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    • 5. 发明授权
    • Method for forming vias in a low dielectric constant material
    • 在低介电常数材料中形成通孔的方法
    • US06180518B2
    • 2001-01-30
    • US09430226
    • 1999-10-29
    • Nace LayadiSailesh Mansinh MerchantSimon John MolloyPradip Kumar Roy
    • Nace LayadiSailesh Mansinh MerchantSimon John MolloyPradip Kumar Roy
    • H01L214763
    • H01L21/02063H01L21/31138H01L21/76802H01L21/76814H01L21/76831
    • A method for making a semiconductor device includes the steps of forming a first conductive layer adjacent a substrate, forming an etch stop layer on the conductive layer, and forming a dielectric layer on the etch stop layer. The dielectric layer includes a material having a low dielectric constant, and a via is formed through the dielectric layer to expose the etch stop layer at the bottom, with porous sidewalls being produced. The exposed etch stop layer is etched using an etchant that cooperates with etched material from the etch stop layer to form a polymeric layer to coat the porous sidewalls of the via. Since the etchant cooperates with the etched material from the etch stop layer to form the polymeric layer coating the porous sidewalls of the via, a separate coating layer deposition step is not required after the via is etched and cleaned. After the porous sidewalls have been coated and polymeric material has been etched from the bottom of the via, a barrier metal layer is formed on the polymeric layer, a seed layer is formed on the barrier metal layer, and a second conductive layer is formed on the seed layer contacting the first conductive layer in the via.
    • 制造半导体器件的方法包括以下步骤:在衬底附近形成第一导电层,在导电层上形成蚀刻停止层,并在蚀刻停止层上形成介电层。 电介质层包括具有低介电常数的材料,并且通过介电层形成通孔以暴露底部的蚀刻停止层,产生多孔侧壁。 使用与蚀刻停止层的蚀刻材料配合的蚀刻剂来蚀刻暴露的蚀刻停止层,以形成聚合物层以涂覆通孔的多孔侧壁。 由于蚀刻剂与来自蚀刻停止层的蚀刻材料配合以形成涂覆通孔的多孔侧壁的聚合物层,在蚀刻和清洁通孔之后不需要单独的涂层沉积步骤。 在已经涂覆多孔侧壁并且已经从通孔的底部蚀刻聚合物材料之后,在聚合物层上形成阻挡金属层,在阻挡金属层上形成种子层,并且在第二导电层上形成第二导电层 种子层与通孔中的第一导电层接触。
    • 7. 发明授权
    • Diffusion preventing barrier layer in integrated circuit inter-metal layer dielectrics
    • 集成电路金属间介质中的防扩散阻挡层
    • US06727588B1
    • 2004-04-27
    • US09377386
    • 1999-08-19
    • Mahjoub Ali AbdelgadirNace LayadiSailesh Mansinh MerchantVivek SaxenaPei H. Yih
    • Mahjoub Ali AbdelgadirNace LayadiSailesh Mansinh MerchantVivek SaxenaPei H. Yih
    • H01L2348
    • H01L23/5329H01L21/76829H01L23/5222H01L2924/0002H01L2924/00
    • A cap or barrier layer that can prevent the migration of impurities in low dielectric constant material, thereby preventing the impurities from attacking conductive elements in subsequent levels of a multi-level integrated circuit structure. The integrated circuit by may be fabricated by disposing the diffusion-preventing barrier layer between a first dielectric layer and the conductive layer at an upper level of the integrated circuit. The diffusion preventing barrier layer may be formed in-situ over the impurity containing dielectric material with the subsequent disposition of a metal layer thereover, and further processing of a multi-layer dielectric structure to include polishing. The in-situ deposition of the cap or barrier layer prevents the exposure of the impurity containing layer to atmosphere, thereby avoiding contamination of the layer by moisture absorption, hydrogen absorption, or the like. In an exemplary embodiment, the diffusion preventing barrier layer is a material containing silicon oxide or silicon rich silicon oxide SiOx, where x is preferably less than 2.
    • 可以防止杂质在低介电常数材料中迁移的帽或阻挡层,从而防止杂质在多级集成电路结构的后续级别中侵袭导电元件。 集成电路可以通过在集成电路的上层设置第一介电层和导电层之间设置防扩散阻挡层来制造。 扩散防止阻挡层可以在含杂质的电介质材料上的原位形成,随后在其上布置金属层,并且进一步处理多层电介质结构以包括抛光。 帽或阻挡层的原位沉积防止了含杂质层暴露于大气中,从而避免了由吸湿,吸氢等引起的层的污染。 在示例性实施例中,防扩散阻挡层是含有氧化硅或富硅氧化硅SiO x的材料,其中x优选小于2。