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1. 发明授权

US5629356A A-aminoacetophenones as photoinitiators 失效
标题翻译： α-氨基苯乙酮作为光引发剂
公开(公告)号：US5629356A
公开(公告)日：1997-05-13
申请号：US614121
申请日：1996-03-12
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

2. 发明授权

US5554663A .alpha.-aminoacetophenones as photoinitiators 失效
公开(公告)号：US5554663A
公开(公告)日：1996-09-10
申请号：US466847
申请日：1995-06-06
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.

3. 发明授权

US5534629A .alpha.-aminoacetophenones as photoinitiators 失效
标题翻译： α-氨基苯乙酮作为光引发剂
公开(公告)号：US5534629A
公开(公告)日：1996-07-09
申请号：US432035
申请日：1995-05-01
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

4. 发明授权

US5077402A Novel alpha-aminoacetophenones as photoinitiators 失效
标题翻译：新型ALPHA-氨基丁二烯作为光敏剂
公开(公告)号：US5077402A
公开(公告)日：1991-12-31
申请号：US501409
申请日：1990-03-28
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

5. 发明授权

US5091439A Process for curing polyurethane coatings and compositions 失效
标题翻译：固化聚氨酯涂料和组合物的方法
公开(公告)号：US5091439A
公开(公告)日：1992-02-25
申请号：US249608
申请日：1988-11-18
申请人： Godwin Berner , Manfred Rembold , Franciszek Sitek , Werner Rutsch
发明人： Godwin Berner , Manfred Rembold , Franciszek Sitek , Werner Rutsch
IPC分类号： B05D7/24 , C08G18/22 , C08J3/24 , C09D175/00 , C09D175/04
CPC分类号： C08G18/222
摘要： Compounds of the formula ##STR1## in which a is 1, 2, or 3, R.sup.1 is an uncharged, carbocyclic or heterocyclic aromatic ring, unsubstituted or substituted, R.sup.2 is an unsubstituted or substituted cyclopentadienyl or indenyl anion, and .vertline.X.vertline..sup.a- is an a-valent anion, are suitable for use as latent curing catalysts for two-component polyurethane coatings which are activated by irradiation with actinic light or by heating.
摘要翻译：式[（R1）FeII（R2）] a + [X] a-（Ⅰ）的化合物，其中a为1,2或3，R1为未被取代或取代的不带电荷的碳环或杂环芳环，R2为未取代或取代的环戊二烯基或茚基阴离子，和| X - 为一价阴离子，适用于通过用光化辐照或加热活化的双组分聚氨酯涂料的潜在固化催化剂。

6. 发明授权

US4960746A Liquid photoinitiator mixtures 失效
标题翻译：液体光引发剂混合物
公开(公告)号：US4960746A
公开(公告)日：1990-10-02
申请号：US386015
申请日：1989-07-26
申请人： Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C08F2/50 , C09D4/00 , C09D5/00 , C09D7/12 , C09D11/00 , C09D11/10 , G03F7/029
CPC分类号： G03F7/029 , Y10S430/148
摘要： Liquid, highly active photoinitiators are obtained by dissolving a solid photoinitiator of a titanocene type in liquid photoinitiators of the type of the .alpha.-hydroxy- or .alpha.-amino-acetophenones or in a liquid mixture of an .alpha.-hydroxy- or .alpha.-aminoacetophenone photocuring agent with one or more other photoinitiators.
摘要翻译：通过将二茂钛型固体光引发剂溶解在α-羟基或α-氨基 - 苯乙酮类型的液体光引发剂中或在α-羟基 - 或α-氨基苯乙酮光固化的液体混合物中来获得液体，高活性光引发剂代理与一种或多种其他光引发剂。

7. 发明授权

US4861806A Process for curing polyisocyanate coatings in the presence of a ferrocenium compound 失效
标题翻译：在二茂铁化合物存在下固化多异氰酸酯涂层的方法
公开(公告)号：US4861806A
公开(公告)日：1989-08-29
申请号：US95726
申请日：1987-09-14
申请人： Manfred Rembold , Franciszek Sitek , Werner Rutsch , Godwin Berner
发明人： Manfred Rembold , Franciszek Sitek , Werner Rutsch , Godwin Berner
IPC分类号： C08G18/22 , C08G18/02 , C09D175/00 , G03C1/00 , G03F7/029 , G03F7/038 , G03F7/38
CPC分类号： G03F7/029 , C08G18/02
摘要： Coatings of polyisocyanates, which contain a latent catalyst of the formula I[(R.sup.1) Fe.sup.II (R.sup.2)].sub.a.sup.+ [X].sup.a- Iin which a is 1, 2 or 3, R.sup.1 is an uncharged carbocyclic or heterocyclic, unsubstituted or substituted aromatic ring, R.sup.2 is an unsubstituted or substituted cyclopentadienyl or indenyl anion and [X].sup.a- is an anion from the series comprising F.sup.-, Cl.sup.-, Br.sup.-, I.sup.-, CN.sup.-, NCO.sup.-, NCS.sup.-, CH.sub.3 COO.sup.-, CF.sub.3 COO.sup.-, SO.sub.4.sup.2-, PO.sub.4.sup.3-, NO.sub.3.sup.-, ClO.sub.4.sup.-, [(phenyl).sub.4 B].sup.-, C.sub.6 H.sub.5 SO.sub.3.sup.-, CH.sub.3 C.sub.6 H.sub.4 SO.sub.3.sup.-, CF.sub.3 C.sub.6 H.sub.4 SO.sub.3.sup.-, CH.sub.3 SO.sub.3.sup.-, CF.sub.3 SO.sub.3.sup.-, C.sub.4 F.sub.9 SO.sub.3.sup.-, C.sub.6 F.sub.13 SO.sub.3.sup.-, C.sub.8 F.sub.17 SO.sub.3.sup.-, C.sub.6 F.sub.5 SO.sub.3.sup.-, BF.sub.4.sup. -, AlF.sub.4.sup.-, AlCl.sub.4.sup.-, TiF.sub.6.sup.2-, PF.sub.6.sup.-, SbF.sub.6.sup.-, SbCl.sub.6.sup.-, GeF.sub.6.sup.-, ZrF.sub.6.sup.2-, AsF.sub.6.sup.-, FeCl.sub.4.sup.-, SnF.sub.6.sup.-, SnCl.sub.6.sup.- or BiCl.sub.6.sup.-, can be cured by irradiation with actinic light and subsequent heating.
摘要翻译：含有式I [（R1）FeII（R2）] a + [X] aI的潜在催化剂的多异氰酸酯涂层，其中a为1,2或3个，R1为不带电的碳环或杂环，未取代或取代的芳环 R2是未取代或取代的环戊二烯基或茚基阴离子，[X] a-是包含F-，Cl-，Br-，I-，CN-，NCO-，NCS-，CH 3 COO-，CF 3 COO- ，SO42-，PO43-，NO3-，ClO4-，[（phenyl）4B] - ，C6H5SO3-，CH3C6H4SO3-，CF3C6H4SO3-，CH3SO3-，CF3SO3-，C4F9SO3-，C6F13SO3-，C8F17SO3-，C6F5SO3-，BF4- ，AlF4-，AlCl4-，TiF62-，PF6-，SbF6-，SbCl6-，GeF6-，ZrF62-，AsF6-，FeCl4-，SnF6-，SnCl6-或BiCl6-可以通过光化光照射而固化加热。

8. 发明授权

US4970136A Titanocenes and their use 失效
标题翻译： Titanocenes及其用途
公开(公告)号：US4970136A
公开(公告)日：1990-11-13
申请号：US361194
申请日：1989-06-05
申请人： Martin Riediker , Eginhard Steiner , Harry Beyeler , Manfred Rembold , Franciszek Sitek
发明人： Martin Riediker , Eginhard Steiner , Harry Beyeler , Manfred Rembold , Franciszek Sitek
IPC分类号： C07F7/28 , C07F17/00 , C08F2/50 , G03F7/029
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/12 , Y10S430/122 , Y10S430/124 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with, for example, .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the matal-carbon bond and being substituted by at least one free or etherified or esterified polyoxaalkylene radical, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates.

9. 发明授权

US4963470A Titanocenes and their use 失效
标题翻译： Titanocenes及其用途
公开(公告)号：US4963470A
公开(公告)日：1990-10-16
申请号：US469736
申请日：1990-01-19
申请人： Bernd Klingert , Franciszek Sitek , Manfred Rembold
发明人： Bernd Klingert , Franciszek Sitek , Manfred Rembold
IPC分类号： C07F7/28 , C07F17/00 , C08F2/50 , C08F4/76 , C08L33/00 , C08L33/02 , C08L61/20 , C08L67/00 , C09D11/101 , G03F7/029
CPC分类号： C09D11/101 , C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with silylated .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine, --CF.sub.3, --C.sub.2 F.sub.5, --CF.sub.2 CL or --CF.sub.2 CH.sub.3 in at least one of the two ortho-positions relative to the metal-carbon bonds, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates. They are distinguished by a high sensitivity, stability to air and the action of heat, and a high activity in the region of UV light to visible light. They are furthermore readily soluble in the photopolymerizable compositions.
摘要翻译：具有甲硅烷基化的1,2-环戊二烯基配位体的二十碳烯烃，其中一个或两个碳环或杂环芳环与钛键合，芳环被氟取代，-CF 3，-C 2 F 5，-CF 2 Cl或-CF 2 CH 3在两个相对于金属 - 碳键的邻位适用作用于烯属不饱和基材的光聚合的光引发剂。它们的特征在于高灵敏度，对空气的稳定性和热的作用，以及在紫外光到可见光区域的高活性。它们还易溶于可光聚合组合物。

10. 发明授权

US4857654A Titanocenes and their use 失效
标题翻译： Titanocenes及其用途
公开(公告)号：US4857654A
公开(公告)日：1989-08-15
申请号：US77261
申请日：1987-07-24
申请人： Martin Riediker , Eginhard Steiner , Harry Beyeler , Manfred Rembold , Franciszek Sitek
发明人： Martin Riediker , Eginhard Steiner , Harry Beyeler , Manfred Rembold , Franciszek Sitek
IPC分类号： C07F7/28 , C07F17/00 , C08F2/50 , G03F7/029
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/12 , Y10S430/122 , Y10S430/124 , Y10S430/126 , Y10S430/148
摘要： Titanocenes with, for example, .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine in at least one of the two ortho-positions relative to the metal-carbon bond and being substituted by at least one free or etherified or esterified polyoxaalkylene radical, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates.
摘要翻译：具有例如其中一个或两个碳环或杂环芳环与钛键合的对 - 环戊二烯基配位体的二十碳烯，芳环在相对于金属碳的两个邻位中的至少一个中被氟取代并且被至少一个游离的或醚化的或酯化的聚氧亚烷基取代，适合作为用于烯属不饱和基材的光聚合的光引发剂。

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