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1. 发明授权

US5445871A Surface-modified plastic plate 失效
标题翻译：表面改性塑料板
公开(公告)号：US5445871A
公开(公告)日：1995-08-29
申请号：US279066
申请日：1994-07-22
申请人： Heihachi Murase , Tsutomu Norimatsu , Masao Ogawa , Naoya Haruta
发明人： Heihachi Murase , Tsutomu Norimatsu , Masao Ogawa , Naoya Haruta
IPC分类号： C08J7/04 , B32B7/02
CPC分类号： C08J7/045 , C08J7/047 , C08J2483/00 , Y10T428/2495 , Y10T428/24967 , Y10T428/265 , Y10T428/31504 , Y10T428/31507 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： A surface-modified plastic plate for use in optical disc bases, windows of aircrafts, automobiles or of architectural structures, solar cell receptors, liquid crystal display panels and protective sheet of computer touch panels, which comprises a laminate consisting of a plastic substrate; a cured film of an actinic ray-curable primer composition, said cured film formed onto a surface of the plastic substrate in a film thickness of 0.1 to 10 .mu.m; and an inorganic material layer formed onto the cured film by a physical deposition process and having a thickness of 0.1 .mu.m or more but less than 1.0 .mu.m; and a surface-modified plastic plate for use in windows, preferably windows of aircrafts, automobiles and architectural structures, which comprises a laminate consisting of a plastic plate, preferably comprising a plastic selected from polymethyl methacrylate polymer and polycarbonate in the case of the window of the aircraft; a cured film of a heat-curable primer composition, said cured film being formed on a surface of the plastic plate in a film thickness of 0.1 to 10 .mu.m; and an inorganic material layer formed onto the cured film by a physical deposition process and having a thickness of 0.25 .mu.m or more but less than 1.0 .mu.m.
摘要翻译：用于光盘基座，飞机窗口，汽车或建筑结构的表面改性塑料板，太阳能电池接收器，液晶显示面板和计算机触摸面板的保护片，其包括由塑料基板组成的层压板; 光固化性底漆组合物的固化膜，所述固化膜形成在塑料基板的表面上，膜厚为0.1〜10μm; 以及通过物理沉积工艺形成在固化膜上并具有0.1μm以上且小于1.0μm的厚度的无机材料层; 以及用于窗户，优选飞机，汽车和建筑结构的窗户的表面改性塑料板，其包括由塑料板组成的层压板，该塑料板优选地包括选自聚甲基丙烯酸甲酯聚合物和聚碳酸酯的塑料，在窗口飞机; 热固性底漆组合物的固化膜，所述固化膜形成在所述塑料板的表面上，膜厚度为0.1-10μm; 以及通过物理沉积工艺在固化膜上形成的厚度为0.25μm以上且小于1.0μm的无机材料层。

2. 发明授权

US06444317B1 Decorative film for use in plastics molding, process for preparing the same and injection-molded part by use of the same 失效
标题翻译：用于塑料成型的装饰膜，其制备方法和使用它的注射成型部件
公开(公告)号：US06444317B1
公开(公告)日：2002-09-03
申请号：US09369201
申请日：1999-08-06
申请人： Naoya Haruta , Tadahiro Kato , Takesi Tomiyama , Koichi Seike
发明人： Naoya Haruta , Tadahiro Kato , Takesi Tomiyama , Koichi Seike
IPC分类号： B32B2740
CPC分类号： B32B27/32 , B29C45/14811 , B32B27/08 , B32B27/20 , B32B27/308 , B32B2451/00 , B32B2605/08 , C08J7/047 , C08J2323/02 , C08J2475/00 , Y10T428/31 , Y10T428/3154 , Y10T428/31551 , Y10T428/31587 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935
摘要： A decorative film for use in plastics molding, the decorative film being a laminate film prepared by outwardly and successively laminating a polyolefin film layer, a primer layer, optionally a topcoating layer and a releasable layer, the primer layer being a coating film formed from an isocyanate-curing type resin composition containing (A) a hydroxyl group-containing resin having a hydroxyl number of 30 to 200 KOH mg/g on an average and a weight average molecular weight of 1000 to 80000, (B) a polyolefin based resin and (C) a (blocked) polyisocyanate compound in such mixing amounts that a number of the isocyanate group in the component (C) is in the range of 0.1 to 0.9 per one hydroxyl group in the component (A) and that the component (B) is in the range of 1 to 90% by weight based on a total weight of the components (A), (B) and (C), and having a static glass transition temperature of 20 to 70° C., an elongation of 10% or more and a tensile strength of 0.5 kgf/mm2 or more; a process for preparing the decorative film and an injection-molded part by use of the decorative film.
摘要翻译：一种用于塑料成型的装饰膜，该装饰膜是通过向外且相继层压聚烯烃膜层，底漆层，任选的表面涂层和可剥离层制备的层压膜，底漆层是由异氰酸酯固化型树脂组合物，其含有（A）羟值为30〜200KOHmg / g的含羟基的树脂，平均重均分子量为1000〜80000，（B）聚烯烃类树脂和（C）以这样的混合量的（封闭的）多异氰酸酯化合物，即组分（C）中的多个异氰酸酯基团在组分（A）中每一个羟基为0.1至0.9，组分（B ）在组分（A），（B）和（C）的总重量的1至90重量％的范围内，并且具有20至70℃的静态玻璃化转变温度， 10％以上，拉伸强度为0.5kgf / mm2以上; 通过使用装饰膜制备装饰膜和注射成型部件的方法。

3. 发明申请

US20070023736A1 Cationic electrodeposition coating compositions 有权
标题翻译：阳离子电沉积涂料组合物
公开(公告)号：US20070023736A1
公开(公告)日：2007-02-01
申请号：US11485476
申请日：2006-07-13
申请人： Masaaki Shinohara , Toshiharu Soga , Naoya Haruta
发明人： Masaaki Shinohara , Toshiharu Soga , Naoya Haruta
IPC分类号： H01B1/12
CPC分类号： H01B1/122 , H01B1/22 , H01B1/24 , H01M8/0206 , H01M8/0213 , H01M8/0226 , H01M8/0228
摘要： This invention provides a cationic electrodeposition coating composition which exhibits high paint stability, forms coating film excelling in conductivity, intimate adhesion, corrosion resistance, finished appearance and acid resistance, and is capable of forming uniform electrocoated film also on substrates having uneven surfaces, characterized by comprising a conductive filler dispersion paste, base resin and a curing agent, said paste being formed by dispersing a conductive filler (A) composed of high conductive carbon black (a1) and at least one conductive powder (a2) selected from furnace black, graphite and conductive whisker, using a pigment-dispersing resin (B), the composition (i) containing 30-100 wt parts of a conductive filler (A) which contains at least 2 wt parts of high conductive carbon black (a1), per 100 wt parts of combined solid content of the base resin and the curing agent, (ii) the weight ratio of the conductive powder (a2)/high conductive carbon black (a1) being within a range of 0.4-20, and (iii) the pigment-dispersing resin (B) being acrylic resin-derived pigment-dispersing resin formed by copolymerization of (meth)acrylic monomer (b1) which is modified with mono- or poly-alkylene glycol or a monoether derivative thereof; nitrogen-containing, radical-polymerizable unsaturated monomer (b2) and other radical-polymerizable unsaturated monomer (b3).
摘要翻译：本发明提供了一种阳离子电沉积涂料组合物，其表现出高的涂料稳定性，形成了导电性优良，粘附力强，耐腐蚀性，成品外观和耐酸性优异的涂膜，并且还能够在具有不均匀表面的基材上形成均匀的电涂膜，包括导电填料分散浆料，基础树脂和固化剂，所述糊料通过将由高导电性炭黑（a 1 SUB）构成的导电填料（A）和至少一种导电粉末（使用颜料分散树脂（B）从炉黑，石墨和导电晶须中选出的一种二级元素，组合物（i）含有30-100重量份的导电填料（A），其含有每100重量份基础树脂和固化剂的组合固体含量至少2重量份的高导电性炭黑（α1 H 2），（ii）导电粉末（一个<2> ）/高导电性炭黑（a <1 _{）在0.4〜20的范围内，和（iii）所述颜料分散树脂（B）为丙烯酸树脂衍生的颜料分散树脂通过用单 - 或聚 - 亚烷基二醇或其单醚衍生物改性的（甲基）丙烯酸单体（b 1 SUB）共聚合; 含氮的可自由基聚合的不饱和单体（b 2 2）和其他可自由基聚合的不饱和单体（b 3/3）。}

4. 发明授权

US06932882B2 Coated film and method of laminating the same 失效
标题翻译：涂膜及其层压方法
公开(公告)号：US06932882B2
公开(公告)日：2005-08-23
申请号：US10311334
申请日：2001-07-11
申请人： Naoya Haruta , Takeshi Tomiyama , Toshio Kondo , Yu Akaki , Osamu Isozaki
发明人： Naoya Haruta , Takeshi Tomiyama , Toshio Kondo , Yu Akaki , Osamu Isozaki
IPC分类号： B32B27/08 , C08J5/12 , C08J7/04 , C09D163/10 , C09D175/04 , C09D175/16 , C09J5/00
CPC分类号： B32B27/08 , B32B27/40 , B32B2305/72 , C08J5/124 , C08J7/042 , C08J2323/12 , C08J2475/00 , C09D163/10 , C09D175/04 , C09D175/16 , Y10T428/31551 , Y10T428/31554 , Y10T428/31558 , Y10T428/31562 , Y10T428/31565 , Y10T428/31569
摘要： A multi-layer application film formed by laminating at least two resin films, a top layer film (I) being formed from a crosslinkable resin coating composition (A), an under layer film (II) being formed from a thermoplastic resin (B), showing practically no stickiness per se, and having a tensile elongation at breakage in the range of 50 to 1000%, said multi-layer application film being applied onto a plastic substrate.
摘要翻译：通过层压至少两种树脂膜形成的多层施加膜，由可交联树脂涂料组合物（A）形成的顶层膜（I），由热塑性树脂（B）形成的下层膜（II），本身几乎没有粘性，断裂拉伸伸长率在50〜1000％的范围内，所述多层涂布膜被涂布在塑料基板上。

5. 发明授权

US07947764B2 Cationic electrodeposition coating compositions 有权
标题翻译：阳离子电沉积涂料组合物
公开(公告)号：US07947764B2
公开(公告)日：2011-05-24
申请号：US11485476
申请日：2006-07-13
申请人： Masaaki Shinohara , Toshiharu Soga , Naoya Haruta
发明人： Masaaki Shinohara , Toshiharu Soga , Naoya Haruta
IPC分类号： C04B9/02
CPC分类号： H01B1/122 , H01B1/22 , H01B1/24 , H01M8/0206 , H01M8/0213 , H01M8/0226 , H01M8/0228
摘要： This invention provides a cationic electrodeposition coating composition which exhibits high paint stability, forms coating film excelling in conductivity, intimate adhesion, corrosion resistance, finished appearance and acid resistance, and is capable of forming uniform electrocoated film also on substrates having uneven surfaces, characterized by comprising a conductive filler dispersion paste, base resin and a curing agent, said paste being formed by dispersing a conductive filler (A) composed of high conductive carbon black (a1) and at least one conductive powder (a2) selected from furnace black, graphite and conductive whisker, using a pigment-dispersing resin (B), the composition (i) containing 30-100 wt parts of a conductive filler (A) which contains at least 2 wt parts of high conductive carbon black (a1), per 100 wt parts of combined solid content of the base resin and the curing agent, (ii) the weight ratio of the conductive powder (a2)/high conductive carbon black (a1) being within a range of 0.4-20, and (iii) the pigment-dispersing resin (B) being acrylic resin-derived pigment-dispersing resin formed by copolymerization of (meth)acrylic monomer (b1) which is modified with mono- or poly-alkylene glycol or a monoether derivative thereof; nitrogen-containing, radical-polymerizable unsaturated monomer (b2) and other radical-polymerizable unsaturated monomer (b3).
摘要翻译：本发明提供了一种阳离子电沉积涂料组合物，其表现出高的涂料稳定性，形成了导电性优良，粘附力强，耐腐蚀性，成品外观和耐酸性优异的涂膜，并且还能够在具有不均匀表面的基材上形成均匀的电涂膜，包括导电填料分散浆料，基础树脂和固化剂，所述糊料通过将由高导电性炭黑（a1）组成的导电填料（A）和至少一种选自炉黑的导电粉末（a2），石墨和导电晶须，使用颜料分散树脂（B），组合物（i）含有30-100重量份含有至少2重量份高导电性炭黑（a1）的导电填料（A），每100重量份基础树脂和固化剂的固体成分的重量份，（ii）导电性粉末（a2）/高导电性炭黑（a1）的重量比为（ⅲ）颜料分散树脂（B）是由（甲基）丙烯酸单体（b1）与单 - 或多 - 甲基丙烯酸改性共聚形成的丙烯酸树脂衍生的颜料分散树脂，亚烷基二醇或其单醚衍生物; 含氮自由基聚合性不饱和单体（b2）等自由基聚合性不饱和单体（b3）。

6. 发明申请

US20110135936A1 WATER-BASED PRIMER COMPOSITION AND COATING METHOD USING THE SAME 审中-公开
标题翻译：使用其的水基原料组合物和涂布方法
公开(公告)号：US20110135936A1
公开(公告)日：2011-06-09
申请号：US13057196
申请日：2009-08-06
申请人： Hideaki Katsuta , Masaharu Ishiguro , Naoya Haruta , Takeshi Kishi , Hisakazu Kotake , Yoshizumi Matsuno
发明人： Hideaki Katsuta , Masaharu Ishiguro , Naoya Haruta , Takeshi Kishi , Hisakazu Kotake , Yoshizumi Matsuno
IPC分类号： H01B1/24 , B32B27/40 , B05D1/36
CPC分类号： C09D123/02 , B05D7/02 , B05D7/57 , C08F220/06 , C08F220/18 , C08F220/26 , C08F2220/1825 , C08F2220/286 , C08F2220/287 , C08L23/12 , C08L23/26 , C08L33/066 , C08L75/04 , C08L2201/50 , C09D5/002 , C09D5/028 , C09D5/24 , C09D133/066 , C09D133/08 , C09D151/06 , C09D175/04 , Y10T428/31551 , C08L2666/02 , C08L2666/04
摘要： This invention provides a water-based primer composition comprising an aqueous dispersion of modified polyolefin, aqueous urethane resin and/or aqueous acrylic resin, specific diester compound and electrically conducting pigment, the content of the diester compound being specific. The water-based primer composition excels in adhesive property to plastic substrates, and use of the water-based primer composition enables formation of multilayered coating film excelling in finished appearance and water resistance, being free of layer mixing even when the top coating of the next step is carried out after the primer's application without an intervening preheating.
摘要翻译：本发明提供一种水性底漆组合物，其包含改性聚烯烃的水分散体，水性聚氨酯树脂和/或水性丙烯酸树脂，特定二酯化合物和导电颜料，二酯化合物的含量是特定的。水性底漆组合物对于塑料基材的粘合性优异，并且使用水性底漆组合物能够形成成品外观和耐水性优异的多层涂膜，即使在下一层的顶涂层在引物施用后进行步骤，而不进行中间预热。

7. 发明申请

US20090061247A1 AQUEOUS RESIN COMPOSITION, AQUEOUS COATING COMPOSITION AND COATING METHOD FOR PLASTIC MOLDED ARTICLES 审中-公开
标题翻译：水性树脂组合物，塑料成型品的水性涂料组合物和涂料方法
公开(公告)号：US20090061247A1
公开(公告)日：2009-03-05
申请号：US12195245
申请日：2008-08-20
申请人： Yoshiaki Chino , Hideaki Katsuta , Hiromi Harakawa , Kazuo Soga , Kouichi Hirayama , Naoya Haruta
发明人： Yoshiaki Chino , Hideaki Katsuta , Hiromi Harakawa , Kazuo Soga , Kouichi Hirayama , Naoya Haruta
IPC分类号： B32B27/32 , C08F2/00
CPC分类号： C08L51/06 , C08F255/00 , C08F255/02 , C08F285/00 , C09D151/06 , Y10T428/31855 , C08L2666/02
摘要： An aqueous resin composition obtained by emulsion polymerization using a polymerizable unsaturated monomer (b) in the presence of an aqueous resin dispersion (A) comprising an acid-modified polyolefin (a), an ether-based solvent and a basic substance. Also, an aqueous coating composition comprising an aqueous resin dispersion (B) obtained by emulsion polymerization of a polymerizable unsaturated monomer (b) in the presence of an aqueous resin dispersion (A) containing an acid-modified polyolefin (a), an ether-based solvent and a basic substance, with resin beads (C), wherein the content of resin beads (C) is 1-30 parts by mass with respect to 100 parts by mass of the total resin solid content of the coating material. The composition has excellent adhesion for plastic bases and allows formation of coated films with excellent water resistance, stain resistance, damage resistance and solvent resistance.
摘要翻译：在含有酸改性聚烯烃（a），醚系溶剂和碱性物质的水性树脂分散体（A）的存在下，使用聚合性不饱和单体（b）进行乳液聚合得到的水性树脂组合物。另外，在含有酸改性聚烯烃（a）的含水树脂分散液（A）和乙酸乙烯酯系聚合物（A）的存在下，通过聚合性不饱和单体（b）的乳液聚合得到的水性树脂分散体（B）（C），其中树脂珠（C）的含量相对于涂料的总树脂固体含量为100质量份为1-30质量份。该组合物对塑料基材具有优异的粘合性，并且可以形成具有优异的耐水性，耐污性，耐破坏性和耐溶剂性的涂膜。

8. 发明授权

US06660337B2 Decorative film for use in plastics molding, process for preparing the same and injection-molded part by use of the same 失效
标题翻译：用于塑料成型的装饰膜，其制备方法和使用它的注射成型部件
公开(公告)号：US06660337B2
公开(公告)日：2003-12-09
申请号：US10145148
申请日：2002-05-15
申请人： Naoya Haruta , Tadahiro Kato , Takesi Tomiyama , Koichi Seike
发明人： Naoya Haruta , Tadahiro Kato , Takesi Tomiyama , Koichi Seike
IPC分类号： B05D302
CPC分类号： B32B27/32 , B29C45/14811 , B32B27/08 , B32B27/20 , B32B27/308 , B32B2451/00 , B32B2605/08 , C08J7/047 , C08J2323/02 , C08J2475/00 , Y10T428/31 , Y10T428/3154 , Y10T428/31551 , Y10T428/31587 , Y10T428/31855 , Y10T428/31909 , Y10T428/31913 , Y10T428/31928 , Y10T428/31935
摘要： A decorative film for use in plastics molding, said decorative film being a laminate film prepared by outwardly and successively laminating a polyolefin film layer, a primer layer, optionally a topcoating layer and a releasable layer, said primer layer being a coating film formed from an isocyanate-curing type resin composition containing (A) a hydroxyl group-containing resin having a hydroxyl number of 30 to 200 KOH mg/g on an average and a weight average molecular weight of 1000 to 80000, (B) a polyolefin based resin and (C) a (blocked)polyisocyanate compound in such mixing amounts that a number of the isocyanate group in the component (C) is in the range of 0.1 to 0.9 per one hydroxyl group in the component (A) and that the component (B) is in the range of 1 to 90% by weight based on a total weight of the components (A), (B) and (C), and having a static glass transition temperature of 20 to 70° C., an elongation of 10% or more and a tensile strength of 0.5 kgf/mm2 or more; a process for preparing the decorative film and an injection-molded part by use of the decorative film.
摘要翻译：一种用于塑料成型的装饰膜，所述装饰膜是通过向外且相继层压聚烯烃膜层，底漆层，任选的表面涂层和可剥离层制备的层压膜，所述底漆层是由异氰酸酯固化型树脂组合物，其含有（A）羟值为30〜200KOHmg / g的含羟基的树脂，平均重均分子量为1000〜80000，（B）聚烯烃类树脂和（C）以这样的混合量的（封闭的）多异氰酸酯化合物，即组分（C）中的多个异氰酸酯基团在组分（A）中每一个羟基为0.1至0.9，组分（B ）在组分（A），（B）和（C）的总重量的1至90重量％的范围内，并且具有20至70℃的静态玻璃化转变温度， 10％以上，拉伸强度为0.5kgf / mm 2以上; 通过使用装饰膜制备装饰膜和注射成型部件的方法。

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