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1. 发明授权

US06841619B2 Compound and coating compositions for adhesion to olefinic substrates 失效
标题翻译：用于粘附到烯烃底物的化合物和涂料组合物
公开(公告)号：US06841619B2
公开(公告)日：2005-01-11
申请号：US09907207
申请日：2001-07-17
申请人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
发明人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
IPC分类号： C08J7/04 , C08G63/00 , C08G63/08 , C08G65/26 , C08L53/00 , C08L71/02 , C09D5/00 , C09D7/12 , C09D153/00 , C09D161/28 , C09D201/00 , C09J5/02 , C08J3/00 , C08K3/04 , C08L67/02 , B32B31/20
CPC分类号： C08L71/02 , C08G63/00 , C08L53/005 , C09D5/002 , C09D7/65 , C09D201/00 , Y10T428/31909 , Y10T428/31913 , Y10T428/31917 , C08L2666/04 , C08L2666/24
摘要： The present invention provides an olefin-based block copolymer that has an olefin block that is substantially saturated and at least one (poly)ester or (poly)ether block. The olefin-based block copolymer of the invention can be prepared by reacting a liquid hydroxyl-functional, saturated or substantially saturated olefin polymer with a chain-extension reagent that is reactive with hydroxyl groups and will polymerize in a head-to-tail arrangement of monomer units. The olefin-based block copolymer of the invention can be used to prepare an adhesion promoter that provides excellent adhesion of subsequent coating layers to olefinic substrates like TPO and superior properties as compared to previously used adhesion promoters containing chlorinated polyolefins. Alternatively, the olefin-based copolymers of the invention can be used as an additive in a curable coating composition to provide excellent adhesion to olefinic substrates like TPO, even when used in very minor amounts compared to the amounts required for previously known agents.
摘要翻译：本发明提供一种具有基本上饱和的烯烃嵌段和至少一种（多）酯或（聚）醚嵌段的烯烃基嵌段共聚物。本发明的烯烃基嵌段共聚物可以通过使液体羟基官能的饱和或基本上饱和的烯烃聚合物与与羟基反应的链延长试剂反应来制备，并且将以头 - 尾排列的方式聚合单体单元。与先前使用的含有氯化聚烯烃的粘合促进剂相比，本发明的烯烃基嵌段共聚物可用于制备粘合促进剂，其对随后的涂层提供与TPO等烯烃基材的优异粘附性和优异的性能。或者，本发明的烯烃基共聚物可用作可固化涂料组合物中的添加剂，以提供与诸如TPO的烯烃基材的优异粘合性，即使以与先前已知的试剂所需量相比非常小的量使用。

2. 发明授权

US06300414B1 Additive for coating compositions for adhesion to TPO substrates 失效
标题翻译：用于粘附到TPO基材上的涂料组合物的添加剂
公开(公告)号：US06300414B1
公开(公告)日：2001-10-09
申请号：US09143156
申请日：1998-08-28
申请人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
发明人： John D. McGee , Daniel Blickberndt , Craig Schang , Walter H. Ohrbom , Keri Krueger
IPC分类号： C08L6702
CPC分类号： C08L71/02 , C08G63/00 , C08L53/005 , C09D5/002 , C09D7/65 , C09D201/00 , Y10T428/31909 , Y10T428/31913 , Y10T428/31917 , C08L2666/04 , C08L2666/24
摘要： The present invention provides an olefin-based block copolymer that has an olefin block that is substantially saturated and at least one (poly)ester or (poly)ether block. The olefin-based block copolymer of the invention can be prepared by reacting a liquid hydroxyl-functional, saturated or substantially saturated olefin polymer with a chain-extension reagent that is reactive with hydroxyl groups and will polymerize in a head-to-tail arrangement of monomer units. The olefin-based block copolymer of the invention can be used to prepare an adhesion promoter that provides excellent adhesion of subsequent coating layers to olefinic substrates like TPO and superior properties as compared to previously used adhesion promoters containing chlorinated polyolefins. Alternatively, the olefin-based copolymers of the invention can be used as an additive in a curable coating composition to provide excellent adhesion to olefinic substrates like TPO, even when used in very minor amounts compared to the amounts required for previously known agents.
摘要翻译：本发明提供一种具有基本上饱和的烯烃嵌段和至少一种（多）酯或（聚）醚嵌段的烯烃基嵌段共聚物。本发明的烯烃基嵌段共聚物可以通过使液体羟基官能的饱和或基本上饱和的烯烃聚合物与与羟基反应的链延长试剂反应来制备，并且将以头 - 尾排列的方式聚合单体单元。与先前使用的含有氯化聚烯烃的粘合促进剂相比，本发明的烯烃基嵌段共聚物可用于制备粘合促进剂，其对随后的涂层提供与TPO等烯烃基材的优异粘附性和优异的性能。或者，本发明的烯烃基共聚物可用作可固化涂料组合物中的添加剂，以提供与诸如TPO的烯烃基材的优异粘合性，即使以与先前已知的试剂所需量相比非常小的量使用。

3. 发明授权

US06423788B1 Curable coating composition 失效
标题翻译：可固化涂料组合物
公开(公告)号：US06423788B1
公开(公告)日：2002-07-23
申请号：US08686929
申请日：1995-10-06
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Paul J. Harris , John W. Rehfuss
IPC分类号： C09D17300
CPC分类号： C09D201/02 , C08G71/00 , C09D167/04 , C09D201/025 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising (1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of (a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone ring or a hydroxy carboxylic acid, and (b) a lactone or a hydroxy carboxylic acid, and (2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that is not reactive with the carbamate or urea groups on compound (A)(1), (B) a compound comprising a plurality of groups that are reactive with carbamate or urea.
摘要翻译：描述了可固化涂料组合物，其包含（A）氨基甲酸酯或脲官能化合物，其为包含（1）包含氨基甲酸酯或脲基团的化合物或可转化为氨基甲酸酯或脲的基团的混合物的反应产物，和作为（a）包含氨基甲酸酯或脲基的化合物或可以转化为氨基甲酸酯或脲基的基团的反应产物的羟基官能团以及与内酯环或羟基羧酸和（b）内酯或羟基羧酸，和（2）与多个化合物（A）（1）分子上的羟基反应但不与氨基甲酸酯反应的化合物或化合物（A）（1）上的脲基，（B）包含与氨基甲酸酯或脲反应的多个基团的化合物。

4. 发明授权

US07030263B2 Method of preparing a carbamate- or urea-functional compound 有权
公开(公告)号：US07030263B2
公开(公告)日：2006-04-18
申请号：US10280619
申请日：2002-10-25
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G63/64
CPC分类号： C09D175/02 , C07C269/04 , C07C269/06 , C07C273/1809 , C07C273/1854 , C08G18/4615 , C09D175/06 , Y10T428/31551 , C08L2666/16
摘要： A method of preparing a carbamate or urea-functional compound is described comprising the step of reacting a lactone or hydroxy carboxylic acid with a compound (A) comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group capable of reacting with the hydroxy carboxylic acid or in a ring-opening reaction with a lactone. The compound thus prepared is useful in curable compositions.

5. 发明授权

US06080825A Curable coating compositions containing blends of carbamate-functional compounds 有权
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US06080825A
公开(公告)日：2000-06-27
申请号：US184197
申请日：1998-11-02
申请人： Walter H Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , John D. McGee , Brian D. Bammel , Danielle Regulski , Christopher Bradford
发明人： Walter H Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , John D. McGee , Brian D. Bammel , Danielle Regulski , Christopher Bradford
IPC分类号： C09D175/04 , C07D251/34 , C08F8/30 , C08G12/40 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/30 , C08G18/38 , C08G18/46 , C08G18/66 , C08G18/79 , C08G18/80 , C08G59/14 , C08G71/00 , C08G81/02 , C08K5/3492 , C08L61/20 , C09D133/06 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D201/02 , C09D201/06 , C08G8/28 , C08L63/00 , C08L67/04
CPC分类号： C07D251/34 , C08G12/40 , C08G18/0823 , C08G18/10 , C08G18/2865 , C08G18/302 , C08G18/3829 , C08G18/3831 , C08G18/3853 , C08G18/4615 , C08G18/6633 , C08G18/792 , C08G18/8077 , C08G59/1438 , C08G59/1477 , C08G59/1494 , C08G71/00 , C08G81/021 , C08K5/34924 , C09D133/062 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/025 , C09D201/06 , C08L61/20
摘要： The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) that includes one or both of a compound (a)(1) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea or a compound (a)(2) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The second component (b) of the coating composition includes a polymer resin comprising active hydrogen-containing functional groups reactive with the third component (c). The resins is selected from polyester, polyurethane, or polyester-polyurethane copolymers Component (c) of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.
摘要翻译：本发明提供了包含至少三种组分的可固化涂料组合物。涂料组合物包括组分（a），其包含根据本发明的具有至少一个氨基甲酸酯基团或末端脲基团的化合物（a）（1）中的一种或两种，并且具有至少两个氨基甲酸酯或脲的连接基团或具有至少两个选自氨基甲酸酯基，末端脲基团或两个和至少四个氨基甲酸酯或脲连接基团的组合的化合物（a）（2）。涂料组合物的第二组分（b）包括含有与第三组分（c）反应的含活性氢官能团的聚合物树脂。树脂选自聚酯，聚氨酯或聚酯 - 聚氨酯共聚物涂料组合物的组分（c）是与前两种组分反应的固化剂。还公开了使用本发明组合物制备涂层制品。

6. 发明授权

US5994479A Curable coating compositions containing blends of carbamate-functional compounds 失效
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US5994479A
公开(公告)日：1999-11-30
申请号：US997317
申请日：1997-12-23
申请人： Marvin L. Green , John D. McGee , Brian D. Bammel , Danielle A. Regulski , Walter H. Ohrbom
发明人： Marvin L. Green , John D. McGee , Brian D. Bammel , Danielle A. Regulski , Walter H. Ohrbom
IPC分类号： C08G18/40 , C08G18/80 , C09D5/02 , C09D5/03 , C09D161/20 , C09D175/00 , C09D201/02 , C08G8/28 , C08G59/14 , C08L63/00 , C08L67/04
CPC分类号： C09D161/20 , C08G18/8077 , C09D201/025 , Y10T428/31551
摘要： The present invention provides a curable coating composition comprising(a) a first component comprising at least two functional groups, at least one of which is a carbamate or urea group that is the reaction product of:(1) a hydroxyl group that is the result of a ring-opening reaction between an epoxy group and an organic acid group, and(2) cyanic acid or a carbamate or urea group;(b) a curing agent having a plurality of functional groups that are reactive with component (a), and(c) a second component having functional groups that are reactive with component (a) or component (b) or both components (a) and (b).
摘要翻译：本发明提供一种可固化涂料组合物，其包含（a）包含至少两个官能团的第一组分，其中至少一个为氨基甲酸酯或脲基，其为：（1）作为结果的羟基的反应产物的环氧基和有机酸基之间的开环反应，和（2）氰酸或氨基甲酸酯或脲基; （b）具有多个与组分（a）反应的官能团的固化剂，和（c）具有与组分（a）或组分（b）或两种组分（a）反应的官能团的第二组分）和（b）。

7. 发明授权

US5760127A Curable coating composition 失效
标题翻译：可固化涂料组合物
公开(公告)号：US5760127A
公开(公告)日：1998-06-02
申请号：US698526
申请日：1996-08-15
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G71/00 , C09D167/04 , C09D201/02 , C08J3/00 , B32B27/00 , C08K3/20 , C08L75/00
CPC分类号： C09D201/02 , C08G71/00 , C09D167/04 , C09D201/025 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising (1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of (a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone ring or a hydroxy carboxylic acid, and (b) a lactone or a hydroxy carboxylic acid, and (2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that is not reactive with the carbamate or urea groups on compound (A)(1), (B) a compound comprising a plurality of groups that are reactive with carbamate or urea.
摘要翻译：描述了可固化涂料组合物，其包含（A）氨基甲酸酯或脲官能化合物，其为包含（1）包含氨基甲酸酯或脲基团的化合物或可转化为氨基甲酸酯或脲的基团的混合物的反应产物，和作为（a）包含氨基甲酸酯或脲基的化合物或可以转化为氨基甲酸酯或脲基的基团的反应产物的羟基官能团以及与内酯环或羟基羧酸和（b）内酯或羟基羧酸，和（2）与多个化合物（A）（1）分子上的羟基反应但不与氨基甲酸酯反应的化合物或化合物（A）（1）上的脲基，（B）包含与氨基甲酸酯或脲反应的多个基团的化合物。

8. 发明授权

US5770650A Curable compositions for coatings 失效
标题翻译：涂料固化组合物
公开(公告)号：US5770650A
公开(公告)日：1998-06-23
申请号：US698523
申请日：1996-08-15
申请人： John D. McGee , Brian D. Bammel , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： John D. McGee , Brian D. Bammel , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G18/80 , C08G71/00 , C09D167/04 , C09D201/02 , C08J3/00 , C08G63/91 , C08K3/20 , C08L75/00
CPC分类号： C08G18/8077 , C08G71/00 , C09D167/04 , C09D201/025 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one ester or amide group derived from a reaction of an active hydrogen group with a lactone ring or a hydroxy carboxylic acid, and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).
摘要翻译：描述了可固化涂料组合物，其包含（A）包含多个官能交联基团的化合物，其中至少一个是氨基甲酸酯或脲官能团，该化合物还包括至少一种衍生自具有内酯环或羟基羧酸的活性氢基，和（B）包含与化合物（A）上的官能团反应的多个基团的固化剂。

9. 发明授权

US5756213A Curable coating composition having carbonate-containing component 失效
标题翻译：具有含碳酸盐成分的可固化涂料组合物
公开(公告)号：US5756213A
公开(公告)日：1998-05-26
申请号：US698528
申请日：1996-08-15
申请人： Walter H. Ohrbom , John W. Rehfuss , John D. McGee , Gregory G. Menovcik , Paul J. Harris
发明人： Walter H. Ohrbom , John W. Rehfuss , John D. McGee , Gregory G. Menovcik , Paul J. Harris
IPC分类号： C09D161/20 , C08G71/00 , C08G71/04 , C09D167/04 , C09D169/00 , C09D175/04 , C09D201/00 , C09D201/02 , C09D161/28
CPC分类号： C09D175/04 , C08G71/00 , C08G71/04 , C09D167/04 , C09D169/00 , C09D201/02 , Y10T428/31507 , Y10T428/31942
摘要： A curable coating composition is described comprising (A) a compound comprising a plurality of functional crosslinking groups, at least one of which is a carbamate or urea functional group, which compound also includes at least one carbonate group having the structure: ##STR1## and (B) a curing agent comprising a plurality of groups that are reactive with the functional groups on compound (A).
摘要翻译：描述了可固化涂料组合物，其包含（A）包含多个官能交联基团的化合物，其中至少一个是氨基甲酸酯或脲官能团，该化合物还包括至少一个具有以下结构的碳酸酯基团：和（B）包含与化合物（A）上的官能团反应的多个基团的固化剂。

10. 发明授权

US06498266B1 Method of preparing a carbamate- or urea-functional compound 失效
标题翻译：制备氨基甲酸酯或脲官能化合物的方法
公开(公告)号：US06498266B1
公开(公告)日：2002-12-24
申请号：US08698525
申请日：1996-08-15
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G6364
CPC分类号： C09D167/04 , C08G71/00 , C09D201/02
摘要： A method of preparing a carbamate or urea-functional compound is described comprising the step of reacting a lactone or hydroxy carboxylic acid with a compound (A) comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group capable of reacting with the hydroxy carboxylic acid or in a ring-opening reaction with a lactone. The compound thus prepared is useful in curable compositions.
摘要翻译：描述了制备氨基甲酸酯或脲官能化合物的方法，其包括使内酯或羟基羧酸与包含氨基甲酸酯或脲基团的化合物（A）或可转化为氨基甲酸酯或脲基团的基团反应的步骤，和能够与羟基羧酸反应或与内酯开环反应的活性氢基团。由此制备的化合物可用于可固化组合物中。

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