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1. 发明申请

US20060292306A1 Process for the multilayer coating of substrates 审中-公开
标题翻译：基板多层涂层工艺
公开(公告)号：US20060292306A1
公开(公告)日：2006-12-28
申请号：US11156769
申请日：2005-06-20
申请人： Armin Goebel , Josef Huybrechts , Paul Bruylants , Stefan Wiggershaus
发明人： Armin Goebel , Josef Huybrechts , Paul Bruylants , Stefan Wiggershaus
IPC分类号： B05D3/02 , B05D7/00
CPC分类号： C08G18/10 , B05D5/005 , B05D7/532 , C08G18/0823 , C09D175/04 , C08G18/3228 , C08G18/348
摘要： The invention is directed to a process for multilayer coating of substrates comprising the following steps: 1. applying a base coat layer of a water-based colour- and/or special effect-imparting base coat composition onto an optionally precoated vehicle substrate, 2. optionally drying or curing the base coat layer obtained in step 1, 3. applying a clear coat layer of a transparent clear coat onto the base coat layer and 4. curing the clear coat layer applied in step 3, optionally together with the base coat layer, wherein the water-based colour- and/or special effect-imparting base coat composition comprises: A) at least one colour- and/or special effect-imparting pigment, B) water and optionally organic solvents and conventional coating additives and C) at least one water-dilutable polyurethane/urea resin with a urethane group content of 80-220 mmol/g of solid resin, a urea group content of 20-150 mmol/g of solid resin of the polyurethane/urea resin and a crosslinked fraction of 20-95%, relative to solid resin of the polyurethane/urea resin.
摘要翻译：本发明涉及一种用于多层涂布基材的方法，包括以下步骤：1.将水性着色和/或特殊效果的底涂层组合物的底涂层施加到任选预涂的载体基材上。任选地干燥或固化步骤1,3中获得的底涂层，3.将透明涂层的透明涂层施加到底涂层上，以及4.将在步骤3中施加的透明涂层固化，任选地与底涂层其中水性着色剂和/或特殊效果赋予底漆组合物包含：A）至少一种着色和/或特殊效果赋予颜料，B）水和任选的有机溶剂和常规涂料添加剂，和C）至少一种氨基甲酸酯基含量为80-220mmol / g的固体树脂的水可稀释的聚氨酯/脲树脂，尿素基含量为20-150mmol / g的聚氨酯/脲树脂的固体树脂和交联部分 20-95岁％，相对于聚氨酯/尿素树脂的固体树脂。

2. 发明申请

US20060142459A1 Aqueous binders containing layered silicate, process for the production thereof and use thereof in aqueous coating compositions 审中-公开
标题翻译：含有层状硅酸盐的水性粘合剂，其制备方法及其在水性涂料组合物中的应用
公开(公告)号：US20060142459A1
公开(公告)日：2006-06-29
申请号：US11355436
申请日：2006-02-16
申请人： Armin Goebel , Werner Bosch , Juergen Doebert , Marcus Brunner , Marco Taschner , Bettina Vogt-Birnbrich
发明人： Armin Goebel , Werner Bosch , Juergen Doebert , Marcus Brunner , Marco Taschner , Bettina Vogt-Birnbrich
IPC分类号： C08K3/34 , C09K3/10
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/6659 , C08K3/34 , C08K7/00 , C09D167/00 , C08G18/289 , C08G18/305 , C08G18/3275 , C08L2666/54
摘要： Aqueous binders containing 0.2 to 7 wt-% of layered silicate, relative to binder solids content, obtainable by converting a homogeneous mixture of layered silicate and non-aqueous binder (precursor) into the aqueous phase by mixing with water and, in the case of a binder precursor, concluding synthesis of the binder in the aqueous phase.
摘要翻译：通过将层状硅酸盐和非水性粘合剂（前体）的均匀混合物通过与水混合而转化成水相而获得的相对于粘合剂固体含量为0.2至7重量％的层状硅酸盐的水性粘合剂，粘合剂前体，水相中粘合剂的结论合成。

3. 发明授权

US06355303B1 Process for the preparation of multi-layer coatings of the water-borne base coat/powder clear coat type 失效
标题翻译：制备水性底漆/粉末透明涂层型多层涂料的方法
公开(公告)号：US06355303B1
公开(公告)日：2002-03-12
申请号：US09560750
申请日：2000-04-28
申请人： Bettina Vogt-Birnbrich , Armin Goebel , Holger Schmidt , Werner Bosch , Frank Mueller , Kornelia Wetzel
发明人： Bettina Vogt-Birnbrich , Armin Goebel , Holger Schmidt , Werner Bosch , Frank Mueller , Kornelia Wetzel
IPC分类号： B05D112
CPC分类号： B05D7/532 , B05D2451/00 , C08G18/0823 , C08G18/12 , C08G18/672 , C08L1/10 , C09D7/65 , C09D175/16 , Y10T428/31605 , Y10T428/31786 , C08G18/302 , C08G18/6659 , C08L2666/26 , B05D2401/20 , B05D2401/32
摘要： A process for multi-layer coating by application of a base coat layer of a water-borne base coat to a substrate and subsequent application of a clear coat layer of a powder clear coat, followed by joint baking of both coating layers, wherein said water-borne base coat contains an effective amount, preferably 0.5 to 10 wt. %, of one or more water-insoluble cellulose esters, largely avoids the formation of blisters in the powder clear coat layer.
摘要翻译：一种通过将水性底涂层的底涂层施加到基底上并随后施加透明涂层的透明涂层，然后两层涂层共同烘烤来进行多层涂布的方法，其中所述水底涂层含有效量，优选为0.5〜10重量％％的一种或多种水不溶性纤维素酯很大程度上避免了在粉末透明涂层中形成起泡。

4. 发明申请

US20100048811A1 PROCESS FOR THE PRODUCTION OF POLYURETHANE UREA RESIN DISPERSIONS 审中-公开
标题翻译：生产聚氨酯尿素树脂分散体的方法
公开(公告)号：US20100048811A1
公开(公告)日：2010-02-25
申请号：US12194877
申请日：2008-08-20
申请人： MARC CHILLA , Armin Goebel , Karl-Friedrich Doessel
发明人： MARC CHILLA , Armin Goebel , Karl-Friedrich Doessel
IPC分类号： C08G18/08
CPC分类号： C08G18/6659 , C08G18/0823 , C08G18/12 , C08G18/4216 , C08G18/755 , C08G18/3228
摘要： A process for the production of an aqueous polyurethane urea resin dispersion with a carboxyl number of 10 to 50 mg KOH/g resin solids and a ketone content of 5 to 10 wt. % relative to resin solids, comprising the steps: 1) producing a carboxylate-functional, non-gelled, water-dispersible polyurethane prepolymer with a free isocyanate group content of 1.5 to 3 wt. % by reacting at least one polyol, at least one tertiary amine-neutralized polyhydroxycarboxylic acid and at least one polyisocyanate, in the presence of at least one ketone, 2) converting the ketone solution into an aqueous dispersion by mixing with water, and 3) chain extending the polyurethane prepolymer by reacting the free isocyanate groups thereof with water and/or at least one compound, having at least two amino groups capable of addition to isocyanate groups, to form urea groups, wherein the proportion of the ketone or ketones used in step 1) is selected in such a way that the aqueous polyurethane urea resin dispersion, obtained contains 5 to 10 wt. % of ketone relative to the resin solids.
摘要翻译：一种制备羧基数为10至50mg KOH / g树脂固体和酮含量为5至10重量％的水性聚氨酯脲树脂分散体的方法。包括以下步骤：1）制备游离异氰酸酯基含量为1.5-3重量％的羧酸盐官能的，非胶凝的水分散性聚氨酯预聚物。通过使至少一种多元醇，至少一种叔胺中和的聚羟基羧酸和至少一种多异氰酸酯在至少一种酮的存在下反应，2）通过与水混合将酮溶液转化成水分散体，和3）通过使其游离异氰酸酯基团与水和/或至少一种具有至少两个能够加成异氰酸酯基团的氨基的化合物反应形成尿素基团来延伸聚氨酯预聚物，其中所用的酮或酮的比例选择步骤1），使得得到的水性聚氨酯脲树脂分散体含有5〜10重量％酮相对于树脂固体的％。

5. 发明授权

US5880209A Binder formulation for producing pigment 失效
标题翻译：用于生产颜料的粘合剂配方
公开(公告)号：US5880209A
公开(公告)日：1999-03-09
申请号：US807379
申请日：1997-02-27
申请人： Hans-Peter Patzschke , Armin Goebel , Jurgen Dobert , Reinhard Windmann
发明人： Hans-Peter Patzschke , Armin Goebel , Jurgen Dobert , Reinhard Windmann
IPC分类号： C08G18/08 , C08G18/42 , C08G18/66 , C09D5/02 , C09D5/06 , C09D17/00 , C09D133/04 , C09D133/06 , C09D163/00 , C09D175/00 , C09D175/04 , C09D175/06 , C09D201/00 , C09J175/04 , C09J175/06 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C09D175/06 , C08G18/0819 , C08G18/6659 , C09D17/00
摘要： A pigment paste forming resin having a viscosity of from about 50 to about 5,000 mPa and a solids content of from about 20 to about 40%, containing from about 20 to about 50 parts of a polyester urethane resin having an acid number of from about 10 to about 50, with from about 70 to about 100% of the acid groups being neutralized, the resin being prepared by the reaction of (a) one or more polyester polyols that do not contain any carboxyl groups, having an OH number of from about 35 to about 200, and a number average molecular weight of from about 500 to about 5000, mixed with from about 2 to about 30 wt. % based on the polyester polyol of one or more low molecular weight diols having a molecular weight of from about 60 to about 350, whereby a part of the low molecular weight diol contains at least one acid group capable of forming an anion, and with 0 to about 6 wt. % based on the polyester polyol of one or more low molecular weight triols having a molecular weight of from about 60 to about 350, said reaction being with (b) one or more diisocyanates in which where the ratio between the OH groups of polyester polyol, diol, and triol to the NCO groups of the diisocyanate is more than from about 1.0 to about 1.3, whereby the quantity of diisocyanate is selected to insure that the polyester urethane produced has a number average molecular weight of from about 2,000 to about 30,000; the reaction being carried out in the presence of (i) from about 0.3 to about 18 parts by weight of ammonia and/or an amine; (ii) from about 4 to about 25 parts by weight of one or more organic solvents that are at least partly miscible with water; and (iii) from about 15 to about 75 parts by weight of water.
摘要翻译：一种颜料糊形成树脂，其粘度为约50至约5,000mPa，固体含量为约20至约40％，含有约20至约50份的酸值为约10的聚酯聚氨酯树脂至约50，约70至约100％的酸基团被中和，所述树脂通过（a）一种或多种不含任何羧基的聚酯多元醇（其OH值为约 35至约200，数均分子量为约500至约5000，与约2至约30重量％基于分子量为约60至约350的一种或多种低分子量二醇的聚酯多元醇，其中低分子量二醇的一部分含有至少一个能够形成阴离子的酸基，并且与0 至约6wt。基于一种或多种分子量为约60至约350的低分子量三醇的聚酯多元醇，所述反应与（b）一种或多种二异氰酸酯反应，其中聚酯多元醇的OH基团之间的比例，二醇和三醇与二异氰酸酯的NCO基团的摩尔比大于约1.0至约1.3，由此选择二异氰酸酯的量以确保所生产的聚酯聚氨酯的数均分子量为约2,000至约30,000; 反应在（i）约0.3至约18重量份的氨和/或胺的存在下进行; （ii）约4至约25重量份的至少部分与水混溶的一种或多种有机溶剂; 和（iii）约15至约75重量份的水。

6. 发明授权

US5066689A Aqueous coating material method for its preparation and its use for electrophoretic coating 失效
标题翻译：水性涂料的制备方法及其电泳涂料的使用方法
公开(公告)号：US5066689A
公开(公告)日：1991-11-19
申请号：US574544
申请日：1990-08-28
申请人： Hans-Peter Patzschke , Armin Goebel
发明人： Hans-Peter Patzschke , Armin Goebel
IPC分类号： C09D163/00 , C08G59/56 , C09D5/44
CPC分类号： C09D5/4434 , C08G59/56
摘要： The invention relates to an aqueous coating agent which contains an organic synthetic resin binding agent which can be made dilutable with water by protonization with acids, containing crosslinking agents and a synthetic resin component containing organic amino groups and hydroxyl groups, and, in some cases, crosslinking catalysts and, if desired, pigments, fillers, corrosion inhibitors or anticorrosives, conventional lacquer adjuvants, and, in some cases, organic solvents in an amount up to 10% of the total weight of the coating agent.
摘要翻译：本发明涉及含有有机合成树脂粘合剂的水性涂料，该有机合成树脂粘合剂可以通过用酸质子化，含有交联剂和含有机氨基和羟基的合成树脂组分用水稀释，并且在某些情况下，交联催化剂和如果需要的话，颜料，填料，腐蚀抑制剂或抗腐蚀剂，常规漆助剂，以及在一些情况下，最高达涂层剂总重量的10％的有机溶剂。

7. 发明授权

US4857580A Crosslinked coating resin 失效
标题翻译：交联涂料树脂
公开(公告)号：US4857580A
公开(公告)日：1989-08-15
申请号：US219863
申请日：1988-07-12
申请人： Hans-Peter Patzschke , Peter W. Cerny , Armin Goebel , Karlheinz Stransky
发明人： Hans-Peter Patzschke , Peter W. Cerny , Armin Goebel , Karlheinz Stransky
IPC分类号： C08F8/00 , C08F8/32 , C09D5/44 , C09D133/04 , C09D133/14
CPC分类号： C09D133/14 , C08F8/32 , C09D5/4411
摘要： An externally crosslinkable aminopoly(meth)acrylate resin free from epoxy groups for water-dilutable lacquers having an amine number of from 30 to 150 and a hydroxyl number of from 30 to 450, obtainable by reacting a poly(meth)acrylate resin containing epoxy groups and having an average molecular weight (Mn) of from 600 to 10,000 and an epoxy equivalent weight of from 300 to 4000 with an excess of primary and/or secondary monoamines and/or amionoalcohols to react all the free epoxy groups with the amine groups and distilling off the unreacted excess amine compound, a process for its production and its use. The invention also relates to a CED bath which contains these aminopoly(meth)acrylate resins and crosslinking agents and, optionally, hydroxyfunctional resins and to its use for coating objects.
摘要翻译：不含环氧基的外部可交联的氨基（甲基）丙烯酸酯树脂，其可通过使含有环氧基的聚（甲基）丙烯酸酯树脂反应而获得的胺可数为30至150，羟基数为30至450的水可稀释漆并且具有600至10,000的平均分子量（＆Upbar＆Mn）和300至4000的环氧当量与过量的伯和/或仲单胺和/或氨基醇与所有游离环氧基团与胺基反应并蒸馏掉未反应的过量胺化合物，其制备方法及其用途。本发明还涉及包含这些氨基聚（甲基）丙烯酸酯树脂和交联剂以及任选的羟基官能树脂的CED浴，以及用于涂覆物体的CED浴。

8. 发明申请

US20060258800A1 Aqueous binder dispersions, process for the production thereof and coating compositions formulated therewith 审中-公开
标题翻译：水性粘合剂分散体，其制备方法和用其配制的涂料组合物
公开(公告)号：US20060258800A1
公开(公告)日：2006-11-16
申请号：US11229784
申请日：2005-09-19
申请人： Armin Goebel , Marcus Brunner , Marco Taschner , Holger Stamm
发明人： Armin Goebel , Marcus Brunner , Marco Taschner , Holger Stamm
IPC分类号： C08G18/08
CPC分类号： C08G18/4238 , C08G18/0823 , C08G18/348 , C09D175/04 , C08L2666/16
摘要： Aqueous binder dispersions, which may be produced by 1) mixing 50 to 95 solids pbw (parts by weight) of non-aqueous polyurethane resin with 5 to 50 solids pbw of non-aqueous aminoplast resin, wherein the total of the solids pbw amounts to 100 and wherein polyurethane resin and aminoplast resin are inert towards each other, 2) converting the resultant non-aqueous mixture into an aqueous dispersion by mixing with water, and 3) subjecting the resultant aqueous dispersion to conditions which give rise to condensation reactions of the aminoplast resin present in the dispersion particles, until a tetrahydrofuran-insoluble binder fraction of the dispersion solids of 20 to 90 wt. % is obtained.
摘要翻译：水性粘合剂分散体，其可以通过以下方式制备：1）将50至95固体含量的重量比的非水性聚氨酯树脂与5至50固体含量的非水性氨基塑料树脂混合，其中固体pbw的总量相当于 100，其中聚氨酯树脂和氨基塑料树脂彼此是惰性的，2）通过与水混合将得到的非水性混合物转化成水分散体，和3）使所得水分散体经受引起存在于分散体颗粒中的氨基塑料树脂，直到分散体固体的四氢呋喃不溶性粘合剂级分为20至90wt。获得％。

9. 发明授权

US06350809B1 Water-borne base coats and process for preparing water-borne base coat/clear coat-two-layer coatings 失效
标题翻译：水性底漆和制备水性底漆/透明涂层 - 两层涂料的方法
公开(公告)号：US06350809B1
公开(公告)日：2002-02-26
申请号：US09631196
申请日：2000-08-03
申请人： Armin Goebel , Holger Schmidt , Manfred Stein , Bettina Vogt-Birnbrich
发明人： Armin Goebel , Holger Schmidt , Manfred Stein , Bettina Vogt-Birnbrich
IPC分类号： C08L6104
CPC分类号： C09D167/00
摘要： Water-borne base coats, the resin solid of which contain 40 to 90 wt-% of a water-dilutable polyester binder, 0 to 50 wt-% of one or more additional binders, 0 to 20 wt-% of one or more paste resins and 10 to 40 wt-% of one or more cross-linking agents, wherein the water-dilutable polyester binder has a weight average molecular mass of 5000 to 50000, an acid value of 10 to 50 mg KOH/g, a hydroxyl value of 30 to 100 mg KOH/g and an average hydroxyl-functionality of 2 to 3 and consists of 5 to 25 wt-% of structural units —O—R—O— derived from one or more macrodiols having a hydroxyl value of 25 to 120 mg KOH/g, wherein R represents residues located between the terminal hydroxyl groups of the one or more macrodiols, are suitable for preparing water-borne base coat/clear coat-two-layer coatings, in particular water-borne base coat/powder clear coat two-layer coatings.
摘要翻译：水性底漆，其树脂固体含有40〜90重量％的水可稀释聚酯粘合剂，0〜50重量％的一种或多种附加粘合剂，0〜20重量％的一种或多种浆料树脂和10〜40重量％的一种或多种交联剂，其中水可稀释聚酯粘合剂的重均分子量为5000〜50000，酸值为10〜50mg KOH / g，羟值 30至100mg KOH / g，平均羟基官能度为2至3，并由5至25重量％的结构单元组成，ORO-衍生自一种或多种羟基值为25至120mg KOH / g，其中R表示位于一种或多种大分子二醇的末端羟基之间的残基，适于制备水性底涂层/透明涂层 - 两层涂层，特别是水性底涂层/ 层涂层。

10. 发明授权

US4600485A Aqueous electrodip lacquer coating compound capable of being deposited at the cathode, and its use 失效
公开(公告)号：US4600485A
公开(公告)日：1986-07-15
申请号：US802155
申请日：1985-11-25
申请人： Hans-Peter Patzschke , Armin Goebel , Klausjorg Klein
发明人： Hans-Peter Patzschke , Armin Goebel , Klausjorg Klein
IPC分类号： C08G59/10 , C09D5/44 , C25D13/00
CPC分类号： C09D5/4453 , C08G59/10 , C09D5/4434 , Y10S524/901
摘要： Aqueous electrodip lacquer coating compound capable of being deposited cathodically, containing, as synthetic resin binder,(A) 55 to 95% by weight of synthetic resin binder which can be rendered water soluble by protonation with acid and(B) 5 to 45% by weight of a cross-linking agent containing ester groups capable of transesterification and/or transamidation and having terminal ester groups which are substantially stable in a neutral aqueous medium but capable of reacting with synthetic resin binder (A) in an alkaline medium at temperatures above 140.degree. C., component (A) containing in its molecule at least one molecule-enlarging diamine of the formula ##STR1## wherein the symbol Y stands for H or C.sub.m H.sub.2m+1 (m=1 to 8) or an organic group used for defunctionalization, which is formed by the reaction of the primary amino group with monoepoxides, and the symbol X represents a molecular grouping having at least one amide and/or urea group.

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