and to wet-processing.
摘要翻译：酸改性聚合物或丙烯腈共聚物与碱性染料的纺丝染色的本发明改进方法，其中聚合物的纺丝溶液含有作为脱水或甲醇碱的游离染料碱形式的碱性染料，完全用透明的纺丝溶液，避免纺丝喷嘴的堵塞和机械磨损，并产生细丝和纤维，其不显示消光效果，但具有高着色强度，并且具有良好和改善的耐摩擦牢度，耐光照和湿润加工性。

2. 发明授权

US4265632A Process for the coloration of thermoplastic polymers and polycondensates in the mass with water-insoluble disazomethine compounds 失效
标题翻译：用水不溶性二氮唑并嗪化合物着色热塑性聚合物和缩聚物的方法
公开(公告)号：US4265632A
公开(公告)日：1981-05-05
申请号：US96473
申请日：1979-11-21
申请人： Theodor Papenfuhs , Wolfgang Teige
发明人： Theodor Papenfuhs , Wolfgang Teige
IPC分类号： C08K5/00 , C09B55/00 , D01F1/06 , D01F6/62 , D06P3/52 , C08J5/00
CPC分类号： D01F6/62 , C08K5/0091 , C09B55/005 , D01F1/06 , Y10S8/922
摘要： For coloring in the mass and spin dyeing water-insoluble thermoplastic polymers and polycondensates, especially polyesters, nickel complex disazomethine compounds are used having the general formula (1) ##STR1## in which A and B have the same meaning or are different from each other and each is an isocyclic or heterocyclic residue. The coloring compounds can be added to the polymeric material without previous dispersion. They are dissolved in said material in molecular disperse form so that generally brilliant and clear colorations are obtained. In spin dyeing the filaments substantially retain their high strength and drawing properties; abrasion and clogging of the nozzles or filters do not occur. The colorations are distinguished by a high color strength as well as by high fastnesses to light and to weather and by a good stability in thermofixation.
摘要翻译：为了在质量和旋转染色的水不溶性热塑性聚合物和缩聚物，特别是聚酯中着色，使用具有通式（1）（1）的镍络合物二氮代吗啉化合物，其中A和B具有相同的含义或不同彼此间各自为一个环状或杂环的残基。可以将着色化合物加入到聚合物材料中，而无需先前的分散。它们以分子分散形式溶解在所述材料中，从而获得通常的明亮和清晰的着色。在纺丝染色中，长丝基本保持其高强度和拉伸性能; 不会发生喷嘴或过滤器的磨损和堵塞。着色的特征在于高的着色强度以及高耐光牢度和耐候性以及在热固化中的良好稳定性。

3. 发明授权

US4294749A Process for the coloration of thermoplastic polymers and polycondensates in the mass with water-insoluble disazo-methine compounds 失效
标题翻译：用水不溶性二偶氮次甲基化合物使质量的热塑性聚合物和缩聚物着色的方法
公开(公告)号：US4294749A
公开(公告)日：1981-10-13
申请号：US107936
申请日：1979-12-28
申请人： Theodor Papenfuhs , Wolfgang Teige
发明人： Theodor Papenfuhs , Wolfgang Teige
IPC分类号： C08K5/00 , C08K5/16 , C08L67/00 , C09B45/32 , C09B55/00
CPC分类号： C08K5/0091
摘要： For coloring in the mass and spin dyeing water-insoluble thermoplastic polymers and polycondensates, especially polyesters, nickel complex disazomethine compounds are used consisting of 2 molecules of 2-hydroxy-naphthaldehyde possibly substituted in 6-position by halogen, cyano, carboxy, a carboxylic acid alkyl ester or an optionally substituted carboxylic acid amide group, and 1 molecule of an o-phenylene diamine possibly substituted in 4 and 5-position by non-ionic substituents, the nickel atoms being bound in complex manner to the nitrogen atoms of the phenylene diamine and the oxyen atoms of the hydroxynaphthaldehyde. Disazomethine compounds in which the phenylene diamine radical is unsubstituted if the hydroxynaphthaldehyde radical is not substituted in 6-position are excluded. The coloring compounds can be added to the polymeric material without previous dispersion. They dissolved in said material in molecular disperse form so that generally brilliant and clear colorations are obtained. In spin dyeing the filaments substantially retain their high strength and drawing properties; abrasion and clogging of the nozzles or filters do not occur. The colorations are distinguished by a high color strength as well as by high fastnesses to light and to weather and by a good stability in thermofixation.
摘要翻译：为了在质量和旋转染色水不溶性热塑性聚合物和缩聚物，特别是聚酯中着色，使用镍复合二氮唑并嗪化合物，其由2分子的2-羟基 - 萘醛在6位上被卤素，氰基，羧基，羧基酸性烷基酯或任选取代的羧酸酰胺基，以及1分子的可能在4位和5位被非离子取代基取代的邻苯二胺，镍原子以亚苯基的氮原子复合结合二胺和羟基萘醛的氧原子。如果羟基萘醛基团在6位没有被取代，其中亚苯基二胺基团未被取代的二氮嗪类化合物被排除。可以将着色化合物加入到聚合物材料中，而无需先前的分散。它们以分子分散形式溶解在所述材料中，从而获得通常的明亮和清晰的着色。在纺丝染色中，长丝基本保持其高强度和拉伸性能; 不会发生喷嘴或过滤器的磨损和堵塞。着色的特征在于高的着色强度以及高耐光牢度和耐候性以及在热固化中的良好稳定性。

4. 发明授权

US4445904A Process for continuously dyeing in the gel state fiber material of acrylonitrile polymers spun from organic solvents with carbinol- or anhydro base of basic dye 失效
标题翻译：丙烯腈聚合物凝胶状态纤维材料连续染色的方法，用丙烯腈聚合物从有机溶剂与碱性染料的甲醇或脱氢碱
公开(公告)号：US4445904A
公开(公告)日：1984-05-01
申请号：US434374
申请日：1982-10-14
申请人： Manfred Hahnke , Wolfgang Teige
发明人： Manfred Hahnke , Wolfgang Teige
IPC分类号： C09B11/10 , C09B11/26 , D01F1/06 , D06P3/70 , D06P1/41
CPC分类号： D01F1/06 , C09B11/10 , C09B11/26 , D06P3/702 , Y10S8/927
摘要： A process for the continuous dyeing of fiber material of one or more acid-modified polymers or copolymers of acrylonitrile in the gel state, said fiber material having been produced by wet spinning from a spinning solution containing one or more organic solvents, which process comprises dyeing the fiber material with a solution of a carbinol base or anhydro base of a carboxyl- or sulfo-free N-arylated triarylmethane dyestuff, a carboxyl- or sulfo-free N-arylated diarylindolylmethane dyestuff, a carboxyl- or sulfo-free N-arylated diaryloxazine dyestuff, a carboxyl- or sulfo-free N-arylated diarylxanthene dyestuff, or a carboxyl- or sulfo-free N-arylated diarylazine dyestuff in a dye bath containing water and the organic spinning solvent or solvents.
摘要翻译：一种在凝胶状态下连续染色一种或多种酸改性聚合物或丙烯腈共聚物的纤维材料的方法，所述纤维材料是通过从含有一种或多种有机溶剂的纺丝溶液进行湿法纺丝制备的，该方法包括染色具有羧基或无磺基的N-芳基化三芳基甲烷染料的甲醇碱或脱水碱的溶液的纤维材料，不含羧基或无磺酸的N-芳基化二芳基甲基吲哚甲烷染料，不含羧基或无磺酸的N-芳基化二氧杂环丙烷染料，不含羧基或无磺酸的N-芳基化二芳基呫吨染料，或含有羧基或磺基的N-芳基化二芳基芳基染料，在含有水的有机纺丝溶剂或溶剂的染浴中。

5. 发明授权

US3960591A Process for the preparation of pigment compositions for the dope dyeing of polyacrylonitrile 失效
标题翻译：制备用于聚丙烯腈染色的颜料组合物的方法
公开(公告)号：US3960591A
公开(公告)日：1976-06-01
申请号：US441936
申请日：1974-02-13
申请人： Reinhold Deubel , Volker Hemmerling , Werner Reitz , Wolfgang Teige
发明人： Reinhold Deubel , Volker Hemmerling , Werner Reitz , Wolfgang Teige
IPC分类号： C08J3/22 , C09B41/00 , C09B67/20 , C09C3/10
CPC分类号： C08J3/226 , C09B41/001 , C09B41/003 , C09B67/006 , C08J2333/20 , C08J2433/00
摘要： A pigment composition for the dyeing of polyacrylonitrile polymers and copolymers prepared by adding a polyacrylonitrile polymer or copolymer as a support in the preparation of formation of the pigment and working up the pigment in usual manner.As support material there are suitable as well pure polyacrylonitrile as copolymers containing, in addition to acrylonitrile, one or more other copolymerizable monoolefinic monomers.The amount of support material to be added ranges from 20 to 80, preferably from 30 to 60% by weight, calculated on the finished composition. As pigments there may be used those which are prepared or formed in purely aqueous systems or in aqueous systems containing organic solvents, for example azo pigments or pigments of perylene tetracarboxylic acid or naphthalene tetracarboxylic acid, dioxazines, phthalocyanines, quinacridones, indigoids, anthraquinone dyestuffs, iron oxide and titanium dioxide.The pulverulent compositions thus obtained are especially suitable for the dyeing of spinning solutions of polyacrylonitrile fibers and the modifications thereof. They may be dispersed by simply stirring them into an appropriate spinning solvent.
摘要翻译：用于染色聚丙烯腈聚合物和共聚物的颜料组合物通过将聚丙烯腈聚合物或共聚物作为载体加入到制备颜料的制备中并以常规方式处理颜料而制备。

6. 发明授权

US4405734A Process for mass coloring thermoplastic plastics 失效
标题翻译：大量着色热塑性塑料的工艺
公开(公告)号：US4405734A
公开(公告)日：1983-09-20
申请号：US414812
申请日：1982-09-03
申请人： Otto Fuchs , Adolf Kroh , Wolfgang Teige
发明人： Otto Fuchs , Adolf Kroh , Wolfgang Teige
IPC分类号： C08L67/00 , C08G63/00 , C08G63/16 , C08K5/34 , C08K5/3412 , C08K5/3437 , C08K5/3447 , C08L1/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L51/00 , C08L51/02 , C08L67/02 , C08L77/00 , C08L101/00 , C09B57/12 , D01F1/06 , D01F6/62 , D06P3/52
CPC分类号： C08K5/3447 , C09B57/12 , D01F1/06
摘要： The invention relates to a process for coloring water-insoluble thermoplastic plastics with dyestuffs of the formula ##STR1## The dyestuffs are added to the melt of the thermoplastic plastic or to its precursors.
摘要翻译：本发明涉及用下式染料的不溶于水的热塑性塑料着色的方法：将染料加入到热塑性塑料或其前体的熔体中。

7. 发明授权

US4097444A Process for the dyeing of water-insoluble thermoplastic polymers and polycondensates in the mass 失效
标题翻译：不溶于水的热塑性聚合物和缩聚物的质量染色方法
公开(公告)号：US4097444A
公开(公告)日：1978-06-27
申请号：US772573
申请日：1977-02-28
申请人： Wolfgang Teige , Rudolf Schickfluss
发明人： Wolfgang Teige , Rudolf Schickfluss
IPC分类号： C08K5/00 , C08K5/35 , C08L1/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L67/00 , C08L67/02 , C08L77/00 , C09B23/00 , C09B23/01 , C09B23/06 , C09B57/00 , C09B69/00 , D06P5/00
CPC分类号： C09B57/00 , C08K5/35 , C09B23/0075 , C09B23/06
摘要： Process for the dyeing of a water-insoluble thermoplastic polymer or polycondensate in mass, which comprises adding to the said thermoplastic material before the final molding thereof, an azlactone dyestuff of the formula (1) ##STR1## in which A and B each represents phenyl, lower alkyl-phenyl, lower alkoxy-phenyl, chlorophenyl, nitrophenyl, cyanophenyl, ##STR2## METHYLENE-DIOXY-PHENYLENE OR NAPHTHYL, A and B being identical or different, D represents phenylene, lower alkyl-phenylene, di-lower alkoxy-phenylene, monochlorophenylene, dichlorophenylene, biphenylene or naphthylene, and n represents the integer 0 or 1, or a mixture of dyestuffs of the said formula (1), the dyeings so obtained representing brilliant yellow dyeings of high tinctorial strength being distinguished by very good fastness to light, rubbing and ironing, and, particularly, by an outstanding stability toward heat.
摘要翻译：用于染色水不溶性热塑性聚合物或缩聚物的方法，其包括在其最终模塑之前向所述热塑性材料中加入式（1）的吖内酯染料（1），其中A和 B各自表示苯基，低级烷基 - 苯基，低级烷氧基 - 苯基，氯苯基，硝基苯基，氰基苯基，亚甲基 - 二苯基或萘基，A和B相同或不同，D表示亚苯基，低级烷基亚苯基，二 - 低级烷氧基 - 亚苯基，一氯代亚苯基，二氯亚苯基，亚联苯基或亚萘基，n表示整数0或1，或所述式（1）的染料混合物，所得到的代表亮度高的亮黄染色的染色被区分通过非常好的耐光牢度，摩擦和熨烫，特别是通过对热量的突出的稳定性。

8. 发明授权

US4782111A Colorant formulation 失效
标题翻译：着色剂配方
公开(公告)号：US4782111A
公开(公告)日：1988-11-01
申请号：US939261
申请日：1986-12-05
申请人： Peter Klein , Bernd Dewald , Wolfgang Teige
发明人： Peter Klein , Bernd Dewald , Wolfgang Teige
IPC分类号： C08L67/00 , C08J3/20 , C08J3/22 , C08K5/00 , C08K9/04 , C08L67/02
CPC分类号： C08J3/226 , C08K5/0041 , C08J2367/02 , C08J2467/00
摘要： A colorant formulation is described for mass-coloring high-melting polyesters. It comprises colorant and support for the colorant. The colorant formulation has a recrystallization exotherm of 8 to 55 joule/g between 210.degree. C. and 150.degree. C.
摘要翻译：描述着色剂配方用于大量着色高熔点聚酯。它包括用于着色剂的着色剂和载体。着色剂配方在210℃至150℃之间具有8至55焦耳/克的重结晶放热。

9. 发明授权

US4732573A Novel dye salts of cationic dyes, having thiocyanatometallate or cyanatometallate complex anions for spin dyeing acid modified polyacrylonitrile 失效
标题翻译：阳离子染料的新型染料盐，具有硫氰酸金属盐酸盐或氰酸金属盐酸盐复合阴离子用于纺丝染色酸改性聚丙烯腈
公开(公告)号：US4732573A
公开(公告)日：1988-03-22
申请号：US945761
申请日：1986-12-23
申请人： Kurt Hohmann , Peter Mischke , Wolfgang Teige
发明人： Kurt Hohmann , Peter Mischke , Wolfgang Teige
IPC分类号： C09B69/02 , C09B69/06 , C09B23/10 , D01F6/18 , D06P3/76
CPC分类号： C09B69/06 , Y10S8/927
摘要： Dye salts of a mono- or polycationic dye where the anion conforms to a general formula (1) or (2)[Me (XCN).sub.4 ].sup.2(-) (1)[Me (SCN).sub.6 ].sup.n(-) (2)in whichMe in the formula (1) is the divalent zinc cation, the divalent iron cation, the divalent cobalt cation, the divalent tin cation or the divalent copper cation, andMe in the formula (2) stands for the divalent iron cation, the divalent nickel cation or the trivalent iron cation,X stands for an oxygen or sulfur atom andn depending on the valency of the corresponding metal cation, denotes the number 4 or 3.The novel dye salts can be obtained for example from aqueous solution or suspension by reacting the corresponding cationic dye which has a customary anion with a metal cation Me donor compound and an alkali metal thiocyanate or cyanate, alkaline earth metal thiocyanate or cyanate or ammonium thiocyanate or cyanate. They are used in particular in the spin-dyeing of acid-modified polyacrylonitrile and copolymers thereof.
摘要翻译：阴离子符合通式（1）或（2）[Me（XCN）4] 2（ - ）（1）[Me（SCN）6] n（ - ）（1）的单 - 或多阳离子染料的染料盐 2）其中式（1）中的Me是二价锌阳离子，二价铁阳离子，二价钴阳离子，二价锡阳离子或二价铜阳离子，和式（2）中的Me代表二价铁阳离子，二价镍阳离子或三价铁阳离子，X代表氧或硫原子，n取决于相应的金属阳离子的化合价，表示数4或3.新的染料盐可以例如由水溶液通过使具有常规阴离子的相应的阳离子染料与金属阳离子Me给体化合物和碱金属硫氰酸盐或氰酸盐，碱土金属硫氰酸盐或氰酸盐或硫氰酸铵或氰酸铵反应而使溶液或悬浮液反应。它们特别用于酸改性聚丙烯腈的旋染和其共聚物。

10. 发明授权

US4235641A Dyeing agent compositions based on polypropylene wax 失效
标题翻译：基于聚丙烯蜡的染色剂组合物
公开(公告)号：US4235641A
公开(公告)日：1980-11-25
申请号：US53032
申请日：1979-06-28
申请人： Manfred Engelmann , Karl Maier , Arno Spange , Bernd Dewald , Hans-Joachim Lenz , Wolfgang Teige
发明人： Manfred Engelmann , Karl Maier , Arno Spange , Bernd Dewald , Hans-Joachim Lenz , Wolfgang Teige
IPC分类号： C08L23/00 , C08J3/22 , C08L7/00 , C08L21/00 , C08L23/12 , C08L101/00
CPC分类号： C08J3/226 , C08J2323/02 , C08J2423/00
摘要： Preparations of insoluble colorants, especially pigments, are obtained by distributing the colorant in molten polypropylene wax having a viscosity of 0.5 to 5 Pa.s, determined at 170.degree. C., and an isotactic proportion of 40 to 90% by weight. These preparations are easily dispersible in polyolefins and especially useful for dyeing polypropylene in the mass.
摘要翻译：不溶性着色剂，特别是颜料的制备通过将着色剂分散在熔融聚丙烯蜡中而获得，所述熔融聚丙烯蜡的粘度为170℃，粘度为0.5-5秒，全同立构比例为40-90重量％。这些制剂易于分散在聚烯烃中，特别适用于在质量上染色聚丙烯。

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