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1. 发明授权

US4517141A Production of microcapsules having walls of polyaddition products of water-insoluble polyamines with water-soluble polyisocyanate adducts 失效
标题翻译：生产具有水不溶性聚胺与水溶性多异氰酸酯加合物的加聚产物壁的微胶囊
公开(公告)号：US4517141A
公开(公告)日：1985-05-14
申请号：US506451
申请日：1983-06-21
申请人： Manfred Dahm , Norbert Weimann , Ulrich Nehen , Hanns P. Muller , Gert Jabs , Albert Awater , James M. Barnes
发明人： Manfred Dahm , Norbert Weimann , Ulrich Nehen , Hanns P. Muller , Gert Jabs , Albert Awater , James M. Barnes
IPC分类号： B01J13/16 , B41M5/165 , C08G18/32 , C08G18/80 , B01J13/02
CPC分类号： C08G18/8083 , B01J13/16 , B41M5/165 , C08G18/3253 , Y10S428/914 , Y10S430/104 , Y10T428/2985 , Y10T428/2989
摘要： Microcapsules having a hydrophobic core material and capsule walls formed by the reaction of water-insoluble polyamines with water-soluble bisulphite adducts of polyisocyanates, a process for the production thereof which is characterized in that a mixture of a hydrophobic core material and water-insoluble polyamines is emulsified in water or in an aqueous protective colloid solution to the required particle size, water-soluble bisulphite adducts of polyisocyanates in the form of powders or aqueous solutions are added and the mixture is left to react to completion at temperatures of from 1.degree. to 140.degree. C., and applications thereof.
摘要翻译：具有疏水性芯材的微胶囊和通过水不溶性多胺与多异氰酸酯的水溶性亚硫酸氢盐加合物的反应形成的胶囊壁，其制造方法，其特征在于，疏水性芯材料与水不溶性多胺在水中或在水性保护胶体溶液中乳化至所需的粒度，加入粉末或水溶液形式的多异氰酸酯的水溶性亚硫酸氢盐加合物，使混合物在1℃至 140℃，及其应用。

2. 发明授权

US4592957A Microcapsules having walls of polyaddition products of water-insoluble polyamines with water-soluble polyisocyanate adducts 失效
标题翻译：具有水不溶性聚胺与水溶性聚异氰酸酯加成物的加聚产物壁的微胶囊
公开(公告)号：US4592957A
公开(公告)日：1986-06-03
申请号：US691402
申请日：1985-01-14
申请人： Manfred Dahm , Norbert Weimann , Ulrich Nehen , Hanns P. Muller , Gert Jabs , Albert Awater , James M. Barnes
发明人： Manfred Dahm , Norbert Weimann , Ulrich Nehen , Hanns P. Muller , Gert Jabs , Albert Awater , James M. Barnes
IPC分类号： B01J13/16 , B41M5/165 , C08G18/32 , C08G18/80 , B01J13/02
CPC分类号： C08G18/8083 , B01J13/16 , B41M5/165 , C08G18/3253 , Y10S428/914 , Y10S430/104 , Y10T428/2985 , Y10T428/2989
摘要： Microcapsules having a hydrophobic core material and capsule walls formed by the reaction of water-insoluble polyamines with water-soluble bisulphite adducts of polyisocyanates, a process for the production thereof which is characterized in that a mixture of a hydrophobic core material and water-insoluble polyamines is emulsified in water or in an aqueous protective colloid solution to the required particle size, water-soluble bisulphite adducts of polyisocyanates in the form of powders or aqueous solutions are added and the mixture is left to react to completion at temperatures of from 1.degree. to 140.degree. C., and applications thereof.
摘要翻译：具有疏水性芯材的微胶囊和通过水不溶性多胺与多异氰酸酯的水溶性亚硫酸氢盐加合物的反应形成的胶囊壁，其制造方法，其特征在于，疏水性芯材料与水不溶性多胺在水中或在水性保护胶体溶液中乳化至所需的粒度，加入粉末或水溶液形式的多异氰酸酯的水溶性亚硫酸氢盐加合物，使混合物在1℃至 140℃，及其应用。

3. 发明授权

US4356275A Aminoplast foams 失效
标题翻译：氨基塑料泡沫
公开(公告)号：US4356275A
公开(公告)日：1982-10-26
申请号：US312225
申请日：1981-10-19
申请人： Kuno Wagner , Manfred Dahm , Hanns P. Muller
发明人： Kuno Wagner , Manfred Dahm , Hanns P. Muller
IPC分类号： C08G12/12 , C08J9/04 , C08J9/30 , C08L61/00
CPC分类号： C08J9/30 , C08G12/12 , C08J9/04 , C08J2361/24
摘要： Aminoplast foams of hardened reaction products of aldehydes and at least bifunctional modified .alpha.,.omega.-ureas which contain at least one ether, thioether, acetal, ester, ester amide and/or carbonate group and have a molecular weight of from 200 to 10,000.
摘要翻译：含有至少一种醚，硫醚，缩醛，酯，酯酰胺和/或碳酸酯基团并具有200至10,000的分子量的醛的至少双功能改性的α，ω-脲的硬化反应产物的氨基塑料泡沫。

4. 发明授权

US4160754A Stable polymer gels 失效
标题翻译：稳定的聚合物凝胶
公开(公告)号：US4160754A
公开(公告)日：1979-07-10
申请号：US886316
申请日：1978-03-13
申请人： Dietmar Schapel , Kuno Wagner , Hanns P. Muller , Manfred Dahm
发明人： Dietmar Schapel , Kuno Wagner , Hanns P. Muller , Manfred Dahm
IPC分类号： C08L61/00 , C08G12/02 , C08G12/40 , C08G12/46 , C08J9/00 , C08J9/14 , C08L61/20 , C11B9/00 , C08L61/24
CPC分类号： C08J9/147 , C08G12/02 , C08G12/40 , C08G12/46 , C08J9/00 , C08J2361/32 , Y10S524/916
摘要： This invention is directed to gels which are stable in storage, comprising a polymer matrix, a liquid dispersing agent embedded therein and optionally fillers or additives, characterized in that said polymer matrix is a polycondensation product of aldehydes and aminoplast-formers, at least 30% by weight of the aminoplast-formers having a molecular weight of between 200 and 10,000 and containing at least one ether, thioether, acetal, ester, urethane and/or carbonate group.
摘要翻译：本发明涉及在储存中稳定的凝胶，其包含聚合物基质，嵌入其中的液体分散剂和任选的填料或添加剂，其特征在于所述聚合物基质是醛和氨基塑料 - 形成剂的缩聚产物，至少30％的分子量为200至10,000的氨基塑料 - 形成剂，并含有至少一种醚，硫醚，缩醛，酯，氨基甲酸酯和/或碳酸酯基团。

5. 发明授权

US5090405A Water-hardening polymer preparations 失效
标题翻译：水硬化聚合物制备
公开(公告)号：US5090405A
公开(公告)日：1992-02-25
申请号：US231738
申请日：1988-08-12
申请人： Bernhard Jansen , Hanns P. Muller , Roland Richter , Wolfram Mayer
发明人： Bernhard Jansen , Hanns P. Muller , Roland Richter , Wolfram Mayer
IPC分类号： A61L15/07 , A61F13/04 , A61L15/12 , B32B20060101 , B32B27/04 , C08G18/10 , C08G18/28 , C08G18/30 , C08G18/48 , C08G18/50 , C08G18/61 , C08G18/80 , C08G18/83 , C08G77/42 , C08G77/458 , C08G77/46 , C08J20060101 , C08J3/20 , C08J5/10 , C08J5/24 , C08J7/04 , C08L33/14 , C08L75/04 , C08L83/10 , C09D175/00 , C09D175/04 , C09K13/10
CPC分类号： C08L75/04 , A61L15/125 , C08G18/10 , C08G18/2815 , C08G18/302 , C08G18/61 , C08G18/8064 , C08G77/458 , C08G77/46 , Y10S428/913 , Y10T29/49732 , Y10T428/1321 , Y10T428/1362 , Y10T428/1376 , Y10T428/249955 , Y10T428/249958
摘要： In a construction material comprising a flexible carrier substrate impregnated or coated with a water-hardening resin, the resin contains as an additive polyether polysiloxane polyurethanes of the formula ##STR1## in which R.sup.1 is lower alkyl,m is the average number of siloxane groups in the range from 5 to 25,R is ##STR2## in which X is lower alkylene,Y is an aliphatic, cycloaliphatic, aromatic or araliphatic moiety, which is unsubstituted or substituted by further ##STR3## Z is a polyether moiety based on ethylene oxide units propylene oxide units, or both with the average number of ethylene oxide and propylene oxide units being in the range fro 10 to 100 andR.sup.2 is lower alkyl.
摘要翻译：在包含浸渍或涂覆有水硬化树脂的柔性载体基材的构造材料中，该树脂含有作为添加剂的式“IMAGE”的聚醚聚硅氧烷聚氨酯，其中R1是低级烷基，m是硅氧烷基团的平均数 5至25的范围，R为其中X为低级亚烷基，Y为脂族，脂环族，芳族或芳脂族部分，未取代或通过进一步取代Z为基于环氧乙烷的聚醚部分单元环氧丙烷单元，或二者的环氧乙烷和环氧丙烷单元的平均数在10至100的范围内，并且R 2是低级烷基。

6. 发明授权

US5061756A Process for the preparation of polyurethane powders 失效
标题翻译：制备聚氨酯粉末的方法
公开(公告)号：US5061756A
公开(公告)日：1991-10-29
申请号：US566017
申请日：1990-08-10
申请人： Tillmann Hassel , Hanns P. Muller , Hugo Vernaleken , Helmut Kipphardt , Rolf Dhein
发明人： Tillmann Hassel , Hanns P. Muller , Hugo Vernaleken , Helmut Kipphardt , Rolf Dhein
IPC分类号： C08J3/12 , C08G18/00 , C08G18/08 , C08G18/10
CPC分类号： C08G18/10 , C08G18/0871
摘要： The present invention is directed to an improved process for the direct preparation of polyurethane powders in a finely divided form by the reaction of polyisocyanates and isocyanate reactive compounds in a carrier phase, using interface active compounds, the improvement wherein the interface active compound used consists of at least one polymer of a urethane of (i) a long chain alkyl isocyanate and (ii) a hydroxyalkyl-acrylic or -metacrylic acid ester.
摘要翻译：本发明涉及一种用于使用界面活性化合物通过多异氰酸酯和异氰酸酯反应性化合物在载体相中反应而以细碎形式直接制备聚氨酯粉末的改进方法，其中使用的界面活性化合物由（i）长链烷基异氰酸酯和（ii）羟烷基 - 丙烯酸或 - 甲基丙烯酸酯的氨基甲酸酯的至少一种聚合物。

7. 发明授权

US5041494A Aqueous solutions or dispersions of polyurethanes, a process for their preparation and their use in coating compositions 失效
标题翻译：聚氨酯的水溶液或分散体，其制备方法及其在涂料组合物中的用途
公开(公告)号：US5041494A
公开(公告)日：1991-08-20
申请号：US264300
申请日：1988-10-28
申请人： Joachim Franke , Hanns P. Muller
发明人： Joachim Franke , Hanns P. Muller
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/38 , C08G18/83 , C08L75/00 , C08L75/04 , C09D175/00
CPC分类号： C08G18/832 , C08G18/0814 , C08G18/10 , C08G18/283 , C08G18/289 , C08G18/3893
摘要： The present invention is directed to aqueous solutions or dispersions of cationically modified polyurethanes, characterized in that the dissolved or dispersed polyurethanes(i) contain about 2 to 200 milliequivalents of incorporated ammonium groups per 100 g of solids content,(ii) contain 0 to about 25% by weight of ethylene oxide units within terminal or lateral polyether chains and(iii) contain at least 1.3% by weight, calculated as SiO.sub.3 (molecular weight=76), of built-in structural units corresponding to the formula ##STR1## wherein R', R" and R"' may be the same or different and represent hydrogen or alkyl groups containing 1 to 4 carbon atoms,the total quantity of hydrophilic structural units (i) and (ii) being sufficient to ensure the solubility or dispersibility of the polyurethanes in water and the solutions or dispersions having a pH value of 3 to 6. The present invention is also directed to a process for the preparation of these storage stable aqueous solutions or dispersions and to their use as coating compounds or for the preparation of coating compositions for any substrates.
摘要翻译：本发明涉及阳离子改性聚氨酯的水溶液或分散体，其特征在于溶解或分散的聚氨酯（i）每100g固体含量含有约2至200毫当量的并入铵基团，（ii）含有0至约末端或侧面聚醚链中的25重量％的环氧乙烷单元和（iii）含有至少1.3重量％（以SiO 3计（分子量= 76）计算）的内置结构单元对应于式，其中 R'，R“和R”可以相同或不同，表示氢或含有1至4个碳原子的烷基，亲水结构单元（i）和（ii）的总量足以确保溶解度或聚氨酯在水中的分散性以及pH值为3至6的溶液或分散体。本发明还涉及制备这些储存稳定的水溶液或分散体的方法离子和它们作为涂料化合物的用途或用于制备用于任何底物的涂料组合物。

8. 发明授权

US5021536A Storage stable resin reaction mixtures, and the preparation and use thereof 失效
标题翻译：储存稳定的树脂反应混合物及其制备和应用
公开(公告)号：US5021536A
公开(公告)日：1991-06-04
申请号：US317162
申请日：1989-02-28
申请人： Hanns P. Muller , Heinrich Heine
发明人： Hanns P. Muller , Heinrich Heine
IPC分类号： C09D175/04 , C08G18/00 , C08G18/04 , C08G18/08 , C08G18/30 , C08G18/58 , C08G18/63 , C08K5/00 , C08L75/00 , C08L75/04 , C09D175/00 , C09J175/00 , C09J175/04 , H01B3/30
CPC分类号： C08G18/04 , C08G18/003 , C08G18/089 , C08G18/637 , H01B3/302 , C08G2101/00
摘要： This invention relates to storage stable resin reaction mixtures obtained by mixing at least one organic polyisocyanate, at least one organic compound containing at least two epoxide groups, at least one alkylating agent that inhibits the reaction of the polyisocyanate and epoxide components, and optional auxiliary agents and additives. The present invention further relates to a process for the preparation of such reaction mixtures and to their use.
摘要翻译：本发明涉及通过混合至少一种有机聚异氰酸酯，至少一种含有至少两个环氧基的有机化合物，至少一种抑制多异氰酸酯和环氧化物组分的反应的烷基化剂和任选的辅助剂而获得的储存稳定的树脂反应混合物和添加剂。本发明还涉及制备这种反应混合物及其用途的方法。

9. 发明授权

US4980441A Liquid crystalline bis-chlorocarbonic acid esters, a process for their preparation and liquid crystalline n-alkyl polyurethanes and polycarbonates prepared from them 失效
标题翻译：液晶双氯碳酸酯，其制备方法和液晶正烷基聚氨酯和由它们制备的聚碳酸酯
公开(公告)号：US4980441A
公开(公告)日：1990-12-25
申请号：US315859
申请日：1989-02-27
申请人： Hanns P. Muller , Bernhard Jansen , Wolfgang Calaminus , Rolf Dhein
发明人： Hanns P. Muller , Bernhard Jansen , Wolfgang Calaminus , Rolf Dhein
IPC分类号： C07C68/02 , C07C69/96 , C08G63/64 , C08G64/06 , C08G64/10 , C08G71/00 , C08G71/04 , C09K19/20 , C09K19/38
CPC分类号： C08G71/04 , C08G64/06 , C08G64/10 , C09K19/2007 , C09K2019/2035
摘要： Liquid crystalline bis-chlorocarbonic acid esters are 4-hydroxybenzoic acid-(4'-hydroxyphenyl) esters corresponding to the following formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 denote, independently of one another, hydrogen, a halogen atom or a C.sub.1 to C.sub.6 alkyl group. Preparation of (I) and liquid crystalline N-alkyl polyurethanes and polycarbonates prepared form (I) are other invention embodiments.
摘要翻译：液晶双氯碳酸酯是对应于下式的4-羟基苯甲酸 - （4'-羟基苯基）酯其中R 1，R 2，R 3和R 4彼此独立地表示氢，卤素原子或C1-C6烷基。（I）和由（I）制备的液晶N-烷基聚氨酯和聚碳酸酯的制备是其它发明实施方案。

10. 发明授权

US4868268A Process for preparing polyurethanes from an organic diisocyanate ester 失效
标题翻译：从有机二异氰酸酯制备聚氨酯的方法
公开(公告)号：US4868268A
公开(公告)日：1989-09-19
申请号：US266557
申请日：1988-11-03
申请人： Hanns P. Muller , Roland Gipp
发明人： Hanns P. Muller , Roland Gipp
IPC分类号： C08G18/76 , C08G18/10 , C08G18/77 , C08G18/78 , C08G18/81 , C08L75/00 , C09K19/38 , G02F1/13
CPC分类号： C09K19/3804 , C08G18/771 , C08G18/7856 , C08G18/7862 , C08G18/8125
摘要： Novel polyurethanes are prepared by reacting(a) an organic diisocyanate of formula ##STR1## wherein M represents --CH.dbd.CH--; --N.dbd.N--; --CH.dbd.N--; ##STR2## or and where R.sub.1 through R.sub.4 may be the same or different and represent hydrogen, halogen, CN, CF.sub.3 or saturated aliphatic C.sub.1 -C.sub.12 alkyl residues which may be interrupted by ether hydrogen atoms with(b) compounds of molecular weights of from between 400 and 10,000 and which contain at least two active hydrogen atoms reactive toward isocyanate groups.
摘要翻译：通过使（a）式（IMAGE）的有机二异氰酸酯（其中M表示-CH = CH-）反应制备新的聚氨酯; -N = N- -CH = N- 或者其中R 1至R 4可以相同或不同，并且表示氢，卤素，CN，CF 3或可被醚氢原子间隔的饱和脂族C 1 -C 12烷基残基，（b）分子量为在400和10,000之间，并且其含有至少两个对异氰酸酯基团反应的活性氢原子。

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