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1. 发明授权

US07807743B2 Coating composition and film system therefrom 有权
标题翻译：涂料组合物和薄膜体系
公开(公告)号：US07807743B2
公开(公告)日：2010-10-05
申请号：US11534352
申请日：2006-09-22
申请人： Marvin L Green , Donald H. Campbell , John E. Boisseau , Bruce Oermann
发明人： Marvin L Green , Donald H. Campbell , John E. Boisseau , Bruce Oermann
IPC分类号： C09B67/00
CPC分类号： C08J7/18 , C08J2377/12
摘要： A coating composition is used to form a clearcoat layer of a film system including a basecoat layer and the clearcoat layer. The coating composition includes a carbamate functional polymer, a cross-linking agent reactive with the carbamate functional polymer, and an acid functional polymer substantially non-reactive with the carbamate functional polymer and the cross-linking agent. The acid functional polymer has an acid value of at least 50 mg KOH/g and contributes to an increased resistance to acid etch of the clearcoat layer. The acid functional polymer also contributes to an increased intercoat adhesion of the basecoat layer and the clearcoat layer thereby decreasing a possibility of separation/delamination of the basecoat layer and the clearcoat layer.
摘要翻译：涂料组合物用于形成包括底涂层和透明涂层的膜系统的透明涂层。涂料组合物包括氨基甲酸酯官能聚合物，与氨基甲酸酯官能聚合物反应的交联剂和与氨基甲酸酯官能聚合物和交联剂基本上不反应的酸官能聚合物。酸官能聚合物具有至少50mg KOH / g的酸值，并且有助于增加对透明涂层的酸蚀刻的耐受性。酸官能聚合物还有助于增加底涂层和透明涂层的层间粘附性，从而降低了底涂层和透明涂层的分离/分层的可能性。

2. 发明授权

US06160058A Curable coating compositions containing blends of carbamate-functional compounds 有权
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US06160058A
公开(公告)日：2000-12-12
申请号：US184196
申请日：1998-11-02
申请人： Walter H. Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss
发明人： Walter H. Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss
IPC分类号： C07D251/34 , C08F8/30 , C08G12/40 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/30 , C08G18/38 , C08G18/46 , C08G18/66 , C08G18/80 , C08G59/14 , C08G71/00 , C08G81/02 , C08K5/3492 , C08L61/20 , C09D133/00 , C09D133/06 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/06 , C08G8/28 , C08L63/00 , C08L67/04
CPC分类号： C09D201/025 , C07D251/34 , C08F8/30 , C08G12/40 , C08G18/0823 , C08G18/10 , C08G18/2865 , C08G18/302 , C08G18/3829 , C08G18/3831 , C08G18/3853 , C08G18/4615 , C08G18/6633 , C08G18/8077 , C08G59/1438 , C08G59/1477 , C08G59/1494 , C08G71/00 , C08G81/021 , C08K5/34924 , C08L61/20 , C09D133/06 , C09D133/062 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/06 , C08L2666/16 , C08L2666/14 , C08L2666/28 , C08L2666/02
摘要： The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) that includes one or both of a compound (a)(1) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea or a compound (a)(2) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The second component (b) of the coating composition includes an acrylic polymer comprising active hydrogen-containing functional groups reactive with the third component(c). Component (c) of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.
摘要翻译：本发明提供了包含至少三种组分的可固化涂料组合物。涂料组合物包括组分（a），其包含根据本发明的具有至少一个氨基甲酸酯基团或末端脲基团的化合物（a）（1）中的一种或两种，并且具有至少两个氨基甲酸酯或脲的连接基团或具有至少两个选自氨基甲酸酯基，末端脲基团或两个和至少四个氨基甲酸酯或脲连接基团的组合的化合物（a）（2）。涂料组合物的第二组分（b）包括含有与第三组分（c）反应的含活性氢官能团的丙烯酸聚合物。涂料组合物的组分（c）是与前两种组分反应的固化剂。还公开了使用本发明组合物制备涂层制品。

3. 发明授权

US6147163A Acrylic oligomeric and polymeric durability enhancing agents, method therefore and cured coating compositions containing the same 失效
标题翻译：丙烯酸低聚物和聚合物耐久性增强剂，因此其方法和含有它们的固化涂料组合物
公开(公告)号：US6147163A
公开(公告)日：2000-11-14
申请号：US769289
申请日：1996-12-18
申请人： John E. Boisseau , Donald L. St. Aubin , Patricia K. Oberg , John W. Rehfuss
发明人： John E. Boisseau , Donald L. St. Aubin , Patricia K. Oberg , John W. Rehfuss
IPC分类号： C08F2/00 , C08K5/00 , C09D7/12 , C07D251/00 , C07D211/92 , C07D211/26 , C07D249/16
CPC分类号： C08K5/005 , C09D7/1241 , C08K5/07 , C08K5/3435 , C08K5/3475 , C08K5/34926
摘要： A durability enhancing agent comprising the reaction product of an acrylic oligomer or acrylic polymer and an ultraviolet light absorbing compound, a hindered amine light stabilizer or mixture thereof, said durability enhancing agent further comprising more than one carbamate functional group, or group convertible to a carbamate group, and optionally, including other reactive functionality capable of undergoing a crosslinking reaction. Also included is a curable coating composition comprising the durability enhancing agent, a method for obtaining a coated substrate and the coated article obtained thereby.
摘要翻译：一种耐久性增强剂，其包含丙烯酸类低聚物或丙烯酸类聚合物与紫外线吸收性化合物的反应产物，受阻胺光稳定剂或其混合物，所述耐久性增强剂还包含多于一个氨基甲酸酯官能团或可转化为氨基甲酸酯的基团并且任选地包括能够经历交联反应的其它反应性官能团。还包括含有耐久性增强剂的可固化涂料组合物，获得涂布基材的方法和由此得到的涂布制品。

4. 发明授权

US07772304B2 Plasticizing component and a curable coating composition including the same 有权
标题翻译：增塑组分和包含其的可固化涂料组合物
公开(公告)号：US07772304B2
公开(公告)日：2010-08-10
申请号：US11560932
申请日：2006-11-17
申请人： Walter H. Ohrbom , John E. Boisseau
发明人： Walter H. Ohrbom , John E. Boisseau
IPC分类号： C08K5/3492 , C07D251/30
CPC分类号： C09D133/066 , C09D133/14
摘要： A curable coating composition includes a plasticizing component. The plasticizing component includes an isocyanurate core and at least one low surface tension group pending from the isocyanurate core. The low surface tension group may be a) a fatty chain includes at least 6 carbon atoms, b) a silicon-containing group having at least 1 silicon atom, c) a fluorocarbon, and combinations thereof. The low surface tension group may have cross-linkable functional groups pending therefrom. In addition to the plasticizing component, the curable coating composition further includes a resin component and a crosslinking agent that is reactive with the resin component. The curable coating composition including the plasticizing component is capable of forming a cured film that has resistance to both cracking and etching that, to date, has not been achieved with known plasticizing components.
摘要翻译：可固化涂料组合物包括增塑组分。增塑组分包括异氰脲酸酯芯和至少一种从异氰脲酸酯芯悬浮的低表面张力组。低表面张力基团可以是a）脂肪链包含至少6个碳原子，b）具有至少1个硅原子的含硅基团，c）碳氟化合物及其组合。低表面张力组可能具有可交联的官能团。除了增塑组分之外，可固化涂料组合物还包括树脂组分和与树脂组分反应的交联剂。包含增塑组分的可固化涂料组合物能够形成耐开裂和蚀刻的固化膜，迄今为止，已知的增塑组分尚未实现。

5. 发明申请

US20080119592A1 PLASTICIZING COMPONENT AND A CURABLE COATING COMPOSITION INCLUDING THE SAME 有权
标题翻译：塑化组分和可固化的涂料组合物，包括它们
公开(公告)号：US20080119592A1
公开(公告)日：2008-05-22
申请号：US11560932
申请日：2006-11-17
申请人： Walter H. Ohrbom , John E. Boisseau
发明人： Walter H. Ohrbom , John E. Boisseau
IPC分类号： C08K5/3492 , C07D251/30
CPC分类号： C09D133/066 , C09D133/14
摘要： A curable coating composition includes a plasticizing component. The plasticizing component includes an isocyanurate core and at least one low surface tension group pending from the isocyanurate core. The low surface tension group may be a) a fatty chain includes at least 6 carbon atoms, b) a silicon-containing group having at least 1 silicon atom, c) a fluorocarbon, and combinations thereof. The low surface tension group may have cross-linkable functional groups pending therefrom. In addition to the plasticizing component, the curable coating composition further includes a resin component and a crosslinking agent that is reactive with the resin component. The curable coating composition including the plasticizing component is capable of forming a cured film that has resistance to both cracking and etching that, to date, has not been achieved with known plasticizing components.
摘要翻译：可固化涂料组合物包括增塑组分。增塑组分包括异氰脲酸酯芯和至少一种从异氰脲酸酯芯悬浮的低表面张力组。低表面张力基团可以是a）脂肪链包含至少6个碳原子，b）具有至少1个硅原子的含硅基团，c）碳氟化合物及其组合。低表面张力组可能具有可交联的官能团。除了增塑组分之外，可固化涂料组合物还包括树脂组分和与树脂组分反应的交联剂。包含增塑组分的可固化涂料组合物能够形成耐开裂和蚀刻的固化膜，迄今为止，已知的增塑组分尚未实现。

6. 发明申请

US20080076868A1 COATING COMPOSITION AND FILM SYSTEM THEREFROM 有权
标题翻译：涂料组合物和薄膜系统
公开(公告)号：US20080076868A1
公开(公告)日：2008-03-27
申请号：US11534352
申请日：2006-09-22
申请人： MARVIN L. GREEN , DONALD H. CAMPBELL , JOHN E. BOISSEAU , BRUCE OERMANN
发明人： MARVIN L. GREEN , DONALD H. CAMPBELL , JOHN E. BOISSEAU , BRUCE OERMANN
IPC分类号： C09B67/00
CPC分类号： C08J7/18 , C08J2377/12
摘要： A coating composition is used to form a clearcoat layer of a film system including a basecoat layer and the clearcoat layer. The coating composition includes a carbamate functional polymer, a cross-linking agent reactive with the carbamate functional polymer, and an acid functional polymer substantially non-reactive with the carbamate functional polymer and the cross-linking agent. The acid functional polymer has an acid value of at least 50 mg KOH/g and contributes to an increased resistance to acid etch of the clearcoat layer. The acid functional polymer also contributes to an increased intercoat adhesion of the basecoat layer and the clearcoat layer thereby decreasing a possibility of separation/delamination of the basecoat layer and the clearcoat layer.
摘要翻译：涂料组合物用于形成包括底涂层和透明涂层的膜系统的透明涂层。涂料组合物包括氨基甲酸酯官能聚合物，与氨基甲酸酯官能聚合物反应的交联剂和与氨基甲酸酯官能聚合物和交联剂基本上不反应的酸官能聚合物。酸官能聚合物具有至少50mg KOH / g的酸值，并且有助于增加对透明涂层的酸蚀刻的耐受性。酸官能聚合物还有助于增加底涂层和透明涂层的层间粘附性，从而降低了底涂层和透明涂层的分离/分层的可能性。

7. 发明授权

US06180240B2 Acrylic ogligomeric and polymeric durability enhancing agents, method therefore and cured coating composition containing the same 有权
标题翻译：丙烯酸低聚物和聚合物耐久性增强剂，因此方法和含有其的固化涂料组合物
公开(公告)号：US06180240B2
公开(公告)日：2001-01-30
申请号：US09271784
申请日：1999-03-18
申请人： Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , Patricia K. Oberg
发明人： Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , Patricia K. Oberg
IPC分类号： B32B2738
CPC分类号： C08K5/005 , C08K5/07 , C08K5/3435 , C08K5/3475 , C08K5/34926 , C09D7/48 , Y10T428/31507
摘要： A durability enhancing agent comprising the reaction product of an acrylic oligomer or acrylic polymer and an ultraviolet light absorbing compound, a hindered amine light stabilizer or mixture thereof, said durability enhancing agent further comprising more than one carbamate functional group, or group convertible to a carbamate group, and optionally, including other reactive functionality capable of undergoing a crosslinking reaction. Also included is a curable coating composition comprising the durability enhancing agent, a method for obtaining a coated substrate and the coated article obtained thereby.
摘要翻译：一种耐久性增强剂，其包含丙烯酸类低聚物或丙烯酸类聚合物与紫外线吸收性化合物的反应产物，受阻胺光稳定剂或其混合物，所述耐久性增强剂还包含多于一个氨基甲酸酯官能团或可转化为氨基甲酸酯的基团并且任选地包括能够经历交联反应的其它反应性官能团。还包括含有耐久性增强剂的可固化涂料组合物，获得涂布基材的方法和由此得到的涂布制品。

8. 发明授权

US06080825A Curable coating compositions containing blends of carbamate-functional compounds 有权
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US06080825A
公开(公告)日：2000-06-27
申请号：US184197
申请日：1998-11-02
申请人： Walter H Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , John D. McGee , Brian D. Bammel , Danielle Regulski , Christopher Bradford
发明人： Walter H Ohrbom , Gregory G. Menovcik , Donald L. St. Aubin , John E. Boisseau , John W. Rehfuss , John D. McGee , Brian D. Bammel , Danielle Regulski , Christopher Bradford
IPC分类号： C09D175/04 , C07D251/34 , C08F8/30 , C08G12/40 , C08G18/08 , C08G18/10 , C08G18/28 , C08G18/30 , C08G18/38 , C08G18/46 , C08G18/66 , C08G18/79 , C08G18/80 , C08G59/14 , C08G71/00 , C08G81/02 , C08K5/3492 , C08L61/20 , C09D133/06 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D201/02 , C09D201/06 , C08G8/28 , C08L63/00 , C08L67/04
CPC分类号： C07D251/34 , C08G12/40 , C08G18/0823 , C08G18/10 , C08G18/2865 , C08G18/302 , C08G18/3829 , C08G18/3831 , C08G18/3853 , C08G18/4615 , C08G18/6633 , C08G18/792 , C08G18/8077 , C08G59/1438 , C08G59/1477 , C08G59/1494 , C08G71/00 , C08G81/021 , C08K5/34924 , C09D133/062 , C09D161/20 , C09D167/00 , C09D167/04 , C09D169/00 , C09D175/00 , C09D175/02 , C09D175/04 , C09D201/02 , C09D201/025 , C09D201/06 , C08L61/20
摘要： The present invention provides a curable coating composition that includes at least three components. The coating composition includes a component (a) that includes one or both of a compound (a)(1) having at least one carbamate group or terminal urea group according to the invention and having at least two linking groups that are urethane or urea or a compound (a)(2) having at least two groups selected from carbamate groups, terminal urea groups, or combinations of the two and at least four urethane or urea linking groups. The second component (b) of the coating composition includes a polymer resin comprising active hydrogen-containing functional groups reactive with the third component (c). The resins is selected from polyester, polyurethane, or polyester-polyurethane copolymers Component (c) of the coating composition is a curing agent that is reactive with the first two components. Preparation of coated articles using the compositions of the invention is also disclosed.
摘要翻译：本发明提供了包含至少三种组分的可固化涂料组合物。涂料组合物包括组分（a），其包含根据本发明的具有至少一个氨基甲酸酯基团或末端脲基团的化合物（a）（1）中的一种或两种，并且具有至少两个氨基甲酸酯或脲的连接基团或具有至少两个选自氨基甲酸酯基，末端脲基团或两个和至少四个氨基甲酸酯或脲连接基团的组合的化合物（a）（2）。涂料组合物的第二组分（b）包括含有与第三组分（c）反应的含活性氢官能团的聚合物树脂。树脂选自聚酯，聚氨酯或聚酯 - 聚氨酯共聚物涂料组合物的组分（c）是与前两种组分反应的固化剂。还公开了使用本发明组合物制备涂层制品。

9. 发明授权

US07169949B2 Silane-modified UV absorbers and coatings 失效
标题翻译：硅烷改性的紫外线吸收剂和涂料
公开(公告)号：US07169949B2
公开(公告)日：2007-01-30
申请号：US10711688
申请日：2004-09-30
申请人： John E. Boisseau , Swaminathan Ramesh
发明人： John E. Boisseau , Swaminathan Ramesh
IPC分类号： C07F7/10
CPC分类号： C08K5/5465
摘要： Including a triazine UV light absorber having a silane group in a coating improves scratch and mar resistance after weathering.
摘要翻译：包括在涂层中具有硅烷基团的三嗪UV光吸收剂在风化后改善了刮擦和耐划伤性。

10. 发明授权

US06685985B2 Method of improving the appearance of coated articles having both vertical and horizontal surfaces, and coating compositions for use therein 有权
标题翻译：改善具有垂直和水平表面的涂覆制品的外观的方法和用于其中的涂料组合物
公开(公告)号：US06685985B2
公开(公告)日：2004-02-03
申请号：US09779948
申请日：2001-02-09
申请人： John E. Boisseau , Mark Kowalewski , Kurt D. Hoffman , Dustin Clinard
发明人： John E. Boisseau , Mark Kowalewski , Kurt D. Hoffman , Dustin Clinard
IPC分类号： B05D302
CPC分类号： B05D7/53 , B05D1/04 , B05D3/0272 , B05D7/16 , C08G18/3831 , C08L61/28 , C09D5/04 , C09D133/14 , C09D175/04 , C09D201/025 , Y10T428/259 , Y10T428/31554 , C08L2666/16
摘要： The invention provides a method of obtaining improvements in the appearance of articles having both vertically and horizontally orientated surfaces and a coating composition for use in said method. The coating composition of the invention has a film-forming component (a) and a rheology control agent (b) having substantially colorless, substantially inorganic microparticles (i) and a compound (ii) comprising the reaction product of an amine and an isocyanate. A particularly preferred method of the invention requires applying the coating composition of the invention to an article having at least one horizontally orientated surface and at least one vertically orientated surface so as to provide a coated horizontally orientated surface and a coated vertically orientated surface, wherein the coated vertically orientated surface has improved sag resistance, most preferably having a sag resistance of at least 1.2 mils. The coated surfaces are then cured to provide a cured horizontally orientated film having an improved surface appearance, most preferably a surface appearance having a DOI of at least 70.
摘要翻译：本发明提供一种获得具有垂直和水平定向表面的制品的外观改进的方法和用于所述方法的涂料组合物。本发明的涂料组合物具有成膜组分（a）和具有基本上无色的，基本上无机的微粒（i）和包含胺和异氰酸酯的反应产物的化合物（ii）的流变控制剂（b）。本发明特别优选的方法需要将本发明的涂料组合物施用于具有至少一个水平取向表面和至少一个垂直定向表面的制品，以便提供涂覆的水平取向表面和涂覆的垂直取向表面，其中涂覆的垂直取向表面具有改善的抗流挂性，最优选具有至少1.2密耳的下垂电阻。然后将涂覆的表面固化以提供具有改进的表面外观的固化的水平取向膜，最优选DOI为至少70的表面外观。

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