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1. 发明申请

US20180187054A1 HYDROCARBON RESIN, METHOD FOR PREPARING HYDROCARBON RESIN, AND ADHESIVE COMPOSITION 审中-公开
公开(公告)号：US20180187054A1
公开(公告)日：2018-07-05
申请号：US15741099
申请日：2015-12-31
申请人： KOLON INDUSTRIES, INC.
发明人： Sang Hyun LEE , Jun Hyo PARK , Joong Suk LEE , Min Sik CHO
IPC分类号： C09J147/00 , C08F32/00 , C09J123/06 , C09J133/06 , C09J123/16
CPC分类号： C09J147/00 , C08F8/04 , C08F32/00 , C08F210/14 , C08F232/08 , C08F240/00 , C08L45/00 , C08L57/02 , C09J123/06 , C09J123/0853 , C09J123/14 , C09J123/16 , C09J133/062 , C09J145/00 , C09J157/02 , C08K5/01 , C08L23/16 , C08L91/06 , C08K5/005 , C08L23/14 , C08L53/02 , C08L23/0853
摘要： Provided are a hydrocarbon resin and a method of preparing the same, wherein thermal polymerization of a diolefin and an olefin is performed, thus obviating a catalyst removal process, material supply problems can be solved, and a hydrogenated hydrocarbon resin can be prepared using a catalyst, which is inexpensive and is easy to handle, thereby realizing a yield and a preparation process that enable real-world application thereof. The hydrogenated hydrocarbon resin prepared by the method of the invention has excellent compatibility and a low specific viscosity, and can thus be efficiently used as a tackifier or an adhesive in a variety of fields.

2. 发明授权

US08093344B2 β-pinene polymer and process for producing the same 有权
标题翻译：蒎烯聚合物及其制备方法
公开(公告)号：US08093344B2
公开(公告)日：2012-01-10
申请号：US12416217
申请日：2009-04-01
申请人： Masami Kamigaito , Kotaro Satoh , Hiroko Sugiyama
发明人： Masami Kamigaito , Kotaro Satoh , Hiroko Sugiyama
IPC分类号： C08F210/00
CPC分类号： C08F32/00
摘要： To provide a β-pinene polymer excellent in heat resistance while having thermoplasticity, and further also having excellent strength, without impairing the inherent characteristics of small specific gravity and excellent transparency. A desired β-pinene polymer having a weight average molecular weight of 90,000 to 1,000,000 and a glass transition temperature of 80° C. or more was obtained by polymerizing β-pinene in the presence of a bifunctional vinyl compound.
摘要翻译：提供具有优异耐热性且具有热塑性的蒎烯聚合物，并且还具有优异的强度，而不损害小比重的固有特性和优异的透明度。通过在双官能乙烯基化合物的存在下聚合β-蒎烯，得到重均分子量为90,000〜1,000,000，玻璃化转变温度为80℃以上的所需蒎烯聚合物。

3. 发明授权

US07910674B2 Polymerized cycloolefins using transition metal catalyst and end products thereof 有权
标题翻译：使用过渡金属催化剂及其最终产物的聚合环烯烃
公开(公告)号：US07910674B2
公开(公告)日：2011-03-22
申请号：US10464978
申请日：2003-06-18
申请人： Larry Funderburk Rhodes , Andrew Bell , Ramakrishna Ravikiran , John C. Fondran , Saikumar Jayaraman , Brian Leslie Goodall , Richard A. Mimna , John-Henry Lipian
发明人： Larry Funderburk Rhodes , Andrew Bell , Ramakrishna Ravikiran , John C. Fondran , Saikumar Jayaraman , Brian Leslie Goodall , Richard A. Mimna , John-Henry Lipian
IPC分类号： C08F32/00 , G01R31/26 , H01L21/00 , H01L21/82 , H01L23/58 , H01L23/02 , H01L23/14 , H01L23/29
CPC分类号： C08G61/06 , C08F32/00 , C08F32/08 , G02B1/04 , C08L65/00
摘要： Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要翻译：使用阳离子第10族金属络合物和式（[（R'）z M（L'）x（L“）y] b [WCA] d的弱配位阴离子进行环烯加成聚合的方法，其中[（R' ）zM（L'）x（L“）y]是阳离子络合物，其中M表示第10族过渡金属; R'表示含阴离子烃基的配体; L'表示15族中性电子给体配体; L“表示不稳定的中性电子给体配体; x为1或2; y为0,1,2或3; 且z为0或1，其中x，y和z之和为4; 和[WCA]代表弱协调的对抗综合体; b和d是表示阳离子络合物和弱配位抗衡阴离子络合物在总体催化剂络合物上平衡电荷的次数的数字。

4. 发明授权

US07786230B2 Method for polymerizing cycloolefin polymer containing polar functional groups and electronics devices employing the polymerized cycloolefins 有权
标题翻译：聚合包含极性官能团的环烯烃聚合物的方法和使用聚合环烯烃的电子器件
公开(公告)号：US07786230B2
公开(公告)日：2010-08-31
申请号：US11489848
申请日：2006-07-20
申请人： Sung-Cheol Yoon , Sung-Ho Chun , Won-Kook Kim , Tae-Sun Lim , Heon Kim , Jung-Min Lee
发明人： Sung-Cheol Yoon , Sung-Ho Chun , Won-Kook Kim , Tae-Sun Lim , Heon Kim , Jung-Min Lee
IPC分类号： C08F4/80 , C08F10/00 , C08F36/00 , C08F38/00 , C08F26/02 , C08F32/00 , C08F12/28 , C08F118/02 , C08F16/12
CPC分类号： C08F4/70 , C08F32/00 , C08F232/08 , C08G61/06 , C08G61/08 , C09K19/38 , Y10T428/1036
摘要： Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising the steps of: a) preparing a catalyst mixture including i) a precatalyst; ii) a first cocatalyst; and iii) a second cocatalyst; and b) subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, wherein the product yield of the prepared polymer is 50% by weight or more based on the total weight of the monomer.
摘要翻译：公开了一种制备含有极性官能团的环烯烃聚合物的方法，包括以下步骤：a）制备催化剂混合物，其包括i）预催化剂; ii）第一助催化剂; 和iii）第二助催化剂; 和b）在有机溶剂和催化剂混合物的存在下，使包含含有极性官能团的降冰片烯系化合物的单体溶液进行加成聚合反应，其中制备的聚合物的产物收率为50重量％以上基于单体的总重量。

5. 发明申请

US20100004412A1 METHOD FOR PREPARING POLYMER BY PRECIPITATION POLYMERIZATION 有权
标题翻译：通过降解聚合制备聚合物的方法
公开(公告)号：US20100004412A1
公开(公告)日：2010-01-07
申请号：US12312859
申请日：2007-12-05
申请人： Seung-Young Park , Sung-Cheol Yoon
发明人： Seung-Young Park , Sung-Cheol Yoon
IPC分类号： C08F2/18
CPC分类号： C08F2/14 , C08F32/00
摘要： The present invention provides a method for preparing a polymer by precipitation polymerization, comprising the steps of mixing an antisolvent a), a monomer b), and a catalyst c), and while polymerizing the monomers, simultaneously precipitating a polymer formed by the monomers b) in a solid phase.
摘要翻译：本发明提供了一种通过沉淀聚合制备聚合物的方法，包括以下步骤：将反溶剂a），单体b）和催化剂c）混合，同时使单体聚合同时沉淀由单体b形成的聚合物）固相。

6. 发明申请

US20090092769A1 METHOD FOR POLYMERIZING CYCLOOLEFIN POLYMER CONTAINING POLAR FUNCTIONAL GROUPS AND ELECTRONIC DEVICES EMPLOYING THE POLYMERIZED CYCLOOLEFINS 有权
标题翻译：聚合含有极性官能团的环烯烃聚合物的方法和使用聚合的环烯烃的电子器件
公开(公告)号：US20090092769A1
公开(公告)日：2009-04-09
申请号：US12274947
申请日：2008-11-20
申请人： Sung-Cheol Yoon , Sung-Ho Chun , Won-Kook Kim , Tae-Sun Lim , Heon Kim , Jung-Min Lee
发明人： Sung-Cheol Yoon , Sung-Ho Chun , Won-Kook Kim , Tae-Sun Lim , Heon Kim , Jung-Min Lee
IPC分类号： G02F1/13363 , C08F4/54
CPC分类号： C08F4/70 , C08F32/00 , C08F232/08 , C08G61/06 , C08G61/08 , C09K19/38 , Y10T428/1036
摘要： Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.
摘要翻译：公开了一种制备含有极性官能团的环烯烃聚合物的方法，包括：制备催化剂混合物，其包括i）含有具有与金属键合的含氧离子的配体的第10族过渡金属的预催化剂; ii）第一助催化剂，其是含有第15族元素的有机化合物; 和iii）能够提供阴离子并与预催化剂的金属弱配位的第二助催化剂; 将含有极性官能团的降冰片烯系化合物的单体溶液在有机溶剂和催化剂混合物的存在下，在80〜200℃的温度下进行加成聚合反应，溶剂为50-800重量％，基于单体溶液中所含单体的总重量，聚合物的产物收率基于单体的总重量为50重量％以上。

7. 发明申请

US20070165300A1 Wave plate for laser optical system 审中-公开
标题翻译：激光光学系统波片
公开(公告)号：US20070165300A1
公开(公告)日：2007-07-19
申请号：US10581523
申请日：2003-12-03
申请人： Masayuki Sekiguchi , Tatsuya Hirono
发明人： Masayuki Sekiguchi , Tatsuya Hirono
IPC分类号： G02B5/30
CPC分类号： C08J5/18 , C08F8/04 , C08J2345/00 , C08J2365/00 , C09D145/00 , G02B5/3083 , G11B7/1275 , G11B7/1365 , G11B2007/0006 , C08F32/00
摘要： A wavelength plate laser optical system which is a wavelength plate using a stretched and oriented film containing a cyclic olefin based resin, and which has values of the formula (a): Re(λ)/λ, (wherein λ represents a wavelength (nm) of the laser beam; and Re(λ) represents a retardation value (nm) of the laser beam having transmitted through the wavelength plate) against two laser beams having a different wavelength such that the value is ((0.2 to 0.3)+X) for a first laser beam and that the value is ((0.8 to 1.2)+Y) for a second laser beam, respectively (wherein X represents 0 or the number of an integral multiple of 0.5; and Y represents 0 or an integer of 1 or more). It is possible to provide a wavelength plate for optical information recording and reproducing devices, which is excellent in initial characteristics, is hardly affected by the use environment and the manufacturing environment, is excellent in long-term reliability, and is corresponding to two laser beams having a different wavelength.
摘要翻译：波长板激光光学系统，其是使用包含环状烯烃类树脂的拉伸取向膜的波长板，并且具有式（a）的值：Re（λ）/λ，（其中λ表示波长（nm ），并且Re（λ）表示穿过波长板的激光束的延迟值（nm）对于具有不同波长的两个激光束，使得值为（（0.2〜0.3）+ X ），第二激光束的值为（（0.8〜1.2）+ Y）（其中，X表示0或0.5的整数倍，Y表示0或整数倍） 1个或更多）。可以提供一种光学信息记录和再现装置的波长板，其初始特性优异，几乎不受使用环境和制造环境的影响，具有优异的长期可靠性，并且对应于两个激光束具有不同的波长。

8. 发明申请

US20070021576A1 Method for polymerizing cycloolefin polymer containing polar functional groups and electronics devices employing the polymerized cycloolefins 有权
标题翻译：聚合包含极性官能团的环烯烃聚合物的方法和使用聚合环烯烃的电子器件
公开(公告)号：US20070021576A1
公开(公告)日：2007-01-25
申请号：US11489848
申请日：2006-07-20
申请人： Sung-Cheol Yoon , Sung-Ho Chun , Won-Kook Kim , Tae-Sun Lim , Heon Kim , Jung-Min Lee
发明人： Sung-Cheol Yoon , Sung-Ho Chun , Won-Kook Kim , Tae-Sun Lim , Heon Kim , Jung-Min Lee
IPC分类号： C08F4/80
CPC分类号： C08F4/70 , C08F32/00 , C08F232/08 , C08G61/06 , C08G61/08 , C09K19/38 , Y10T428/1036
摘要： Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising the steps of: a) preparing a catalyst mixture including i) a precatalyst; ii) a first cocatalyst; and iii) a second cocatalyst; and b) subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, wherein the product yield of the prepared polymer is 50% by weight or more based on the total weight of the monomer.
摘要翻译：公开了一种制备含有极性官能团的环烯烃聚合物的方法，包括以下步骤：a）制备催化剂混合物，其包括i）预催化剂; ii）第一助催化剂; 和iii）第二助催化剂; 和b）在有机溶剂和催化剂混合物的存在下，使包含含有极性官能团的降冰片烯系化合物的单体溶液进行加成聚合反应，其中制备的聚合物的产物收率为50重量％以上基于单体的总重量。

9. 发明申请

US20060241317A1 High metathesis activity ruthenium and osmium metal carbene complexes 有权
标题翻译：高复分解活性钌和锇金属卡宾络合物
公开(公告)号：US20060241317A1
公开(公告)日：2006-10-26
申请号：US11472137
申请日：2006-06-20
申请人： Robert Grubbs , Peter Schwab , Sonbinh Nguyen
发明人： Robert Grubbs , Peter Schwab , Sonbinh Nguyen
IPC分类号： C07F15/00
CPC分类号： C08F4/80 , B01J31/18 , B01J31/2265 , B01J31/24 , B01J31/2404 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X are independently selected from any anionic ligand; and L and L are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译：公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。还公开了制备卡宾化合物的方法。卡宾化合物具有下式：其中M是Os或Ru; R 1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性电子给体。本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。

10. 发明授权

US06946533B2 Synthesis of macrocyclic polymers by ring insertion polymerization of cyclic olefin monomers 有权
标题翻译：通过环烯烃单体的环插入聚合合成大环聚合物
公开(公告)号：US06946533B2
公开(公告)日：2005-09-20
申请号：US10632528
申请日：2003-08-01
申请人： Robert Grubbs , Chris Bielawski , Diego Benitez
发明人： Robert Grubbs , Chris Bielawski , Diego Benitez
IPC分类号： C08G61/08 , C07F15/00 , C08F4/44 , C08F4/70 , C08F4/80 , C08F32/00 , C08F110/02 , C08G61/06 , B01J31/00
CPC分类号： C08F32/00 , C08F110/02 , C08G61/06 , C08F4/80
摘要： A method for synthesizing cyclic polymers using transition metal alkylidene complexes as reaction catalysts is provided, wherein the complexes contain a cyclic group. Polymerization is carried out on the catalyst, using cyclic olefin monomers that undergo ring insertion polymerization, and no linear intermediates are generated. Following completion of polymerization, the cyclic polymer detaches from the complex via an intramolecular chain transfer reaction and the catalytic complex is regenerated. The invention also provides novel transition metal alkylidene complexes useful as catalysts in the aforementioned process, as well as novel cyclic hydrocarbons.
摘要翻译：提供了使用过渡金属亚烷基络合物作为反应催化剂合成环状聚合物的方法，其中络合物含有环状基团。使用进行环插入聚合的环状烯烃单体，在催化剂上进行聚合，不产生线性中间体。聚合完成后，环状聚合物通过分子内链转移反应与络合物分离，催化络合物再生。本发明还提供了在上述方法中可用作催化剂的新型过渡金属亚烷基络合物，以及新的环状烃。

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