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1. 发明授权

US06903171B2 Polymerized cycloolefins using transition metal catalyst and end products thereof 有权
标题翻译：使用过渡金属催化剂及其最终产物的聚合环烯烃
公开(公告)号：US06903171B2
公开(公告)日：2005-06-07
申请号：US10271393
申请日：2002-10-15
申请人： Larry Funderburk Rhodes , Andrew Bell , Ramakrishna Ravikiran , John C. Fondran , Saikumar Jayaraman , Brian Leslie Goodall , Richard A. Mimna , John-Henry Lipian
发明人： Larry Funderburk Rhodes , Andrew Bell , Ramakrishna Ravikiran , John C. Fondran , Saikumar Jayaraman , Brian Leslie Goodall , Richard A. Mimna , John-Henry Lipian
IPC分类号： C08F4/70 , C08F32/00 , C08F32/08 , C08G61/06 , G02B1/04 , C08F4/80
CPC分类号： C08G61/06 , C08F32/00 , C08F32/08 , G02B1/04 , C08L65/00
摘要： Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译：使用阳离子第10族金属络合物和下式的弱配位阴离子加成聚合环烯的方法：<？in-line-formula description =“In-line formula”end =“lead”？> [（R' M（L'）x（L“）Y'B <？in-line-formula description =“In-line Formulas”end =“tail”？>其中[（R'）Z M（L'）x < （L“）Y是阳离子络合物，其中M表示第10族过渡金属; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1，其中x，y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位抗衡阴离子络合物在总体催化剂络合物上平衡电荷的次数的数字。

2. 发明授权

US06232417B1 Photoresist compositions comprising polycyclic polymers with acid labile pendant groups 失效
标题翻译：包含具有酸不稳定侧基的多环聚合物的光致抗蚀剂组合物
公开(公告)号：US06232417B1
公开(公告)日：2001-05-15
申请号：US08928573
申请日：1997-09-12
申请人： Larry F Rhodes , Andrew Bell , Saikumar Jayaraman , John-Henry Lipian , Brian L. Goodall , Robert A. Shick
发明人： Larry F Rhodes , Andrew Bell , Saikumar Jayaraman , John-Henry Lipian , Brian L. Goodall , Robert A. Shick
IPC分类号： C08F480
CPC分类号： G03F7/0045 , C08G61/08 , G03F7/038 , G03F7/039 , Y10S430/109 , Y10S430/111 , Y10S430/115
摘要： The present invention relates to a radiation sensitive photoresist composition comprising a photoacid initiator and a polycyclic polymer comprising repeating units that contain pendant acid labile groups. Upon exposure to an imaging radiation source the photoacid initiator generates an acid which cleaves the pendant acid labile groups effecting a polarity change in the polymer. The polymer is rendered soluble in an aqueous base in the areas exposed to the imaging source. The polymer repeating units are polymerized from polycyclic monomers in the presence of single or multicomponent catalyst systems containing a Group VIII metal
摘要翻译：本发明涉及包含光酸引发剂和包含含有酸不稳定基团的重复单元的多环聚合物的辐射敏感性光致抗蚀剂组合物。在暴露于成像辐射源时，光酸引发剂产生酸，该酸切割引起聚合物极性变化的侧链酸不稳定基团。聚合物在暴露于成像源的区域中变得可溶于碱性水溶液。聚合物重复单元在含有VIII族金属的单组分或多组分催化剂体系存在下由多环单体聚合

3. 发明授权

US07674847B2 Vinyl addition polycyclic olefin polymers prepared with non-olefinic chain transfer agents and uses thereof 有权
标题翻译：用非烯烃链转移剂制备的乙烯基加成多环烯烃聚合物及其用途
公开(公告)号：US07674847B2
公开(公告)日：2010-03-09
申请号：US10782547
申请日：2004-02-19
申请人： Larry F. Rhodes , Dennis A. Barnes , Andrew Bell , Brian K. Bennet , Chung Chang , John-Henry Lipian , Xiaoming Wu
发明人： Larry F. Rhodes , Dennis A. Barnes , Andrew Bell , Brian K. Bennet , Chung Chang , John-Henry Lipian , Xiaoming Wu
IPC分类号： C08F4/44
CPC分类号： C08F2/38 , C08F232/00 , C08F232/08 , Y10S526/905
摘要： A method of polymerizing poly(cyclic)olefin monomers encompassing (a) combining a monomer composition containing the poly(cyclic)olefin monomers, a non-olefinic chain transfer agent and an activator compound to form a mixture; (b) heating the mixture; and (c) adding a polymerization catalyst containing Ni and/or Pd. The non-olefinic chain transfer agent includes one or more compounds selected from H2, alkylsilanes, alkylalkoxysilanes, alkylgermanes, alkylalkoxygermanes, alkylstannanes, and alkylalkoxystannanes. The activator is characterized as having an active hydrogen with a pKa of at least 5. The resulting poly(cyclic)olefin polymers can be used in photoresist compositions.
摘要翻译：聚合聚（环状）烯烃单体的方法包括（a）将含有聚（环状）烯烃单体，非烯烃链转移剂和活化剂化合物的单体组合物混合以形成混合物; （b）加热混合物; 和（c）加入含有Ni和/或Pd的聚合催化剂。非烯烃链转移剂包括一种或多种选自H 2，烷基硅烷，烷基烷氧基硅烷，烷基锗烷，烷基烷氧基锗烷，烷基锡烷和烷基烷氧基烷烃的化合物。活化剂的特征在于具有pKa至少为5的活性氢。所得聚（环状）烯烃聚合物可用于光致抗蚀剂组合物中。

4. 发明申请

US20060074206A1 Catalyst for polymerization of norbornene 失效
公开(公告)号：US20060074206A1
公开(公告)日：2006-04-06
申请号：US11242227
申请日：2005-10-03
申请人： John-Henry Lipian
发明人： John-Henry Lipian
IPC分类号： C08F4/70 , B01J31/00
CPC分类号： C08F232/08 , C08F4/70 , Y10S526/904
摘要： This invention is based upon the discovery that a catalyst system which is comprised of (a) palladium or a palladium compound and (b) a fluorinated alcohol is effective for polymerizing norbornene-functional monomers into polynorbornene-functional polymers. It has been further discovered that this catalyst system is more effective in polymerizing certain norbornene-functional monomers that are difficult to polymerize, such as norbornene ester monomers, than prior art catalyst systems. The activity of the catalyst systems of this invention can be further improved with respect to polymerizing some monomers by including a Lewis acid and/or a ligand, such as a phosphine or a carbene, in the system. In any case, the catalyst systems of this invention offer the advantage of being soluble in a wide variety of solvents, relatively inexpensive, and capable of polymerizing many norbornene-functional monomers that are difficult to polymerize with conventional catalyst systems. The subject invention more specifically discloses a catalyst system that is especially useful for the polymerization of norbornene-functional monomers which is comprised of (a) palladium or a palladium compound and (b) a fluorinated alcohol. The present invention also reveals a process for synthesizing a norbornene-functional polymer which comprised polymerizing a norbornene-functional monomer in a solvent in the presence of a catalyst system that is comprised of (a) palladium or a palladium compound and (b) a fluorinated alcohol.

5. 发明授权

US06649714B2 Processes for making polymers containing pendant cyclic anhydride groups 失效
标题翻译：制备含有侧链环酐基团的聚合物的方法
公开(公告)号：US06649714B2
公开(公告)日：2003-11-18
申请号：US10375231
申请日：2003-02-27
申请人： Saikumar Jayaraman , Brian L. Goodall , Richard Vicari , John-Henry Lipian
发明人： Saikumar Jayaraman , Brian L. Goodall , Richard Vicari , John-Henry Lipian
IPC分类号： C08F480
CPC分类号： C08G61/122 , C08G61/06 , C08G61/08
摘要： A process for polymerizing polycycloolefins containing pendant anhydride moieties is disclosed. The process utilizes a single component nickel containing catalyst of the formula EnNi(C6F5)2 wherein n is 1 or 2 and E represents a neutral electron donor ligand.
摘要翻译：公开了一种聚合含有侧链酸酐部分的聚环烯烃的方法。该方法使用式为EnNi（C6F5）2的单组分含镍催化剂，其中n为1或2，E为中性电子给体配体。

6. 发明授权

US07851575B2 Polycyclic polymers containing pendant ion conducting moieties 有权
标题翻译：含有侧离子导电部分的多环聚合物
公开(公告)号：US07851575B2
公开(公告)日：2010-12-14
申请号：US11983505
申请日：2007-11-09
申请人： Ramakrishna Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
发明人： Ramakrishna Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
IPC分类号： C08F30/02
CPC分类号： C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要： A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译：公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途，特别是在燃料电池中。

7. 发明申请

US20100177488A1 Vinyl Addition Polycyclic Olefin Polymers Prepared With Non-Olefinic Chain Transfer Agents And Uses Thereof 有权
标题翻译：用非烯烃链转移剂制备的乙烯基加成多环烯烃聚合物及其用途
公开(公告)号：US20100177488A1
公开(公告)日：2010-07-15
申请号：US12699909
申请日：2010-02-04
申请人： Larry F. Rhodes , Dennis A. Barnes , Andrew Bell , Brian K. Bennett , Chun Chang , Xiaoming Wu , John-Henry Lipian
发明人： Larry F. Rhodes , Dennis A. Barnes , Andrew Bell , Brian K. Bennett , Chun Chang , Xiaoming Wu , John-Henry Lipian
IPC分类号： H05K7/02 , G03F7/004 , G03F7/20 , C08F232/08 , C08F4/72
CPC分类号： C08F2/38 , C08F232/00 , C08F232/08 , Y10S526/905
摘要： A method of polymerizing poly(cyclic)olefin monomers encompassing (a) combining a monomer composition containing the poly(cyclic)olefin monomers, a non-olefinic chain transfer agent and an activator compound to faun a mixture; (b) heating the mixture; and (c) adding a polymerization catalyst containing Ni and/or Pd. The non-olefinic chain transfer agent includes one or more compounds selected from H2, alkylsilanes, alkylalkoxysilanes, alkylgermanes, alkylalkoxygermanes, alkylstannanes, and alkylalkoxystannanes. The activator is characterized as having an active hydrogen with a pKa of at least 5. The resulting poly(cyclic)olefin polymers can be used in photoresist compositions.
摘要翻译：聚合聚（环状）烯烃单体的方法包括（a）将含有聚（环状）烯烃单体，非烯烃链转移剂和活化剂化合物的单体组合物混合以形成混合物; （b）加热混合物; 和（c）加入含有Ni和/或Pd的聚合催化剂。非烯烃链转移剂包括一种或多种选自H 2，烷基硅烷，烷基烷氧基硅烷，烷基锗烷，烷基烷氧基锗烷，烷基锡烷和烷基烷氧基烷烃的化合物。活化剂的特征在于具有pKa至少为5的活性氢。所得聚（环状）烯烃聚合物可用于光致抗蚀剂组合物中。

8. 发明申请

US20050019638A1 Polycyclic polymers containing pendant ion conducting moieties 有权
标题翻译：含有侧离子导电部分的多环聚合物
公开(公告)号：US20050019638A1
公开(公告)日：2005-01-27
申请号：US10860876
申请日：2004-06-04
申请人： R. Ravikiran , Xiaoming Wu , Larry Rhodes , Robert Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Saikumar Jayaraman , Robert Duff , John-Henry Lipian
发明人： R. Ravikiran , Xiaoming Wu , Larry Rhodes , Robert Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Saikumar Jayaraman , Robert Duff , John-Henry Lipian
IPC分类号： C08G61/06 , C08J5/22 , H01B1/12 , H01M4/86 , H01M8/10 , C08G75/24 , C08G79/02
CPC分类号： C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要： A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译：公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途，特别是在燃料电池中。

9. 发明授权

US06525153B1 Polycyclic polymers containing pendant cyclic anhydride groups 有权
标题翻译：含有环状酸酐基团的多环聚合物
公开(公告)号：US06525153B1
公开(公告)日：2003-02-25
申请号：US09521351
申请日：2000-03-09
申请人： Saikumar Jayaraman , Brian L. Goodall , Richard Vicari , John-Henry Lipian , Robert David Allen , Juliann Opitz , Thomas I. Wallow
发明人： Saikumar Jayaraman , Brian L. Goodall , Richard Vicari , John-Henry Lipian , Robert David Allen , Juliann Opitz , Thomas I. Wallow
IPC分类号： C08F1000
CPC分类号： C08G61/122 , C08G61/08 , G03F7/0045 , G03F7/039 , G03F7/0395
摘要： Polymers comprising polycyclic repeating units containing pendant anhydride moieties are disclosed. The polymer can be polymerized from polycycloolefins containing pendant anhydride moieties in the presence of a nickel containing single component catalyst. In optional embodiments the polycycloolefin monomer containing the pendant anhydride functionality can be copolymerized with other polycycloolefin monomers that contain pendant functional groups to yield random copolymer products.
摘要翻译：公开了包含含有侧链酸酐部分的多环重复单元的聚合物。聚合物可以在含镍单组分催化剂的存在下由含有侧链酸酐部分的聚环烯烃聚合。在任选的实施方案中，含有侧链官能团的聚环烯烃单体可与含有侧链官能团的其它聚环烯烃单体共聚以产生无规共聚物产物。

10. 发明申请

US20080242750A1 Polycyclic polymers containing pendant ion conducting moieties 有权
标题翻译：含有侧离子导电部分的多环聚合物
公开(公告)号：US20080242750A1
公开(公告)日：2008-10-02
申请号：US11983505
申请日：2007-11-09
申请人： R. Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
发明人： R. Ravikiran , Xiaoming Wu , Larry F. Rhodes , Robert A. Shick , Hiroko Nakano , Hirotaka Nonaka , Huabin Wang , Robert John Duff , Saikumar Jayaraman , John-Henry Lipian
IPC分类号： B01J47/12
CPC分类号： C08J5/2256 , C08G61/06 , C08J2385/04 , H01B1/122 , H01M4/8605 , H01M8/1023 , H01M8/1025 , H01M8/1032 , H01M8/1039
摘要： A polymer comprising polycyclic repeating units having recurring ion conducting groups and optional crosslinkable groups is disclosed. The present invention provides the capability of tailoring polymers to impart unique properties to membranes fabricated from the polymers. Membranes comprising the polymers and methods for preparing the membranes and their use in ion conducting membranes, particularly in fuel cells, are also provided.
摘要翻译：公开了包含具有重复离子导电基团和任选的可交联基团的多环重复单元的聚合物。本发明提供了定制聚合物以赋予由聚合物制造的膜独特的性能的能力。还提供了包含聚合物的膜和用于制备膜的方法及其在离子传导膜中的用途，特别是在燃料电池中。

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