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1. 发明申请

US20050143541A1 Water- and oil-repellent fluoroacrylates 有权
标题翻译：拒水拒油氟代丙烯酸酯
公开(公告)号：US20050143541A1
公开(公告)日：2005-06-30
申请号：US11027604
申请日：2004-12-28
申请人： Gregg Caldwell , John Clark , David Kinning , Alan Kirk , Thomas Klun , Ramesh Kumar , Roger Mader , George Moore , Zai-Ming Qiu , Richard Ross
发明人： Gregg Caldwell , John Clark , David Kinning , Alan Kirk , Thomas Klun , Ramesh Kumar , Roger Mader , George Moore , Zai-Ming Qiu , Richard Ross
IPC分类号： C07C69/653 , C07C233/18 , C07C271/08 , C07C271/20 , C07C271/28 , C07C311/04 , C07C311/09 , C08F20/24 , C08F220/38 , C08F114/18
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf═CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diisocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译：氟代丙烯酸酯包括以下反应产物：（a）至少一种由下式表示的含氟醇：<？in-line-formula description =“In-line Formulas”end =“lead”？> C

2. 发明申请

US20070173149A1 WATER- AND OIL-REPELLENT FLUOROACRYLATES 失效
标题翻译：水和油的氟代丙烯酸酯
公开(公告)号：US20070173149A1
公开(公告)日：2007-07-26
申请号：US11688074
申请日：2007-03-19
申请人： Gregg CALDWELL , John Clark , David Kinning , Alan Kirk , Thomas Klun , Ramesh Kumar , Roger Mader , George Moore , Zai-Ming Qiu , Richard Ross
发明人： Gregg CALDWELL , John Clark , David Kinning , Alan Kirk , Thomas Klun , Ramesh Kumar , Roger Mader , George Moore , Zai-Ming Qiu , Richard Ross
IPC分类号： B32B27/04 , C08L31/00 , C08F8/30 , C07C271/14
CPC分类号： C08F220/38 , C07C271/20 , C07C271/28 , C07C311/09 , Y10T442/2287
摘要： Fluoroacrylates comprise the reaction product of: (a) at least one fluorochemical alcohol represented by the formula: CnF2n+1—X—OH wherein: n=1 to 4, R=hydrogen or an alkyl group of 1 to 4 carbon atoms, m=2 to 8, Rf=CnF2n+1, y=0 to 6, and q=1 to 8; (b) at least one unbranched symmetric diusocyanate; and (c) at least one hydroxy-terminated alkyl (meth)acrylate or 2-fluoro acrylate monomer having 2 to about 30 carbon atoms in its alkylene portion.
摘要翻译：氟代丙烯酸酯包括以下反应产物：（a）至少一种由下式表示的含氟醇：<？in-line-formula description =“In-line Formulas”end =“lead”？> C

3. 发明申请

US20050214531A1 Release compositions and articles made therefrom 有权
标题翻译：释放组合物和由其制成的制品
公开(公告)号：US20050214531A1
公开(公告)日：2005-09-29
申请号：US11137769
申请日：2005-05-25
申请人： David Kinning , Audrey Sherman , Jeffrey Schwab , Patrick Seleski , Wendi Winkler
发明人： David Kinning , Audrey Sherman , Jeffrey Schwab , Patrick Seleski , Wendi Winkler
IPC分类号： C08L27/06 , C08L31/04 , C08L33/26 , C09J7/02 , C09J123/06 , C09J123/08 , B32B7/12
CPC分类号： C09J123/0869 , C08L27/06 , C08L31/04 , C08L33/26 , C08L2666/02 , C08L2666/04 , C09J7/201 , C09J7/21 , C09J7/22 , C09J7/30 , C09J7/401 , C09J123/06 , C09J2201/606 , C09J2205/114 , C09J2400/163 , C09J2400/22 , C09J2400/226 , C09J2400/263 , C09J2400/283 , C09J2401/006 , C09J2407/00 , C09J2421/00 , C09J2423/00 , C09J2423/005 , C09J2423/046 , C09J2429/00 , C09J2431/005 , C09J2433/00 , C09J2433/005 , C09J2453/00 , C09J2475/00 , C09J2483/00 , Y10T428/28 , Y10T428/2839 , Y10T428/2848 , Y10T428/2852 , Y10T428/2891
摘要： The invention relates to compatibilized release compositions useful in release layers of release articles (e.g., release liners) and adhesive articles (e.g., pressure sensitive adhesive tapes). The compatibilized release compositions comprise a mixture of a thermoplastic olefin-based polymer comprising an acid or a base functionality and a polymeric release material comprising an acid or a base functionality. The functionality of the thermoplastic olefin-based polymer and the functionality of the polymeric release material are selected to provide an acid-base interaction.
摘要翻译：本发明涉及可用于脱模制品（例如脱模衬垫）和粘合剂制品（例如压敏粘合带）的脱模层中的相容性脱模组合物。增容的脱模组合物包含含有酸或碱官能团的热塑性烯烃基聚合物和包含酸或碱官能团的聚合物脱模材料的混合物。选择热塑性烯烃基聚合物的功能性和聚合物脱模材料的官能度以提供酸碱相互作用。

4. 发明申请

US20060141246A1 Fluorochemical containing low adhesion backsize 有权
标题翻译：含有低附着力的含氟化合物
公开(公告)号：US20060141246A1
公开(公告)日：2006-06-29
申请号：US11027602
申请日：2004-12-28
申请人： James DiZio , David Kinning , George Moore
发明人： James DiZio , David Kinning , George Moore
IPC分类号： B32B7/12 , B32B15/04
CPC分类号： C08F214/18 , C08F220/18 , C08L31/04 , C08L33/08 , C08L33/16 , C08L33/20 , C08L35/06 , Y10T428/28 , Y10T428/2848 , Y10T428/2852 , C08L2666/04
摘要： In one aspect, the invention provides a water-based release coating composition comprising a mixture of (A.) from about 5 to about 100 wt % of a polymer comprising the reaction product of (a.) from 1 to about 15 wt % of a fluorinated monomer selected from the group consisting of monomers according to the general formula: RfX—OC(O)—C(R)═CH2, wherein Rf represents a perfluorinated aliphatic group having 3 or 4 carbon atoms, X is an organic divalent linking group, and R represents a hydrogen or methyl group, (b.) from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, (c.) from about 3 to about 20 wt % of (meth)acrylic acid, (d.) from about 20 to about 40 wt % acrylonitrile, and (e.) from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of (a.) through (e.) equals 100%; and (B.) from 0 to about 95 wt % of an extender polymer, wherein the sum of (A.) and (B.) is 100% and wt % is based on the total amount of solids in the composition.
摘要翻译：在一个方面，本发明提供一种水性剥离涂料组合物，其包含（A）约5至约100重量％的聚合物的混合物，所述聚合物包含（a。）的反应产物，所述反应产物为（a。）1至约15重量％选自以下通式的单体的氟化单体：<？in-line-formula description =“In-line Formulas”end =“lead”？> R X X-OC （O）-C（R）-CH 2，<βin-line-formula description =“In-line Formulas”end =“tail”？>其中R 1 f 表示具有3或4个碳原子的全氟化脂族基团，X是有机二价连接基团，R表示氢或甲基，（b。）约40至约70重量％的（甲基）丙烯酸烷基酯，其中烷基含有16至22个碳原子，（c）约3至约20重量％的（甲基）丙烯酸，（d。）约20至约40重量％的丙烯腈，（e） 0至约15重量％的乙烯基单体，除丙烯腈之外，其中（ a。）通过（e。）等于100％; 和（B.）0至约95重量％的增量聚合物，其中（A.）和（B.）的总和为100％，wt％基于组合物中固体的总量。

5. 发明申请

US20060141194A1 Water-based release coating containing fluorochemical 有权
标题翻译：含氟化合物的水性防粘涂层
公开(公告)号：US20060141194A1
公开(公告)日：2006-06-29
申请号：US11027606
申请日：2004-12-28
申请人： James Carlson , John Clark , James DiZio , David Kinning , Ramesh Kumar , Chetan Jariwala
发明人： James Carlson , John Clark , James DiZio , David Kinning , Ramesh Kumar , Chetan Jariwala
IPC分类号： B32B33/00
CPC分类号： C09D133/02 , Y10S525/902 , Y10T428/14
摘要： In one aspect, the invention provides a water-based release coating composition comprising a mixture of: A. from 0.1 to about 5 wt % of a fluoro(meth)acrylate (co)polymer or a fluorochemical urethane compound containing at least one fluorinated group having the formula —(CF2)nCF3, wherein n is an integer from 1 to 3; B. from about 5 to about 99.9 wt % of a copolymer comprising the reaction product of a. from about 40 to about 70 wt % of an alkyl (meth)acrylate, wherein the alkyl group contains from 16 to 22 carbon atoms, b. from about 3 to about 20 wt % of (meth)acrylic acid, c. from about 20 to about 40 wt % acrylonitrile, and d. from 0 to about 15 wt % of vinyl monomer, other than acrylonitrile, wherein the sum of a. through d. equals 100%; and C. from 0 to about 94.9 wt % of an extender polymer, wherein the sum of A., B., and C. is 100% and wt % is based on the total amount of solids in the composition.
摘要翻译：一方面，本发明提供了一种水性防粘涂料组合物，其包含以下混合物：A.从0.1至约5wt％的氟（甲基）丙烯酸酯（共）聚合物或含有至少一个氟化基团的含氟氨基甲酸酯化合物具有式 - （CF 2）n CF 3，其中n为1至3的整数; B.约5至约99.9重量％的包含a的反应产物的共聚物。约40至约70重量％的（甲基）丙烯酸烷基酯，其中烷基含有16至22个碳原子，b。约3至约20重量％的（甲基）丙烯酸，c。约20至约40重量％的丙烯腈，以及d。 0至约15重量％的乙烯基单体，除了丙烯腈，其中a。通过d。等于100％; 和C.0至约94.9重量％的增量聚合物，其中A.，B.和C.的总和为100％，wt％基于组合物中固体的总量。

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