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1. 发明授权

US07141537B2 Mixture of fluorinated polyethers and use thereof as surfactant 失效
标题翻译：氟化聚醚的混合物及其作为表面活性剂的用途
公开(公告)号：US07141537B2
公开(公告)日：2006-11-28
申请号：US10696950
申请日：2003-10-30
申请人： Frans A. Audenaert , Rudolf J. Dams , Lian S. Tan
发明人： Frans A. Audenaert , Rudolf J. Dams , Lian S. Tan
IPC分类号： C11D17/00
CPC分类号： C08G65/007 , C08G65/08 , C08G65/329 , C08L71/00 , C08L71/02
摘要： The present invention provides the use of a fluorinated polyether composition as a surfactant, said fluorinated polyether composition comprising a mixture of fluorinated polyethers of the formula: (Rf)n—Xw—Z (I) wherein n is 1 or 2, w is 0 or 1, X is a divalent or trivalent organic linking group, Z is a polar group selected from the group consisting of an acid group or a salt thereof, an ammonium group, an amine-oxide group and an amphoteric group, and Rf represents a perfluorinated polyether group of the formula: CF3CF2CF2—O—[CF(CF3)CF2O]k—CF(CF3)— wherein k is at least 1; said mixture of fluorinated polyethers having a weight average molecular weight between 750 g/mol and 5000 g/mol and the amount of perfluorinated polyether groups in said mixture where k is 2 or less, is not more than 10% by weight of the total amount of perfluorinated polyether groups in said mixture.
摘要翻译：本发明提供氟化聚醚组合物作为表面活性剂的用途，所述氟化聚醚组合物包含下列化学式的氟化聚醚的混合物：<？in-line-formula description =“In-line Formulas”end =“lead”？（R>）））-X -X -X w w w <<<<<<<<<<<<<<<<<<<<<<<<<<<“”“”“”“”“”“”“”“ 其中n为1或2，w为0或1，X为二价或三价有机连接基团，Z为选自酸基或其盐的极性基团，铵基团，氧化胺基团和两性基团，R f表示下式的全氟化聚醚基团：<？in-line-formula description =“In-line Formulas”end =“ CF 3 CF 3 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 3 > 2 -CF（CF 3） - <？in-line-formula description =“In-line Formulas”end =“tail” 其中k至少为1; 所述重均分子量在750g / mol至5000g / mol之间的所述氟化聚醚的混合物和所述混合物中的全氟化聚醚基团的量不超过总量的10重量％的全氟化聚醚基团。

2. 发明授权

US07722955B2 Flooring substrate having a coating of a curable composition 有权
标题翻译：具有可固化组合物涂层的地板基材
公开(公告)号：US07722955B2
公开(公告)日：2010-05-25
申请号：US11279657
申请日：2006-04-13
申请人： Frans A. Audenaert , Rudolf J. Dams , Zai-Ming Qiu , Naiyong Jing , Thomas P. Klun
发明人： Frans A. Audenaert , Rudolf J. Dams , Zai-Ming Qiu , Naiyong Jing , Thomas P. Klun
IPC分类号： B32B27/40
CPC分类号： C08G18/2885 , C08F283/00 , C08F283/006 , C08F283/06 , C08G18/3812 , C08G18/673 , C08G18/7831 , C08G18/792 , C08L2312/00 , C09D133/14 , C09D175/16 , Y10T428/31544 , Y10T428/31551
摘要： A flooring substrate comprising a coating of a curable composition that comprises (a) a reaction product of (i) a polyisocyanate, (ii) one or more perfluoropolyether compounds having at least one hydroxyl group and (iii) an organic compound having one or more free radical polymerizable groups and at least one hydroxyl group; and (b) a compound capable of free radical copolymerization with the reaction product and comprising at least two free radical polymerizable groups.
摘要翻译：一种地板基材，其包含可固化组合物的涂层，其包含（a）（i）多异氰酸酯，（ii）一种或多种具有至少一个羟基的全氟聚醚化合物的反应产物和（iii）具有一个或多个自由基聚合性基团和至少一个羟基; 和（b）能够与反应产物自由基共聚并包含至少两个自由基可自由基团的化合物。

3. 发明授权

US07214736B2 Fluorochemical composition for treatment of a fibrous substrate 有权
标题翻译：用于处理纤维基材的氟化合物组合物
公开(公告)号：US07214736B2
公开(公告)日：2007-05-08
申请号：US10444713
申请日：2003-05-23
申请人： Frans A. Audenaert , Rudolf J. Dams , Richard S. Buckanin , Cheryl L. S. Elsbernd , Chetan P. Jariwala , E. Steven McAlister , Pierre J. Vander Elst
发明人： Frans A. Audenaert , Rudolf J. Dams , Richard S. Buckanin , Cheryl L. S. Elsbernd , Chetan P. Jariwala , E. Steven McAlister , Pierre J. Vander Elst
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08G18/28 , B05D3/04
CPC分类号： C08G18/3876 , C08G18/2825 , C08G18/283 , C08G18/2885 , C08G18/3812 , C08G18/3857 , C08G18/3861 , C08G18/4833 , C08G18/5015 , C08G18/6212 , C08G18/71 , C08G18/792 , D06M15/53 , D06M15/576 , Y10T442/172 , Y10T442/198 , Y10T442/20 , Y10T442/2189
摘要： Fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain or soil repellent. The composition comprises a dispersion or a solution of a fluorinated compound which comprises the reaction product of the following combination of reactants: (i) a fluorinated polyether according to the formula: Rf—Q—Tk (I) wherein Rf represents a monovalent perfluorinated polyether group having a molecular weight of at least 750 g/mol, Q represents a chemical bond or a divalent or trivalent organic linking group, T represents a functional group capable of reacting with an isocyanate and k is 1 or 2; (ii) an isocyanate component selected from a polyisocyanate compound that has at least 3 isocyanate groups or a mixture of polyisocyanate compounds wherein the average number of isocyanate groups per molecule is more than 2; and (iii) optionally one or more co-reactants capable of reacting with an isocyanate group.
摘要翻译：用于使纤维基质防油，防水和/或染色或防污的氟化合物。该组合物包含含氟化合物的分散体或溶液，其包含以下反应物组合的反应产物：（i）根据下式的含氟聚醚：<？in-line-formula description =“In-Line Formulas” end =“lead”？？？？？？？？？？？？？？？？？？？？？？？？？？？？在线公式描述=“内联公式”end =“tail”？其中R≠表示分子量为至少750g / mol的一价全氟化聚醚基团，Q表示化学键或二价或三价有机连接基团，T表示可以与异氰酸酯反应，k为1或2; （ii）选自具有至少3个异氰酸酯基团的多异氰酸酯化合物的异氰酸酯成分或每分子的异氰酸酯基平均数大于2的多异氰酸酯化合物的混合物; 和（iii）任选的一种或多种能够与异氰酸酯基反应的共反应物。

4. 发明授权

US07094829B2 Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith 有权
标题翻译：含氟化合物的氟化合物组合物和其纤维基质的处理
公开(公告)号：US07094829B2
公开(公告)日：2006-08-22
申请号：US10444878
申请日：2003-05-23
申请人： Frans A. Audenaert , Rudolf J. Dams , Richard S. Buckanin
发明人： Frans A. Audenaert , Rudolf J. Dams , Richard S. Buckanin
IPC分类号： C08K3/00
CPC分类号： C08G65/007 , C08G2650/48 , C08L71/02 , C08L2205/05 , D06M15/256 , D06M15/277 , D06M15/295 , D06M15/568 , D06M15/576 , D06M2200/01 , D06M2200/10 , D06M2200/11 , D06M2200/12 , C08L2666/22
摘要： A fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain repellent and comprising a fluorinated polymer dispersed in water or dissolved or dispersed in an organic solvent, the fluorinated polymer comprising units derived from (i) a mixture of two or more fluorinated polyether monomers that differ in at least their molecular weight, the fluorinated polyether monomers having an ethylenically unsaturated group and a perfluorinated polyether group and wherein at least 90% by weight of the mixture consists of fluorinated polyether monomers that have a perfluorinated polyether group having a molecular weight of at least 750 g/mol and (ii) one or more units derived from one or more co-monomers other than a fluorinated polyether monomer and wherein the co-monomers comprise at least one non-fluorinated monomer. Also, method for treating fibrous substrate with such composition, fluorinated polyether monomers, and fluorinated polymers derived from such monomers.
摘要翻译：一种氟化合物，用于使纤维基质具有防油性，防水性和/或防污性，并且包含分散在水中或溶解或分散在有机溶剂中的氟化聚合物，所述氟化聚合物包含衍生自（i）两种或至少其分子量不同的氟化聚醚单体，具有烯属不饱和基团的氟化聚醚单体和全氟化聚醚基团，其中至少90重量％的混合物由具有全氟化聚醚基团的氟化聚醚单体组成，至少750g / mol的分子量和（ii）一种或多种衍生自除氟化聚醚单体之外的一种或多种共聚单体的单元，其中共聚单体包含至少一种非氟化单体。此外，用这种组合物处理纤维基材的方法，氟化聚醚单体和衍生自这些单体的氟化聚合物。

5. 发明授权

US08663741B2 Method for treating wheel rims and composition for use therein 有权
标题翻译：用于处理轮辋和组合物的方法
公开(公告)号：US08663741B2
公开(公告)日：2014-03-04
申请号：US13062233
申请日：2009-09-23
申请人： Rudolf J. Dams , Bernd Kuehneweg , Leonardus Doelen , Frank Koehler , Christoph Furtak , Frans A. Audenaert
发明人： Rudolf J. Dams , Bernd Kuehneweg , Leonardus Doelen , Frank Koehler , Christoph Furtak , Frans A. Audenaert
IPC分类号： B05D3/02
CPC分类号： C08G77/458 , C08G77/442 , C08L83/10 , C09D4/00 , C09D183/10 , C08L83/00
摘要： There is provided a method of treatment including (i) applying a treatment composition to at least a portion of the surface of a wheel rim and (ii) allowing a thus applied treatment composition to cure. There is also provided compounds and compositions useful in the method.
摘要翻译：提供了一种处理方法，包括（i）将处理组合物施加到轮缘表面的至少一部分，和（ii）允许如此施加的处理组合物固化。还提供了在该方法中有用的化合物和组合物。

6. 发明申请

US20110189404A1 METHOD FOR TREATING WHEEL RIMS AND COMPOSITION FOR USE THEREIN 有权
标题翻译：用于处理轮胎的方法和用于其的组合物
公开(公告)号：US20110189404A1
公开(公告)日：2011-08-04
申请号：US13062233
申请日：2009-09-23
申请人： Rudolf J. Dams , Bernd Kuehneweg , Leonardus Doelen , Frank Koehler , Christoph Furtak , Frans A. Audenaert
发明人： Rudolf J. Dams , Bernd Kuehneweg , Leonardus Doelen , Frank Koehler , Christoph Furtak , Frans A. Audenaert
IPC分类号： B05D3/10 , C08F30/08 , C09D183/04
CPC分类号： C08G77/458 , C08G77/442 , C08L83/10 , C09D4/00 , C09D183/10 , C08L83/00
摘要： There is provided a method of treatment including (i) applying a treatment composition to at least a portion of the surface of a wheel rim and (ii) allowing a thus applied treatment composition to cure. There is also provided compounds and compositions useful in the method.
摘要翻译：提供了一种处理方法，包括（i）将处理组合物施加到轮缘表面的至少一部分，和（ii）允许如此施加的处理组合物固化。还提供了在该方法中有用的化合物和组合物。

7. 发明申请

US20090149616A1 FLUORINATED SURFACTANTS 审中-公开
标题翻译：氟化表面活性剂
公开(公告)号：US20090149616A1
公开(公告)日：2009-06-11
申请号：US12095205
申请日：2006-11-22
申请人： Frans A. Audenaert , Rudolf J. Dams
发明人： Frans A. Audenaert , Rudolf J. Dams
IPC分类号： C08F14/18
CPC分类号： C08F214/18 , C08F290/062 , C08J3/03 , C08J2351/08
摘要： The present invention provides a fluorinated surfactant comprising fluorinated units and hydrophilic non-fluorinated units wherein said fluorinated surfactant can be obtained by(i) a free radical polymerization of: (a) one or more fluorinated monomers having the general formula (I): (Rf)n—X—C(R1)═CH2 (I) wherein Rf represents a perfluorinated polyether group, X represents a bond or a linking group, R1 represents a hydrogen atom or an alkyl group of 1 to 4 carbon atoms, and n is 1 or 2; and (b) at least one non-fluorinated monomer having at least one hydrophilic group or a precursor thereof; and (ii) conversion of said precursor when present, into a corresponding hydrophilic group.
摘要翻译：本发明提供含氟单体和亲水性非氟化单元的含氟表面活性剂，其中所述氟化表面活性剂可以通过以下方法获得：（i）自由基聚合：（a）一种或多种具有通式（I）的氟化单体：（在线公式）end =“lead”？>（Rf）nXC（R1）-CH2（I）<？in-line-formula description =“In-line Formulas”end = “尾”→其中Rf表示全氟化聚醚基团，X表示键或连接基团，R 1表示氢原子或碳原子数1〜4的烷基，n为1或2; 和（b）至少一种具有至少一个亲水基团的非氟化单体或其前体; 和（ii）当存在时所述前体的转化成相应的亲水基团。

8. 发明授权

US06440321B1 Mixed fluorochemical hydrocarbon condensates to impart oil and water repellency to a substrate 失效
标题翻译：混合的含氟烃缩合物以赋予基底油和拒水性
公开(公告)号：US06440321B1
公开(公告)日：2002-08-27
申请号：US09381572
申请日：1999-09-17
申请人： Frans A. Audenaert , Dirk M. Coppens , Rudolf J. Dams
发明人： Frans A. Audenaert , Dirk M. Coppens , Rudolf J. Dams
IPC分类号： C08G1240
CPC分类号： D06M15/437 , C08G12/40 , D06M15/423 , D06M15/429 , D06M2200/11 , D06M2200/12
摘要： A fluorochemical composition to impart water repellency and/or oil repellency to a substrate, the composition comprising one or more condensates of (i) a methylolated amine or a C1-C4 alkoxylated derivative thereof, (ii) a hydrocarbon compound represented by formula (II) and (iii) a fluorinated compound represented by formula (I): Rf—(X1)n—Z1 (I) wherein: Rf is a fluorinated aliphatic group; X1 is an organic divalent linking group; Z1 is selected from the group consisting of hydroxy, thiol, amide or acid groups; and n is 0 or 1; and Rh—Z2 (II) wherein: Rh is a hydrocarbon group having at least 6 carbon atoms and optionally being substituted with 1 to 3 subsituents; Z2 is selected from the group consisting of hydroxy, thiol, amide or acid groups. The invention further provides a method of treatment of a substrate with the fluorochemical composition and a treated substrate.
摘要翻译：一种含氟化合物，其对基质赋予拒水性和/或拒油性，所述组合物包含一种或多种（i）羟甲基化胺或其C1-C4烷氧基化衍生物的缩合物，（ii）由式（II）表示的烃化合物）和（iii）由式（I）表示的氟化化合物：其中：Rf是氟化脂肪族基团; X1是有机二价连接基团; Z1选自羟基，硫醇，酰胺或酸基; 并且n为0或1; 并且其中：Rh是具有至少6个碳原子并且任选地被1至3个取代基取代的烃基; Z2选自羟基，硫醇，酰胺或酸基。本发明还提供了一种用含氟化合物组合物和经处理的底物处理底物的方法。

9. 发明授权

US5466770A Fluorine-efficient oil- and water-repellent compositions 失效
标题翻译：氟化防油防水组合物
公开(公告)号：US5466770A
公开(公告)日：1995-11-14
申请号：US249798
申请日：1994-05-26
申请人： Frans A. Audenaert , Rudolf J. Dams , Robert F. Kamrath
发明人： Frans A. Audenaert , Rudolf J. Dams , Robert F. Kamrath
IPC分类号： C09K3/18 , C08G18/30 , C08G18/72 , C09D5/00 , C09D133/14 , C09D133/16 , D06M15/19 , D06M15/277 , D06M15/356 , D06M15/564 , D06M15/576 , D06N3/04 , D06N3/14
CPC分类号： D06M15/576 , C08G18/302 , C08G18/728 , D06M15/19 , D06M15/277 , D06M15/3562 , D06M15/564 , D06N3/047 , D06N3/14 , Y10T428/3154 , Y10T428/31551 , Y10T428/31573 , Y10T428/3158 , Y10T428/31583 , Y10T442/2172
摘要： The invention provides new fluorine-efficient oil- and water-repellent compositions comprising a fluorochemical oil- and water-repellent agent and a polymer extender comprising at least one percent by weight based on the weight of the extender of interpolymerized units derived from monomers containing at least one blocked or masked isocyanate function.
摘要翻译：本发明提供了新的含氟化学防油疏水剂和含氟化合物防水防水剂的组合物和聚合物增量剂，其包含至少1重量％，基于来自含有至少一种封闭或掩蔽的异氰酸酯官能团。

10. 发明授权

US09290619B2 Triazine containing fluoropolyether elastomers having low glass transition temperature 有权
标题翻译：具有低玻璃化转变温度的含氟聚醚弹性体的三嗪
公开(公告)号：US09290619B2
公开(公告)日：2016-03-22
申请号：US14003141
申请日：2012-02-24
申请人： Miguel A. Guerra , Rudolf J. Dams , Steven G. Corveleyn
发明人： Miguel A. Guerra , Rudolf J. Dams , Steven G. Corveleyn
IPC分类号： C08G67/02 , C08K5/16 , B01J8/36 , C08G73/24 , C08G65/00 , C08L71/00
CPC分类号： C08G65/00 , C08G65/007 , C08G2650/48 , C08L71/00
摘要： There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.
摘要翻译：提供了一种可固化组合物，其包含：a）具有约400g / mol至约20,000g / mol的分子量的含氟聚醚，并且含有选自（ - （CF 2）4 O-），（ - （CF 2）），（-CF 2 O-）或其组合，并且在末端位置或与末端位置相邻的位置还含有至少一个腈基; 和b）一种或多种选自含有一个或多个与普通残基连接的官能团的非氟化合物的固化剂，所述残基含有至少三个碳原子，其中官能团选自伯胺，仲胺和官能团，其中在热处理时产生伯胺或仲胺，其中组合物可以通过产生具有三嗪结构的基团来固化。还提供固化组合物，固化组合物的制备方法，固化组合物固化的制品以及使用该可固化组合物制造制品的方法。

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