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1. 发明授权

US5760108A Self-dispersing curable epoxy resin esters, dispersions thereof and coating compositions made therefrom 失效
标题翻译：自分散固化环氧树脂酯，其分散体和由其制成的涂料组合物
公开(公告)号：US5760108A
公开(公告)日：1998-06-02
申请号：US735298
申请日：1996-10-22
申请人： Kartar S. Arora , Grannis S. Johnson , James Aloye
发明人： Kartar S. Arora , Grannis S. Johnson , James Aloye
IPC分类号： C08G59/06 , C08G59/10 , C08G59/16 , C08L63/00 , C09D163/10 , C08L63/02
CPC分类号： C09D163/10 , C08G59/066 , C08G59/10 , C08G59/1461 , C08L63/00
摘要： Self-dispersing curable epoxy resin ester dispersions prepared by a process comprising reacting a self-dispersing curable epoxy resin based on a polyoxyalkyleneamine with a fatty acid selected from the group consisting of drying oil and semi-drying oil fatty acids, are provided. The self-dispersing curable epoxy resin is based on a polyoxyalkyleneamine. Thus, a polyoxyalkyleneamine was present as a chemical precursor of the epoxy resin or a starting material therefor. The self-dispersing curable epoxy resin ester of the invention is in the form of an aqueous dispersion. When dried, films of the self-dispersing curable epoxy resin ester dispersion are useful as a coating composition.
摘要翻译：提供通过包括使基于聚氧化烯胺的自分散可固化环氧树脂与选自干油和半干油脂肪酸的脂肪酸反应的方法制备的自分散可固化环氧树脂酯分散体。自分散固化型环氧树脂基于聚氧化烯胺。因此，存在聚氧亚烷基胺作为环氧树脂的化学前体或其原料。本发明的自分散固化型环氧树脂酯是水分散体的形式。当干燥时，自分散固化型环氧树脂酯分散体的膜可用作涂料组合物。

2. 发明授权

US06225398B1 Aqueous dispersions of polymers 失效
标题翻译：聚合物的水分散体
公开(公告)号：US06225398B1
公开(公告)日：2001-05-01
申请号：US09045133
申请日：1998-03-20
申请人： Chase J. Boudreaux , Stephen A. Fischer , Kartar S. Arora , Grannis S. Johnson
发明人： Chase J. Boudreaux , Stephen A. Fischer , Kartar S. Arora , Grannis S. Johnson
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08F8/32 , C08G18/6229 , C08G18/706 , C08J3/07 , C08F220/14
摘要： A method for formulating an aqueous dispersion of a polymer includes dissolving a polymer such as an acrylic polyol in a solvent to form a polymer solution. A surfactant is added to the polymer solution, and water is then added with mixing sufficient to dispersed the polymer in the water. The resulting aqueous dispersion can be mixed with a water dispersible polyisocyanate to produce coating materials which can be cured to form tough films and coatings.
摘要翻译：用于配制聚合物的水性分散体的方法包括将聚合物如丙烯酸多元醇溶解在溶剂中以形成聚合物溶液。向聚合物溶液中加入表面活性剂，然后加入足以将聚合物分散在水中的混合物。所得到的水分散体可以与水分散性多异氰酸酯混合以产生可固化以形成韧性膜和涂层的涂料。

3. 发明授权

US5874490A Aqueous self-dispersible epoxy resin based on epoxy-amine adducts 失效
标题翻译：基于环氧胺加合物的水性自分散环氧树脂
公开(公告)号：US5874490A
公开(公告)日：1999-02-23
申请号：US739979
申请日：1996-10-30
申请人： Kartar S. Arora , John G. Papalos , Grannis S. Johnson
发明人： Kartar S. Arora , John G. Papalos , Grannis S. Johnson
IPC分类号： C08G59/06 , C08G59/10 , C08L63/00 , C09D163/00 , C08K3/20 , C08L63/02
CPC分类号： C08G59/066 , C08G59/10 , C08L63/00 , C09D163/00
摘要： There is disclosed a self-dispersing curable epoxy resin composition comprising the addition product of reactants comprising (a) 1.0 reactive equivalent of an epoxy resin, (b) from about 0.40 to 0.95 reactive equivalents of a polyhydric phenol, and (c) from about 0.005 to 0.5 reactive equivalents of an amine-epoxy adduct comprising the addition product of reactants comprising 1.0 reactive equivalent of a polyepoxide and from about 0.3 to 0.9 reactive equivalents of a polyoxyalkyleneamine with the structural formulaH.sub.2 N--CH(R.sub.2)CH.sub.2 --O--R.sub.1 --CH.sub.2 CH(R.sub.2)--NH.sub.2wherein:R.sub.1 represents a polyoxyalkylene chain having the structural formula:(CH.sub.2 --CH.sub.2 --O).sub.a --(CH.sub.2 --CH(R.sub.3)--O).sub.bwherein:R.sub.3 is a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.4 aliphatic hydrocarbons,`a` designates a number of ethoxy groups (CH.sub.2 --CH.sub.2 --O),`b` designates a number of monosubstituted ethoxy groups (CH.sub.2 --CH(R.sub.3)O), the sum of `a` and `b` is equal to or greater than 10 but less than or equal to 300, and where the ratio of `a` to `b` is between 1:0 and 1:1. For any values of `a` and `b` the sequence of ethoxy and monosubstituted ethoxy groups within a polyoxyalkylene chain may be completely random and/or there may be blocks of ethoxy and/or monosubstituted ethoxy groups.R.sub.2 designates hydrogen or a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.4 aliphatic hydrocarbons.
摘要翻译：公开了一种自分散可固化环氧树脂组合物，其包含反应物的加成产物，其包含（a）1.0反应当量的环氧树脂，（b）约0.40至0.95反应性当量的多元酚，和（c）约 0.005至0.5反应当量的胺 - 环氧加合物，其包含反应物的加成产物，其包含1.0反应性当量的聚环氧化物和约0.3至0.9反应当量的具有结构式为H 2 -NH-CH（R 2）CH 2 -O-R 1 - 的聚氧亚烷基胺， CH2CH（R2）-NH2其中R1表示具有以下结构式的聚氧化烯链：（CH 2 -CH 2 -O）a - （CH 2 -CH（R 3）-O）b）其中R 3是选自以下的一价有机基团： C1-C4脂族烃，'a'表示多个乙氧基（CH 2 -CH 2 -O），'b'表示多个单取代的乙氧基（CH 2 -CH（R 3）O）），'a'和 'b'等于或大于10但小于或等于300，而大鼠 “a”到“b”的io在1：0和1：1之间。对于“a”和“b”的任何值，聚氧化烯链中的乙氧基和单取代的乙氧基的顺序可以是完全随机的，和/或可以有乙氧基和/或单取代的乙氧基的嵌段。 R2表示氢或选自C1-C4脂族烃的一价有机基团。

4. 发明授权

US5648409A Aqueous self-dispersible epoxy resin based on epoxy-amine adducts containing aromatic polyepoxide 失效
标题翻译：基于含有芳族聚环氧化物的环氧 - 胺加合物的水性自分散型环氧树脂
公开(公告)号：US5648409A
公开(公告)日：1997-07-15
申请号：US366343
申请日：1994-12-29
申请人： Kartar S. Arora , David I. Devore , Reuben H. Grinstein , Grannis S. Johnson , John G. Papalos , Shailesh Shah
发明人： Kartar S. Arora , David I. Devore , Reuben H. Grinstein , Grannis S. Johnson , John G. Papalos , Shailesh Shah
IPC分类号： C08G59/06 , C08G59/10 , C08L63/00 , C09D163/00 , C08K3/20
CPC分类号： C08L63/00 , C08G59/066 , C08G59/10 , C09D163/00
摘要： There is disclosed a self-disbursing curable epoxy resin composition comprising the addition product of reactants comprising (a) 1.0 reactive equivalent of an epoxy resin, (b) from about 0.40 to 0.95 reactive equivalents of a polyhydric phenol, and (c) from about 0.005 to 0.5 reactive equivalents of an amine-epoxy adduct comprising the addition product of reactants comprising 1.0 reactive equivalent of an aromatic polyepoxide and from about 0.3 to 0.9 reactive equivalents of a polyoxyalkyleneamine.
摘要翻译：公开了一种自发式可固化环氧树脂组合物，其包含反应物的加成产物，其包含（a）1.0反应当量的环氧树脂，（b）约0.40至0.95反应性当量的多元酚，和（c）约 0.005至0.5反应当量的胺 - 环氧加合物，其包含反应物的加成产物，其包含1.0反应当量的芳族聚环氧化物和约0.3至0.9反应性当量的聚氧化烯胺。

5. 发明授权

US4879414A Polythiols and use as epoxy resin curing agents 失效
标题翻译：聚硫醇并用作环氧树脂固化剂
公开(公告)号：US4879414A
公开(公告)日：1989-11-07
申请号：US156692
申请日：1988-02-17
申请人： Grannis S. Johnson , Reuben H. Grinstein , Stuart J. Hartman , Raymond P. Dallago
发明人： Grannis S. Johnson , Reuben H. Grinstein , Stuart J. Hartman , Raymond P. Dallago
IPC分类号： B01J23/04 , B01J31/02 , C07B61/00 , C07C319/02 , C07C319/14 , C07C323/25 , C08G59/18 , C08G59/40 , C08G59/66
CPC分类号： C07C323/25 , C08G59/182 , C08G59/66 , C07C2101/14
摘要： Polythiols prepared by the reaction of hydrogen sulfide or organic dithiols with polyglycidyl substituted amines have been found to be outstanding curing agents for epoxy resins. Epoxy resins cured with these polythiols are characterized by not only improved gel times, but also improved cure rates, better heat resistance and greater resistance to absorption of water.A useful polythiol is the reaction product of N,N,N',N'-tetraglycidyl-m-xylylenediamine with hydrogen sulfide.

6. 发明授权

US5525125A Process for fixing dyes in textile materials 失效
标题翻译：在纺织材料中固定染料的方法
公开(公告)号：US5525125A
公开(公告)日：1996-06-11
申请号：US437261
申请日：1995-05-08
申请人： Arthur H. Cole , Susan C. Glenn , Grannis S. Johnson
发明人： Arthur H. Cole , Susan C. Glenn , Grannis S. Johnson
IPC分类号： D06P1/52 , D06P3/24 , D06P5/08
CPC分类号： D06P1/5214 , D06P1/5221 , D06P1/5242 , D06P1/5257 , D06P5/08 , D06P3/241 , Y10S8/924 , Y10S8/926 , Y10S8/929
摘要： A process for fixing dyes impregnated in fine-dimensional synthetic textile substrates in an environmentally safe manner. The process comprises contacting the dyed synthetic substrates with an aqueous solution of a phenol- and formaldehyde-free dye-fixative composition containing a copolymer ofa) 1.0 to about 20 percent by weight of vinyl sulfonic acid residues;b) 5 to 20 percent by weight of nonpolar or hydrophobic monomer residues; andc) 60 to about 94 percent by weight of hydrophilic ethylenically unsaturated carboxylic acid residues, the copolymers having a weight average molecular weight of from about 1,500 to about 15,000. The contacting step is for a time sufficient so that the dye-fixative composition is absorbed by the fabric.
摘要翻译：以环境安全的方式固定浸渍在细小的合成纺织品基材中的染料的方法。该方法包括使染色的合成底物与含有a）1.0至约20重量％的乙烯基磺酸残基的共聚物的不含苯酚和无甲醛的染料固定剂组合物的水溶液接触; b）5至20重量％的非极性或疏水单体残基; 和c）60至约94重量％的亲水性烯属不饱和羧酸残基，所述共聚物的重均分子量为约1,500至约15,000。接触步骤足以使染料固定组合物被织物吸收。

7. 发明授权

US4441929A Superplasticizers for cementitious compositions 失效
标题翻译：水泥组合物的超增塑剂
公开(公告)号：US4441929A
公开(公告)日：1984-04-10
申请号：US411034
申请日：1982-08-24
申请人： Alphonso W. Marcellis , Grannis S. Johnson , Joseph P. Fleming
发明人： Alphonso W. Marcellis , Grannis S. Johnson , Joseph P. Fleming
IPC分类号： C04B28/04 , C04B7/35
CPC分类号： C04B28/04
摘要： Superplasticizers for cementitious compositions are produced from a raw material mixture of (1) naphthalenesulfonic acid formaldehyde condensate and (2) free sulfuric acid using a 1-step process or a 2-step process. In the 1-step process, the mixture is neutralized with a zinc compound such as zinc oxide to a pH of about 2 to obtain a superplasticizer mixture of the free acid of the naphthalenesulfonic acid formaldehyde condensate and zinc sulfate. In the 2-step process, the mixture is first neutralized with a zinc compound such as zinc oxide to a pH of about 2 and then with a base such as sodium hydroxide to a pH of about 6 to obtain a superplasticizer mixture of the sodium salt of the naphthalenesulfonic acid formaldehyde condensate and zinc sulfate. These superplasticizer mixtures are superior to a low salt content commercial sodium salt of a naphthalenesulfonic acid formaldehyde condensate where sodium sulfate content has been reduced by lime treatment.
摘要翻译：用于水泥组合物的超增塑剂由（1）萘磺酸甲醛缩合物和（2）游离硫酸的原料混合物使用1步法或2步法制备。在一步法中，将混合物用锌化合物如氧化锌中和至约2的pH，以获得萘磺酸甲醛缩合物的游离酸和硫酸锌的超增塑剂混合物。在两步法中，首先用锌化合物如氧化锌将混合物中和至约2的pH，然后用碱如氢氧化钠中和至pH约6，得到钠盐的超增塑剂混合物的萘磺酸甲醛缩合物和硫酸锌。这些超增塑剂混合物优于通过石灰处理使硫酸钠含量降低的萘磺酸甲醛缩合物的低盐含量的商业钠盐。

8. 发明授权

US5464452A Process for fixing dyes in textile materials 失效
标题翻译：在纺织材料中固定染料的方法
公开(公告)号：US5464452A
公开(公告)日：1995-11-07
申请号：US240305
申请日：1994-05-10
申请人： Arthur H. Cole , Susan C. Glenn , Grannis S. Johnson
发明人： Arthur H. Cole , Susan C. Glenn , Grannis S. Johnson
IPC分类号： D06P1/52 , D06P3/24 , D06P5/08 , D06P5/00
CPC分类号： D06P1/5257 , D06P1/5214 , D06P1/5221 , D06P1/5242 , D06P5/08 , D06P3/241
摘要： A process for fixing dyes impregnated in fine-dimensional synthetic textile substrates in an environmentally safe manner. The process comprises contacting the dyed synthetic substrates with a phenol- and formaldehyde-free dye-fixative composition comprising: (a) polymethacrylic acid, (b) copolymers of methacrylic acid consisting essentially of methacrylic acid and an ethylenically unsaturated comonomer selected from the group consisting of 2-acrylamido-2-methyl-propanesulfonic acid, sodium vinyl sulfonate, sodium styrene sulfonate, alkyl acrylate, and combinations thereof, (c) combinations of (a) and (b), and (d) water.
摘要翻译：以环境安全的方式固定浸渍在细小的合成纺织品基材中的染料的方法。所述方法包括使经染色的合成底物与不含苯酚和无甲醛的染料固定剂组合物接触，所述组合物包含：（a）聚甲基丙烯酸，（b）基本上由甲基丙烯酸和烯属不饱和共聚单体组成的甲基丙烯酸的共聚物，所述共聚单体选自的2-丙烯酰胺基-2-甲基 - 丙磺酸，乙烯基磺酸钠，苯乙烯磺酸钠，丙烯酸烷基酯及其组合，（c）（a）和（b）的组合和（d）水。

9. 发明授权

US4501594A Anionic polyhydroxy polyphenyl compounds as dispersants for aqueous slurries of carbonaceous materials 失效
标题翻译：阴离子多羟基聚苯基化合物作为含碳材料的水性浆料的分散剂
公开(公告)号：US4501594A
公开(公告)日：1985-02-26
申请号：US544076
申请日：1983-10-21
申请人： Alphonso W. Marcellis , Grannis S. Johnson , Reuben H. Grinstein
发明人： Alphonso W. Marcellis , Grannis S. Johnson , Reuben H. Grinstein
IPC分类号： C10L1/32 , C10L1/18
CPC分类号： C10L1/326 , Y10S516/01 , Y10S516/03
摘要： Aqueous carbonaceous slurries having reduced viscosity, a stabilized network of carbonaceous material in water and improved pumpability are obtained by having present as a dispersant one or more particular water soluble sulfomethylated hydroxy aromatic products. Examples of dispersants are the water soluble sulfomethylation product of the water soluble residue obtained from resorcinol production by the alkaline fusion method, sulfomethylated phenol and sulfomethylated bisphenol A.
摘要翻译：通过具有一种或多种特定的水溶性磺甲基化羟基芳族化合物作为分散剂，可获得具有降低的粘度的含水碳质浆料，水中含碳材料的稳定网络和改进的可泵送性。分散剂的实例是通过碱性熔融法从间苯二酚生产获得的水溶性残基的水溶性磺甲基化产物，磺甲基化苯酚和磺甲基化双酚A.

10. 发明授权

US4440577A Polyhydroxy polyphenyl compounds as additives for cementitious materials 失效
标题翻译：多羟基聚苯基化合物作为水泥质材料的添加剂
公开(公告)号：US4440577A
公开(公告)日：1984-04-03
申请号：US415018
申请日：1982-09-07
申请人： Alphonso W. Marcellis , Grannis S. Johnson
发明人： Alphonso W. Marcellis , Grannis S. Johnson
IPC分类号： C04B24/00 , C04B24/22 , C04B7/35
CPC分类号： C04B24/001 , C04B24/22
摘要： A superplasticizer with improved water reducing properties for cement, cement slurries, mortar, grout and concrete is Penacolite Resin RM-441 as is or sulfonated, sulfomethylated, sulfonated and condensed with formaldehyde, sulfomethylated and condensed with formaldehyde, condensed with formaldehyde, co-condensed with ligninsulfonates and formaldehyde or co-condensed with naphthalenesulfonic acid formaldehyde condensate and formaldehyde. These materials can be used alone or in combination with salts of aromatic sulfonic acid formaldehyde condensates.
摘要翻译：具有改善水泥，水泥浆，砂浆，灌浆和混凝土的减水性能的超增塑剂是Penacolite Resin RM-441或磺化，磺甲基化，磺化和甲醛缩合，磺甲基化和与甲醛缩合，与甲醛缩合，共缩合与木素磺酸盐和甲醛或与萘磺酸甲醛缩合物和甲醛共缩合。这些材料可以单独使用或与芳族磺酸甲醛缩合物的盐组合使用。

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