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1. 发明申请

US20060247357A1 Process for the production of aqueous binder latices 有权
标题翻译：生产含水粘合剂胶乳的方法
公开(公告)号：US20060247357A1
公开(公告)日：2006-11-02
申请号：US11273834
申请日：2005-11-15
申请人： Tonnie Willems , Matthieu Barrere , Kok-Far Lee , Frank Tessari , Stefan Wiggerhaus , Paul Bruylants , Eric Houze
发明人： Tonnie Willems , Matthieu Barrere , Kok-Far Lee , Frank Tessari , Stefan Wiggerhaus , Paul Bruylants , Eric Houze
IPC分类号： C09B67/00 , C08F283/00
CPC分类号： C09D151/003 , C08F265/02 , C08F265/06 , C08F2/22
摘要： A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a mixture A of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture A of 10 to 100 mg of KOH/g and 0.5 to 5 wt. % of at least one olefinically polyunsaturated monomer, in the aqueous phase, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one mixture B of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture B or each of the mixtures B of 0 to below 5 mg of KOH/g, at least one monomer with at least one hydroxyl group in a proportion corresponding to a hydroxyl value of mixture B or each of the mixtures B of 0 to below 5 mg of KOH/g and at least one olefinically polyunsaturated monomer in a proportion of 0.5 to 5 wt. %, relative to mixture B or each of the mixtures B, in the presence of the product obtained in process step 2), wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt. % of the monomers of mixture A have been polymerized to completion.
摘要翻译：一种在水相中通过多级乳液聚合生产含水粘合剂胶乳的方法，包括以下连续步骤：1）烯属不饱和的可自由基聚合的单体的混合物A的自由基聚合，其包含至少一种单体，至少一个酸基团，其比例对应于混合物A的酸值为10至100mg KOH / g和0.5至5wt。在水相中至少一种烯属多不饱和单体的％）2）中和方法步骤1）中形成的聚合物的酸基团，和3）至少一种烯属不饱和的可自由基聚合的混合物B的自由基聚合单体，其包含至少一种具有至少一个酸基团的单体，其比例对应于混合物B的酸值或0至低于5mg KOH / g的混合物B的每一种，至少一种具有至少一个羟基的单体以对应于混合物B或混合物B的每一种为0至低于5mg KOH / g的羟基值的比例和至少一种0.5至5wt。％的烯属多不饱和单体。在工艺步骤2）中获得的产物存在下，相对于混合物B或混合物B中的每一种，其中混合物A与至少一种混合物B的重量比为15:85至85:15 并且其中中和在工艺步骤2）中不开始直至至少90wt。混合物A的单体的％已经聚合完成。

2. 发明授权

US07825173B2 Process for the production of aqueous binder latices 有权
标题翻译：生产含水粘合剂胶乳的方法
公开(公告)号：US07825173B2
公开(公告)日：2010-11-02
申请号：US11273834
申请日：2005-11-15
申请人： Tonnie Willems , Matthieu Barrere , Kok-Far Lee , Frank Tessari , Stefan Wiggershaus , Paul P. Bruylants , Eric C. Houze
发明人： Tonnie Willems , Matthieu Barrere , Kok-Far Lee , Frank Tessari , Stefan Wiggershaus , Paul P. Bruylants , Eric C. Houze
IPC分类号： C08F265/02 , C08F265/06 , C09D151/00
CPC分类号： C09D151/003 , C08F265/02 , C08F265/06 , C08F2/22
摘要： A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a mixture A of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture A of 10 to 100 mg of KOH/g and 0.5 to 5 wt. % of at least one olefinically polyunsaturated monomer, in the aqueous phase, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one mixture B of olefinically unsaturated, free-radically polymerizable monomers, comprising at least one monomer with at least one acid group in a proportion corresponding to an acid value of mixture B or each of the mixtures B of 0 to below 5 mg of KOH/g, at least one monomer with at least one hydroxyl group in a proportion corresponding to a hydroxyl value of mixture B or each of the mixtures B of 0 to below 5 mg of KOH/g and at least one olefinically polyunsaturated monomer in a proportion of 0.5 to 5 wt. %, relative to mixture B or each of the mixtures B, in the presence of the product obtained in process step 2), wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt. % of the monomers of mixture A have been polymerized to completion.
摘要翻译：一种在水相中通过多级乳液聚合生产含水粘合剂胶乳的方法，包括以下连续步骤：1）烯属不饱和的可自由基聚合的单体的混合物A的自由基聚合，其包含至少一种单体，至少一个酸基团，其比例对应于混合物A的酸值为10至100mg KOH / g和0.5至5wt。在水相中至少一种烯属多不饱和单体的％）2）中和方法步骤1）中形成的聚合物的酸基团，和3）至少一种烯属不饱和的可自由基聚合的混合物B的自由基聚合单体，其包含至少一种具有至少一个酸基团的单体，其比例对应于混合物B的酸值或0至低于5mg KOH / g的混合物B的每一种，至少一种具有至少一个羟基的单体以对应于混合物B或混合物B的每一种为0至低于5mg KOH / g的羟基值的比例和至少一种0.5至5wt。％的烯属多不饱和单体。在工艺步骤2）中获得的产物存在下，相对于混合物B或混合物B中的每一种，其中混合物A与至少一种混合物B的重量比为15:85至85:15 并且其中中和在工艺步骤2）中不开始直至至少90wt。混合物A的单体的％已经聚合完成。

3. 发明授权

US07888439B2 Process for the production of aqueous binder latices 失效
标题翻译：生产含水粘合剂胶乳的方法
公开(公告)号：US07888439B2
公开(公告)日：2011-02-15
申请号：US12532730
申请日：2008-04-07
申请人： Tanja Renkes , Frank Tessari , Matthieu Barrere
发明人： Tanja Renkes , Frank Tessari , Matthieu Barrere
IPC分类号： C08F265/00 , C08F291/00 , C08F2/22 , C08F265/02 , C08L51/00 , C09D151/00
CPC分类号： C08F2/22 , C08F2/001 , C08F220/14 , C08F257/02 , C08F265/00 , C08F265/04 , C08F291/00 , C08L51/003 , C09D151/003 , C08L2666/02 , C08F2220/1825 , C08F220/20 , C08F220/06 , C08F220/40 , C08F2220/325 , C08F212/08
摘要： A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a monomer mixture A comprising acidic monomers in a proportion corresponding to an acid value of 10 to 100 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt %, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one monomer mixture B comprising acidic monomers in a proportion corresponding to an acid value of mixture(s) B of 0 to below 5 mg of KOH/g, hydroxyl-functional monomers in a proportion corresponding to a hydroxyl value of mixture(s) B of 0 to below 5 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt %, wherein the monomer composition of mixtures A and B is selected in such a manner that the calculated glass transition temperature (Tg) of a copolymer composed of a combination of only the olefinically monounsaturated monomers of mixtures A and B is in the range from 30 to 100° C., wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt. % of the monomers of mixture A have been polymerized to completion.
摘要翻译：一种在水相中通过多级乳液聚合制备含水粘合剂胶乳的方法，包括以下连续步骤：1）包含酸性单体的单体混合物A的自由基聚合，其比例对应于酸值为10至100mg 的KOH / g和烯属多不饱和单体的比例为0.5〜5重量％，2）中和工艺步骤1）中形成的聚合物的酸基和3）至少一种包含酸性单体的单体混合物B的自由基聚合以对应于0至低于5mg KOH / g的混合物B的酸值的比例，羟基官能单体的比例对应于混合物B的羟基值为0至低于5mg KOH / g和烯属多不饱和单体的比例为0.5-5wt％，其中混合物A和B的单体组成以这样的方式选择，即所计算的共聚物玻璃化转变温度（Tg）由混合物A和B仅烯烃单不饱和单体的组合在30至100℃的范围内，其中混合物A与至少一种混合物B的重量比为15:85至85:15，其中在工艺步骤2）中不开始中和，直到至少90wt。混合物A的单体的％已经聚合完成。

4. 发明申请

US20100113675A1 PROCESS FOR THE PRODUCTION OF AQUEOUS BINDER LATICES 审中-公开
标题翻译：生产水性粘合剂的方法
公开(公告)号：US20100113675A1
公开(公告)日：2010-05-06
申请号：US12532717
申请日：2008-04-07
申请人： Tanja Renkes , Frank Tessari , Matthieu Barrere
发明人： Tanja Renkes , Frank Tessari , Matthieu Barrere
IPC分类号： C08L37/00
CPC分类号： C08F265/04 , C08F257/02 , C08F265/00 , C08F265/02 , C08F265/06 , C08F283/10 , C08L51/00 , C09D151/00
摘要： A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a monomer mixture A comprising acidic monomers in a proportion corresponding to an acid value of 10 to 100 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt %, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one monomer mixture B comprising acidic monomers in a proportion corresponding to an acid value of mixture(s) B of 0 to below 5 mg of KOH/g, hydroxyl-functional monomers in a proportion corresponding to a hydroxyl value of mixture(s) B of 0 to below 5 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt %, wherein mixture A and/or the at least one mixture B comprise at least one epoxy-functional, olefinically monounsaturated, free-radically polymerizable monomer in a total proportion of 2 to 20 wt.-% relative to the sum of the weights of mixtures A and B, wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt. % of the monomers of mixture A have been polymerized to completion.
摘要翻译：一种在水相中通过多级乳液聚合制备含水粘合剂胶乳的方法，包括以下连续步骤：1）包含酸性单体的单体混合物A的自由基聚合，其比例对应于酸值为10至100mg 的KOH / g和烯属多不饱和单体的比例为0.5〜5重量％，2）中和工艺步骤1）中形成的聚合物的酸基和3）至少一种包含酸性单体的单体混合物B的自由基聚合以对应于0至低于5mg KOH / g的混合物B的酸值的比例，羟基官能单体的比例对应于混合物B的羟基值为0至低于5mg KOH / g和烯属多不饱和单体，其中混合物A和/或至少一种混合物B包含至少一种环氧官能的烯属单不饱和的可自由基聚合的单体，总比例为2至20重量％，相对于混合物A和B的重量之和，其中混合物A与至少一种混合物B的重量比为15:85至85:15，其中在工艺步骤2）中不起始中和，直到至少90wt。混合物A的单体的％已经聚合完成。

5. 发明申请

US20100130680A1 PROCESS FOR THE PRODUCTION OF AQUEOUS BINDER LATICES 失效
标题翻译：生产水性粘合剂的方法
公开(公告)号：US20100130680A1
公开(公告)日：2010-05-27
申请号：US12532730
申请日：2008-04-07
申请人： Tanja Renkes , Frank Tessari , Matthieu Barrere
发明人： Tanja Renkes , Frank Tessari , Matthieu Barrere
IPC分类号： C08F2/22 , C08F265/00
CPC分类号： C08F2/22 , C08F2/001 , C08F220/14 , C08F257/02 , C08F265/00 , C08F265/04 , C08F291/00 , C08L51/003 , C09D151/003 , C08L2666/02 , C08F2220/1825 , C08F220/20 , C08F220/06 , C08F220/40 , C08F2220/325 , C08F212/08
摘要： A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a monomer mixture A comprising acidic monomers in a proportion corresponding to an acid value of 10 to 100 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt %, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one monomer mixture B comprising acidic monomers in a proportion corresponding to an acid value of mixture(s) B of 0 to below 5 mg of KOH/g, hydroxyl-functional monomers in a proportion corresponding to a hydroxyl value of mixture(s) B of 0 to below 5 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt %, wherein the monomer composition of mixtures A and B is selected in such a manner that the calculated glass transition temperature (Tg) of a copolymer composed of a combination of only the olefinically monounsaturated monomers of mixtures A and B is in the range from 30 to 100° C., wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt. % of the monomers of mixture A have been polymerized to completion.
摘要翻译：一种在水相中通过多级乳液聚合制备含水粘合剂胶乳的方法，包括以下连续步骤：1）包含酸性单体的单体混合物A的自由基聚合，其比例对应于酸值为10至100mg 的KOH / g和烯属多不饱和单体的比例为0.5〜5重量％，2）中和工艺步骤1）中形成的聚合物的酸基和3）至少一种包含酸性单体的单体混合物B的自由基聚合以对应于0至低于5mg KOH / g的混合物B的酸值的比例，羟基官能单体的比例对应于混合物B的羟基值为0至低于5mg KOH / g和烯属多不饱和单体的比例为0.5-5wt％，其中混合物A和B的单体组成以这样的方式选择，即所计算的共聚物玻璃化转变温度（Tg）由混合物A和B仅烯烃单不饱和单体的组合在30至100℃的范围内，其中混合物A与至少一种混合物B的重量比为15:85至85:15，其中在工艺步骤2）中不开始中和，直到至少90wt。混合物A的单体的％已经聚合完成。

6. 发明申请

US20100120986A1 PROCESS FOR THE PRODUCTION OF AQUEOUS BINDER LATICES 审中-公开
标题翻译：生产水性粘合剂的方法
公开(公告)号：US20100120986A1
公开(公告)日：2010-05-13
申请号：US12532742
申请日：2008-04-07
申请人： Tanja Renkes , Frank Tessari , Matthieu Barrere
发明人： Tanja Renkes , Frank Tessari , Matthieu Barrere
IPC分类号： C08L25/06
CPC分类号： C08F257/02 , C08F265/00 , C08F265/02 , C08F265/04 , C08F265/06 , C08F291/00 , C08L51/00 , C09D151/00
摘要： A process for the production of aqueous binder latices by multistage emulsion polymerization in the aqueous phase, comprising the successive steps: 1) free-radical polymerization of a monomer mixture A comprising acidic monomers in a proportion corresponding to an acid value of 10 to 100 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt %, 2) neutralization of acid groups of the polymer formed in process step 1) and 3) free-radical polymerization of at least one monomer mixture B comprising acidic monomers in a proportion corresponding to an acid value of mixture(s) B of 0 to below 5 mg of KOH/g, hydroxyl-functional monomers in a proportion corresponding to a hydroxyl value of mixture(s) B of 0 to below 5 mg of KOH/g and olefinically polyunsaturated monomers in a proportion of 0.5 to 5 wt %, wherein mixture A and/or the at least one mixture B comprise at least one aromatic monomer in a total proportion of 10 to 50 wt.-% relative to the sum of the weights of mixtures A and B, wherein the ratio by weight of mixture A to the at least one mixture B is from 15:85 to 85:15 and wherein neutralization is not begun in process step 2) until at least 90 wt. % of the monomers of mixture A have been polymerized to completion.
摘要翻译：一种在水相中通过多级乳液聚合制备含水粘合剂胶乳的方法，包括以下连续步骤：1）包含酸性单体的单体混合物A的自由基聚合，其比例对应于酸值为10至100mg 的KOH / g和烯属多不饱和单体的比例为0.5〜5重量％，2）中和工艺步骤1）中形成的聚合物的酸基和3）至少一种包含酸性单体的单体混合物B的自由基聚合以对应于0至低于5mg KOH / g的混合物B的酸值的比例，羟基官能单体的比例对应于混合物B的羟基值为0至低于5mg KOH / g和0.5-5重量％的烯属多不饱和单体，其中混合物A和/或至少一种混合物B包含至少一种芳族单体，总比例为10至50重量％，相对于总重量混合物A和B的混合物，其中混合物A与至少一种混合物B的重量比为15:85至85:15，并且其中中和在工艺步骤2）中不开始直至至少90wt。混合物A的单体的％已经聚合完成。

7. 发明申请

US20110160379A1 COATING COMPOSITION TO OBTAIN SURFACE EFFECTS 审中-公开
标题翻译：涂料组合物可获得表面活性
公开(公告)号：US20110160379A1
公开(公告)日：2011-06-30
申请号：US12940404
申请日：2010-11-05
申请人： GABRIELE BUETTNER , Matthieu Barrere , Joern Vestweber
发明人： GABRIELE BUETTNER , Matthieu Barrere , Joern Vestweber
IPC分类号： C09D175/04
CPC分类号： C08G18/6254 , C08G18/6229
摘要： This invention provides a coating composition providing a soft-feel effect and enhanced suntan cream resistance, the composition comprising A) 5 to 50 wt %, preferably 20 to 40 wt %, of an dispersion and/or solution of at least one hydroxyl functional polyurethane, the dispersion and/or solution having a solids content in a range of 25 to 90 wt %, the wt % being based on the weight of the dispersion and/or solution, B) 0 to 35 wt %, preferably 5 to 20 wt %, of at least one polyisocyanate as cross-linking agent, C) 0.1 to 20 wt %, preferably 4 to 15 wt %, of at least one aqueous hydroxyl functional crosslinked (meth) acrylic latex, D) 0 to 20 wt %, preferably 4 to 15 wt %, of organic solvent, and E) 0.1 to 10 wt %, preferably 4 to 10 wt %, of at least one pigment, extender and/or coating additive, the wt % being based on the total weight of the composition of A) to E).
摘要翻译：本发明提供一种提供柔软效果和增强的防晒霜的涂料组合物，该组合物包含A）5至50重量％，优选20至40重量％的至少一种羟基官能聚氨酯的分散体和/或溶液，所述分散体和/或溶液的固体含量在25至90重量％的范围内，wt％基于分散体和/或溶液的重量，B）0-35重量％，优选5-20重量％％的至少一种作为交联剂的多异氰酸酯，C）0.1至20重量％，优选4至15重量％的至少一种羟基官能交联的（甲基）丙烯酸羟丙酯胶乳，D）0-20重量％优选4至15重量％的有机溶剂，和E）0.1至10重量％，优选4至10重量％的至少一种颜料，增量剂和/或涂料添加剂，所述wt％基于 A）到E）的组成。

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