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1. 发明授权

US5091439A Process for curing polyurethane coatings and compositions 失效
标题翻译：固化聚氨酯涂料和组合物的方法
公开(公告)号：US5091439A
公开(公告)日：1992-02-25
申请号：US249608
申请日：1988-11-18
申请人： Godwin Berner , Manfred Rembold , Franciszek Sitek , Werner Rutsch
发明人： Godwin Berner , Manfred Rembold , Franciszek Sitek , Werner Rutsch
IPC分类号： B05D7/24 , C08G18/22 , C08J3/24 , C09D175/00 , C09D175/04
CPC分类号： C08G18/222
摘要： Compounds of the formula ##STR1## in which a is 1, 2, or 3, R.sup.1 is an uncharged, carbocyclic or heterocyclic aromatic ring, unsubstituted or substituted, R.sup.2 is an unsubstituted or substituted cyclopentadienyl or indenyl anion, and .vertline.X.vertline..sup.a- is an a-valent anion, are suitable for use as latent curing catalysts for two-component polyurethane coatings which are activated by irradiation with actinic light or by heating.
摘要翻译：式[（R1）FeII（R2）] a + [X] a-（Ⅰ）的化合物，其中a为1,2或3，R1为未被取代或取代的不带电荷的碳环或杂环芳环，R2为未取代或取代的环戊二烯基或茚基阴离子，和| X - 为一价阴离子，适用于通过用光化辐照或加热活化的双组分聚氨酯涂料的潜在固化催化剂。

2. 发明授权

US4861806A Process for curing polyisocyanate coatings in the presence of a ferrocenium compound 失效
标题翻译：在二茂铁化合物存在下固化多异氰酸酯涂层的方法
公开(公告)号：US4861806A
公开(公告)日：1989-08-29
申请号：US95726
申请日：1987-09-14
申请人： Manfred Rembold , Franciszek Sitek , Werner Rutsch , Godwin Berner
发明人： Manfred Rembold , Franciszek Sitek , Werner Rutsch , Godwin Berner
IPC分类号： C08G18/22 , C08G18/02 , C09D175/00 , G03C1/00 , G03F7/029 , G03F7/038 , G03F7/38
CPC分类号： G03F7/029 , C08G18/02
摘要： Coatings of polyisocyanates, which contain a latent catalyst of the formula I[(R.sup.1) Fe.sup.II (R.sup.2)].sub.a.sup.+ [X].sup.a- Iin which a is 1, 2 or 3, R.sup.1 is an uncharged carbocyclic or heterocyclic, unsubstituted or substituted aromatic ring, R.sup.2 is an unsubstituted or substituted cyclopentadienyl or indenyl anion and [X].sup.a- is an anion from the series comprising F.sup.-, Cl.sup.-, Br.sup.-, I.sup.-, CN.sup.-, NCO.sup.-, NCS.sup.-, CH.sub.3 COO.sup.-, CF.sub.3 COO.sup.-, SO.sub.4.sup.2-, PO.sub.4.sup.3-, NO.sub.3.sup.-, ClO.sub.4.sup.-, [(phenyl).sub.4 B].sup.-, C.sub.6 H.sub.5 SO.sub.3.sup.-, CH.sub.3 C.sub.6 H.sub.4 SO.sub.3.sup.-, CF.sub.3 C.sub.6 H.sub.4 SO.sub.3.sup.-, CH.sub.3 SO.sub.3.sup.-, CF.sub.3 SO.sub.3.sup.-, C.sub.4 F.sub.9 SO.sub.3.sup.-, C.sub.6 F.sub.13 SO.sub.3.sup.-, C.sub.8 F.sub.17 SO.sub.3.sup.-, C.sub.6 F.sub.5 SO.sub.3.sup.-, BF.sub.4.sup. -, AlF.sub.4.sup.-, AlCl.sub.4.sup.-, TiF.sub.6.sup.2-, PF.sub.6.sup.-, SbF.sub.6.sup.-, SbCl.sub.6.sup.-, GeF.sub.6.sup.-, ZrF.sub.6.sup.2-, AsF.sub.6.sup.-, FeCl.sub.4.sup.-, SnF.sub.6.sup.-, SnCl.sub.6.sup.- or BiCl.sub.6.sup.-, can be cured by irradiation with actinic light and subsequent heating.
摘要翻译：含有式I [（R1）FeII（R2）] a + [X] aI的潜在催化剂的多异氰酸酯涂层，其中a为1,2或3个，R1为不带电的碳环或杂环，未取代或取代的芳环 R2是未取代或取代的环戊二烯基或茚基阴离子，[X] a-是包含F-，Cl-，Br-，I-，CN-，NCO-，NCS-，CH 3 COO-，CF 3 COO- ，SO42-，PO43-，NO3-，ClO4-，[（phenyl）4B] - ，C6H5SO3-，CH3C6H4SO3-，CF3C6H4SO3-，CH3SO3-，CF3SO3-，C4F9SO3-，C6F13SO3-，C8F17SO3-，C6F5SO3-，BF4- ，AlF4-，AlCl4-，TiF62-，PF6-，SbF6-，SbCl6-，GeF6-，ZrF62-，AsF6-，FeCl4-，SnF6-，SnCl6-或BiCl6-可以通过光化光照射而固化加热。

3. 发明授权

US5629356A A-aminoacetophenones as photoinitiators 失效
标题翻译： α-氨基苯乙酮作为光引发剂
公开(公告)号：US5629356A
公开(公告)日：1997-05-13
申请号：US614121
申请日：1996-03-12
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

4. 发明授权

US5534629A .alpha.-aminoacetophenones as photoinitiators 失效
标题翻译： α-氨基苯乙酮作为光引发剂
公开(公告)号：US5534629A
公开(公告)日：1996-07-09
申请号：US432035
申请日：1995-05-01
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

5. 发明授权

US5077402A Novel alpha-aminoacetophenones as photoinitiators 失效
标题翻译：新型ALPHA-氨基丁二烯作为光敏剂
公开(公告)号：US5077402A
公开(公告)日：1991-12-31
申请号：US501409
申请日：1990-03-28
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

6. 发明授权

US5554663A .alpha.-aminoacetophenones as photoinitiators 失效
公开(公告)号：US5554663A
公开(公告)日：1996-09-10
申请号：US466847
申请日：1995-06-06
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.

7. 发明授权

US4960746A Liquid photoinitiator mixtures 失效
标题翻译：液体光引发剂混合物
公开(公告)号：US4960746A
公开(公告)日：1990-10-02
申请号：US386015
申请日：1989-07-26
申请人： Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C08F2/50 , C09D4/00 , C09D5/00 , C09D7/12 , C09D11/00 , C09D11/10 , G03F7/029
CPC分类号： G03F7/029 , Y10S430/148
摘要： Liquid, highly active photoinitiators are obtained by dissolving a solid photoinitiator of a titanocene type in liquid photoinitiators of the type of the .alpha.-hydroxy- or .alpha.-amino-acetophenones or in a liquid mixture of an .alpha.-hydroxy- or .alpha.-aminoacetophenone photocuring agent with one or more other photoinitiators.
摘要翻译：通过将二茂钛型固体光引发剂溶解在α-羟基或α-氨基 - 苯乙酮类型的液体光引发剂中或在α-羟基 - 或α-氨基苯乙酮光固化的液体混合物中来获得液体，高活性光引发剂代理与一种或多种其他光引发剂。

8. 发明授权

US4736055A Oxime sulfonates containing reactive groups 失效
标题翻译：含有反应性基团的肟磺酸盐
公开(公告)号：US4736055A
公开(公告)日：1988-04-05
申请号：US851032
申请日：1986-04-11
申请人： Kurt Dietliker , Werner Rutsch , Godwin Berner , Max Hunziker , Christopher G. Demmer
发明人： Kurt Dietliker , Werner Rutsch , Godwin Berner , Max Hunziker , Christopher G. Demmer
IPC分类号： C07C301/00 , C07C67/00 , C07C309/63 , C07C309/73 , C07C309/75 , C07C309/76 , C07C309/77 , C07D303/20 , C07D307/38 , C07D333/24 , C07D333/38 , C08F12/00 , C08F16/00 , C08F16/14 , C08F20/00 , C08F20/38 , C08F20/52 , C08F20/58 , C08F26/00 , C08F26/02 , C08F26/04 , C08F28/00 , C08F28/02 , C08G65/22 , C08G85/00 , G03C1/72 , G03F7/004 , G03F7/039 , C07C131/00
CPC分类号： G03F7/039 , C07C309/63 , C07C309/73 , C07C309/75 , C07C309/76 , C07C309/77 , C07D333/24 , C08F20/38 , C07C2103/18
摘要： Oxime sulfonates of formula I ##STR1## wherein Y is a polymerizable unsaturated group or epoxide group or an --OH, --NHR.sup.5, --COOH, COOR.sup.6, --COCl, --CH.sub.2 Hal, --SO.sub.2 Cl or --NCO group, Z is an (x+y)-valent connecting member, R.sup.1 and R.sup.2 are monovalent organic radicals, m is 0 or 1, x is 1 or 2 and y is 1 or 2, can be converted into polymers which can be thermally or photochemically dissociated to form free sulfonic acid groups. Said polymers can therefore be used as photoresists which can be developed with aqueous alkalis.
摘要翻译：式I的肟磺酸盐其中Y是可聚合不饱和基团或环氧基团或-OH，-NHR 5，-COOH，COOR 6，-COCl，-CH 2 Hal，-SO 2 Cl或-NCO基团，Z是（x + y）价的连接元件，R1和R2是一价有机基团，m是0或1，x是1或2，y是1或2，可以转化成可以热或光化学解离形成的聚合物游离磺酸基团。因此，所述聚合物可以用作可用碱性水溶液显影的光致抗蚀剂。

9. 发明授权

US4699949A Hardening of acid-hardenable compositions containing a blocked hardening catalyst, using heat 失效
标题翻译：使用热量使含有封闭硬化催化剂的酸可硬化组合物硬化
公开(公告)号：US4699949A
公开(公告)日：1987-10-13
申请号：US747147
申请日：1985-06-20
申请人： Godwin Berner , Werner Rutsch
发明人： Godwin Berner , Werner Rutsch
IPC分类号： C08K5/00 , C07D295/185 , C08K5/41 , C08K5/42 , C08L33/00 , C08L33/02 , C08L33/08 , C08L87/00 , C09D123/00 , C09D201/00 , C08L61/00
CPC分类号： C07D295/185 , C07C309/00 , C08K5/42
摘要： Compounds of formula I or II ##STR1## in which n is 1 or 2, R.sup.1 is phenyl, substituted phenyl, alkyl, substituted alkyl, hydrogen, --OH or amino, R.sup.2 is hydrogen, R.sup.3 is hydrogen, alkyl, substituted alkyl, phenyl or substituted phenyl, R.sup.4 is alkyl, phenyl, substituted phenyl, alkylene or arylene, X is --O--, --S--, --CH.sub.2 -- and Y is a direct bond or --CH.sub.2 -- are latent hardening catalysts for acid curable resins. The catalysts are activated by heat and are used in heat-hardening high-solids industrial varnishes and for coil-coatings, can and wood varnishes.
摘要翻译：式I或II的化合物其中n为1或2，R1为苯基，取代的苯基，烷基，取代的烷基，氢，-OH或氨基，R2为氢，R3，是氢，烷基，取代的烷基，苯基或取代的苯基，R4是烷基，苯基，取代的苯基，亚烷基或亚芳基，X是-O - ， - S-，-CH2-，Y是直接键或-CH2- 酸固化树脂的潜硬化催化剂。催化剂由热活化，用于加热硬化高固含量工业清漆和卷材涂料，罐头和木材清漆。

10. 发明授权

US4540598A Process for curing acid-curable finishes 失效
标题翻译：固化可酸性涂饰的方法
公开(公告)号：US4540598A
公开(公告)日：1985-09-10
申请号：US639040
申请日：1984-08-09
申请人： Godwin Berner , Werner Rutsch
发明人： Godwin Berner , Werner Rutsch
IPC分类号： C08K5/00 , C08F2/50 , C08K5/41 , C08K5/42 , C08L33/00 , C08L33/02 , C08L33/04 , C08L61/00 , C08L61/04 , C08L61/06 , C08L61/20 , C08L67/00 , C09D5/00 , C09D133/04 , C09D161/00 , C09D161/20 , C09D161/28 , B05D3/06
CPC分类号： C08K5/42 , C09D161/00
摘要： Oxime sulfonates of the formula I ##STR1## in which m is 0 or 1 and n is 1 or 2, R.sup.1 and R.sup.2 are monovalent radicals or, together with the atoms to which they are linked, form a ring system, and R.sup.3 is the n-valent radical of a mono- or di-sulfonic acid, can be split photochemically to give the free sulfonic acid. They can therefore be used as latent acid catalysts for combined radiation curing and heat curing of acid-curable finishes.
摘要翻译：式I的肟磺酸盐其中m为0或1，n为1或2，R 1和R 2为一价基团，或与它们连接的原子一起形成环系，并且 R3是单 - 或二 - 磺酸的n价基团，可以光化学分解，得到游离的磺酸。因此，它们可以用作潜酸催化剂，用于组合辐射固化和酸固化整理剂的热固化。

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