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    • 3. 发明授权
    • Aqueous dispersions of polyamides
    • 聚酰胺的水分散体
    • US5770680A
    • 1998-06-23
    • US738402
    • 1996-10-25
    • Stephen A. FischerDavid I. DevoreKartar S. AroraReimar Heucher
    • Stephen A. FischerDavid I. DevoreKartar S. AroraReimar Heucher
    • C08J3/07C09J177/00C08G69/08C08G47/08C08G73/10
    • C08J3/07C09J177/00C08J2377/00
    • A process is provided for preparing a dispersion of a polyamide in water, said process comprising: dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of, said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material, adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, and removing at least a major amount of said organic solvent from said oil-in-water dispersion. The resulting dispersion is useful in preparing a coating of the polyamide, which coating is useful as an adhesive.
    • 提供了一种制备聚酰胺在水中的分散体的方法,所述方法包括:将具有大于约2的胺值的聚酰胺溶解在有机溶剂中以形成所述聚酰胺在所述溶剂中的溶液,所述聚酰胺和所述溶剂 在所述溶解期间处于低于所述聚酰胺的软化点的温度下,所述溶液还包含表面活性剂和无机碱性材料,在混合下向所述溶液中加入足够的含有酸的水以形成水包油分散体, 所述溶液的温度和所述水在所述添加期间低于所述聚酰胺的软化点,所述酸的量足以中和所述无机碱性物质的一部分,但不足以使所述聚酰胺从所得水包油中凝结 分散,并从所述水包油分散体中除去至少大量的所述有机溶剂。 得到的分散体可用于制备聚酰胺的涂层,该涂层可用作粘合剂。
    • 4. 发明授权
    • Self-dispersing curable epoxy resin dispersions and coating compositions
made therefrom
    • 自分散固化环氧树脂分散体和由其制成的涂料组合物
    • US5643976A
    • 1997-07-01
    • US366189
    • 1994-12-29
    • Kartar S. AroraMichael S. Wiggins
    • Kartar S. AroraMichael S. Wiggins
    • C08G59/06C08G59/10C08G59/22C09D163/00C08K3/20
    • C09D163/00C08G59/066C08G59/10C08G59/226
    • There is disclosed a self-dispersing curable epoxy resin composition comprising the addition product of reactants comprising (a) 1.0 reactive equivalent of an epoxy resin, (b) from about 0.40 to 0.95 reactive equivalents of a polyhydric phenol, and (c) from about 0.005 to 0.5 reactive equivalents of an amine-epoxy adduct comprising the addition product of reactants comprising 1.0 reactive equivalent of a polyepoxide and from about 0.3 to 0.9 reactive equivalents of a polyoxyalkyleneamine having the structural formula:R.sub.1 --O--R.sub.2 --CH.sub.2 CH(R.sub.3)--X--R.sub.4 --NH2wherein:R.sub.1 designates a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.12 aliphatic, alicyclic or aromatic hydrocarbons, andR.sub.2 represents a polyoxyalkylene chain having the structural formula:(CH.sub.2 --CH.sub.2 --O).sub.a --(CH.sub.2 --CH(R.sub.5)--O).sub.b wherein:R.sub.5 is a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.4 aliphatic hydrocarbons, `a` designates a number of ethoxy groups (CH.sub.2 --CH.sub.2 --O), `b` designates a number of monosubstituted ethoxy groups (CH.sub.2 --CH(R.sub.5)O) where the substitution of one monosubstituted ethoxy group is independent from the substitution of any other monosubstituted ethoxy group in the polyoxyalkylene chain, the sum of `a` and `b` is equal to or greater than 10 but less than or equal to 200, and where the sequence of ethoxy and monosubstituted ethoxy groups within a polyoxyalkylene chain may be completely random and/or there may be blocks of ethoxy and/or monosubstituted ethoxy groups, andR.sub.3 designates H or a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.4 aliphatic hydrocarbons.R.sub.4 designates aliphatic, cycloaliphatic or aromatic radical containing 6 to 18 carbon atoms and X is OC(O)NH.
    • 公开了一种自分散可固化环氧树脂组合物,其包含反应物的加成产物,其包含(a)1.0反应当量的环氧树脂,(b)约0.40至0.95反应性当量的多元酚,和(c)约 0.005至0.5反应当量的胺 - 环氧加合物,其包含反应物的加成产物,其包含1.0反应性当量的聚环氧化物和约0.3至0.9的反应当量的具有以下结构式的聚氧亚烷基胺:R 1 -O-R 2 -CH 2 CH(R 3) -X-R4-NH2其中R1表示选自C1至C12脂族,脂环族或芳族烃的一价有机基团,R2表示具有以下结构式的聚氧化烯链:(CH 2 -CH 2 -O)a - ( CH2-CH(R5)-O)b其中:R5是选自C1-C4脂族烃的一价有机基团,'a'表示多个乙氧基(CH 2 -CH 2 -O),'b' 指定一些monosub 取代乙氧基(CH 2 -CH(R 5)O),其中一个单取代的乙氧基的取代独立于聚氧化烯链中任何其它单取代的乙氧基的取代,“a”和“b”之和等于或等于 大于10但小于或等于200,并且其中聚氧化烯链中的乙氧基和单取代的乙氧基的顺序可以是完全无规的,和/或可以有乙氧基和/或单取代的乙氧基的嵌段,并且R 3表示H或 选自C1-C4脂族烃的一价有机基团。 R 4表示含有6至18个碳原子且X为OC(O)NH的脂族,脂环族或芳族基团。
    • 7. 发明授权
    • Self-dispersing curable epoxy resin dispersions and coating compositions
made therefrom
    • 自分散固化环氧树脂分散体和由其制成的涂料组合物
    • US5750595A
    • 1998-05-12
    • US457932
    • 1995-06-01
    • Kartar S. AroraMichael S. Wiggins
    • Kartar S. AroraMichael S. Wiggins
    • C08G59/06C08G59/10C08G59/22C09D163/00C08K3/20C08L63/00
    • C08G59/226C08G59/066C08G59/10C09D163/00
    • There is disclosed a self-dispersing curable epoxy resin composition comprising the addition product of reactants comprising (a) 1.0 reactive equivalent of an epoxy resin, (b) from about 0.1 to 1.0. reactive equivalents of a polyhydric phenol, and (c) from about 0.005 to 0.5 reactive equivalents of an amine-epoxy adduct comprising the addition product of reactants comprising 1.0 reactive equivalent of a polyepoxide and from about 0.3 to 0.9 reactive equivalents of a compound having the structural formula: �R.sub.1 --O--!.sub.2-m --R.sub.2 --�--CH.sub.2 CH(R.sub.3)--X--R.sub.4 --NH.sub.2 !.sub.m wherein: R.sub.1 designates a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.12 aliphatic, alicyclic or aromatic hydrocarbons, and R.sub.2 represents a polyoxyalkylene chain having the structural formula: (CH.sub.2 --CH.sub.2 --O).sub.a --(CH.sub.2 --CH(R.sub.5)--O).sub.b wherein: R.sub.5 is a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.4 aliphatic hydrocarbons, `a` designates a number of ethoxy groups (CH.sub.2 --CH.sub.2 --O), `b` designates a number of monosubstituted ethoxy groups (CH.sub.2 --CH(R.sub.5)O) where the substitution of one monosubstituted ethoxy group is independent from the substitution of any other monosubstituted ethoxy group in the polyoxyalkylene chain, the sum of `a` and `b` is equal to or greater than 10 but less than or equal to 200, and where the sequence of ethoxy and monosubstituted ethoxy groups within a polyoxyalkylene chain may be completely random and/or there may be blocks of ethoxy and/or monosubstituted ethoxy groups, and where the ratio of a:b is greater than 1:1. R.sub.3 designates H or a monovalent organic radical selected from the group consisting of C.sub.1 to C.sub.4 aliphatic hydrocarbons. R.sub.4 designates aliphatic, cycloaliphatic or aromatic radical containing 6 to 18 carbon atoms and X is OC(O)NH. And m is equal to 1 or 2.
    • 公开了一种自分散可固化环氧树脂组合物,其包含反应物的加成产物,其包含(a)1.0反应当量的环氧树脂,(b)为约0.1至1.0。 多元酚的反应性当量,和(c)约0.005至0.5反应性当量的胺 - 环氧加合物,其包含反应物的加成产物,其包含1.0反应性当量的聚环氧化物和约0.3至0.9反应当量的具有 结构式:[R1-O-] 2-m-R2- [-CH2CH(R3)-X-R4-NH2] m其中R1表示选自C1-C12脂族,脂环族或芳族的一价有机基团 烃,R2表示具有结构式:(CH 2 -CH 2 -O)a - (CH 2 -CH(R 5)-O)b的聚氧化烯链,其中:R 5是选自C 1至C 4脂族 烃,“a”表示多个乙氧基(CH 2 -CH 2 -O),'b'表示多个单取代的乙氧基(CH 2 -CH(R 5)O)),其中一个单取代的乙氧基的取代独立于 取代聚氧化烯链中任何其他单取代的乙氧基 “a”和“b”的总和等于或大于10但小于或等于200,而聚氧化烯链中的乙氧基和单取代的乙氧基的顺序可以是完全随机的,和/或可以是 乙氧基和/或单取代的乙氧基的嵌段,并且其中a:b的比例大于1:1。 R3表示H或选自C1-C4脂族烃的一价有机基团。 R 4表示含有6至18个碳原子且X为OC(O)NH的脂族,脂环族或芳族基团。 m等于1或2。