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1. 发明授权

US07671150B2 Polymerization of acyclic aliphatic olefins 有权
标题翻译：无环脂族烯烃的聚合
公开(公告)号：US07671150B2
公开(公告)日：2010-03-02
申请号：US12070632
申请日：2008-02-20
申请人： David M. Conner , Brian Leslie Goodall , Lester Howard McIntosh, III
发明人： David M. Conner , Brian Leslie Goodall , Lester Howard McIntosh, III
IPC分类号： C08F4/80 , B01J31/12
CPC分类号： C08F10/00 , C08F110/02 , C08F4/80
摘要： A robust, impurity tolerant method of making substantially linear polymers of acyclic aliphatic olefins using catalyst complexes comprising a single palladium metal center and a substituted tri-aryl ligand is disclosed.
摘要翻译：公开了使用包含单一钯金属中心和取代的三芳基配体的催化剂络合物制备非循环脂族烯烃基本上线性聚合物的稳健的耐杂质方法。

2. 发明授权

US07524912B2 Preparation of linear ethylene-acrylate copolymers with palladium catalysts and free radical scavengers 有权
标题翻译：用钯催化剂和自由基清除剂制备线性乙烯 - 丙烯酸酯共聚物
公开(公告)号：US07524912B2
公开(公告)日：2009-04-28
申请号：US12069769
申请日：2008-02-13
申请人： Brian Leslie Goodall , Thomas Cleveland Kirk , Lester Howard McIntosh, III
发明人： Brian Leslie Goodall , Thomas Cleveland Kirk , Lester Howard McIntosh, III
IPC分类号： C07D207/00 , C07D221/00 , C07D207/46 , C08F4/72 , C08F220/14 , C07C15/16
CPC分类号： C08F210/00 , C08F210/02 , C08F2/38 , C08F4/80 , C08F220/14 , C08F2500/03
摘要： A polymerizable composition including a late transition metal complex, a non-polar olefin, a polar olefin, and a free radical scavenger, wherein the polymerizable composition is capable of forming a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer, is disclosed. A method of copolymerizing a non-polar olefin with a polar olefin, catalyzed by a late transition metal complex in the presence of a free radical scavenger, to produce a linear poly[(non-polar olefin)-(polar olefin)] substantially free of free radical addition polymer is also disclosed.
摘要翻译：一种包含后过渡金属络合物，非极性烯烃，极性烯烃和自由基清除剂的可聚合组合物，其中所述可聚合组合物能够形成直链聚[（非极性烯烃） - （极性烯烃）] - 基本上不含自由基加成聚合物。一种在自由基清除剂存在下，由后过渡金属配合物催化的非极性烯烃与极性烯烃共聚的方法，以产生基本上没有的线型聚[（非极性烯烃） - （极性烯烃）] 的自由基加成聚合物也被公开。

3. 发明授权

US07524905B2 Substantially linear copolymers and methods of making the same 有权
标题翻译：基本线性共聚物及其制备方法
公开(公告)号：US07524905B2
公开(公告)日：2009-04-28
申请号：US12070639
申请日：2008-02-20
申请人： David M. Conner , Brian Leslie Goodall , Lester Howard McIntosh, III
发明人： David M. Conner , Brian Leslie Goodall , Lester Howard McIntosh, III
IPC分类号： C08F4/06 , B01J31/18
CPC分类号： C08F10/00 , C08F210/02 , C08F4/80 , C08F226/08 , C08F2500/03 , C08F226/10 , C08F226/06 , C08F226/12 , C08F220/56
摘要： Substantially linear copolymers derived from at least one acyclic aliphatic olefin monomer and at least one nitrogen containing vinyl monomer, wherein the at least one nitrogen containing vinyl monomer is according to Formula (I) wherein R19 is selected —C═C; and —C(O)—C═C; wherein R20 and R21 are independently selected from H, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a biphenyl group, a carboxylate group, a carboxyalkyl group, a carboxyarylalkyl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, an aryloxy group, an alkoxycarbonyl group, and derivatives thereof. Also disclosed are methods of making such copolymers using late transition metal catalyst complexes.
摘要翻译：衍生自至少一种无环脂族烯烃单体和至少一种含氮乙烯基单体的基本线性共聚物，其中所述至少一种含氮乙烯基单体是根据其中R 19选自-C-C的式（I）; 和-C（O）-C-C; 其中R 20和R 21独立地选自H，烷基，烯基，炔基，芳基，联苯基，羧酸酯基，羧基烷基，羧基芳基烷基，烷氧基，烯氧基，炔氧基，芳氧基，烷氧基羰基及其衍生物。还公开了使用晚期过渡金属催化剂络合物制备这种共聚物的方法。

4. 发明授权

US07435701B2 Catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers 有权
标题翻译：催化组合物及其制备和用于从烯属不饱和单体制备聚合物的用途
公开(公告)号：US07435701B2
公开(公告)日：2008-10-14
申请号：US11418676
申请日：2006-05-04
申请人： Han Shen , Brian Leslie Goodall
发明人： Han Shen , Brian Leslie Goodall
IPC分类号： B01J31/22 , C08F4/70
CPC分类号： B01J31/2226 , B01J31/16 , B01J31/1805 , B01J31/226 , B01J31/2291 , B01J31/2404 , B01J2231/005 , B01J2531/001 , B01J2531/0291 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07F11/00 , C07F11/005 , C07F15/006 , C07F15/0066 , C07F15/0073 , C07F15/04 , C07F15/045 , C08F4/619 , C08F10/00 , C08F110/02 , C08F210/02 , C08F2410/03 , C08F4/80 , C08F4/78 , C08F2500/03 , C08F220/06 , C08F232/00 , C08F212/08 , C08F4/7031 , C08F4/7022 , C08F4/7006 , C08F4/6912
摘要： A catalytic composition, including a neutral metal-pair complex, is disclosed, along with a method for its preparation. A method for the polymerization of ethylenically unsaturated monomers using the catalytic composition, and the addition polymers produced thereby are also disclosed.
摘要翻译：公开了包括中性金属对络合物的催化组合物及其制备方法。还公开了使用催化组合物聚合烯键式不饱和单体的方法和由其制备的加成聚合物。

5. 发明申请

US20080207789A1 Porous linear polymer composition 审中-公开
标题翻译：多孔线性聚合物组合物
公开(公告)号：US20080207789A1
公开(公告)日：2008-08-28
申请号：US12069826
申请日：2008-02-13
申请人： Francis V. Acholla , Brian Leslie Goodall , Lester Howard McIntosh , Han Shen
发明人： Francis V. Acholla , Brian Leslie Goodall , Lester Howard McIntosh , Han Shen
IPC分类号： C08F110/00
CPC分类号： C08F10/02 , C08F110/02 , C08F210/02 , C08F4/26 , C08F4/80 , C08F220/10
摘要： A porous polymer composition including plural linear mixed polarity polymer particles, wherein the particles include a linear poly[(non-polar olefin)-(polar olefin)] and at least one pore, is disclosed, as are those particles further including a catalytic component. A method of forming the plural linear mixed polarity polymer particles is also disclosed. A method of using plural linear mixed polarity polymer particles which include a catalytic component to catalyze polymerization is further disclosed. A porous polymer composition including plural linear non-polar polymer particles and a catalytic component is further disclosed, along with a method of making those linear non-polar polymer particles including the catalytic component and a method of using them to catalyze polymerization.
摘要翻译：公开了包含多个线性混合极性聚合物颗粒的多孔聚合物组合物，其中所述颗粒包括直链聚[（非极性烯烃） - （极性烯烃）]和至少一个孔，还包括催化组分。还公开了形成多个线性混合极性聚合物颗粒的方法。进一步公开了使用包括催化组分催化聚合的多种线性混合极性聚合物颗粒的方法。进一步公开了包含多个线性非极性聚合物颗粒和催化组分的多孔聚合物组合物，以及制备包含催化组分的线性非极性聚合物颗粒的方法和使用它们催化聚合的方法。

6. 发明授权

US06451499B1 Polycyclic resist compositions with increased etch resistance 有权
标题翻译：具有增加的耐蚀性的多环抗蚀剂组合物
公开(公告)号：US06451499B1
公开(公告)日：2002-09-17
申请号：US09604749
申请日：2000-06-27
申请人： Saikumar Jayaraman , Brian Leslie Goodall , Larry Funderburk Rhodes , Robert Adam Shick , Richard Vicari , Robert David Allen , Juliann Opitz , Ratnam Sooriyakumaran , Thomas Wallow
发明人： Saikumar Jayaraman , Brian Leslie Goodall , Larry Funderburk Rhodes , Robert Adam Shick , Richard Vicari , Robert David Allen , Juliann Opitz , Ratnam Sooriyakumaran , Thomas Wallow
IPC分类号： G03F7004
CPC分类号： C08F232/08 , C08G61/08 , G03F7/0045 , G03F7/0382 , G03F7/039 , Y10S430/115
摘要： Polycyclic polymers containing pendant aromatic moieties are disclosed. The polymers exhibit light transparency properties to deep UV wave lengths making them useful for high resolution photolithographic applications. These polymers are particularly useful in chemically amplified positive and negative tone resists.
摘要翻译：公开了含有侧芳基部分的多环聚合物。聚合物对深UV波长显示出透光性，使其可用于高分辨率光刻应用。这些聚合物特别适用于化学放大的正和负色调抗蚀剂。

7. 发明授权

US06265506B1 Method for the preparation of copolymers of ethylene/norbornene-type monomers with cationic palladium catalysts 失效
标题翻译：乙烯/降冰片烯型单体与阳离子钯催化剂的共聚物的制备方法
公开(公告)号：US06265506B1
公开(公告)日：2001-07-24
申请号：US09094349
申请日：1998-06-09
申请人： Brian Leslie Goodall , Lester Howard McIntosh, III
发明人： Brian Leslie Goodall , Lester Howard McIntosh, III
IPC分类号： C08F480
CPC分类号： C08F232/08 , C08F10/00 , C08F210/02 , C08F232/00 , C08F4/7006 , C08F4/7016 , C08F4/7014 , C08F4/7032 , C08F4/7018
摘要： A method of preparing generally amorphous copolymers of ethylene and at least one norbornene (NB)-type comonomer. These polymers may be random or alternating, depending on the choice of catalyst and/or the relative ratio of the monomers used. This method comprises polymerizing said monomers in a diluent or in bulk in the presence of a cationic palladium catalyst resulting from reacting a chelating ligand with a palladium (II) compound. The catalysts employed in this invention may be represented by the formula: wherein X and Y each independently is a donor heteroatom selected from P, N, O, S and As or an organic group containing said heteroatoms, and the heteroatoms are bonded to the bridging group A; A is a divalent group selected from an organic group and phosphorus forming together with X, Y and Pd a 4, 5, 6, or 7-membered ring, and preferably a 5-membered ring; R is a hydrocarbyl group; and CA is a weakly coordinating anion.
摘要翻译：通常制备乙烯和至少一种降冰片烯（NB）型共聚单体的无定形共聚物的方法。这些聚合物可以是随机的或交替的，这取决于催化剂的选择和/或所用单体的相对比例。该方法包括在由螯合配体与钯（II）化合物反应得到的阳离子钯催化剂的存在下，以稀释剂或本体聚合所述单体。本发明中使用的催化剂可以由下式表示：其中X和Y各自独立地是选自P，N，O，S和As的供体杂原子或含有所述杂原子的有机基团，并且杂原子与桥连基团键合 A; A是选自有机基团的二价基团和与X，Y和Pd一起形成的磷，4,5,6或7元环，优选为5元环; R为烃基; 而CA是弱配位阴离子。

8. 发明授权

US5741869A Addition polymers derived from norbornene-functional monomers and process therefor 失效
公开(公告)号：US5741869A
公开(公告)日：1998-04-21
申请号：US481027
申请日：1995-06-07
申请人： Brian Leslie Goodall , George Martin Benedikt , Lester Howard McIntosh, III , Dennis Allen Barnes , Larry Funderburk Rhodes
发明人： Brian Leslie Goodall , George Martin Benedikt , Lester Howard McIntosh, III , Dennis Allen Barnes , Larry Funderburk Rhodes
IPC分类号： C08F4/70 , C08F4/30 , C08F4/42 , C08F4/80 , C08F32/00 , C08F32/08 , C08F36/04 , C08F36/20 , C08F210/14 , C08F232/08 , C08F236/20 , C08F4/76 , C08F4/78 , C08F10/00
CPC分类号： C08F232/08 , C08F32/08
摘要： Addition polymers derived from norbornene-functional monomers are terminated with an olefinic moiety derived from a chain transfer agent selected from a compound having a terminal olefinic double bond between adjacent carbon atoms, excluding styrenes, vinyl ethers, and conjugated dienes and at least one of said carbon atoms has two hydrogen atoms attached thereto. The addition polymers of this invention are prepared from a single or multicomponent catalyst system including a Group VIII metal ion source. The catalyst systems are unique in that they catalyze the insertion of the chain transfer agent exclusively at a terminal end of the polymer chain.

9. 发明授权

US5705503A Addition polymers of polycycloolefins containing functional substituents 失效
标题翻译：含有官能取代基的聚环烯烃的加成聚合物
公开(公告)号：US5705503A
公开(公告)日：1998-01-06
申请号：US449876
申请日：1995-05-25
申请人： Brian Leslie Goodall , Wilhelm Risse , Joice P. Mathew
发明人： Brian Leslie Goodall , Wilhelm Risse , Joice P. Mathew
IPC分类号： C08F4/42 , C08F4/70 , C08F32/00 , C08F32/08 , C08F36/00
CPC分类号： C08F32/08
摘要： Addition polymers containing functionally substituted polycyclic repeat units are prepared in the presence of a single or multicomponent catalyst system containing a palladium metal ion source. The catalysts are not poisoned by functional substituents and show good catalytic activity for polymerizing both endo and exo isomers of the substituted monomers. Optionally, the polymers are terminated with olefinic end groups.
摘要翻译：含有功能取代的多环重复单元的加成聚合物在含有钯金属离子源的单组分或多组分催化剂体系的存在下制备。催化剂不会被功能性取代基中毒，并且对于取代单体的内部和外部异构体的聚合都显示出良好的催化活性。任选地，聚合物用烯属端基封端。

10. 发明授权

US07635739B2 Substantially linear polymers and methods of making and using same 有权
标题翻译：基本线性聚合物及其制造和使用方法
公开(公告)号：US07635739B2
公开(公告)日：2009-12-22
申请号：US11457982
申请日：2006-07-17
申请人： Nathan Tait Allen , Brian Leslie Goodall , Lester Howard McIntosh, III
发明人： Nathan Tait Allen , Brian Leslie Goodall , Lester Howard McIntosh, III
IPC分类号： C08F4/80 , C08F118/08 , C08F220/44 , C08F220/56 , C08F220/10 , C08F212/06 , B01J31/18
CPC分类号： C08F212/08 , C08F210/02 , C08F220/18 , C08F4/80 , C08F4/26 , C08F220/10 , C08F2500/03
摘要： Copolymers and terpolymers containing acyclic aliphatic olefin derived units and polar monomer derived units are disclosed. Also disclosed are methods of making such copolymers and terpolymers using late transition metal catalyst complexes.
摘要翻译：公开了含有非环脂族烯烃衍生单元和极性单体衍生单元的共聚物和三元共聚物。还公开了使用后过渡金属催化剂络合物制备这种共聚物和三元共聚物的方法。

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