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    • 5. 发明授权
    • Mixtures of blue mono-azo disperse dyestuffs and their use for dyeing
polyester
    • 蓝色单偶氮分散染料的混合物及其用于染色聚酯的用途
    • US4678476A
    • 1987-07-07
    • US911746
    • 1986-09-26
    • Horst TappeHubert KruseReinhard KuhnAlbert BodeMargareta Boos
    • Horst TappeHubert KruseReinhard KuhnAlbert BodeMargareta Boos
    • C09B29/01C09B29/085C09B67/22D06P1/18C09B29/00D06P1/04
    • C09B67/0051C09B29/0003Y10S8/921Y10S8/922Y10S8/924
    • Synthetic fiber materials are effectively colored by dyeing or printing with a dyestuff mixture containing at least two separate dyestuffs (I) and (II) in a weight ratio of (I):(II) of from (20 to 99):(80 to 1) wherein:(I) is at least one dyestuff of the formula ##STR1## and (II) is at least one dyestuff of the formula ##STR2## in which X and Y are the same or different and each is independently chloro and bromo:R.sup.1 and R.sup.2 are the same or different and each independently denotes hydrogen, alkoxy having 1 to 4 carbon atoms, alkenyl having 3 or 4 carbon atoms, cyclohexyl, benzyl, chlorobenzyl, bromobenzyl, nitrobenzyl, cyanobenzyl, alkylbenzyl having 1 to 4 carbon atoms in the alkyl moiety, alkoxybenzyl having 1 to 4 alkoxy carbon atoms, alkyl having 1 to 11 carbon atoms, alkyl having 1 to 11 carbon atoms interrupted by 1 to 3 oxygen atoms or substituted alkyl having 1 to 11 carbon atoms wherein the substituent is one selected from the group consisting of chloro, bromo, cyano, phenyl, phenoxy, hydroxy, (C.sub.1 -to-C.sub.4 -alkyl)-carbonyloxy, (C.sub.1 -to-C.sub.4 -alkoxy)-carbonyl, phenylcarbonyloxy, (C.sub.3 -to-C.sub.5 -alkenyloxy)-carbonyloxy, (C.sub.1 -to-C.sub.4 -alkoxy)-carbonyloxy, phenoxycarbonyloxy, tetrahydrofurfuryl, (C.sub.1 -to-C.sub.4 -alkyl)-tetrahydrofurfuryl, tetrahydrophyronyl and (C.sub.1 -to-C.sub.4 -alkyl)-tetrahydropyronyl;R.sup.3 and R.sup.4 are the same or different and each is independently methyl, ethyl, n-propyl or i-propyl;R.sup.5 and R.sup.6 are the same or different and each is independently one of the definitions of R.sup.1 and R.sup.2 excepting hydrogen.
    • 合成纤维材料通过用含有至少两种分开的染料(I)和(II)的染料混合物以(20〜99):( 80〜(80〜 1)其中:(I)是至少一种式IMA的染料,(II)是至少一种式“IMAGE”的染料,其中X和Y相同或不同,并且各自独立地是氯和溴 :R1和R2相同或不同,各自独立地表示氢,具有1-4个碳原子的烷氧基,具有3或4个碳原子的链烯基,环己基,苄基,氯苄基,溴苄基,硝基苄基,氰基苄基,具有1-4个碳原子的烷基苄基 在烷基部分中,具有1-4个烷氧基碳原子的烷氧基苄基,具有1至11个碳原子的烷基,具有1至3个碳原子的1至11个碳原子的烷基或被取代的具有1至11个碳原子的烷基,其中取代基是1 选自氯,溴,氰基,苯基,杂环基 羟基,(C 1 -C 4 - 烷基) - 羰基氧基,(C 1 -C 4 - 烷氧基) - 羰基,苯基羰氧基,(C 3 -C 5 - 烯氧基) - 羰基氧基,(C 1 -C 4 - ) - 羰基氧基,苯氧基羰基氧基,四氢糠基,(C 1 -C 4 - 烷基) - 四氢糠基,四氢化芴基和(C 1 -C 4烷基) - 四氢吡喃基; R 3和R 4相同或不同,各自独立地为甲基,乙基,正丙基或异丙​​基; R 5和R 6相同或不同,并且各自独立地是除氢之外的R 1和R 2的定义之一。
    • 8. 发明授权
    • Water-insoluble azo dyestuffs, processes for their manufacture and their
use for dyeing and printing synthetic hydrophobic fiber material
    • 水不溶性偶氮染料,其制造方法及其用于染色和印刷合成疏水纤维材料的用途
    • US4431585A
    • 1984-02-14
    • US237628
    • 1981-02-24
    • Horst TappeUlrich BuhlerKurt RothHans-J. WeyerUwe Kosubek
    • Horst TappeUlrich BuhlerKurt RothHans-J. WeyerUwe Kosubek
    • C09B29/08C09B31/043C09B43/40C09B43/42C09B29/06C09B29/00
    • C09B43/405C09B29/0813C09B31/043C09B43/40C09B43/42
    • Water-insoluble azo dyestuffs suitable for dyeing and printing synthetic hydrophobic fiber materials are produced by azo coupling and have the formula ##STR1## wherein D is free from ionic moieties and is an unsubstituted or substituted phenyl, thiazole, isothiazole, benzthiazole, thiadiazole, benzisothiazole or thiophene moiety;A is alkylene having 2 to 6 carbon atoms which is unsubstituted or substituted by --OH;B is hydrogen, alkyl having 1 to 4 carbon atoms, hydroxyalkyl having 2 to 4 carbon atoms, alkoxyalkyl having 1 to 4 carbon atoms in the alkoxy moiety and a total of 3 to 8 carbon atoms, alkanoyloxyalkyl having 2 to 6 carbon atoms in the alkanoyl moiety and a total of 3 to 8 carbon atoms, hydroxypolyoxyalkylene having 4 to 12 carbon atoms, alkoxypolyoxyalkylene having 1 to 4 carbon atoms in the alkoxy moiety and a total of 5 to 16 carbon atoms, alkanoyloxypolyoxyalkylene having 2 to 5 carbon atoms in the alkanoyl moiety and a total of 5 to 16 carbon atoms, alkanoyl having 2 to 6 carbon atoms or benzoyl;R.sup.1 is hydrogen, methyl or chlorine;R.sup.2 is hydrogen, halogen, alkyl having 1 to 4 carbon atoms or alkoxy having 1 to 4 carbon atoms;and R.sup.3 is hydrogen or alkoxy having 1 to 8 carbon atoms.
    • 适用于染色和印刷合成疏水性纤维材料的水不溶性偶氮染料是通过偶氮偶合产生的,并具有式“IMAGE”,其中D不含离子部分,是未取代或取代的苯基,噻唑,异噻唑,苯并噻唑,噻二唑,苯并异噻唑 或噻吩部分; A是未被取代或被-OH取代的具有2至6个碳原子的亚烷基; B是氢,具有1至4个碳原子的烷基,具有2至4个碳原子的羟基烷基,烷氧基部分中具有1至4个碳原子的烷氧基烷基和总共3至8个碳原子,在该化合物中具有2至6个碳原子的烷酰氧基烷基 烷酰基部分和总共3至8个碳原子,具有4至12个碳原子的羟基聚氧化烯,烷氧基部分中具有1至4个碳原子的烷氧基聚氧化烯和总共5至16个碳原子,在2至5个碳原子上具有2至5个碳原子的烷酰氧基聚氧化烯 烷酰基部分和总共5至16个碳原子,具有2至6个碳原子的烷酰基或苯甲酰基; R1是氢,甲基或氯; R2是氢,卤素,具有1至4个碳原子的烷基或具有1至4个碳原子的烷氧基; 并且R 3是氢或具有1至8个碳原子的烷氧基。
    • 10. 发明授权
    • Process for the manufacture of aromatic sulphonic acid esters of
aromatic amino-hydroxy compounds
    • 芳香族氨基 - 羟基化合物的芳香族磺​​酸酯的制造方法
    • US4158670A
    • 1979-06-19
    • US879852
    • 1978-02-22
    • Rolf MullerJoachim RibkaHorst Tappe
    • Rolf MullerJoachim RibkaHorst Tappe
    • C07B61/00B01J31/00B01J31/02C07C20060101C07C67/00C07C301/00C07C303/28C07C309/63C07C309/72C07C143/68
    • C07C303/28
    • A process for the manufacture of esters of aromatic sulphonic acids and aromatic aminohydroxy compounds, of the formula Ih.sub.2 n--a--o--so.sub.2 --b (i)comprising reacting an aromatic aminohydroxy compound of the formula IIh.sub.2 n--a--oh (ii)having a pK.sub.a value of from 8.5 to 10.1, with a sulphochloride of the formula IIIcl--SO.sub.2 --B (III)whereinA is phenylene, substituted phenylene, naphthylene or substituted naphthylene,B is phenyl, substituted phenyl, naphthyl or substituted naphthyl, and both A and B are free from --COOH and --SO.sub.3 H substituents;The reaction taking place in a reaction medium consisting essentially of water and a water-immiscible organic solvent for the sulphochloride,At a temperature of from 0.degree. to 95.degree. C., at a pH which is determined from and associated with the pK.sub.a value of said aromatic aminohydroxy compound of formula II by the equationpK.sub.a -pH=0.5 to -1.5, and in the presence of a phase transfer catalyst.
    • 制备式I H 2 N-AO-SO 2 -B(I)的芳族磺酸和芳族氨基羟基化合物的酯的方法,包括使具有式II的芳族氨基羟基化合物H 2 N-A-OH(II) 其中A为亚苯基,取代亚苯基,亚萘基或取代亚萘基,B为苯基,取代的苯基,萘基或取代的萘基,并且两者均为 A和B不含-COOH和-SO 3 H取代基; 在pH为0〜95℃的温度下,在由碱性水溶液组成的反应介质中进行反应和在硫酸盐的水不溶性有机溶剂中反应,其pH值由pKa值 所述式II的芳族氨基羟基化合物通过PKa-pH = 0.5至-1。