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1. 发明授权

US5629356A A-aminoacetophenones as photoinitiators 失效
标题翻译： α-氨基苯乙酮作为光引发剂
公开(公告)号：US5629356A
公开(公告)日：1997-05-13
申请号：US614121
申请日：1996-03-12
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

2. 发明授权

US5554663A .alpha.-aminoacetophenones as photoinitiators 失效
公开(公告)号：US5554663A
公开(公告)日：1996-09-10
申请号：US466847
申请日：1995-06-06
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo H usler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.

3. 发明授权

US5534629A .alpha.-aminoacetophenones as photoinitiators 失效
标题翻译： α-氨基苯乙酮作为光引发剂
公开(公告)号：US5534629A
公开(公告)日：1996-07-09
申请号：US432035
申请日：1995-05-01
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

4. 发明授权

US5077402A Novel alpha-aminoacetophenones as photoinitiators 失效
标题翻译：新型ALPHA-氨基丁二烯作为光敏剂
公开(公告)号：US5077402A
公开(公告)日：1991-12-31
申请号：US501409
申请日：1990-03-28
申请人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
发明人： Vincent Desobry , Kurt Dietliker , Rinaldo Husler , Werner Rutsch , Manfred Rembold , Franciszek Sitek
IPC分类号： C07D209/12 , C07C67/00 , C07C209/86 , C07C213/00 , C07C219/02 , C07C219/04 , C07C225/16 , C07C225/22 , C07C229/06 , C07C229/14 , C07C229/16 , C07C229/34 , C07C229/52 , C07C233/36 , C07C253/00 , C07C255/56 , C07C313/00 , C07C317/32 , C07C317/36 , C07C323/23 , C07C323/25 , C07C323/31 , C07C323/32 , C07C323/65 , C07D209/86 , C07D219/02 , C07D219/04 , C07D223/22 , C07D263/32 , C07D263/56 , C07D265/30 , C07D265/36 , C07D265/38 , C07D279/18 , C07D283/00 , C07D295/02 , C07D295/10 , C07D295/104 , C07D295/112 , C07D295/12 , C07D307/91 , C07F7/18 , C08F2/46 , C08F2/50 , C09D4/00 , C09D5/32 , C09D7/12 , C09D11/10 , G03F7/031
CPC分类号： C07D295/112 , C07D209/86 , C07D295/104 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II, III and IIIa ##STR1## in which Ar.sup.1 is an unsubstituted or substituted aromatic radical and at least one of the radicals R.sup.1 and R.sup.2 is an alkenyl, cycloalkenyl or arylmethyl group, are effective photoinitiators for photopolymerization of unsaturated compounds. They are particularly suitable for photocuring of pigmented systems.
摘要翻译：式I，II，III和IIIa的化合物其中Ar1是未取代或取代的芳族基团，并且基团R 1和R 2中的至少一个是烯基，环烯基或芳基甲基是用于光聚合不饱和化合物的有效光引发剂。它们特别适用于着色系统的光固化。

5. 发明授权

US5192642A Oxygen-containing titanocenes, and the use thereof 失效
标题翻译：含氧含钛，以及其使用
公开(公告)号：US5192642A
公开(公告)日：1993-03-09
申请号：US527988
申请日：1990-05-23
申请人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
发明人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
IPC分类号： C07F7/28 , C07F17/00 , C08F2/50 , C09D4/00 , G03F7/029
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/124 , Y10S430/148 , Y10S526/943
摘要： Titanocenes of the formula I ##STR1## in which R.sup.1 are cyclopentadienyl.sup..crclbar. groups and R.sup.2 and R.sup.3 are aromatic radicals which are substituted in both ortho-positions by fluorine and, in addition, are substituted by an acyloxy group are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译：其中R 1是环戊二烯基（ - ）基团并且R 2和R 3是在两个邻位被氟取代并且被酰氧基取代的芳族基团的式I化合物（I）的十六碳烯是合适的作为烯属不饱和化合物的光聚合的光引发剂。

6. 发明授权

US5306600A Oxygen-containing titanocenes, and the use thereof 失效
标题翻译：含氧二茂钛及其用途
公开(公告)号：US5306600A
公开(公告)日：1994-04-26
申请号：US975042
申请日：1992-11-12
申请人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
发明人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
IPC分类号： C07F7/28 , C07F17/00 , C08F2/50 , C09D4/00 , G03F7/029
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/124 , Y10S430/148 , Y10S526/943
摘要： Titanocenes of the formula I ##STR1## in which R.sup.1 are cyclopentadienyl.sup..crclbar. groups and R.sup.2 and R.sup.3 are aromatic radicals which are substituted in both ortho-positions by fluorine and, in addition, are substituted by an acyloxy group are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译：其中R 1是环戊二烯基（ - ）基团并且R 2和R 3是在两个邻位被氟取代并且被酰氧基取代的芳族基团的式I化合物（I）的十六碳烯是合适的作为烯属不饱和化合物的光聚合的光引发剂。

7. 发明授权

US4498964A Process for the photopolymerization of unsaturated compounds 失效
标题翻译：不饱和化合物的光聚合方法
公开(公告)号：US4498964A
公开(公告)日：1985-02-12
申请号：US502860
申请日：1983-06-09
申请人： Rinaldo Husler , Werner Rutsch , Kurt Dietliker
发明人： Rinaldo Husler , Werner Rutsch , Kurt Dietliker
IPC分类号： C08F2/00 , C07C45/00 , C07C49/835 , C07C49/84 , C07C67/00 , C07C213/00 , C07C225/20 , C07C225/22 , C07C231/00 , C07C233/33 , C07C313/00 , C07C323/22 , C07F7/18 , C08F2/50 , C09D4/00 , G03F7/031
CPC分类号： C08F2/50 , G03F7/031 , Y10S430/124 , Y10S430/125
摘要： Compounds of the formula I, II, III, IV or V ##STR1## in which Ar, X, Y, Y', R.sup.1 to R.sup.5 and R.sup.1' to R.sup.5' are as defined in claim 1, can be used as photoinitiators for the photopolymerization of unsaturated compounds. They can be prepared by a Diels-Alder reaction and/or a Grignard reaction.
摘要翻译：其中Ar，X，Y，Y'，R 1至R 5和R 1'的化合物是式I，II，III，IV或V的化合物。至R5'如权利要求1中所定义，可用作光引发剂用于不饱和化合物的光聚合。它们可以通过Diels-Alder反应和/或Grignard反应来制备。

8. 发明授权

US5218009A Mono- and di-acylphosphine oxides 失效
标题翻译：单酰基和二酰基氧化膦
公开(公告)号：US5218009A
公开(公告)日：1993-06-08
申请号：US751048
申请日：1991-08-28
申请人： Werner Rutsch , Kurt Dietliker , Roger G. Hall
发明人： Werner Rutsch , Kurt Dietliker , Roger G. Hall
IPC分类号： C07F9/32 , C07F9/53 , C07F9/6568 , C08F2/50 , G03F7/029
CPC分类号： C07F9/5337 , C07F9/3252 , C07F9/65685 , C08F2/50 , G03F7/029
摘要： Compounds of the formula I ##STR1## in which at least one of the radicals R.sub.1, R.sub.2 and R.sub.3 is a substituted alkyl radical or cycloalkyl radical, or R.sub.1 and R.sub.2 together with the phosphorus atom form a monocyclic or tricyclic ring, are effective photoinitiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译：其中基团R 1，R 2和R 3中的至少一个是取代的烷基或环烷基，或者R 1和R 2与磷原子一起形成单环或三环的式I的化合物是有效的光引发剂用于烯属不饱和化合物的光聚合。

9. 发明授权

US4795766A Propiophenone derivatives as photoinitiators for photopolymerization 失效
标题翻译：用于光聚合的苯丙酮衍生物作为光引发剂
公开(公告)号：US4795766A
公开(公告)日：1989-01-03
申请号：US880654
申请日：1986-06-30
申请人： Werner Rutsch , Rudolf Kirchmayr , Rinaldo Husler , Kurt Dietliker
发明人： Werner Rutsch , Rudolf Kirchmayr , Rinaldo Husler , Kurt Dietliker
IPC分类号： C08F2/00 , C07C45/00 , C07C45/71 , C07C49/175 , C07C49/35 , C07C49/577 , C07C49/83 , C07C49/84 , C07C67/00 , C07C313/00 , C07C323/22 , C07D309/12 , C07D317/26 , C07F7/18 , C08F2/50 , C08F4/00 , C09D4/00 , C09D5/00 , C09D11/00 , C09D11/10 , D21H19/20 , D21H19/24 , G03F7/031 , C07D317/72
CPC分类号： G03F7/031 , C07C45/71 , C07C49/83 , C07C49/84 , C07D317/26 , C07F7/1852 , C08F2/50 , Y10S522/901
摘要： Propiophenones of the formula I ##STR1## in which R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, --Si(CH.sub.3).sub.3, allyl or benzyl, R.sup.2 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.4 -alkyl which is substituted by C.sub.1 -C.sub.4 -alkoxy or --OH, --(CH.sub.2 --CH.sub.2 --O).sub.n --R.sup.5 where n is 2 to 20 and R.sup.5 is H or C.sub.1 -C.sub.4 -alkyl, --Si(CH.sub.3).sub.3, benzyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkynyl or 2-tetrahydrofuranyl, or R.sup.1 and R.sup.2 together are a C.sub.1 -C.sub.6 -alkylidene radical or a C.sub.2 -C.sub.6 -alkylidene radical which is substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy or phenyl, a linear or branched C.sub.2 -C.sub.6 -alkanediyl radical, a benzylidene, cyclopentylidene or cyclohexylidene radical or a 2,2,2-trichloroethylidene, 2-furylimethylidene or dimethylsilylidene radical, R.sup.3 is phenyl which is unsubstituted or substituted by one or more --Cl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio radicals, and is also benzoylphenyl, phenoxyphenyl or phenylthiophenyl, R.sup.4 is C.sub.1 -C.sub.4 -alkyl, or phenyl which is unsubstituted or substituted by one or more --Cl, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy radicals, and R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.4 and R.sup.5 together are a trimethylene or tetramethylene radical, and R.sup.6 is hydrogen, C.sub.1 -C.sub.4 -alkyl, --CCl.sub.3 or phenyl, subject to the condition that, if R.sup.2, R.sup.5 and R.sup.6 at the same time are hydrogen and R.sup.3 and R.sup.4 ar at the same time phenyl, R.sup.1 must not be hydrogen or C.sub.1 -C.sub.4 -alkyl, also, if R.sup.3 and R.sup.4 at the same time are phenyl and R.sup.5 and R.sup.6 are at the same time hydrogen, R.sup.1 and R.sup.2 together must not be alkylidene or benzylidene, and also, if R.sup.3 and R.sup.4 at the same time are p-methoxyphenyl and R.sup.2, R.sup.5 and R.sup.6 are at the same time hydrogen, R.sup.1 must not be hydrogen, and, finally, if R.sup.2 and R.sup.5 at the same time are hydrogen and R.sup.3, R.sup.4 and R.sup.6 are at the same time phenyl, R.sup.1 must not be hydrogen, are valuable initiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译：其中R 1是氢或C 1 -C 4烷基，-Si（CH 3）3，烯丙基或苄基，R 2是氢，C 1 -C 8烷基，C 1 -C 4烷基，其中R 1是氢或C 1 -C 4烷基，被C 1 -C 4 - 烷氧基或-OH取代， - （CH 2 -CH 2 -O）n -R 5，其中n为2至20，R 5为H或C 1 -C 4烷基，-Si（CH 3）3，苄基，C 3 C 1-6 - 烯基，C 3 -C 4 - 炔基或2-四氢呋喃基，或者R 1和R 2一起是被羟基，C 1 -C 4烷氧基或苯基取代的C 1 -C 6亚烷基或C 2 -C 6亚烷基，直链或支链的C 2 -C 6烷二基，亚苄基，亚环戊叉基或亚环己基或2,2,2-三氯亚乙基，2-呋喃基亚甲基或二甲基亚甲基基，R3是未取代或被一个或多个-Cl， C1-C4-烷基，C1-C4-烷氧基或C1-C4-烷硫基，也是苯甲酰基苯基，苯氧基苯基或苯硫基苯基，R4是C1-C4-烷基或未被取代或被一个或多个-Cl， C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基，R 5是氢或C 1-C4-烷基或R4和R5一起是三亚甲基或四亚甲基，并且R 6是氢，C 1 -C 4 - 烷基，-CCl 3或苯基，条件是如果同时为R 2，R 5和R 6 是氢，R3和R4Ar同时是苯基，R1不能是氢或C1-C4-烷基，同样，如果R3和R4同时为苯基，R5和R6同时为氢，R1和 R2一起不能是亚烷基或亚苄基，如果R3和R4同时是对甲氧基苯基，R2，R5和R6同时是氢，R1不能是氢，最后如果R2和 R5同时为氢，R3，R4和R6同时为苯基，R1不能为氢，是烯属不饱和化合物的光聚合的有价值的引发剂。

10. 发明授权

US5147901A Propionphenone derivatives as photoinitiators for photopolymerization 失效
标题翻译：丙酮衍生物作为光合作用的光敏剂
公开(公告)号：US5147901A
公开(公告)日：1992-09-15
申请号：US411436
申请日：1989-09-22
申请人： Werner Rutsch , Rudolf Kirchmayr , Rinaldo Husler , Kurt Dietliker
发明人： Werner Rutsch , Rudolf Kirchmayr , Rinaldo Husler , Kurt Dietliker
IPC分类号： C08F2/00 , C07C45/00 , C07C45/71 , C07C49/175 , C07C49/35 , C07C49/577 , C07C49/83 , C07C49/84 , C07C67/00 , C07C313/00 , C07C323/22 , C07D309/12 , C07D317/26 , C07F7/18 , C08F2/50 , C08F4/00 , C09D4/00 , C09D5/00 , C09D11/00 , C09D11/10 , D21H19/20 , D21H19/24 , G03F7/031
CPC分类号： G03F7/031 , C07C45/71 , C07C49/83 , C07C49/84 , C07D317/26 , C07F7/1852 , C08F2/50 , Y10S522/901
摘要： Propiophenones of the formula I ##STR1## in which R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl, --Si(CH.sub.3).sub.3, allyl or benzyl, R.sup.2 is hydrogen, C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.4 -alkyl which is substituted by C.sub.1 -C.sub.4 -alkoxy or --OH, --(CH.sub.2 --CH.sub.2 --O).sub.n --R.sup.5 where n is 2 to 20 and R.sup.5 is H or C.sub.1 -C.sub.4 -alkyl, --Si(CH.sub.3).sub.3, benzyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.4 -alkynyl or 2-tetrahydrofuranyl, or R.sup.1 and R.sup.2 together are a C.sub.1 -C.sub.6 -alkylidene radical or a C.sub.2 -C.sub.6 -alkylidene radical which is substituted by hydroxyl, C.sub.1 -C.sub.4 -alkoxy or phenyl, a linear or branched C.sub.2 -C.sub.6 -alkanediyl radical, a benzylidene, cyclopentylidene or cyclohexylidene radical or a 2,2,2-trichloroethylidene, 2-furylmethylidene or dimethylsilylidene radical, R.sup.3 is phenyl which is unsubstituted or substituted by one or more --Cl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio radicals, and is also benzoylphenyl, phenoxyphenol or phenylthiophenyl, R.sup.4 is C.sub.1 -C.sub.4 -alkyl, or phenyl which is unsubstituted or substituted by one or more --Cl, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy radicals, and R.sup.5 is hydrogen or C.sub.1 -C.sub.4 -alkyl, or R.sup.4 and R.sup.5 together are a trimethylene or tetramethylene radical, and R.sup.6 is hydrogen, C.sub.1 -C.sub.4 -alkyl, --CCl.sub.3 or phenyl, subject to the condition that, if R.sup.2, R.sup.5 and R.sup.6 at the same time are hydrogen and R.sup.3 and R.sup.4 are at the same time phenyl, R.sup.1 must not be hydrogen or C.sub.1 -C.sub.4 -alkyl, also, if R.sup.3 and R.sup.4 at the same time are phenyl and R.sup.5 and R.sup.6 are at the same time hydrogen, R.sup.1 and R.sup.2 together must not be alkylidene or benzylidene, and also, if R.sup.3 and R.sup.4 at the same time are p-methoxyphenyl and R.sup.2, R.sup.5 and R.sup.6 are at the same time hydrogen, R.sup.1 must not be hydrogen, and, finally, if R.sup.2 and R.sup.6 at the same time are hydrogen and R.sup.3, R.sup.4 and R.sup.5 are at the same time phenyl, R.sup.1 must not be hydrogen, are valuable initiators for the photopolymerization of ethylenically unsaturated compounds.

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