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1. 发明授权

US06815494B2 Aqueous coating material, especially aqueous filler or protective base against stones 失效
标题翻译：水性涂料，特别是水性填料或防锈底物
公开(公告)号：US06815494B2
公开(公告)日：2004-11-09
申请号：US10396893
申请日：2003-03-25
申请人： Georg Wigger , Ulrike Röckrath , Bärbel Wiatr , Marita Schilling , Ralf Stein
发明人： Georg Wigger , Ulrike Röckrath , Bärbel Wiatr , Marita Schilling , Ralf Stein
IPC分类号： C08J303
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/348 , C08G18/4288 , C08G18/6659 , C09D175/04 , Y10T428/31511 , Y10T428/31551 , C08G18/42 , C08G18/286 , C08G18/792 , C08L75/04 , C08L67/00
摘要： Aqueous coating material comprising (A) water-dispersible hydroxy-functional binder component containing urethane groups, (B) water-dispersible binder component containing urethane groups and blocked isocyanate groups, (C) water-dispersible amino resin, and optionally (D) water-dispersible hydroxy-functional polyester, the binder component (B) being preparable by (B1) preparing a polyurethane prepolymer containing isocyanate groups from at least one polyol and at least one polyisocyanate, (B2) reacting the polyurethane prepolymer (B1) containing isocyanate groups with a chain extender to give a hydroxyl-containing chain-extended polyurethane prepolymer, (B3) reacting the hydroxyl-containing chain-extended polyurethane prepolymer (B2) with at least one polyisocyanate to give a further polyurethane prepolymer containing isocyanate groups, and (B4) blocking some or all of the isocyanate groups of the chain-extended polyurethane prepolymer (B3) containing isocyanate groups with a blocking agent to give a polyurethane containing blocked isocyanate groups, and then, where appropriate, (B5) reacting remaining free isocyanate groups in the polyurethane (B4) with a chain extender.
摘要翻译：包含（A）含有氨基甲酸酯基的水分散性羟基官能粘合剂组分的水性涂料，（B）含有氨基甲酸酯基和封端异氰酸酯基的水分散性粘合剂组分，（C）水分散性氨基树脂和任选的（D）水可分解的羟基官能的聚酯，（B1）由至少一种多元醇和至少一种多异氰酸酯制备含有异氰酸酯基团的聚氨酯预聚物（B2）制备的粘合剂组分（B），（B2）使含有异氰酸酯基团的聚氨酯预聚物与扩链剂一起得到含羟基的链延长的聚氨酯预聚物，（B3）使含羟基的链延长的聚氨酯预聚物（B2）与至少一种多异氰酸酯反应，得到另外的含异氰酸酯基团的聚氨酯预聚物，和（B4 ）阻断含有异氰酸酯基团的链延长聚氨酯预聚物（B3）的一部分或全部异氰酸酯基团得到含有封端异氰酸酯基团的聚氨酯，然后在适当的情况下（B5）使聚氨酯（B4）中剩余的游离异氰酸酯基与扩链剂反应。

2. 发明授权

US06620511B1 Aqueous coating material, especially aqueous filler or protective base against stones 失效
公开(公告)号：US06620511B1
公开(公告)日：2003-09-16
申请号：US10018155
申请日：2001-12-14
申请人： Georg Wigger , Ulrike Röckrath , Bärbel Wiatr , Marita Schilling , Ralf Stein
发明人： Georg Wigger , Ulrike Röckrath , Bärbel Wiatr , Marita Schilling , Ralf Stein
IPC分类号： B32B2738
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/348 , C08G18/4288 , C08G18/6659 , C09D175/04 , Y10T428/31511 , Y10T428/31551 , C08G18/42 , C08G18/286 , C08G18/792 , C08L75/04 , C08L67/00
摘要： Aqueous coating material comprising (A) water-dispersible hydroxy-functional binder component containing urethane groups, (B) water-dispersible binder component containing urethane groups and blocked isocyanate groups, (C) water-dispersible amino resin, and optionally (D) water-dispersible hydroxy-functional polyester, the binder component (B) being preparable by (B1) preparing a polyurethane prepolymer containing isocyanate groups from at least one polyol and at least one polyisocyanate, (B2) reacting the polyurethane prepolymer (B1) containing isocyanate groups with a chain extender to give a hydroxyl-containing chain-extended polyurethane prepolymer, (B3) reacting the hydroxyl-containing chain-extended polyurethane prepolymer (B2) with at least one polyisocyanate to give a further polyurethane prepolymer containing isocyanate groups, and (B4) blocking some or all of the isocyanate groups of the chain-extended polyurethane prepolymer (B3) containing isocyanate groups with a blocking agent to give a polyurethane containing blocked isocyanate groups, and then, where appropriate, (B5) reacting remaining free isocyanate groups in the polyurethane (B4) with a chain extender.

3. 发明授权

US06620884B2 Method for producing scratch resistant coatings, especially for producing multi-layer enamels 失效
标题翻译：制备耐刮涂层的方法，特别是用于生产多层瓷漆
公开(公告)号：US06620884B2
公开(公告)日：2003-09-16
申请号：US10083811
申请日：2002-02-27
申请人： Ulrike Röckrath , Peter Betz , Fritz Bartol , Georg Wigger , Hubert Baumgart
发明人： Ulrike Röckrath , Peter Betz , Fritz Bartol , Georg Wigger , Hubert Baumgart
IPC分类号： C08F830
CPC分类号： C09D175/04
摘要： A process for producing scratch-resistant coatings, especially scratch-resistant multicoat finishes, involving use of coating compositions which after curing have a storage modulus E′ in the rubber-elastic range of at least 107.5 Pa and a loss factor tan &dgr; at 20° C. of at least 0.05, the storage modulus E′ and the loss factor having been measured by dynamic mechanical thermoanalysis on free films having a film thickness of 40±10 &mgr;m, and comprise as binders one or more polyacrylate resins having a hydroxyl number of from 100 to 240, an acid number of from 0 to 35, and a number-average molecular weight of from 1500 to 10,000, and as crosslinkers one or more free or blocked isocyanates and/or triazine-based components which crosslink with the hydroxyl groups of the binder to form ether and/or ester structures.
摘要翻译：一种用于生产耐擦伤涂层的方法，特别是耐刮擦多孔涂层，涉及使用固化后的涂料组合物，其橡胶弹性范围中的储能模量E'至少为107.5Pa，损耗因子tanδ在20° C至少为0.05，储存模量E'和损耗因子已经通过动态机械热分析测量，膜厚度为40±10um的游离膜，并且包含作为粘合剂的一种或多种具有羟基数的聚丙烯酸酯树脂 100至240，酸值为0至35，数均分子量为1500至10,000，并且作为交联剂，与羟基交联的一种或多种游离或封闭的异氰酸酯和/或三嗪基组分的粘合剂以形成醚和/或酯结构。

4. 发明授权

US06410646B1 Method for producing scratch resistant coatings, especially for producing multi-layer enamels 失效
标题翻译：制备耐刮涂层的方法，特别是用于生产多层瓷漆
公开(公告)号：US06410646B1
公开(公告)日：2002-06-25
申请号：US09380524
申请日：1999-11-08
申请人： Ulrike Röckrath , Peter Betz , Fritz Bartol , Georg Wigger , Hubert Baumgart
发明人： Ulrike Röckrath , Peter Betz , Fritz Bartol , Georg Wigger , Hubert Baumgart
IPC分类号： C08F890
CPC分类号： C09D175/04
摘要： A process for producing scratch-resistant coatings, especially scratch-resistant multicoat finishes, involving use of coating compositions which, after curing, have a storage modulus E′ in the rubber-elastic range of at least 107.5 Pa and a loss factor tan&dgr; at 20° C. of at least 0.05, the storage modulus E′ and the loss factor having been measured by dynamic mechanical thermoanalysis on free films having a film thickness of 40±10 &mgr;m, and comprise as binders one or more polyacrylate resins having a hydroxyl number of from 100 to 240, an acid number of from 0 to 35, and a number-average molecular weight of from 1500 to 10,000, and as crosslinkers one or more free or blocked isocyanates and/or triazine-based components which crosslink with the hydroxyl groups of the binder to form ether and/or ester structures.
摘要翻译：一种用于生产耐刮擦涂层的方法，特别是耐刮擦多层涂饰，涉及使用涂料组合物，其在固化之后的橡胶弹性范围内的储能模量E'至少为107.5Pa，损耗因子tandelta为20 ℃至少为0.05，储存模量E'和损失因子已经通过动态机械热分析测量了膜厚度为40±10um的游离膜，并且包含作为粘合剂的一种或多种具有羟值的聚丙烯酸酯树脂为100至240，酸值为0至35，数均分子量为1500至10,000，并且作为交联剂，与羟基交联的一种或多种游离或封端的异氰酸酯和/或三嗪基组分组合的粘合剂以形成醚和/或酯结构。

5. 发明授权

US06943210B2 Pseudoplastic powdered lacquer slurry free of organic solvents method for production and the use thereof 失效
标题翻译：不含有机溶剂的假塑料粉末浆料，用于生产和使用
公开(公告)号：US06943210B2
公开(公告)日：2005-09-13
申请号：US10169699
申请日：2001-01-11
申请人： Ulrike Röckrath , Günther Ott , Jan Berg , Werner-Alfons Jung , Joachim Woltering
发明人： Ulrike Röckrath , Günther Ott , Jan Berg , Werner-Alfons Jung , Joachim Woltering
IPC分类号： B05D7/14 , B05D7/24 , C08G18/08 , C08G18/62 , C08G18/80 , C08J3/07 , C08L75/04 , C09D5/00 , C09D5/02 , C09D133/00 , C09D133/06 , C09D175/04 , C09D201/00 , C08J3/00 , C08F8/30 , C08F20/00 , C08K3/20 , C08L75/00
CPC分类号： C09D175/04 , C08G18/0866 , C08G18/6254 , C08G18/8025 , C08G18/807 , C08G2150/20 , C08J3/07 , C08L75/04 , C09D5/02 , C09D133/066 , C08L2666/14
摘要： A pseudoplastic powder clearcoat slurry which is free from organic solvents and comprises solid and/or highly viscous, particles which are dimensionally stable under storage and application conditions and have an average size of from 0.8 to 20 μm, at least 99% of the particles having a size ≦30 μm, which is preparable by 1) emulsifying an organic solution comprising binder and crosslinking agent to give an emulsion of the oil-in-water type, 2) removing the organic solvent or solvents, and 3) wet grinding the resulting slurry; and also the use of the powder clearcoat slurry to produce clearcoats for automotive OEM finishing and automotive refinish, for furniture coating and for industrial coating, including coil coating, container coating and the coating of electrical components.
摘要翻译：一种不含有机溶剂并含有固体和/或高粘度的颗粒的假塑性粉末透明涂料浆料，其在储存和使用条件下尺寸稳定，平均尺寸为0.8至20μm，至少99％的颗粒具有可以通过1）乳化含有粘合剂和交联剂的有机溶液得到水包油型的乳液，2）除去有机溶剂或溶剂，并且3）湿磨产生浆料; 并且还使用粉末清漆浆料来生产用于汽车OEM整理和汽车修补漆的清漆，用于家具涂料和用于工业涂料的清漆，包括卷材涂层，容器涂层和电气部件的涂覆。

6. 发明授权

US06652919B1 Highly scratch-resistant multilayer coat, method for producing and use of the same 失效
标题翻译：高耐刮擦多层涂层，其制造和使用方法
公开(公告)号：US06652919B1
公开(公告)日：2003-11-25
申请号：US09890760
申请日：2001-08-02
申请人： Donald H. Campbell , Hubert Baumgart , Thomas Farwick , Ulrike Röckrath
发明人： Donald H. Campbell , Hubert Baumgart , Thomas Farwick , Ulrike Röckrath
IPC分类号： C08G1810
CPC分类号： B05D7/574 , B05D7/577 , C09D175/04 , Y10T428/31551
摘要： A highly scratch-resistant multicoat paint system on a primed or unprimed substrate, comprising above one another in this order (A) a basecoat, (B) a first clearcoat as intermediate coat, and (C) a second clearcoat as the topmost coat, wherein the second clearcoat (C) is producible from a coating coating material (C) comprising (C1) at least one oligomer and/or polymer containing at least one pendant carbamate and/or allophanate group (c11), especially carbamate group (c11), of the formula: —O—(CO)—NH2—O—(CO)—NH—(CO)—NH2 and (C2) at least one crosslinking agent containing at least two functional groups (c21) which undergo crosslinking reactions with the carbamate group and/or allophanate group (c11); and also a process for producing highly scratch-resistant multicoat systems.
摘要翻译：在底漆或未底漆基材上的高度耐刮擦的多色漆系统，其顺序包括（A）底漆，（B）第一透明涂层作为中间涂层，和（C）作为最上层涂层的第二透明涂层，其中所述第二透明涂层（C）可由包含（C1）至少一种含有至少一个氨基甲酸酯和/或脲基甲酸酯基（c11），特别是氨基甲酸酯基（c11）的至少一种低聚物和/或聚合物的涂层涂料（C），和（C2）至少一种含有至少两个与氨基甲酸酯基和/或脲基甲酸酯基团（c11）发生交联反应的官能团（c21）的交联剂;以及用于生产高耐划伤性的方法多点系统

7. 发明授权

US07022748B2 Aqueous dispersions, which can be hardened thermally and by using actinic radiation, method for the production thereof and their use 失效
标题翻译：水分散体，其可以热和通过使用光化辐射固化，其制备方法及其用途
公开(公告)号：US07022748B2
公开(公告)日：2006-04-04
申请号：US10468886
申请日：2002-03-21
申请人： Guido Wilke , Ulrike Röckrath
发明人： Guido Wilke , Ulrike Röckrath
IPC分类号： C08L75/04 , C08L75/14 , C09D175/04 , C09J175/04 , C08J3/03
CPC分类号： C09D175/16 , C08G18/6254 , C08G18/7837 , C08G18/807 , C08G18/8175 , C08G2150/20
摘要： Aqueous dispersions curable thermally and with actinic radiation, comprising (I) liquid, and/or highly viscous solid particles dimensionally stable under storage and application conditions, comprising (IA) a binder free of carbon-carbon double bonds activatable with actinic radiation, comprising at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group and at least one dispersive functional group, and (IB) at least one blocked polyisocyanate; (II) liquid, highly viscous and/or solid particles dimensionally stable under storage and application conditions, comprising at least one polyurethane (II) containing at least one isocyanate-reactive functional group, at least one functional group having at least one bond activatable with actinic radiation, and at least one dispersive functional group, and (III) at least one unsaturated constituent which is free of isocyanate-reactive functional groups and contains on average per molecule more than one carbon-carbon double bond activatable with actinic radiation; processes for preparing them, and their use.
摘要翻译：包括（I）在储存和使用条件下尺寸稳定的（I）液体和/或高粘度固体颗粒的水分散体，其包含（IA）不含可活化光化辐射的碳 - 碳双键的粘合剂，其包含：至少一种平均每分子含有至少一个异氰酸酯反应性官能团和至少一个分散官能团的（甲基）丙烯酸酯共聚物，和（IB）至少一种封端多异氰酸酯; （II）在储存和使用条件下尺寸稳定的液体，高粘度和/或固体颗粒，包含至少一种含有至少一个异氰酸酯反应性官能团的聚氨酯（II），至少一个具有至少一个能与光化辐射和至少一种分散官能团，和（III）至少一种不含异氰酸酯反应性官能团的不饱和组分，并且每分子平均含有多于一个可用光化辐射活化的碳 - 碳双键; 制备它们的过程及其用途。

8. 发明授权

US06818303B2 Powder clearcoat dispersions (powder slurry clearcoats), method for producing them and the use thereof 失效
标题翻译：粉末透明涂料分散体（粉末浆料清漆），其制造方法及其用途
公开(公告)号：US06818303B2
公开(公告)日：2004-11-16
申请号：US10296029
申请日：2002-11-19
申请人： Walter Lassmann , Horst Hintze-Brüning , Wolfgang Bremser , Ulrike Röckrath
发明人： Walter Lassmann , Horst Hintze-Brüning , Wolfgang Bremser , Ulrike Röckrath
IPC分类号： B32B2718
CPC分类号： B05D7/572 , B05D7/577 , C09D5/02 , C09D7/47 , Y10S524/904 , Y10T428/31504
摘要： Powder clearcoat dispersions (powder slurry clearcoats) preparable by dispersing a powder clearcoat in an aqueous medium and wet milling the resulting powder slurry, at least one adduct of ethylene oxide and/or propylene oxide with at least one glycol being added to the powder slurry prior to wet milling; and the use of the powder slurry clearcoats for producing clearcoat finishes, especially as part of multicoat color and/or effect finishes.
摘要翻译：通过将粉末透明涂料分散在水性介质中并湿法研磨所得粉末浆料，将至少一种环氧乙烷和/或环氧丙烷的加合物与至少一种二醇加入到粉末浆料中，可制备粉末透明涂料分散体（粉末浆料透明涂层）湿磨; 以及使用粉末浆料清漆来生产透明涂层，特别是作为多色彩和/或效果整理的一部分。

9. 发明授权

US06624280B1 OLIGOMERIC AND HIGH-MOLECULAR CONVERSION PRODUCTS OF ALLOPHANIC ACID ESTERS WITH NUCLEOPHILIC COMPOUNDS AND LOW-MOLECULAR, OLIGOMERIC AND HIGH-MOLECULAR COMPOUNDS WITH ALLOPHANATE SIDE AND/OR TERMINAL GROUPS, AND THE USE THEREOF 有权
标题翻译：具有单核酸化合物和低分子量，低分子量和高分子量化合物与异丙醇侧和/或末端基团的异戊酸酯的低分子和高分子转化产物及其用途
公开(公告)号：US06624280B1
公开(公告)日：2003-09-23
申请号：US09762121
申请日：2001-03-02
申请人： Heinz-Peter Rink , Werner Jung , Ulrike Röckrath , Thomas Savino
发明人： Heinz-Peter Rink , Werner Jung , Ulrike Röckrath , Thomas Savino
IPC分类号： C08G1810
CPC分类号： C07C275/60 , C08G12/44 , C08G18/3819 , C09D161/32 , C09K3/1021
摘要： Oligomeric and high molecular mass products of reaction of alkyl and aryl allophanates with nucleophilic compounds, and also low molecular mass, oligomeric and high molecular mass compounds containing lateral and/or terminal allophanate groups, and also the use of the reaction products and/or of the compounds in coating compositions, adhesives and sealing compounds or for producing films.
摘要翻译：烷基和芳基脲基甲酸酯与亲核化合物的反应的低分子量和高分子量产物，以及含有侧基和/或末端脲基甲酸酯基团的低分子量，低聚物和高分子量化合物，以及反应产物和/或涂料组合物，粘合剂和密封化合物中的化合物或用于生产膜。

10. 发明授权

US07132472B2 Intrinsically-viscous clear-lacquer slurry, method for production and use thereof 有权
标题翻译：本质粘稠的清漆浆料，其生产方法和用途
公开(公告)号：US07132472B2
公开(公告)日：2006-11-07
申请号：US10479918
申请日：2002-07-23
申请人： Joachim Woltering , Fatmir Raka , Ulrike Röckrath , Ute Schumacher
发明人： Joachim Woltering , Fatmir Raka , Ulrike Röckrath , Ute Schumacher
IPC分类号： C08L31/02 , C08L33/02
CPC分类号： C09D133/10 , C08G18/6254 , C08G18/807 , C08G2190/00 , C09D175/04 , C09J133/10
摘要： A pseudoplastic clearcoat slurry comprising solid and/or highly viscous particles which are dimensionally stable under storage and application conditions and which comprise as binders methacrylate copolymers containing in copolymerized form, based on a given methacrylate copolymer, at least 90% by weight of methacrylate comonomers, including (meth)acrylate comonomers having potentially ionic groups; process for preparing it, and its use.
摘要翻译：包含在储存和使用条件下尺寸稳定的固体和/或高粘度颗粒的假塑性透明浆料浆料，其包含作为粘合剂的甲基丙烯酸酯共聚物，所述甲基丙烯酸酯共聚物以共聚形式，基于给定的甲基丙烯酸酯共聚物，至少90重量％的甲基丙烯酸酯共聚单体，包括具有潜在离子基团的（甲基）丙烯酸酯共聚单体; 其准备过程及其使用。

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