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    • 7. 发明授权
    • Polymer particles
    • 聚合物颗粒
    • US09339781B2
    • 2016-05-17
    • US14122700
    • 2012-05-31
    • Matthew Paul BakerTimothy Warren DaveyBrian Stanley HawkettDuc Ngoc NguyenChristopher Henry Such
    • Matthew Paul BakerTimothy Warren DaveyBrian Stanley HawkettDuc Ngoc NguyenChristopher Henry Such
    • B01J13/18B01J13/22
    • B01J13/18B01J13/22C01P2002/88C01P2004/04C08F2/18C08F2/44C09B67/0013C09C1/3676Y10T428/2989
    • The present invention relates to a method of preparing an aqueous dispersion of polymer encapsulated particulate material, the method comprising: providing a dispersion of the particulate material in a continuous aqueous phase, the dispersion comprising ethylenically unsaturated monomer and a stabilizer for the particulate material; and polymerizing the ethylenically unsaturated monomer by non-living free radical polymerization to form polymer that encapsulates the particulate material, thereby providing the aqueous dispersion of polymer encapsulated particulate material; wherein polymerization of the ethylenically unsaturated monomer comprises: (a) polymerizing a monomer composition that includes ionizable ethylenically unsaturated monomer so as to form a base responsive water swellable non-living polymer layer that encapsulates the particulate material; and (b) polymerizing a monomer composition that includes non-ionizable ethylenically unsaturated monomer so as to form an extensible, water and base permeable non-living polymer layer that encapsulates the base responsive water swellable polymer layer.
    • 本发明涉及一种制备聚合物包封的颗粒材料的水分散体的方法,所述方法包括:提供颗粒材料在连续水相中的分散体,所述分散体包含烯键式不饱和单体和用于颗粒材料的稳定剂; 并通过非活性自由基聚合使烯属不饱和单体聚合形成包封颗粒材料的聚合物,从而提供聚合物包封的颗粒材料的水性分散体; 其中所述烯键式不饱和单体的聚合包括:(a)聚合包含可离子化的烯属不饱和单体的单体组合物,以便形成包封所述颗粒材料的碱性响应性水溶胀性非活性聚合物层; 和(b)使包含不可离子化的烯属不饱和单体的单体组合物聚合,以便形成包封碱性响应性水溶胀性聚合物层的可延伸的水和基底可渗透的非活性聚合物层。