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1. 发明授权

US06323296B1 Metathesis polymerized olefin composites including sized reinforcement material 有权
标题翻译：复分解聚合烯烃复合材料，包括尺寸增强材料
公开(公告)号：US06323296B1
公开(公告)日：2001-11-27
申请号：US09514481
申请日：2000-02-28
申请人： Mark Warner , Steven D. Drake , Michael A. Giardello
发明人： Mark Warner , Steven D. Drake , Michael A. Giardello
IPC分类号： C08F480
CPC分类号： C08J5/06 , C08J2365/00 , C08K9/04 , C08K9/06 , C08L45/00 , C08L65/00 , C08L23/02
摘要： A reinforced polyolefin article is provided which includes a sized reinforcement material incorporated in the article. The article may be prepared by polymerizing a cyclic olefin monomer in the presence of the sizing agent and a metathesis polymerization catalyst which includes ruthenium or osmium.
摘要翻译：提供了一种增强聚烯烃制品，其包括结合在制品中的尺寸增强材料。该制品可以通过在施胶剂和包含钌或锇的易位聚合催化剂存在下聚合环烯烃单体来制备。

2. 发明授权

US06306987B1 Ruthenium and osmium catalysts 有权
标题翻译：钌和锇催化剂
公开(公告)号：US06306987B1
公开(公告)日：2001-10-23
申请号：US09446052
申请日：1999-12-16
申请人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Mühlebach
发明人： Paul Adriaan Van Der Schaaf , Andreas Hafner , Andreas Mühlebach
IPC分类号： C08F480
CPC分类号： B01J31/181 , B01J31/1825 , B01J31/2265 , B01J31/2282 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/0013 , C07F15/002 , C08G61/08
摘要： Disclosed is a compound of formula (I), and its use in preparing metathesis polymers of dicyclopentadiene and/or other strained cycloolefins in which Me is ruthenium or osmium; X1 and X2 independently of one another are anionic ligands, or X1 and X2 together are a bis-anionic ligand; Y is oxygen, sulfur or the groups —NR7— or —PR7—, where R7 is hydrogen or a substituent selected from the group C1-C6alkyl, C6-C13aralkyl, sulfonyl and —C(═O)Rs2 and Rs2 is hydrogen or a substituent selected from the group C1-C12alkyl, C2-C12alkenyl, C3-C12cycloalkyl, C3-C12cycloalkenyl, C2-C11heterocycloalkyl, C2-C11heterocycloalkenyl, C5-C12aryl, C1-C9heteroaryl, C6-C14aralkyl, C2-C13heteroaralkyl, C6-C14aralkenyl and C3-C13heteroaralkenyl; n is 0 or 1; L1 is tertiary phosphine; and L2 is a neutral e− donor ligand which is coordinated to the metal atom and is attached via the bridge group C* to the carbon atom of the carbene group if n is 0 and to Y if n is 1.
摘要翻译：公开了式（I）化合物及其用于制备Me是钌或锇的二环戊二烯和/或其它应变环烯烃的复分解聚合物; X1和X2彼此独立的是阴离子配体，或者X1和X2一起是双 - 阴离子配体; Y是氧，硫或基团-NR7-或-PR7-，其中R7是氢或选自C1-C6烷基，C6-C13芳烷基，磺酰基和-C（= O）Rs2和Rs2 是选自C 1 -C 12烷基，C 2 -C 12烯基，C 3 -C 12环烷基，C 3 -C 12环烯基，C 2 -C 11杂环烷基，C 2 -C 11杂环烯基，C 5 -C 12芳基，C 1 -C 9杂芳基，C 6 -C 14芳烷基，C 2 -C 13杂芳烷基，C 6 -C14链烯基和C3-C13杂碳烯基; n为0或1; L1为叔膦; L2为与金属原子配位并通过桥基C *连接至卡宾的碳原子的中性e-供体配体如果n为0，则为组，如果n为1则为Y。

3. 发明授权

US06252022B1 Molecular weight control in olefin polymerization 有权
标题翻译：烯烃聚合中的分子量控制
公开(公告)号：US06252022B1
公开(公告)日：2001-06-26
申请号：US09317104
申请日：1999-05-21
申请人： Samuel David Arthur , Joel David Citron
发明人： Samuel David Arthur , Joel David Citron
IPC分类号： C08F480
CPC分类号： C08F10/02 , C08F10/00 , C08F2410/01 , C08F4/7042
摘要： The molecular weight of polyolefins produced using iron or cobalt complexes of 2,6-pyridinecarboxaldehyde diimines or a 2,6-diacylpyridine diimines as polymerization catalysts may be lowered by carrying out the polymerization in the presence of hydrogen.
摘要翻译：使用2,6-吡啶甲醛二亚胺的铁或钴络合物或作为聚合催化剂的2,6-二酰基吡啶二亚胺生产的聚烯烃的分子量可以通过在氢存在下进行聚合来降低。

4. 发明授权

US06528598B1 Processes of making polymers containing pendant cyclic anhydride groups with nickel-ligand catalyst 失效
标题翻译：用镍配体催化剂制备含有环状酸酐基团的聚合物的方法
公开(公告)号：US06528598B1
公开(公告)日：2003-03-04
申请号：US09521349
申请日：2000-03-09
申请人： Saikumar Jayaraman , Brian L. Goodall , Richard Vicari , John-Henry Lipian
发明人： Saikumar Jayaraman , Brian L. Goodall , Richard Vicari , John-Henry Lipian
IPC分类号： C08F480
CPC分类号： C08G61/122 , C08G61/06 , C08G61/08
摘要： A process for polymerizing polycycloolefins containing pendant anhydride moieties is disclosed. The process utilizes a single component nickel containing catalyst of the formula EnNi(C6F5)2 wherein n is 1 or 2 and E represents a neutral electron donor ligand.
摘要翻译：公开了一种聚合含有侧链酸酐部分的聚环烯烃的方法。该方法使用式为EnNi（C6F5）2的单组分含镍催化剂，其中n为1或2，E为中性电子给体配体。

5. 发明授权

US06506860B1 Regio-regular copolymer and methods of forming same 失效
标题翻译： Regio-regular共聚物及其形成方法
公开(公告)号：US06506860B1
公开(公告)日：2003-01-14
申请号：US09671163
申请日：2000-09-28
申请人： Donald Albert Bansleben , Truc-Chi Thi Huynh-Tran , Rusty Lew Blanski , Paul Anthony Hughes , William Peyton Roberts , Robert Howard Grubbs , Galen Richard Hatfield
发明人： Donald Albert Bansleben , Truc-Chi Thi Huynh-Tran , Rusty Lew Blanski , Paul Anthony Hughes , William Peyton Roberts , Robert Howard Grubbs , Galen Richard Hatfield
IPC分类号： C08F480
CPC分类号： C08G61/08 , C08G61/06
摘要： A new and novel linear, regio-regular vicinal functionalized polymer methods of forming the same are described. The polymer has a linear hydrocarbon polymer backbone with vicinal functional groups having oxygen and/or nitrogen atom containing groups, such as hydroxy, carboxylic acid or ester, carbonyl acetate, amide, nitrile and the like, pendent from the polymer backbone chain in a regio-regular manner.
摘要翻译：描述了一种新的和新型的线性，区域规则的邻位官能化聚合物形成方法。该聚合物具有带有邻位官能团的直链烃聚合物骨架，其具有含氧和/或氮原子的基团，例如羟基，羧酸或酯，羰基乙酸酯，酰胺，腈等，从区域中的聚合物主链不规律的方式。

6. 发明授权

US06455650B1 Catalyst and methods for polymerizing cycloolefins 有权
标题翻译：用于聚合环烯烃的催化剂和方法
公开(公告)号：US06455650B1
公开(公告)日：2002-09-24
申请号：US09412935
申请日：1999-10-05
申请人： John-Henry Lipian , Larry F. Rhodes , Brian L. Goodall , Andrew Bell , Richard A. Mimna , John C. Fondran , Saikumar Jayaraman , April D. Hennis , Christine N. Elia , Jennifer D. Polley , Ayusman Sen
发明人： John-Henry Lipian , Larry F. Rhodes , Brian L. Goodall , Andrew Bell , Richard A. Mimna , John C. Fondran , Saikumar Jayaraman , April D. Hennis , Christine N. Elia , Jennifer D. Polley , Ayusman Sen
IPC分类号： C08F480
CPC分类号： C08F32/08 , C08F32/00 , Y02P20/582
摘要： Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译：使用阳离子10族金属络合物和下式的弱配位阴离子进行环烯加成聚合的方法：其中[（R'）z M（L'）x（L“）y]是阳离子络合物，其中M表示第10组过渡金属; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1，其中x，y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位抗衡阴离子络合物在总体催化剂络合物上平衡电荷的次数的数字。

7. 发明授权

US06552139B1 Process for preparing acyclic olefins using homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands 有权
标题翻译：使用含有N-杂环卡宾配体的钌的均双金属和异双金属亚烷基络合物制备无环烯烃的方法
公开(公告)号：US06552139B1
公开(公告)日：2003-04-22
申请号：US09488630
申请日：2000-01-20
申请人： Wolfgang Anton Herrmann , Florian J. Kohl , Thomas Weskamp
发明人： Wolfgang Anton Herrmann , Florian J. Kohl , Thomas Weskamp
IPC分类号： C08F480
CPC分类号： C07C6/04 , C07C2527/1213 , C07C2527/122 , C07C2527/138 , C07C2531/22 , C07C2531/26 , C07C2531/30 , C07F15/0046
摘要： The invention relates to complexes of ruthenium of the structural formula I where X is an anionic ligand, Z is a monodentate to tridentate ligand which contains a metal and is nonionically bound to the ruthenium center, R1 and R2 are identical or different and are each hydrogen or/and a hydrocarbon group, but may also form a ring, and Ligand L is an N-heterocyclic carbene, and also to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having three or more carbon atoms and the use of at least one complex of the formula I in olefin metathesis.
摘要翻译：本发明涉及结构式I的络合物，其中X是阴离子配体，Z是含有金属并与钌中心非离子键合的三齿配体的单齿至三齿配体，R 1和R 2相同或不同，各自为氢或/ 烃基，也可以形成环，而配体L是N-杂环卡宾，也可以是制备碳原子数为2以上的非环状烯烃或碳原子数为3以上的环状烯烃的方法，的至少一种式I的络合物在烯烃复分解中。

8. 发明授权

US06426396B2 Process for producing poly (cyclic conjugated diene) 失效
标题翻译：聚（环状共轭二烯）的制造方法
公开(公告)号：US06426396B2
公开(公告)日：2002-07-30
申请号：US09306054
申请日：1999-05-06
申请人： Mitsuru Nakano , Arimitsu Usuki , Qing Yao
发明人： Mitsuru Nakano , Arimitsu Usuki , Qing Yao
IPC分类号： C08F480
CPC分类号： C08F4/602 , C08F4/70 , C08F4/80 , C08F32/06 , C08F36/14 , C08G61/08 , C08G61/12
摘要： Poly(cyclic conjugated diene) polymers are prepared by polymerizing a cyclic conjugated diene monomer or cyclic conjugated diene monomer and a double bond-containing monomer using a transition metal catalyst, preferably a Ni-based catalyst, in a non-polar solvent containing a basic compound or an aromatic halide solvent. The poly(cyclic conjugated diene) polymer may then be subsequently modified by reaction of at least one of the double bonds of the polymer with a modifying substance, for example hydrogen.
摘要翻译：聚（环状共轭二烯）聚合物通过使用过渡金属催化剂，优选Ni基催化剂在含有碱性的非极性溶剂中使环状共轭二烯单体或环状共轭二烯单体和含双键单体聚合来制备化合物或芳族卤化物溶剂。然后可以通过聚合物的至少一个双键与修饰物质例如氢的反应来修饰聚（环状共轭二烯）聚合物。

9. 发明授权

US06414099B1 Single-site catalysts based on caged diimide ligands 失效
公开(公告)号：US06414099B1
公开(公告)日：2002-07-02
申请号：US09691285
申请日：2000-10-18
申请人： Gregory G. Hlatky , Jonathan L. Schuchardt
发明人： Gregory G. Hlatky , Jonathan L. Schuchardt
IPC分类号： C08F480
CPC分类号： C07F15/065 , C07C251/20 , C07C2603/90 , C07F15/045 , C08F10/00 , C08F4/7006
摘要： Single-site catalysts useful for polymerizing olefins are disclosed. The organometallic catalysts incorporate a Group 3 to 10 transition, lanthanide or actinide metal and a caged diimide ligand. The diimide ligands are made by a tandem Diels-Alder and photochemical [2+2] cycloaddition sequence to give a multicyclic dione, followed by condensation with a primary amine. Because a wide variety of caged diimide ligands are easy to prepare from commercially available dienes and dienophiles, the invention enables the preparation of a new family of single-site catalysts. Based on their unique structure and geometry, the catalysts offer polyolefin producers new ways to improve activity, control comonomer incorporation, or regulate polyolefin tacticity.

10. 发明授权

US06320002B1 Olefin polymerization catalyst 失效
标题翻译：烯烃聚合催化剂
公开(公告)号：US06320002B1
公开(公告)日：2001-11-20
申请号：US09213627
申请日：1998-12-18
申请人： Rex E. Murray , Simon Mawson , Clark C. Williams , James D. Schreck
发明人： Rex E. Murray , Simon Mawson , Clark C. Williams , James D. Schreck
IPC分类号： C08F480
CPC分类号： C08F10/00 , C07F7/00 , C07F7/10 , C07F17/00 , C08F4/659 , C08F4/65908 , C08F4/65912 , C08F210/16 , Y10S526/901 , Y10S526/943 , C08F210/14 , C08F2500/12 , C08F2500/10 , C08F4/65904 , C08F2500/05 , C08F4/64044 , C08F4/64055 , C08F4/68112 , C08F4/69112 , C08F4/52
摘要： This invention relates to a process to polymerize olefins comprising contacting an olefin with a composition comprising the product of the combination of an activator and a transition metal compound provided that if the process occurs in the slurry phase then the activator and the transition metal compound are allowed to react for at least fifteen minutes before being contacted with the olefin.
摘要翻译：本发明涉及聚合烯烃的方法，包括使烯烃与包含活化剂和过渡金属化合物的组合的产物的组合物接触，条件是如果该方法在浆料相中发生，则允许活化剂和过渡金属化合物在与烯烃接触之前反应至少十五分钟。

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