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    • 3. 发明授权
    • Disazo dyestuffs having a triazine moiety and a fiberreactive group of
vinylsulfone series
    • 具有三嗪部分和乙烯基砜系列的纤维反应性基团的双偶氮染料
    • US5243034A
    • 1993-09-07
    • US794688
    • 1991-11-18
    • Horst TappeDieter OehmeHolger M. BuchWerner H. Russ
    • Horst TappeDieter OehmeHolger M. BuchWerner H. Russ
    • C09B62/44C09B62/513
    • C09B62/4415C09B62/513
    • Disazo dyestuffs containing sulfo groups and having fiber-reactive properties, which are capable of dyeing materials containing hydroxyl groups and/or carboxamide groups, in particular fiber materials, such as synthetic polyamide fibers, wool and in particular cellulose fiber materials, in deep fast shades. They contain a group corresponding to the formula ##STR1## in which R.sup..alpha. is hydrogen or alkyl having 1 to 4 carbon atoms, which can be substituted by carboxyl, sulfo, cyano, hydroxyl or chlorine;B is fluorine, chlorine, bromine, lower alkylsulfonyl, phenylsulfonyl, methoxy or sulfo;Q is a group of the formula ##STR2## in which Y is vinyl, .beta.-sulfatoethyl, .beta.-halogenoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl or .beta.-acetoxyethyl,R is hydrogen or lower alkyl,k is the number zero to 4 andX, together with the N atom, forms the bivalent radical of a heterocyclic ring which optionally contains additional hetero atoms.
    • 能够染色含有羟基和/或羧酰胺基团的物质的具有磺基并具有纤维反应性的双偶氮染料,特别是纤维材料,例如合成聚酰胺纤维,羊毛,特别是纤维素纤维材料,具有深快速色调 。 它们包含对应于其中Rα是氢或具有1至4个碳原子的烷基的式“IMAGE”的基团,其可以被羧基,磺基,氰基,羟基或氯取代; B是氟,氯,溴,低级烷基磺酰基,苯基磺酰基,甲氧基或磺基; Q是其中Y是乙烯基,β-磺基乙基,β-卤代乙基,β-硫代乙酰基乙基,β-磷酰乙基或β-乙酰氧基乙基的式 的基团,R是氢或低级烷基,k是数 0至4和X与N原子一起形成杂环的二价基团,其任选地含有另外的杂原子。
    • 4. 发明授权
    • Monoazo compounds containing a fiber-reactive group and an
oxazolopyridone or oxazinopyridone coupling component
    • 含有纤维反应性基团和恶唑吡啶酮或恶嗪吡酮偶联组分的单偶氮化合物
    • US4948879A
    • 1990-08-14
    • US272781
    • 1988-11-17
    • Horst TappeDieter OehmeWerner H. Russ
    • Horst TappeDieter OehmeWerner H. Russ
    • D06P1/38C09B62/008C09B62/085C09B62/51
    • C09B62/0088
    • Monoazo compounds conforming to the general formula (1) shown and defined hereinafter have very good fiber-reactive dye properties and dye hydroxy- and/or carboxamido-containing material, in particular fiber material, such as wool and in particular cellulose fibers, in strong fast shades. ##STR1## where the symbols have the following meanings: D is a benzene or naphthalene ring or a heterocyclic radical,R.sup.1 and R.sup.2 are each independently of the other hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen, carboxy or sulfo,Z is a fiber-reactive grouping bonded to D either directly or via a bridge member,m stands for the number 1 or 2, preferably 1,R is alkyl of 1 to 4 carbon atoms which may be substituted for example by halogen, such as bromine and in particular chlorine, hydroxy, cyano, sulfo, carboxy, sulfato or phosphato, or is phenyl which may be substituted, for example by 1 or 2 substituents from the group consisting of methyl, ethyl, methoxy, ethoxy, chlorine, sulfo and carboxy, or is carboxy, carbamoyl or carbalkoxy of 2 to 5 carbon atoms,n stands for the number 2 or 3.
    • 符合以下所示和定义的通式(1)的单偶氮化合物具有非常好的纤维反应性染料性质和含羟基和/或羧酰胺基染料的材料,特别是纤维材料,如羊毛,特别是纤维素纤维,强度 快速阴影 (1)其中符号具有以下含义:D是苯或萘环或杂环基,R 1和R 2各自独立地为氢,1至4个碳原子的烷基,1至4的烷氧基 碳原子,卤素,羧基或磺基,Z是直接或通过桥连构件与D键合的纤维反应性分子,m代表数字1或2,优选1,R是1至4个碳原子的烷基, 例如可以被卤素取代,例如溴,特别是氯,羟基,氰基,磺基,羧基,硫酸基或磷酸酯,或者是可被取代的苯基,例如被1或2个选自甲基,乙基 ,甲氧基,乙氧基,氯,磺基和羧基,或是2至5个碳原子的羧基,氨基甲酰基或烷氧基,n代表2或3。
    • 5. 发明授权
    • Water-insoluble azo dyestuffs, processes for their manufacture and their
use for dyeing and printing synthetic hydrophobic fiber material
    • 水不溶性偶氮染料,其制造方法及其用于染色和印刷合成疏水纤维材料的用途
    • US4431585A
    • 1984-02-14
    • US237628
    • 1981-02-24
    • Horst TappeUlrich BuhlerKurt RothHans-J. WeyerUwe Kosubek
    • Horst TappeUlrich BuhlerKurt RothHans-J. WeyerUwe Kosubek
    • C09B29/08C09B31/043C09B43/40C09B43/42C09B29/06C09B29/00
    • C09B43/405C09B29/0813C09B31/043C09B43/40C09B43/42
    • Water-insoluble azo dyestuffs suitable for dyeing and printing synthetic hydrophobic fiber materials are produced by azo coupling and have the formula ##STR1## wherein D is free from ionic moieties and is an unsubstituted or substituted phenyl, thiazole, isothiazole, benzthiazole, thiadiazole, benzisothiazole or thiophene moiety;A is alkylene having 2 to 6 carbon atoms which is unsubstituted or substituted by --OH;B is hydrogen, alkyl having 1 to 4 carbon atoms, hydroxyalkyl having 2 to 4 carbon atoms, alkoxyalkyl having 1 to 4 carbon atoms in the alkoxy moiety and a total of 3 to 8 carbon atoms, alkanoyloxyalkyl having 2 to 6 carbon atoms in the alkanoyl moiety and a total of 3 to 8 carbon atoms, hydroxypolyoxyalkylene having 4 to 12 carbon atoms, alkoxypolyoxyalkylene having 1 to 4 carbon atoms in the alkoxy moiety and a total of 5 to 16 carbon atoms, alkanoyloxypolyoxyalkylene having 2 to 5 carbon atoms in the alkanoyl moiety and a total of 5 to 16 carbon atoms, alkanoyl having 2 to 6 carbon atoms or benzoyl;R.sup.1 is hydrogen, methyl or chlorine;R.sup.2 is hydrogen, halogen, alkyl having 1 to 4 carbon atoms or alkoxy having 1 to 4 carbon atoms;and R.sup.3 is hydrogen or alkoxy having 1 to 8 carbon atoms.
    • 适用于染色和印刷合成疏水性纤维材料的水不溶性偶氮染料是通过偶氮偶合产生的,并具有式“IMAGE”,其中D不含离子部分,是未取代或取代的苯基,噻唑,异噻唑,苯并噻唑,噻二唑,苯并异噻唑 或噻吩部分; A是未被取代或被-OH取代的具有2至6个碳原子的亚烷基; B是氢,具有1至4个碳原子的烷基,具有2至4个碳原子的羟基烷基,烷氧基部分中具有1至4个碳原子的烷氧基烷基和总共3至8个碳原子,在该化合物中具有2至6个碳原子的烷酰氧基烷基 烷酰基部分和总共3至8个碳原子,具有4至12个碳原子的羟基聚氧化烯,烷氧基部分中具有1至4个碳原子的烷氧基聚氧化烯和总共5至16个碳原子,在2至5个碳原子上具有2至5个碳原子的烷酰氧基聚氧化烯 烷酰基部分和总共5至16个碳原子,具有2至6个碳原子的烷酰基或苯甲酰基; R1是氢,甲基或氯; R2是氢,卤素,具有1至4个碳原子的烷基或具有1至4个碳原子的烷氧基; 并且R 3是氢或具有1至8个碳原子的烷氧基。
    • 7. 发明授权
    • Process for the manufacture of aromatic sulphonic acid esters of
aromatic amino-hydroxy compounds
    • 芳香族氨基 - 羟基化合物的芳香族磺​​酸酯的制造方法
    • US4158670A
    • 1979-06-19
    • US879852
    • 1978-02-22
    • Rolf MullerJoachim RibkaHorst Tappe
    • Rolf MullerJoachim RibkaHorst Tappe
    • C07B61/00B01J31/00B01J31/02C07C20060101C07C67/00C07C301/00C07C303/28C07C309/63C07C309/72C07C143/68
    • C07C303/28
    • A process for the manufacture of esters of aromatic sulphonic acids and aromatic aminohydroxy compounds, of the formula Ih.sub.2 n--a--o--so.sub.2 --b (i)comprising reacting an aromatic aminohydroxy compound of the formula IIh.sub.2 n--a--oh (ii)having a pK.sub.a value of from 8.5 to 10.1, with a sulphochloride of the formula IIIcl--SO.sub.2 --B (III)whereinA is phenylene, substituted phenylene, naphthylene or substituted naphthylene,B is phenyl, substituted phenyl, naphthyl or substituted naphthyl, and both A and B are free from --COOH and --SO.sub.3 H substituents;The reaction taking place in a reaction medium consisting essentially of water and a water-immiscible organic solvent for the sulphochloride,At a temperature of from 0.degree. to 95.degree. C., at a pH which is determined from and associated with the pK.sub.a value of said aromatic aminohydroxy compound of formula II by the equationpK.sub.a -pH=0.5 to -1.5, and in the presence of a phase transfer catalyst.
    • 制备式I H 2 N-AO-SO 2 -B(I)的芳族磺酸和芳族氨基羟基化合物的酯的方法,包括使具有式II的芳族氨基羟基化合物H 2 N-A-OH(II) 其中A为亚苯基,取代亚苯基,亚萘基或取代亚萘基,B为苯基,取代的苯基,萘基或取代的萘基,并且两者均为 A和B不含-COOH和-SO 3 H取代基; 在pH为0〜95℃的温度下,在由碱性水溶液组成的反应介质中进行反应和在硫酸盐的水不溶性有机溶剂中反应,其pH值由pKa值 所述式II的芳族氨基羟基化合物通过PKa-pH = 0.5至-1。
    • 9. 发明授权
    • 2,4-Diaminophenyl tetrahydrofurfuryl ethers, processes for their
preparation and tinting compositions, which contain them for keratinic
fibres
    • 2,4-二氨基苯基四氢糠醚,它们的制备方法和着色组合物,其含有角蛋白纤维
    • US4857070A
    • 1989-08-15
    • US154495
    • 1988-02-08
    • Winfried SeidelHorst Tappe
    • Winfried SeidelHorst Tappe
    • A61K8/00A61K8/49A61Q5/10C07D307/12C09B53/00D06P1/32D06P3/08
    • D06P1/32A61K8/4973A61Q5/10C07D307/12
    • The invention relates to new 2,4-diaminophenyl tetrahydrofurfuryl ethers of the general formula VIII and to their salts with inorganic or organic acids ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4, independently of one another, each represent a hydrogen atom, a (C.sub.1 -C.sub.4)alkyl group, hydroxy(C.sub.2 -C.sub.4)alkyl group, dihydroxy(C.sub.3 -C.sub.4)alkyl group, halogeno(C.sub.2 -C.sub.4)alkyl group, amino(C.sub.2 -C.sub.4)alkyl group or an amino(C.sub.2 -C.sub.4)alkyl group which is substituted once or twice by methyl, ethyl or hydroxyethyl radicals on the nitrogen, the carbon chain having a straight or branched arrangement, and it being a proviso that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a hydrogen atom, to processes for their preparation, and to aqueous tinting compositions for keratin fibres such as fur and human hair, containing at least one coupler and at least one developing component together with customary additives and auxiliaries, the coupler corresponding to the general formula VIII or to the acid salts of these compounds.
    • 本发明涉及通式VIII的新的2,4-二氨基苯基四氢糠基醚及其与无机或有机酸(VIII)的盐,其中R 1,R 2,R 3和R 4彼此独立地表示 氢原子,(C1-C4)烷基,羟基(C2-C4)烷基,二羟基(C3-C4)烷基,卤代(C2-C4)烷基,氨基(C2-C4)烷基或氨基 (C 2 -C 4)烷基,其被氮上的甲基,乙基或羟乙基取代一次或两次,所述碳链具有直链或支链排列,条件是R1,R2,R3和 R4代表氢原子,其制备方法,以及含有至少一种偶联剂和至少一种显影组分以及常规添加剂和助剂的角蛋白纤维如毛皮和人发的水性着色组合物,所述成色剂对应于 通式VIII或这些化合物的酸式盐。