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    • 2. 发明授权
    • Light-sensitive silver halide photographic material feasible for rapid
processing comprising high boiling solvent and gold compounds
    • 感光卤化银照相材料可用于快速加工,包括高沸点溶剂和金化合物
    • US4912026A
    • 1990-03-27
    • US328721
    • 1989-03-23
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • G03C1/34G03C1/76
    • G03C1/346G03C1/7614
    • A light-sensitive silver halide photographic material having a support with at least one silver halide emulsion layer containing a dye-forming coupler, where the light-sensitive silver halide photographic material is characterized in that at least one of the silver halide emulsion layers contains (i) the dye-forming coupler dispersed with the use of a high boiling organic solvent having a dielectric constant of 6.0 or less, (ii) silver halide grains containing a gold compound and having silver chloride content of 90 mole % or more, and (iii) a compound represented by General Formula (S) shown below. General Formula (S): ##STR1## where Q is a group of atoms necessary to complete a 5- or 6-membered heterocyclic ring or a 5- or 6-membered ring fused with a benzene ring and M is a hydrogen atom, an alkali metal or an ammonium group.The light-sensitive material can achieve excellent preservation of the dye image, is feasible for rapid processing, has superior BF contamination resistance and pH variation resistance.
    • 一种感光卤化银照相材料,其具有至少一个含有染料形成成色剂的卤化银乳剂层的载体,其中感光卤化银照相材料的特征在于至少一种卤化银乳剂层含有 i)成色剂通过使用介电常数为6.0以下的高沸点有机溶剂分散,(ii)含有金化合物的卤化银颗粒和氯化银含量为90摩尔%以上,( iii)由以下所示的通式(S)表示的化合物。 通式(S):其中Q是完成5或6元杂环或与苯环稠合的5或6元环所必需的一组原子,M是氢原子, 碱金属或铵基。 感光材料可以实现对染料影像的优异保存,对于快速加工是可行的,具有优异的BF耐污染性和耐pH变异性。
    • 3. 发明授权
    • Method of forming dye image having superior rapid processing performance
    • US4839263A
    • 1989-06-13
    • US79220
    • 1987-07-29
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • G03C1/035G03C1/30G03C7/30G03C7/392G03C7/407
    • G03C7/3924G03C1/305Y10S430/164
    • A silver halide photographic material containing a support and, provided thereon, at least one silver halide emulsion layer, this silver halide emulsion layer containing silver halide grains containing 90 mol % or more of silver chloride, a dye-forming coupler, and a compound represented by general formula [S]; ##STR1## wherein Q is a group of atoms necessary to complete a 5- or 6-membered heterocyclic ring or a 5- or 6-membered ring fused with a benzene ring and M is a hydrogen atom, an alkali metal or an ammonium group;the silver halide layer having been hardened by a hardener represented by formula [HDA] or [HDB]; ##STR2## wherein Rd.sub.1 is selected from the group consisting of a chlorine atom, a hydroxyl group, an alkyl group, an alkoxy group, an alkylthio group, an --OM group, wherein M is an mono-valent metal atom, a --NR'R" group, wherein R' and R" are independently selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group and a --NHCOR'" group, in which R'" is selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group; Rd.sub.2 is selected from the group consisting of a hydroxyl group, an alkyl group, an alkoxy group, an alkylthio group, an --OM group, wherein M is an mono-valent metal atom, a --NR'R" group, wherein R' and R" are independently selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group and a --NHCOR'" group, in which R'" is selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group; ##STR3## wherein Rd.sub.3 and Rd.sub.4 are independently selected from the group consisting of a chlorine atom, a hydroxyl group, an alkyl group, an alkoxy group and an --OM group, in which is a mono-valent metal atom; Q and Q' is a divalent atom or group selected from --O--, --S-- and --NH--; L is an alkylene group or an arylene group; and p and q are independently integers of 0 or 1. The above-described silver halide photographic material is processed with a color developing solution containing a sulfite ion in a quantity of 2.times.10.sup.-4 to 1.times.10.sup.-2 moles per liter, this developing solution being substantially free of bromide ion. The above-described material and process for developing the same, being better suited for use in rapid developing processes.
    • 6. 发明授权
    • Light-sensitive silver halide color photographic material
    • 感光卤化银彩色照相材料
    • US5278038A
    • 1994-01-11
    • US679937
    • 1991-04-03
    • Masanobu MiyoshiMakoto KajiwaraKaoru Onodera
    • Masanobu MiyoshiMakoto KajiwaraKaoru Onodera
    • G03C1/035G03C7/38G03C1/34
    • G03C7/3825G03C1/035
    • Light-sensitive silver halide color photographic material, having at least one light-sensitive silver halide emulsion layer on a support, wherein at least one of said emulsion layer contains light-sensitive silver halide grains having outer surfaces principally comprised of {100} face, and a magenta dye image forming coupler represented by Formula (I) shown below: ##STR1## wherein Z represents a group of nonmetal atom necessary for formation of a nitrogen-containing hetero ring; said ring formed by Z may have a substituent; X represents a hydrogen atom or a substituent eliminable by the reaction with an oxidant in a color developing agent; and R represents a hydrogen atom or a substituent.which can porovide a light-sensitive silver halide color photographic material having high sensitivity, being low in fogs, and having improved color reproducibility.
    • 感光卤化银彩色照相材料,其在载体上具有至少一个感光卤化银乳剂层,其中所述乳剂层中的至少一个含有感光卤化银颗粒,其外表面主要包括(100)面, (I)表示的品红染料影像成色剂:(*化学结构*)式(I):其中Z表示形成含氮杂环所必需的非金属原子团; 由Z形成的所述环可具有取代基; X表示氢原子或通过与彩色显影剂中的氧化剂反应可消除的取代基; R表示氢原子或取代基。 其可以具有高灵敏度的感光卤化银彩色照相材料,雾度低,并且具有改进的颜色再现性。
    • 7. 发明授权
    • Light-sensitive silver halide color photographic material
    • 感光卤化银彩色照相材料
    • US5023170A
    • 1991-06-11
    • US569778
    • 1990-08-21
    • Masanobu MiyoshiMakoto KajiwaraKaoru Onodera
    • Masanobu MiyoshiMakoto KajiwaraKaoru Onodera
    • G03C7/26G03C1/005G03C1/035G03C1/38G03C7/38
    • G03C7/3825G03C1/035
    • A light-sensitive silver halide color photographic material, having at least one light-sensitive silver halide emulsion layer on a support, wherein at least one of said emulsion layer contains light-sensitive silver halide grains having outer surfaces principally comprised of {100} face, and a magenta dye image forming coupler represented by Formula (I) shown below: ##STR1## wherein Z represents a group of nonmetal atom necessary for formation of a nitrogen-containing hetero ring; said ring formed by Z may have a substituent; X represents a hydrogen atom or a substituent eliminable by the reaction with an oxidant in a color developing agent; and R represents a hydrogen atom or a substituent,which can provide a light-sensitive silver halide color photographic material having high sensitivity, being low in fogs, and having improved color reproducibility.
    • 一种感光卤化银彩色照相材料,其在载体上具有至少一个感光卤化银乳剂层,其中至少一个所述乳剂层含有感光卤化银颗粒,其外表面主要由{100}面 ,和由下式(I)表示的品红染料影像形成成色剂:其中Z表示形成含氮杂环所必需的非金属原子团; 由Z形成的所述环可具有取代基; X表示氢原子或通过与彩色显影剂中的氧化剂反应可消除的取代基; 并且R表示氢原子或取代基,其可以提供具有高灵敏度,雾度低并且具有改善的颜色再现性的感光卤化银彩色照相材料。
    • 9. 发明授权
    • Color photographic light-sensitive material for printing use
    • 彩色照相感光材料,用于印刷用途
    • US5342748A
    • 1994-08-30
    • US158354
    • 1993-11-23
    • Masanobu MiyoshiMakoto KajiwaraMakoto Onodera
    • Masanobu MiyoshiMakoto KajiwaraMakoto Onodera
    • G03C7/38
    • G03C7/3825
    • A color photographic light-sensitive material for printing use comprising a reflection type support bearing thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer; wherein a silver halide emulsion contained in said green-sensitive silver halide emulsion layer is a monodispersed silver halide emulsion and a coupler combined with said monodispersed silver halide emulsion is a magneta coupler represented by the following formula I ##STR1## wherein Z represents a group of non-metal atoms necessary for forming a nitrogen-containing heterocyclic ring, and the ring formed by the Z is allowed to have substituents; X represents a substituent capable of splitting off through the reaction thereof on the oxidation products of a color developing agent; and R represents hydrogen or a substituent.
    • 一种用于印刷用途的彩色摄影感光材料,包括其上具有感蓝卤化银乳剂层的反射型支撑轴承,感绿卤化银乳剂层和感红卤化银乳剂层; 其中包含在所述感绿卤化银乳剂层中的卤化银乳剂是单分散卤化银乳剂,并且与所述单分散卤化银乳剂组合的成色剂是由下式I表示的磁性耦合剂,其中Z表示 形成含氮杂环所必需的非金属原子,由Z形成的环可以具有取代基; X表示能够通过其在彩色显影剂的氧化产物上的反应分解的取代基; R表示氢或取代基。