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    • 2. 发明授权
    • Method for continuously preparing water-soluble azo dye by coupling a nebulizer with a pipeline
    • 通过将雾化器与管道连接连续制备水溶性偶氮染料的方法
    • US09394445B2
    • 2016-07-19
    • US14384070
    • 2012-11-30
    • DALIAN UNIVERSITY OF TECHNOLOGY
    • Shufen ZhangBingtao TangRongwen LvDong Liang
    • C09B41/00C09B62/44
    • C09B41/008C09B41/006C09B62/4413
    • Disclosed is a method for continuously preparing a water-soluble azo dye by coupling a nebulizer with a pipeline. According to the method, the nebulizer is coupled with a pipeline with an interception tower plate, atomized and mixed reaction liquid flow flows through the pipeline with the interception tower plate, and mixing and reacting are further enhanced through turbulent mixing on the tower plate, so that instant separation of reaction heat generated in an atomizing contact reaction from a reactant is achieved, and normal-temperature rapid continuous production of the water-soluble azo dye is achieved. Fog drops which are atomized by using the nebulizer have small particle diameter and large specific surface area, so that a diazo salt and a coupling component are sprayed separately, move face to face and can be fully contacted, and mixing and reacting speeds are increased. The preparation method is simple, and compared with preparation of a dye of the same kind with a batch reactor, in the reparation process of the water-soluble azo dye, a cold source is not required to be added additionally for cooling, thereby reducing energy consumption and improving production quality and efficiency.
    • 公开了通过将喷雾器与管道连接来连续制备水溶性偶氮染料的方法。 根据该方法,喷雾器与拦截塔板管道耦合,雾化混合反应液流通过拦截塔板流过管道,混合反应进一步通过塔板上的紊流混合而增强, 实现了在雾化接触反应中从反应物产生的反应热的即时分离,并且实现了常温快速连续生产水溶性偶氮染料。 使用雾化器雾化的雾滴具有较小的粒径和较大的比表面积,使得重氮盐和偶联组分分别喷涂,面对面地进行移动并且可以完全接触,并且混合和反应速度提高。 制备方法简单,与间歇式反应器制备同型染料相比,在水溶性偶氮染料的制备过程中,不需要另外加入冷源进行冷却,从而降低能量 消费,提高生产质量和效率。