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    • 4. 发明授权
    • Benzo-1,2,3-thiadiazole derivatives
    • 苯并-1,2,3-噻二唑衍生物
    • US5248683A
    • 1993-09-28
    • US893292
    • 1992-06-04
    • Hans-Georg BrunnerWalter KunzRolf Schurter
    • Hans-Georg BrunnerWalter KunzRolf Schurter
    • A01N43/82A01N43/828C07D285/14C07D405/06C07D409/06C07D417/06
    • C07D285/14A01N43/82C07D405/06C07D409/06C07D417/06
    • Compounds of the formula ##STR1## in which A.sub.1 and A.sub.2 independently of one another are CO--C.sub.1 -C.sub.4 alkyl, COO--C.sub.1 -C.sub.4 alkyl, CO--CF.sub.3, CO--N(R).sub.2 or cyano;A.sub.1 and A.sub.2 together are CO(X).sub.n --C.sub.1 -C.sub.3 alkylene-(X).sub.n CO, CO(X).sub.n --C.sub.1 -C.sub.3 alkylene-(X).sub.n CO which is substituted by C.sub.1 -C.sub.4 alkyl, COOR, CON(R).sub.2, cyano or phenyl, it being possible for the phenyl ring, in turn, to be substituted by halogen, methyl, trifluoromethyl, methoxy, nitro or cyano; CO--N(R)--CO--N(R)--CO;R is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 alkenyl or C.sub.3 -C.sub.6 alkynyl;X is oxygen, sulfur or N(CH.sub.3);X.sub.1, X.sub.2 and X.sub.3 independently of one another are hydrogen, halogen, methyl, methylthio, methoxy or nitro;n is 0 or 1;including the salts of the compounds of the formula I with agriculturally acceptable organic or inorganic bases, and including the metal complexes; have valuable microbicidal properties.The novel compounds can be used in crop protection for preventing the attack of crop plants by phytopathogenic microorganisms and for the control of these pests.
    • 其中A 1和A 2彼此独立的式“IMAGE”的化合物是CO-C 1 -C 4烷基,COO-C 1 -C 4烷基,CO-CF 3,CO-N(R)2或氰基; A1和A2一起是被C1-C4烷基,COOR,CON(R)2取代的CO(X)n-C1-C3亚烷基 - (X)nCO,CO(X)n-C1-C3亚烷基 - (X) 氰基或苯基,苯环可以被卤素,甲基,三氟甲基,甲氧基,硝基或氰基取代; CO-N(R)-CO-N(R)-CO; R是氢,C 1 -C 6烷基,C 3 -C 6烯基或C 3 -C 6炔基; X是氧,硫或N(CH 3); X1,X2和X3彼此独立地是氢,卤素,甲基,甲硫基,甲氧基或硝基; n为0或1; 包括式I化合物与农业上可接受的有机或无机碱的盐,并包括金属络合物; 具有有价值的杀菌特性。 新型化合物可用于作物保护,以防止植物病原微生物侵袭作物和控制这些害虫。
    • 7. 发明授权
    • Heterocyclically fused pyridine compounds as herbicides
    • 杂环稠合吡啶化合物作为除草剂
    • US4743296A
    • 1988-05-10
    • US936214
    • 1986-12-01
    • Dieter DurrHans-Georg BrunnerHenry Szczepanski
    • Dieter DurrHans-Georg BrunnerHenry Szczepanski
    • A01N43/90C07D471/14A01N43/40A01N43/42
    • C07D471/14A01N43/90
    • This is a continuation in part application derived from our copending application Ser. No. 837,977 (filing date Mar. 10, 1986). This continuation in part is directed to novel pyridine compounds of formula I below have good selective herbicidal properties pre- and postemergence and also influence or inhibit plant growth. The compounds are of formula I ##STR1## wherein each of X, Y and Z independently of one another is hydrogen or a C.sub.1 -C.sub.4 alkyl group, or two adjacent substituents together also form a saturated or unsaturated 3- or 4-membered alkylene chain or alkenyl chain, each of which chains may in turn by substituted by one to four C.sub.1 -C.sub.4 alkyl groups, R is a C.sub.1 -C.sub.4 nitroalkyl group, a substituted C.sub.1 -C.sub.4 alkylthio group or C.sub.1 -C.sub.4 alkoxy group, an unsubstituted or substituted C.sub.3 -C.sub.4 alkenylthio or C.sub.3 -C.sub.4 alkynylthio group, the hydroxyamino group, a C.sub.1 -C.sub.4 alkoxyamino, C.sub.3 -C.sub.4 alkenyloxyamino or C.sub.3 -C.sub.4 alkynyloxyamino group, a --PO(C.sub.1 -C.sub.4 alkyl).sub.2 or --PO(CH.sub.3)OC.sub.1 -C.sub.4 -alkyl radical or an unsubstituted or substituted hydrazino radical.
    • 这是来自我们的共同未决申请Ser的部分申请的延续。 837,977号(1986年3月10日提交)。 这一延续部分涉及式I的新型吡啶化合物具有良好的选择性除草性能和芽后效应,并且还影响或抑制植物生长。 所述化合物具有式I(I)其中X,Y和Z各自独立地为氢或C 1 -C 4烷基,或两个相邻的取代基一起也形成饱和或不饱和的3-或4-元 亚烷基链或烯基链,其中每个链依次可被一至四个C 1 -C 4烷基取代,R是C 1 -C 4硝基烷基,取代的C 1 -C 4烷硫基或C 1 -C 4烷氧基,未取代或取代的C 3 -C 4烷氧基, C 4链烯基硫基或C 3 -C 4炔硫基,羟基氨基,C 1 -C 4烷氧基氨基,C 3 -C 4链烯氧基氨基或C 3 -C 4炔氧基氨基,-PO(C 1 -C 4烷基)2或-PO(CH 3)OC 1 -C 4烷基或未取代或未取代的 取代的肼基。
    • 10. 发明授权
    • Herbicidally, acaricidally and insecticidally active pyrazolidine
compounds
    • 除草剂,杀螨剂和杀虫活性吡唑烷化合物
    • US5506193A
    • 1996-04-09
    • US119103
    • 1993-09-17
    • Frederik CederbaumHans-Georg BrunnerManfred Boger
    • Frederik CederbaumHans-Georg BrunnerManfred Boger
    • A01N43/56A01N43/90C07C251/76C07C251/78C07C255/65C07C271/62C07C281/02C07C281/04C07C317/44C07C323/62C07D231/08C07D231/32C07D231/34C07D231/36C07D237/04C07D401/04C07D401/12C07D487/04
    • C07D401/12A01N43/56A01N43/90C07C251/76C07C251/78C07C281/02C07C281/04C07D231/32C07D237/04C07D487/04
    • The present invention relates to herbicidally, acaricidally and insecticidally active pyrazolidine-3,5-diones of the formula I ##STR1## in which R.sub.1 is ##STR2## R.sub.2 and R.sub.3 independently of one another are C.sub.1 -C.sub.6 alkyl; C.sub.3 -C.sub.6 alkenyl; or C.sub.3 -C.sub.6 alkynyl; orR.sub.2 and R.sub.3 together are a --(CH.sub.2).sub.3 --, --(CH.sub.2).sub.4 --, --CH.sub.2 --CH.dbd.CH--CH.sub.2 --, --CH.sub.2 --CH.dbd.CH-- or --(CH.sub.2).sub.2 --CH.dbd.CH-- bridge which is unsubstituted or up to trisubstituted by C.sub.1 -C.sub.4 alkyl;n is 0; 1; 2; 3; or 4;m is 0; or 1; the total of m and n being less than, or equal to, 4; theR.sub.4 radicals independently of one another are halogen; nitro; cyano, C.sub.1 -C.sub.4 alkyl; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.10 alkoxy; C.sub.1 -C.sub.4 haloalkoxy; C.sub.3 -C.sub.6 alkenyloxy; C.sub.1 -C.sub.4 alkoxy-C.sub.2 -.sub.4 alkoxy; C.sub.3 -C.sub.6 alkynyloxy; C.sub.1 -C.sub.4 alkylcarbonyl; C.sub.1 -C.sub.4 alkoxycarbonyl; C.sub.1 -C.sub.4 alkylthio; C.sub.1 -C.sub.4 alkylsulfinyl; C.sub.1 -C.sub.4 alkylsulfonyl; amino; mono-C.sub.1 -C.sub.4 alkylamino; di-C.sub.1 -C.sub.4 alkylamino;R.sub.5 is ##STR3## X is oxygen; sulfur; CH.sub.2 ; or NR.sub.7 ; o is 0; 1; 2; or 3;R.sub.6 radicals independently of one another are C.sub.1 -C.sub.4 alkyl; halogen; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.4 haloalkoxy; C.sub.1 -C.sub.4 alkoxy; nitro; cyano; C.sub.1 -C.sub.4 alkoxycarbonyl; amino; mono-C.sub.1 -C.sub.4 alkylamino; or di-C.sub.1 -C.sub.4 alkylamino; andR.sub.7 is hydrogen; C.sub.1 -C.sub.4 alkyl; formyl; or C.sub.1 -C.sub.4 alkylcarbonyl;the acid addition salts thereof, as well as processes for their preparation, and novel intermediates for these processes. The invention furthermore relates to herbicidally, acaricidally or insecticidally active compositions as well as to methods for controlling weeds, Acarina or insects.
    • PCT No.PCT / EP92 / 00452 Sec。 371日期:1993年9月17日 102(e)日期1993年9月17日PCT提交1992年3月2日PCT公布。 出版物WO92 / 本发明涉及除草,杀螨剂和杀虫活性的式I(I)的吡唑烷-3,5-二酮,其中R 1和R 3独立地为 彼此是C1-C6烷基; C 3 -C 6烯基; 或C 3 -C 6炔基; 或者R 2和R 3一起是 - (CH 2)3 - , - (CH 2)4 - , - CH 2 -CH = CH-CH 2 - , - CH 2 -CH = CH-或 - (CH 2)2 -CH = 其是未取代的或被C1-C4烷基三取代; n为0; 1; 2; 3; 或4; m为0; 或1; m和n的总和小于或等于4; R4基彼此独立地是卤素; 硝基 氰基,C 1 -C 4烷基; C 1 -C 4卤代烷基; C1-C10烷氧基; C1-C4卤代烷氧基; C3-C6链烯氧基; C1-C4烷氧基-C2-4烷氧基; C3-C6炔氧基; C1-C4烷基羰基; C1-C4烷氧基羰基; C 1 -C 4烷硫基; C 1 -C 4烷基亚磺酰基; C 1 -C 4烷基磺酰基; 氨基; 单C 1 -C 4烷基氨基; 二-C 1 -C 4烷基氨基; R5是氧; 硫; CH2; 或NR7; o是0; 1; 2; 或3; R 6基彼此独立地是C 1 -C 4烷基; 卤素; C 1 -C 4卤代烷基; C1-C4卤代烷氧基; C1-C4烷氧基; 硝基 氰基; C1-C4烷氧基羰基; 氨基; 单C 1 -C 4烷基氨基; 或二-C 1 -C 4烷基氨基; 而R7是氢; C 1 -C 4烷基; 甲酰基 或C 1 -C 4烷基羰基; 其酸加成盐及其制备方法,以及这些方法的新型中间体。 本发明还涉及除草,杀螨剂或杀虫活性组合物以及控制杂草,螨虫或昆虫的方法。