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1. 发明申请

US20060141194A1 Water-based release coating containing fluorochemical 有权
标题翻译：含氟化合物的水性防粘涂层
公开(公告)号：US20060141194A1
公开(公告)日：2006-06-29
申请号：US11027606
申请日：2004-12-28
申请人： James Carlson , John Clark , James DiZio , David Kinning , Ramesh Kumar , Chetan Jariwala
发明人： James Carlson , John Clark , James DiZio , David Kinning , Ramesh Kumar , Chetan Jariwala
IPC分类号： B32B33/00
CPC分类号： C09D133/02 , Y10S525/902 , Y10T428/14
摘要： In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —(CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.
摘要翻译：一方面，本发明提供了一种水性防粘涂料组合物，其包含以下混合物：A.从0.1至约5wt％的氟（甲基）丙烯酸酯（共）聚合物或含有至少一个氟化基团的含氟氨基甲酸酯化合物具有式 - （CF 2）n CF 3，其中n为1至3的整数; B.约5至约99.9重量％的包含a的反应产物的共聚物。约40至约70重量％的（甲基）丙烯酸烷基酯，其中烷基含有16至22个碳原子，b。约3至约20重量％的（甲基）丙烯酸，c。约20至约40重量％的丙烯腈，以及d。 0至约15重量％的乙烯基单体，除了丙烯腈，其中a。通过d。等于100％; 和C.0至约94.9重量％的增量聚合物，其中A.，B.和C.的总和为100％，wt％基于组合物中固体的总量。

2. 发明申请

US20060142530A1 Water- and oil-repellent fluorourethanes and fluoroureas 审中-公开
标题翻译：防水和防油氟聚氨酯和氟脲
公开(公告)号：US20060142530A1
公开(公告)日：2006-06-29
申请号：US11027633
申请日：2004-12-28
申请人： George Moore , Ramesh Kumar , Zai-Ming Qiu , John Clark , Chetan Jariwala
发明人： George Moore , Ramesh Kumar , Zai-Ming Qiu , John Clark , Chetan Jariwala
IPC分类号： C08G18/00
CPC分类号： C08G18/2885 , C08G18/2845 , C08G18/3228 , C08G18/61 , C08G18/6212 , C08G18/6705 , C08G18/71 , C09D175/04 , Y10T428/31551
摘要： A fluorochemical compound comprises the reaction product of: (a) the reaction product of: (i) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: n=1 to 6, R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, q=1 to 8; and (ii) at least one unbranched symmetric diisocyanate, and (b) at least one co-reactant comprising two or more functional groups that are capable of reacting with an isocyanate group.
摘要翻译：含氟化合物包括以下反应产物：（a）反应产物：（i）至少一种由下式表示的含氟醇：<？in-line-formula description =“In-Line Formulas”end =“lead” 其中：在线式公式描述=“在线公式”end =“tail”→>其中： n = 1至6，R =氢或1至4个碳原子的烷基，m = 2至8，R f = C n N +1，y = 0〜6，q = 1〜8; 和（ii）至少一种非支化的对称二异氰酸酯，和（b）至少一种包含两个或更多个能够与异氰酸酯基团反应的官能团的共反应物。

3. 发明申请

US20060142474A1 WATER- AND OIL-REPELLENT FLUOROURETHANES AND FLUOROUREAS 有权
标题翻译：水和油脂氟和氟
公开(公告)号：US20060142474A1
公开(公告)日：2006-06-29
申请号：US11275114
申请日：2005-12-12
申请人： George Moore , Ramesh Kumar , Zai-Ming Qiu , John Clark , Chetan Jariwala , Thomas Klun
发明人： George Moore , Ramesh Kumar , Zai-Ming Qiu , John Clark , Chetan Jariwala , Thomas Klun
IPC分类号： C08G18/08 , C08G18/28 , B32B27/40
CPC分类号： C08G18/2885 , C08G18/2845 , C08G18/3228 , C08G18/61 , C08G18/6212 , C08G18/6705 , C08G18/71 , C09D175/04 , Y10T428/31551
摘要： A fluorochemical compound comprises the reaction product of: (a) the reaction product of: (i) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, q=1 to 8; and (ii) at least one unbranched symmetric diisocyanate, and (b) at least one co-reactant comprising two or more functional groups that are capable of reacting with an isocyanate group.
摘要翻译：含氟化合物包括以下反应产物：（a）反应产物：（i）至少一种由下式表示的含氟醇：<？in-line-formula description =“In-Line Formulas”end =“lead” 其中：在线式公式描述=“在线公式”end =“tail”→>其中： R =氢或1至4个碳原子的烷基，m = 2至8，R f = C n N 2n + 1 y = 0〜6，q = 1〜8; 和（ii）至少一种非支化的对称二异氰酸酯，和（b）至少一种包含两个或更多个能够与异氰酸酯基团反应的官能团的共反应物。

4. 发明申请

US20070004895A1 Polyurethanes derived from oligomeric fluoroacrylates 失效
标题翻译：衍生自低聚氟代丙烯酸酯的聚氨酯
公开(公告)号：US20070004895A1
公开(公告)日：2007-01-04
申请号：US11478219
申请日：2006-06-29
申请人： Cheryl Elsbernd , Frans Audenaert , John Clark , Chetan Jariwala , George Moore , Zai-Ming Qiu
发明人： Cheryl Elsbernd , Frans Audenaert , John Clark , Chetan Jariwala , George Moore , Zai-Ming Qiu
IPC分类号： C08G18/00
CPC分类号： C09D175/04 , C08G18/2825 , C08G18/2885 , C08G18/6279 , C08G18/672 , C08G18/792 , C08G18/8077 , C14C11/006
摘要： The present invention relates to fluorochemical polyurethane compounds, a method for their preparation, a method of application, and compositions comprising that fluorochemical polyurethane compound. The compound and the composition comprising that compound are suitable to impart durable oil- and water-repellency to substrates.
摘要翻译：本发明涉及含氟聚氨酯化合物，其制备方法，应用方法和包含该含氟聚氨酯化合物的组合物。该化合物和包含该化合物的组合物适用于赋予基材持久的耐油和拒水性。

5. 发明申请

US20060094851A1 Carbodiimide compound and compositions for rendering substrates oil and water repellent 有权
公开(公告)号：US20060094851A1
公开(公告)日：2006-05-04
申请号：US10982107
申请日：2004-11-04
申请人： Frans Audenaert , Chetan Jariwala
发明人： Frans Audenaert , Chetan Jariwala
IPC分类号： C08G18/00
CPC分类号： C07C267/00 , C08G18/095 , C08G18/2825 , C08G18/6229
摘要： The invention relates to a carbodiimide compound or mixture of carbodiimide compounds derived from a carbodiimidization reaction of at least one oligomer having at least one isocyanate group and comprising at least two repeating units deriving from one or more ethylenically unsaturated monomers.

6. 发明申请

US20050113508A1 Fluorochemical oligomeric composition and use thereof 失效
标题翻译：氟化物低聚物组合物及其用途
公开(公告)号：US20050113508A1
公开(公告)日：2005-05-26
申请号：US10723510
申请日：2003-11-26
申请人： Chetan Jariwala , Dirk Coppens , Frank Godefroidt
发明人： Chetan Jariwala , Dirk Coppens , Frank Godefroidt
IPC分类号： C08G18/62 , C08G18/71 , C08G18/80 , C08G18/81 , D06M13/252 , D06M15/256 , D06M15/277 , D06M15/576 , D06M15/63 , C08K3/00
CPC分类号： D06M15/63 , C08G18/6279 , C08G18/71 , D06M13/252 , D06M15/256 , D06M15/277 , D06M15/576
摘要： A method of treating fibrous substrates by contacting the substrate with a fluorochemical composition comprising: a fluorochemical oligomeric component and an antisoiling component is described. The compositions provide desirable antisoiling properties, as well as oil, water and stain repellency to fibrous substrates.
摘要翻译：描述了通过使基底与含氟化合物组合物接触来处理纤维基材的方法，其包含：含氟低聚物组分和防污组分。所述组合物提供所需的防污性能，以及对纤维基材的油，水和防污性。

7. 发明申请

US20060013983A1 Adhesive delivery of oil and water repellents 审中-公开
标题翻译：拒水拒油胶
公开(公告)号：US20060013983A1
公开(公告)日：2006-01-19
申请号：US10891736
申请日：2004-07-15
申请人： John Sebastian , Stefan H. Gryska , Thomas P. Klun , Chetan Jariwala
发明人： John Sebastian , Stefan H. Gryska , Thomas P. Klun , Chetan Jariwala
IPC分类号： B32B33/00
CPC分类号： C09J7/21 , C09J7/22 , C09J7/38 , C09J2205/102 , Y10T428/14 , Y10T428/28
摘要： A repellent article is disclosed comprising a layer of a thermoplastic polymer, and an adhesive layer having a fluorochemical repellent additive dispersed therein. The additive migrates from the adhesive layer to the thermoplastic polymer layer, rendering it oil- and/or water repellent.
摘要翻译：公开了一种驱虫制品，其包含一层热塑性聚合物，以及一种其中分散有氟化学驱避添加剂的粘合剂层。添加剂从粘合剂层迁移到热塑性聚合物层，使其具有油和/或拒水性。

8. 发明申请

US20050129922A1 Fluid repellent microporous materials 有权
标题翻译：防流体微孔材料
公开(公告)号：US20050129922A1
公开(公告)日：2005-06-16
申请号：US11050507
申请日：2005-02-03
申请人： James Mrozinski , Chetan Jariwala
发明人： James Mrozinski , Chetan Jariwala
IPC分类号： C08J9/00 , B29C55/00 , B32B5/18 , B32B27/32 , C08K5/04 , C08L23/00 , D01D1/00 , B32B3/00 , B32B3/26 , C06B21/00
CPC分类号： B32B5/18 , B29C55/005 , B29K2105/04 , B29K2105/16 , Y10T428/249921 , Y10T428/249953 , Y10T428/249978 , Y10T428/24998 , Y10T428/29 , Y10T428/2913 , Y10T428/2915 , Y10T428/2969
摘要： Microporous articles formed by thermally induced phase separation from a diluent in combination with a thermoplastic polymer and a fluorochemical additive providing novel fluid repellent articles. Such articles are useful in clothing, barrier membranes, optical films in electronic devices (such as light reflective and dispersive films), and protective garments.
摘要翻译：通过与热塑性聚合物和含氟化合物添加剂的热诱导相分离形成的微孔制品，其提供新的流体驱避物品。这样的制品可用于衣服，隔离膜，电子设备（如光反射和分散膜）中的光学膜和防护服。

9. 发明申请

US20060135673A1 Fluorochemical esters blends as repellent polymer melt additives 审中-公开
标题翻译：氟化合物混合物作为驱避聚合物熔体添加剂
公开(公告)号：US20060135673A1
公开(公告)日：2006-06-22
申请号：US11012566
申请日：2004-12-15
申请人： John Temperante , Chetan Jariwala
发明人： John Temperante , Chetan Jariwala
IPC分类号： C08F220/24
CPC分类号： C08K5/10 , C08K5/435
摘要： A thermoplastic polymer comprising a blend of a first fluorochemical ester composition of the formula (I): [Rh(CO2)]m-A-[(CO2)-QRf1]n (I) wherein A is the residue of a polyol, polyacid or mixed bydroxy acid, optionally having one or more unreacted hydroxyl or carboxyl functional groups, having 3 to 12, preferably 3 to 6 carbon atoms, Rh is an alkyl group of 12 to 72 carbon atoms, Rf is a fluoroalkyl group or 3 to 12 carbon atoms, Q is a divalent linking group, each (CO2) group is non-directional, and m and n are each at least 1; and a second fluorochemical ester composition of formula (II) Rf2—O—C(O)—R1 or Rf—C(O)—O—R1 (II) wherein Rf is F(CF2)x—SO2N(R2)-R3 wherein x is a positive integer from about 4 to about 20, R2 is an alkyl radical of from 1 to about 4 carbon atoms, and R3 is an alkylene radical of from 1 to about 12 carbon atoms; and R1 is an aliphatic linear hydrocarbon having an average of from 12 to 66 carbon atoms.
摘要翻译：一种热塑性聚合物，其包含式（I）的第一含氟化合物酯组合物的共混物：<？in-line-formula description =“In-line Formulas”end =“lead”？> [R / （CO 2 2）] - - - （（CO 2）2 - ）（C 1 -C 6）其中A是多元醇，多酸或混合的二羟基酸的残基，任选地具有一个或多个（例如，具有3至12个，优选3至6个碳原子的未反应的羟基或羧基官能团R 12是具有12至72个碳原子的烷基，R 1是氟代烷基或3至12个碳原子，Q是二价连接基团，每个（CO 2/2）基团是无方向性的，m和n各自至少为1; 和式（II）的第二含氟化合物酯组合物<？in-line-formula description =“In-line Formulas”end =“lead”？> R＆lt; 2＆gt; -OC（O）-R 1或R 1 -C（O）-OR 1（II）<β在线式 description =“In-line Formulas”end =“tail”？>其中R f是F（CF 2）x SO - SUB 其中x为约4至约20的正整数，R 2为（R 2）是1至约4个碳原子的烷基，R 3是1至约12个碳原子的亚烷基; R 1是具有平均12至66个碳原子的脂肪族直链烃。

10. 发明申请

US20060128850A1 Fluorochemical diesters as repellent polymer melt additives 有权
标题翻译：氟化物二酯作为驱避聚合物熔体添加剂
公开(公告)号：US20060128850A1
公开(公告)日：2006-06-15
申请号：US11012444
申请日：2004-12-15
申请人： Chetan Jariwala , John Temperante
发明人： Chetan Jariwala , John Temperante
IPC分类号： C08K5/43 , C08K5/02
CPC分类号： D01F1/10 , C08K5/435 , C08L23/02
摘要： A thermoplastic polymer comprising a fluorochemical ester composition of formula I: C4F9SO2N(Q1)(CH2)n—O—C(O)—(CH2)n—C(O)O(CH2)bNQ2SO2C4F9 (I) wherein Q1 and Q2 which may be the same or different are each a hydrogen or an alkyl group of 1 to 4 carbon atoms; a is an integer from 2 to 11; b is an integer from 2 to 11; and n is at least 10.
摘要翻译：包含式I的含氟化合物酯组合物的热塑性聚合物：<？in-line-formula description =“In-line formula”end =“lead”？> C 4 （CH 2）n（O） - （CH 2）n（Q 1） C（O）O（CH 2）2 N 2 O 2 CH 2 O（CH 2）（I）<？in-line-formula description =“In-line Formulas”end =“tail 其中Q 1和2彼此可以相同或不同，分别为氢或1-4个碳原子的烷基; a是从2到11的整数; b为2〜11的整数; n为至少10。

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