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1. 发明授权

US06558796B2 Aqueous coating compositions with phosphonic acid based compounds 失效
标题翻译：含有膦酸基化合物的水性涂料组合物
公开(公告)号：US06558796B2
公开(公告)日：2003-05-06
申请号：US09731305
申请日：2000-12-06
申请人： Josef Huybrechts , Paul Bruylants , Michael Koerner , Kenneth S. Kirshenbaum
发明人： Josef Huybrechts , Paul Bruylants , Michael Koerner , Kenneth S. Kirshenbaum
IPC分类号： B23B2738
CPC分类号： C09D5/38 , C08G59/4071 , C09D163/00 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , C08L2666/54
摘要： The invention is directed to gassing stabilized aqueous coating compositions comprising A) a metallic pigment and at least one reaction product of: (a) 5 to 95 weight percent of a at least one phosphonic acid derivative selected form compound I and II wherein R1 is H or O═P(OH)2; R2 and R3 are independently H, OH or an aliphatic, cycloaliphatic and aromatic substituent having 1 to 25 carbon atoms and optionally up to 10 heteroatoms of at least one of oxygen and phosphorus; and R′ is an aliphatic, cycloaliphatic and aromatic substituent having 1 to 25 carbon atoms and optionally up to 10 heteroatoms of at least one of oxygen and phosphorus; (b) 5 to 95 weight percent of a at least one compound having at least two epoxy groups and a number average molecular weight Mn of 300 to 5000 g/mol; and (c) 0 to 90 weight percent of a compound having one epoxy-functional group, wherein the proportions by weight of components (a), (b) and (c) total 100 weight percent. B) at least one metallic pigment.
摘要翻译：本发明涉及放气稳定的水性涂料组合物，其包含A）金属颜料和至少一种反应产物：（a）5-95重量％的选自化合物I和II的至少一种膦酸衍生物，其中R 1是H或O = P（OH）2; R2和R3独立地是H，OH或具有1至25个碳原子和任选至多10个氧和磷中的至少一个的杂原子的脂族，脂环族和芳族取代基; 并且R'是具有1至25个碳原子和任选至多10个至少10个氧和磷的杂原子的脂族，脂环族和芳族取代基;（b）5至95重量％的至少一种具有至少两个环氧基，数均分子量Mn为300〜5000g / mol; 和（c）0至90重量％的具有一个环氧官能团的化合物，其中组分（a），（b）和（c）的重量百分比总计为100重量％。B）至少一种金属颜料。

2. 发明申请

US20060270782A1 Aqueous coating compositions 失效
标题翻译：水性涂料组合物
公开(公告)号：US20060270782A1
公开(公告)日：2006-11-30
申请号：US11436238
申请日：2006-05-18
申请人： Josef Huybrechts , Koen Linsen , Paul Bruylants
发明人： Josef Huybrechts , Koen Linsen , Paul Bruylants
IPC分类号： C08G18/08
CPC分类号： C08G18/792 , C08G18/3271 , C08G18/6241 , C08G18/6258 , C09D175/04 , C09J175/04
摘要： The invention is directed to aqueous coating compositions with improved rheology performance, comprising A) at least one water-dilutable binder, optionally, at least one cross-linking agent B), at least one sagging control agent C) obtainable by reacting a polyisocyanate with an amine, water and optionally usual coating additives, pigments and/or organic solvents, wherein the sagging control agent is obtained by reacting in an aqueous phase in presence of a water-dilutable binder C1) at least one polyisocyanate with C2) at least one amine having at least one primary amino group and at least one hydroxyl group.
摘要翻译：本发明涉及具有改进的流变性能的水性涂料组合物，其包含A）至少一种水可稀释粘合剂，任选的至少一种交联剂B），至少一种流挂控制剂C），其可通过使多异氰酸酯与胺，水和任选通常的涂料添加剂，颜料和/或有机溶剂，其中流挂控制剂通过在水可溶性粘合剂C1）至少一种多异氰酸酯与C2存在下在水相中反应获得，至少一种胺，其具有至少一个伯氨基和至少一个羟基。

3. 发明授权

US07662875B2 Aqueous coating compositions 失效
标题翻译：水性涂料组合物
公开(公告)号：US07662875B2
公开(公告)日：2010-02-16
申请号：US11436238
申请日：2006-05-18
申请人： Josef Huybrechts , Koen Linsen , Paul Bruylants
发明人： Josef Huybrechts , Koen Linsen , Paul Bruylants
IPC分类号： C08G18/28
CPC分类号： C08G18/792 , C08G18/3271 , C08G18/6241 , C08G18/6258 , C09D175/04 , C09J175/04
摘要： The invention is directed to aqueous coating compositions with improved rheology performance, comprising A) at least one water-dilutable binder, optionally, at least one cross-linking agent B), at least one sagging control agent C) obtainable by reacting a polyisocyanate with an amine, water and optionally usual coating additives, pigments and/or organic solvents, wherein the sagging control agent is obtained by reacting in an aqueous phase in presence of a water-dilutable binder C1) at least one polyisocyanate with C2) at least one amine having at least one primary amino group and at least one hydroxyl group.
摘要翻译：本发明涉及具有改进的流变性能的水性涂料组合物，其包含A）至少一种水可稀释粘合剂，任选的至少一种交联剂B），至少一种流挂控制剂C），其可通过使多异氰酸酯与胺，水和任选通常的涂料添加剂，颜料和/或有机溶剂，其中流挂控制剂通过在水可溶性粘合剂C1）至少一种多异氰酸酯与C2存在下在水相中反应获得，至少一种胺，其具有至少一个伯氨基和至少一个羟基。

4. 发明申请

US20060292306A1 Process for the multilayer coating of substrates 审中-公开
标题翻译：基板多层涂层工艺
公开(公告)号：US20060292306A1
公开(公告)日：2006-12-28
申请号：US11156769
申请日：2005-06-20
申请人： Armin Goebel , Josef Huybrechts , Paul Bruylants , Stefan Wiggershaus
发明人： Armin Goebel , Josef Huybrechts , Paul Bruylants , Stefan Wiggershaus
IPC分类号： B05D3/02 , B05D7/00
CPC分类号： C08G18/10 , B05D5/005 , B05D7/532 , C08G18/0823 , C09D175/04 , C08G18/3228 , C08G18/348
摘要： The invention is directed to a process for multilayer coating of substrates comprising the following steps: 1. applying a base coat layer of a water-based colour- and/or special effect-imparting base coat composition onto an optionally precoated vehicle substrate, 2. optionally drying or curing the base coat layer obtained in step 1, 3. applying a clear coat layer of a transparent clear coat onto the base coat layer and 4. curing the clear coat layer applied in step 3, optionally together with the base coat layer, wherein the water-based colour- and/or special effect-imparting base coat composition comprises: A) at least one colour- and/or special effect-imparting pigment, B) water and optionally organic solvents and conventional coating additives and C) at least one water-dilutable polyurethane/urea resin with a urethane group content of 80-220 mmol/g of solid resin, a urea group content of 20-150 mmol/g of solid resin of the polyurethane/urea resin and a crosslinked fraction of 20-95%, relative to solid resin of the polyurethane/urea resin.
摘要翻译：本发明涉及一种用于多层涂布基材的方法，包括以下步骤：1.将水性着色和/或特殊效果的底涂层组合物的底涂层施加到任选预涂的载体基材上。任选地干燥或固化步骤1,3中获得的底涂层，3.将透明涂层的透明涂层施加到底涂层上，以及4.将在步骤3中施加的透明涂层固化，任选地与底涂层其中水性着色剂和/或特殊效果赋予底漆组合物包含：A）至少一种着色和/或特殊效果赋予颜料，B）水和任选的有机溶剂和常规涂料添加剂，和C）至少一种氨基甲酸酯基含量为80-220mmol / g的固体树脂的水可稀释的聚氨酯/脲树脂，尿素基含量为20-150mmol / g的聚氨酯/脲树脂的固体树脂和交联部分 20-95岁％，相对于聚氨酯/尿素树脂的固体树脂。

5. 发明申请

US20060247357A1 Process for the production of aqueous binder latices 有权
标题翻译：生产含水粘合剂胶乳的方法
公开(公告)号：US20060247357A1
公开(公告)日：2006-11-02
申请号：US11273834
申请日：2005-11-15
申请人： Tonnie Willems , Matthieu Barrere , Kok-Far Lee , Frank Tessari , Stefan Wiggerhaus , Paul Bruylants , Eric Houze
发明人： Tonnie Willems , Matthieu Barrere , Kok-Far Lee , Frank Tessari , Stefan Wiggerhaus , Paul Bruylants , Eric Houze
IPC分类号： C09B67/00 , C08F283/00
CPC分类号： C09D151/003 , C08F265/02 , C08F265/06 , C08F2/22
摘要： A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a mixture A of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture A of 10 to 100 mg of KOH/g and 0.5 to 5 wt. % of at least one olefinically polyunsaturated monomer, in the aqueous phase, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one mixture B of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture B or each of the mixtures B of 0 to below 5 mg of KOH/g, at least one monomer with at least one hydroxyl group in a proportion corresponding to a hydroxyl value of mixture B or each of the mixtures B of 0 to below 5 mg of KOH/g and at least one olefinically polyunsaturated monomer in a proportion of 0.5 to 5 wt. %, relative to mixture B or each of the mixtures B, in the presence of the product obtained in process step 2), wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt. % of the monomers of mixture A have been polymerized to completion.
摘要翻译：一种在水相中通过多级乳液聚合生产含水粘合剂胶乳的方法，包括以下连续步骤：1）烯属不饱和的可自由基聚合的单体的混合物A的自由基聚合，其包含至少一种单体，至少一个酸基团，其比例对应于混合物A的酸值为10至100mg KOH / g和0.5至5wt。在水相中至少一种烯属多不饱和单体的％）2）中和方法步骤1）中形成的聚合物的酸基团，和3）至少一种烯属不饱和的可自由基聚合的混合物B的自由基聚合单体，其包含至少一种具有至少一个酸基团的单体，其比例对应于混合物B的酸值或0至低于5mg KOH / g的混合物B的每一种，至少一种具有至少一个羟基的单体以对应于混合物B或混合物B的每一种为0至低于5mg KOH / g的羟基值的比例和至少一种0.5至5wt。％的烯属多不饱和单体。在工艺步骤2）中获得的产物存在下，相对于混合物B或混合物B中的每一种，其中混合物A与至少一种混合物B的重量比为15:85至85:15 并且其中中和在工艺步骤2）中不开始直至至少90wt。混合物A的单体的％已经聚合完成。

6. 发明授权

US5936026A Coatings comprising self-stabilized lattices prepared in a aqueous carrier 失效
标题翻译：包含在水性载体中制备的自稳定晶格的涂层
公开(公告)号：US5936026A
公开(公告)日：1999-08-10
申请号：US737574
申请日：1996-11-14
申请人： Jozef Huybrechts , Michael Fryd , Paul Bruylants , Kerstin Stranimaier
发明人： Jozef Huybrechts , Michael Fryd , Paul Bruylants , Kerstin Stranimaier
IPC分类号： C08F290/04 , C09D155/00 , C08L51/00
CPC分类号： C08F290/04 , C08F290/046 , C09D155/00 , C09D155/005
摘要： An aqueous coating composition comprising a graft copolymer characterized by carboxylic-acid or amine functional macromonomers attached at a terminal end thereof to a polymeric backbone, wherein the macromonomers are grafted in an aqueous carrier in which the carboxylic-acid or amine functional groups have been neutralized. Such compositions provide improved properties for an automotive finish.
摘要翻译： PCT No.PCT / US95 / 05767 Sec。 371日期：1996年11月14日 102（e）日期1996年11月14日PCT提交1995年5月9日PCT公布。公开号WO95 / 32229 日期1995年11月30日一种包含接枝共聚物的水性涂料组合物，其特征在于在其末端连接到聚合物主链上的羧酸或胺官能大分子单体，其中大分子单体接枝在水性载体中，其中羧酸或胺官能团已被中和。这样的组合物为汽车饰面提供了改进的性能。

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