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    • 1. 发明授权
    • Herbicidally, acaricidally and insecticidally active pyrazolidine
compounds
    • 除草剂,杀螨剂和杀虫活性吡唑烷化合物
    • US5494890A
    • 1996-02-27
    • US460486
    • 1995-06-02
    • Frederik CederbaumHans-Georg BrunnerManfred Boger
    • Frederik CederbaumHans-Georg BrunnerManfred Boger
    • A01N43/56A01N43/90C07C251/76C07C251/78C07C255/65C07C271/62C07C281/02C07C281/04C07C317/44C07C323/62C07D231/08C07D231/32C07D231/34C07D231/36C07D237/04C07D401/04C07D401/12C07D487/04
    • C07D401/12A01N43/56A01N43/90C07C251/76C07C251/78C07C281/02C07C281/04C07D231/32C07D237/04C07D487/04
    • The present invention relates to herbicidally, acaricidally and insecticidally active pyrazolidine-3,5-diones of the formula I ##STR1## in which R.sub.1 is ##STR2## R.sub.2 and R.sub.3 independently of one another are C.sub.1 -C.sub.6 alkyl; C.sub.3 -C.sub.6 alkenyl; or C.sub.3 -C.sub.6 alkynyl; orR.sub.2 and R.sub.3 together are a --(CH.sub.2).sub.3 --, --(CH.sub.2).sub.4 --, --CH.sub.2 --CH.dbd.CH--CH.sub.2 --, --CH.sub.2 --CH.dbd.CH-- or --(CH.sub.2).sub.2 --CH.dbd.CH-- bridge which is unsubstituted or up to trisubstituted by C.sub.1 -C.sub.4 alkyl;n is 0; 1; 2; 3; or 4;m is 0; or 1; the total of m and n being less than, or equal to, 4; theR.sub.4 radicals independently of one another are halogen; nitro; cyano, C.sub.1 -C.sub.4 alkyl; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.10 alkoxy; C.sub.1 -C.sub.4 haloalkoxy; C.sub.3 -C.sub.6 alkenyloxy; C.sub.1 -C.sub.4 alkoxy-C.sub.2 -C.sub.4 alkoxy; C.sub.3 -C.sub.6 alkynyloxy; C.sub.1 -C.sub.4 alkylcarbonyl; C.sub.1 -C.sub.4 alkoxycarbonyl; C.sub.1 -C.sub.4 alkylthio; C.sub.1 -C.sub.4 alkylsulfinyl; C.sub.1 -C.sub.4 alkylsulfonyl; amino; mono-C.sub.1 -C.sub.4 alkylamino; di-C.sub.1 -C.sub.4 alkylamino;R.sub.5 is ##STR3## X is oxygen; sulfur; CH.sub.2 ; or NR.sub.7 ; o is 0; 1; 2; or 3;R.sub.6 radicals independently of one another are C.sub.1 -C.sub.4 alkyl; halogen; C.sub.1 -C.sub.4 haloalkyl; C.sub.1 -C.sub.4 haloalkoxy; C.sub.1 -C.sub.4 alkoxy; nitro; cyano; C.sub.1 -C.sub.4 alkoxycarbonyl; amino; mono-C.sub.1 -C.sub.4 alkylamino; or di-C.sub.1 -C.sub.4 alkylamino; andR.sub.7 is hydrogen; C.sub.1 -C.sub.4 alkyl; formyl; or C.sub.1 -C.sub.4 alkylcarbonyl;the acid addition salts thereof, herbicidally, acaricidally or insecticidally active compositions as well as to methods for controlling weeds, Acarina or insects.
    • 本发明涉及除草,杀螨和杀虫活性的式I(I)的吡唑烷-3,5-二酮,其中R 1和R 3彼此独立地为C 1 -C 6烷基; C 3 -C 6烯基; 或C 3 -C 6炔基; 或者R 2和R 3一起是 - (CH 2)3 - , - (CH 2)4 - , - CH 2 -CH = CH-CH 2 - , - CH 2 -CH = CH-或 - (CH 2)2 -CH = 其是未取代的或被C1-C4烷基三取代; n为0; 1; 2; 3; 或4; m为0; 或1; m和n的总和小于或等于4; R4基彼此独立地是卤素; 硝基 氰基,C 1 -C 4烷基; C 1 -C 4卤代烷基; C1-C10烷氧基; C1-C4卤代烷氧基; C3-C6链烯氧基; C1-C4烷氧基-C2-C4烷氧基; C3-C6炔氧基; C1-C4烷基羰基; C1-C4烷氧基羰基; C 1 -C 4烷硫基; C 1 -C 4烷基亚磺酰基; C 1 -C 4烷基磺酰基; 氨基; 单C 1 -C 4烷基氨基; 二-C 1 -C 4烷基氨基; R5是氧; 硫; CH2; 或NR7; o是0; 1; 2; 或3; R 6基彼此独立地是C 1 -C 4烷基; 卤素; C 1 -C 4卤代烷基; C1-C4卤代烷氧基; C1-C4烷氧基; 硝基 氰基; C1-C4烷氧基羰基; 氨基; 单C 1 -C 4烷基氨基; 或二-C 1 -C 4烷基氨基; 而R7是氢; C 1 -C 4烷基; 甲酰基 或C 1 -C 4烷基羰基; 其酸加成盐,除草剂,杀螨剂或杀虫活性组合物以及控制杂草,螨虫或昆虫的方法。
    • 5. 发明授权
    • Certain insecticidal N-2-pyridyloxyphenylbenzimidates
    • 某些杀虫剂N-2-吡啶氧基苯基亚氨酸酯
    • US4723015A
    • 1988-02-02
    • US658004
    • 1984-10-04
    • Manfred BogerJozef Drabek
    • Manfred BogerJozef Drabek
    • A01N47/34C07D213/64C07D213/643A01N43/40
    • C07D213/643A01N47/34
    • The invention relates to novel substituted N-[[[pyridyloxyphenyl]amino]carbonyl]phenylcarboximidates of the formula ##STR1## wherein R.sub.1 is hydrogen, halogen, methyl or methoxy,R.sub.2 is halogen, methyl, trifluoromethyl or methoxy,R.sub.3 is C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.3 haloalkyl containing 1 to 3 halogen atoms, allyl or propargyl,R.sub.4 and R.sub.5 are each independently of the other hydrogen, halogen, methyl or trifluoromethyl,R.sub.6 and R.sub.7 are hydrogen, andA is the ##STR2## radical, in which R.sub.8 is hydrogen, chlorine, trifluoromethyl or perhalogenated ethyl, and R.sub.9 is hydrogen, halogen, methoxy or ethoxy;to the preparation of these novel compounds and to compositions containing them for controlling insects and representatives of the order Acarina. The novel compounds are especially effective against plant-destructive insects.
    • 本发明涉及式(I)的新的取代的N - [[吡啶氧基苯基]氨基]羰基]苯基肟基,其中R 1是氢,卤素,甲基或甲氧基,R 2是卤素,甲基,三氟甲基或甲氧基,R 3是 C1-C5烷基,含1至3个卤素原子的C1-C3卤代烷基,烯丙基或炔丙基,R4和R5各自独立地为氢,卤素,甲基或三氟甲基,R6和R7为氢,A为 其中R8是氢,氯,三氟甲基或全卤代乙基,R9是氢,卤素,甲氧基或乙氧基; 这些新化合物的制备和含有它们的组合物用于控制昆虫和蜱螨目的代表。 新型化合物对植物破坏性昆虫特别有效。
    • 6. 发明授权
    • 1,3,5-Oxadiazine-2,4-diones and pesticidal use
    • 1,3,5-恶二嗪-2,4-二酮和杀虫剂使用
    • US4550108A
    • 1985-10-29
    • US639039
    • 1984-08-09
    • Manfred BogerJozef Drabek
    • Manfred BogerJozef Drabek
    • A01N43/88C07D213/64C07D213/643C07D413/12C07D413/10
    • C07D213/643A01N43/88C07D413/12
    • There are disclosed novel 1,3,5-oxadiazine-2,4-diones of the formula I ##STR1## wherein R.sub.1 is halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio,R.sub.3 and R.sub.4 are each hydrogen, halogen or C.sub.1 -C.sub.4 -alkyl,R.sub.5 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl or --COOR.sub.8,R.sub.6 is hydrogen or halogen,R.sub.7 is mono- or polyhalogenated C.sub.1 -C.sub.4 -alkyl,R.sub.8 is hydrogen or C.sub.1 -C.sub.4 -alkyl, andm is 1 or 2,the production thereof, their use for controlling pests, and pesticidal compositions containing these oxadiazines as active ingredients. The preferred field of application is the control of pests on animals and plants.
    • 公开了式I的新的1,3,5-恶二嗪-2,4-二酮,其中R 1是卤素,C 1 -C 4烷基,C 1 -C 4烷氧基或C 1 -C 4 - 烷硫基,R 2为氢,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基或C 1 -C 4 - 烷硫基,R 3和R 4各自为氢,卤素或C 1 -C 4烷基,R 5为氢, C 1 -C 4烷基或-COOR 8,R 6是氢或卤素,R 7是单或多卤代C 1 -C 4 - 烷基,R 8是氢或C 1 -C 4烷基,m是1或2,其生产, 含有这些恶二嗪作为活性成分的害虫和杀虫剂组合物。 优选的应用领域是控制动物和植物上的害虫。
    • 7. 发明授权
    • Thiourea derivatives having pesticidal activity
    • 硫脲衍生物具有杀虫活性
    • US4404225A
    • 1983-09-13
    • US270755
    • 1981-06-05
    • Manfred BogerJozef Drabek
    • Manfred BogerJozef Drabek
    • A01N47/30A01N47/32A01N47/42C07C335/18C07C157/09
    • C07C335/32A01N47/30A01N47/32A01N47/42
    • Compounds of the formula I and II ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, methoxy, halogen, trifluoromethyl or nitro, R.sub.4 is hydrogen or methyl, R.sub.5 is C.sub.1 -C.sub.3 -alkyl, R.sub.6 is C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -aklenyl, C.sub.3 -C.sub.5 -alkynyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.4 -(alkoxyalkyl) or C.sub.2 -C.sub.4 -(alkylthioalkyl), and R.sub.7 is C.sub.1 -C.sub.12 -alkyl, C.sub.3 -C.sub.5 -alkenyl or C.sub.3 -C.sub.8 -cycloalkyl, and the acid addition salts of compounds of the formulae I, are novel. The compounds of the formula II can be used as starting materials for producing compounds of the formula I. The mentioned compounds of the formulae I and II have a pesticidal action, especially an acaricidal and insecticidal action, and are particularly effective against plant pest
    • 式I和II的化合物其中R 1,R 2和R 3彼此独立地为氢,C 1 -C 4 - 烷基,甲氧基,卤素,三氟甲基或硝基,R 4为氢 或甲基,R 5是C 1 -C 3烷基,R 6是C 1 -C 6烷基,C 2 -C 6 - 烯基,C 3 -C 5炔基,C 3 -C 6环烷基,C 2 -C 4 - (烷氧基烷基)或C 2 -C 4 - ( 烷基硫代烷基),并且R 7是C 1 -C 12 - 烷基,C 3 -C 5 - 烯基或C 3 -C 8 - 环烷基,式I化合物的酸加成盐是新颖的。 式II的化合物可以用作制备式I化合物的起始原料。所述的式I和II化合物
    • 10. 发明授权
    • Pesticidal sulphenylated formamidine compounds
    • 杀虫磺化甲脒化合物
    • US4115583A
    • 1978-09-19
    • US792754
    • 1977-05-02
    • Manfred BogerJozef Drabek
    • Manfred BogerJozef Drabek
    • C07C145/04A01N9/12
    • Compounds of the formula I ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 independently of one another represent hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, trifluoromethyl, cyano or nitro,R.sub.4 represents C.sub.1 -C.sub.4 -alkyl,R.sub.5 represents an optionally halogen substituted C.sub.1 -C.sub.10 -alkyl; or C.sub.3 -C.sub.10 -cycloalkyl, C.sub.4 -C.sub.10 -(cycloalkylalkyl) or C.sub.2 -C.sub.10 -(alkoxyalkyl) andR.sub.6 represents hydrogen; optionally halogen substituted C.sub.1 -C.sub.10 -alkyl or C.sub.1 -C.sub.10 -alkoxy; or C.sub.2 -C.sub.10 -cycloalkyl, C.sub.3 -C.sub.10 -cycloalkoxy, C.sub.4 -C.sub.10 -(cycloalkylalkyl), C.sub.4 -C.sub.10 -(cycloalkylalkoxy), C.sub.2 -C.sub.10 -(alkoxyalkyl) or C.sub.2 -C.sub.10 -(alkoxyalkoxy)Are valuable pesticidal, in particular insecticidal and acaricidal, agents.
    • 式I的化合物其中R 1,R 2和R 3彼此独立地表示氢,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,三氟甲基,氰基或硝基, R 4表示C 1 -C 4烷基,R 5表示任选卤素取代的C 1 -C 10 - 烷基; 或C 3 -C 10 - 环烷基,C 4 -C 10 - (环烷基烷基)或C 2 -C 10 - (烷氧基烷基),R 6表示氢; 任选卤素取代的C 1 -C 10 - 烷基或C 1 -C 10 - 烷氧基; 或C 2 -C 10 - 环烷基,C 3 -C 10 - 环烷氧基,C 4 -C 10 - (环烷基烷基),C 4 -C 10 - (环烷基烷氧基),C 2 -C 10 - (烷氧基烷基)或C 2 -C 10 - (烷氧基烷氧基) 杀虫剂和杀虫剂,药剂。