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    • 8. 发明申请
    • QUASI-HYDROPHOBIC Si-Si WAFER BONDING USING HYDROPHILIC Si SURFACES AND DISSOLUTION OF INTERFACIAL BONDING OXIDE
    • 使用水解硅表面和界面结合氧化物的溶解度的偶氮硅Si-Si波形粘结
    • US20090298258A1
    • 2009-12-03
    • US12538115
    • 2009-08-08
    • Joel P. de SouzaJohn A. OttAlexander ReznicekDevendra K. SadanaKatherine L. Saenger
    • Joel P. de SouzaJohn A. OttAlexander ReznicekDevendra K. SadanaKatherine L. Saenger
    • H01L21/30
    • H01L21/187H01L21/76251
    • The present invention provides a method for removing or reducing the thickness of ultrathin interfacial oxides remaining at Si—Si interfaces after silicon wafer bonding. In particular, the invention provides a method for removing ultrathin interfacial oxides remaining after hydrophilic Si—Si wafer bonding to create bonded Si—Si interfaces having properties comparable to those achieved with hydrophobic bonding. Interfacial oxide layers of order of about 2 to about 3 nm are dissolved away by high temperature annealing, for example, an anneal at 1300°-1330° C. for 1-5 hours. The inventive method is used to best advantage when the Si surfaces at the bonded interface have different surface orientations, for example, when a Si surface having a (100) orientation is bonded to a Si surface having a (110) orientation. In a more general aspect of the invention, the similar annealing processes may be used to remove undesired material disposed at a bonded interface of two silicon-containing semiconductor materials. The two silicon-containing semiconductor materials may be the same or different in surface crystal orientation, microstructure (single-crystal, polycrystalline, or amorphous), and composition.
    • 本发明提供一种在硅晶片接合之后去除或减少残留在Si-Si界面处的超薄界面氧化物的厚度的方法。 特别地,本发明提供了一种去除在亲水性Si-Si晶片接合之后残留的超薄界面氧化物以产生具有与通过疏水性接合实现的性能相当的特性的结合Si-Si界面的方法。 约2至约3nm的界面氧化物层通过高温退火(例如1300°-1330℃退火1-5小时)被溶解掉。 当粘合界面处的Si表面具有不同的表面取向时,例如当具有(100)取向的Si表面被结合到具有(110)取向的Si表面时,本发明的方法被用于最好的优点。 在本发明的更一般的方面中,类似的退火工艺可用于去除设置在两个含硅半导体材料的键合界面处的不期望的材料。 两种含硅半导体材料在表面晶体取向,微结构(单晶,多晶或无定形)和组成上可以相同或不同。
    • 10. 发明授权
    • Dual SIMOX hybrid orientation technology (HOT) substrates
    • 双SIMOX混合取向技术(HOT)底物
    • US07253034B2
    • 2007-08-07
    • US10902557
    • 2004-07-29
    • Kevin K. ChanJoel P. de SouzaAlexander ReznicekDevendra K. SadanaKatherine L. Saenger
    • Kevin K. ChanJoel P. de SouzaAlexander ReznicekDevendra K. SadanaKatherine L. Saenger
    • H01L21/70H01L21/762
    • H01L21/84H01L21/76243H01L21/76267H01L27/1203H01L27/1207
    • This invention provides a separation by implanted oxygen (SIMOX) method for forming planar hybrid orientation semiconductor-on-insulator (SOI) substrates having different crystal orientations, thereby making it possible for devices to be fabricated on crystal orientations providing optimal performance. The method includes the steps of selecting a substrate having a base semiconductor layer having a first crystallographic orientation separated by a thin insulating layer from a top semiconductor layer having a second crystallographic orientation; replacing the top semiconductor layer in selected regions with an epitaxially grown semiconductor having the first crystallographic orientation; then using an ion implantation and annealing method to (i) form a buried insulating region within the epitaxially grown semiconductor material, and (ii) thicken the insulating layer underlying the top semiconductor layer, thereby forming a hybrid orientation substrate in which the two semiconductor materials with different crystallographic orientations have substantially the same thickness and are both disposed on a common buried insulator layer. In a variation of this method, an ion implantation and annealing method is instead used to extend an auxiliary buried insulator layer (initially underlying the base semiconductor layer) upwards (i) into the epitaxially grown semiconductor, and (ii) up to the insulating layer underlying the top semiconductor layer.
    • 本发明提供了通过注入氧(SIMOX)分离方法,用于形成具有不同晶体取向的平面杂化取向绝缘体上半导体(SOI)衬底,从而使得可以以提供最佳性能的晶体取向来制造器件。 该方法包括以下步骤:从具有第二晶体取向的顶部半导体层选择具有由薄绝缘层分离的第一晶体取向的基底半导体层的衬底; 用具有第一晶体取向的外延生长的半导体代替选定区域中的顶部半导体层; 然后使用离子注入和退火方法来(i)在外延生长的半导体材料内形成掩埋绝缘区,并且(ii)加厚顶部半导体层下面的绝缘层,从而形成混合取向衬底,其中两个半导体材料 具有不同的晶体取向具有基本上相同的厚度并且均设置在公共掩埋绝缘体层上。 在该方法的变型中,替代地使用离子注入和退火方法将辅助掩埋绝缘体层(最初在基底半导体层下面)向上(i)延伸到外延生长的半导体中,以及(ii)直到绝缘层 在顶部半导体层下面。