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    • 1. 发明申请
    • Fluorochemical esters blends as repellent polymer melt additives
    • 氟化合物混合物作为驱避聚合物熔体添加剂
    • US20060135673A1
    • 2006-06-22
    • US11012566
    • 2004-12-15
    • John TemperanteChetan Jariwala
    • John TemperanteChetan Jariwala
    • C08F220/24
    • C08K5/10C08K5/435
    • A thermoplastic polymer comprising a blend of a first fluorochemical ester composition of the formula (I): [Rh(CO2)]m-A-[(CO2)-QRf1]n  (I) wherein A is the residue of a polyol, polyacid or mixed bydroxy acid, optionally having one or more unreacted hydroxyl or carboxyl functional groups, having 3 to 12, preferably 3 to 6 carbon atoms, Rh is an alkyl group of 12 to 72 carbon atoms, Rf is a fluoroalkyl group or 3 to 12 carbon atoms, Q is a divalent linking group, each (CO2) group is non-directional, and m and n are each at least 1; and a second fluorochemical ester composition of formula (II) Rf2—O—C(O)—R1 or Rf—C(O)—O—R1  (II) wherein Rf is F(CF2)x—SO2N(R2)-R3 wherein x is a positive integer from about 4 to about 20, R2 is an alkyl radical of from 1 to about 4 carbon atoms, and R3 is an alkylene radical of from 1 to about 12 carbon atoms; and R1 is an aliphatic linear hydrocarbon having an average of from 12 to 66 carbon atoms.
    • 一种热塑性聚合物,其包含式(I)的第一含氟化合物酯组合物的共混物:<?in-line-formula description =“In-line Formulas”end =“lead”?> [R / (CO 2 2)] - - - ((CO 2)2 - )(C 1 -C 6) 其中A是多元醇,多酸或混合的二羟基酸的残基,任选地具有一个或多个(例如, 具有3至12个,优选3至6个碳原子的未反应的羟基或羧基官能团R 12是具有12至72个碳原子的烷基,R 1是 氟代烷基或3至12个碳原子,Q是二价连接基团,每个(CO 2/2)基团是无方向性的,m和n各自至少为1; 和式(II)的第二含氟化合物酯组合物<?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; 2&gt; -OC(O)-R 1或R 1 -C(O)-OR 1(II)<β在线式 description =“In-line Formulas”end =“tail”?>其中R f是F(CF 2)x SO - SUB 其中x为约4至约20的正整数,R 2为(R 2) 是1至约4个碳原子的烷基,R 3是1至约12个碳原子的亚烷基; R 1是具有平均12至66个碳原子的脂肪族直链烃。