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1. 发明授权

US06727395B1 Method for producing hexanediol 失效
标题翻译：己二醇的制备方法
公开(公告)号：US06727395B1
公开(公告)日：2004-04-27
申请号：US10018338
申请日：2001-12-19
申请人： Frank Stein , Thomas Krug , Thomas Nöbel , Harald Rust
发明人： Frank Stein , Thomas Krug , Thomas Nöbel , Harald Rust
IPC分类号： C07C2700
CPC分类号： C07C29/149 , C07C31/20
摘要： A process for preparing 1,6-hexanediol from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol after water extraction of the reaction mixture followed by extraction with aqueous sodium hydroxide solution, by esterification of the acids and hydrogenation comprises a) liberating the carboxylic acids from the alkaline extract by addition of a mineral acid, b) fractionating the organic phase comprising carboxylic acids to give a distillate comprising the low molecular weight monocarboxylic acids and a residue comprising adipic acid and 6-hydroxycaproic acid, c) reacting the monocarboxylic an dicarboxylic acids present in the aqueous dicarboxylic acid mixture with a low molecular weight alcohol to give the corresponding carboxylic esters, d) freeing the esterification mixture obtained of excess alcohol and low boilers in a first distillation step, e) fractionating the bottom product in a second distillation step to give an ester fraction essentially free of 1,4-cyclohexanediols and a fraction comprising at least the major part of the 1,4-cyclohexanediols, f) catalytically hydrogenating the ester fraction which is essentially free of 1,4-cyclohexanediols and g) isolating 1,6-hexanediol from the hydrogenation product in a manner known per se in a final distillation step.
摘要翻译：从包含己二酸，6-羟基己酸和少量1,4-环己二醇的羧酸混合物制备1,6-己二醇的方法，其在水提取后在环己烷氧化成环己酮/环己醇时作为副产物获得的反应混合物，然后用氢氧化钠水溶液萃取，通过酸的酯化和氢化反应，包括a）通过加入无机酸从碱性提取物中释放出羧酸，b）将包含羧酸的有机相分馏得到馏出物包括低分子量单羧酸和包含己二酸和6-羟基己酸的残基，c）使一元羧酸与二羧酸混合物中存在的二羧酸与低分子量醇反应，得到相应的羧酸酯，d）释放在第一馏出物中获得过量酒精和低锅炉的酯化混合物 e步骤，e）在第二蒸馏步骤中分馏底部产物，得到基本上不含1,4-环己烷二醇的酯馏分和至少包含大部分1,4-环己烷二醇的馏分，f）催化氢化酯基本上不含1,4-环己烷二醇的馏分，和g）在最终蒸馏步骤中以本身已知的方式从氢化产物中分离出1,6-己二醇。

2. 发明授权

US07329330B2 Method and device for the distillative processing of 1,6-hexanediol, 1,5-pentanediol and caprolactone 有权
标题翻译： 1,6-己二醇，1,5-戊二醇和己内酯的蒸馏加工方法和装置
公开(公告)号：US07329330B2
公开(公告)日：2008-02-12
申请号：US10451738
申请日：2002-01-08
申请人： Martin Gall , Gerd Kaibel , Thomas Krug , Harald Rust , Frank Stein
发明人： Martin Gall , Gerd Kaibel , Thomas Krug , Harald Rust , Frank Stein
IPC分类号： B01D3/14 , B01D3/42 , C07C29/80
CPC分类号： C07D315/00 , B01D3/14 , B01D3/141 , C07C29/80 , Y10S203/20 , C07C31/26 , C07C31/20
摘要： A process for working up by distillation the crude products obtained in the process according to DE-A 196 07 954 and containing 1,6-hexanediol (HDO), 1,5-pentanediol (PDO) or caprolactone (CLO) in order to obtain the corresponding pure products, the working-up by distillation being carried out in each case in a dividing wall column (TK) in which a dividing wall (T) is arranged in the longitudinal direction of the column with formation of an upper common column region (1), a lower common column region (6), a feed section (2, 4) having a rectification section (2) and stripping section (4), and a take-off section (3, 5) having a stripping section (3) and rectification section (5), with feeding of the respective crude product HDO, PLO or CLO in the middle region of the feed section (2, 4) and removal of the high boiler fraction (C) from the bottom of the column, of the low boiler fraction (A) via the top of the column and of the medium boiler fraction (B) from the middle region of the take-off section (3, 5), or in thermally coupled columns.
摘要翻译：通过蒸馏处理根据DE-A 196 07954的方法获得的含有1,6-己二醇（HDO），1,5-戊二醇（PDO）或己内酯（CLO）的粗产物的方法，以获得相应的纯产品，在各种情况下在分隔壁塔（TK）中进行蒸馏处理，其中分隔壁（T）沿塔的纵向方向排列，形成上共同区域（1），较低的公共列区域（6），具有整流部分（2）和汽提部分（4）的进料部分（2,4）和具有汽提部分的取出部分（3,5）（3）和整流部分（5），在进料部分（2,4）的中间区域供给相应的粗产物HDO，PLO或CLO，并将高沸点馏分（C）从底部通过塔顶和中间锅炉馏分（B）从中间排出低沸点馏分（A）起飞段（3,5）的区域，或热耦合柱。

3. 发明授权

US06288286B1 Method for producing hexanediol-1,6 失效
标题翻译：己二醇-1,6-
公开(公告)号：US06288286B1
公开(公告)日：2001-09-11
申请号：US09700366
申请日：2000-11-15
申请人： Frank Stein , Thomas Krug , Martin Gall , Gabriele Iffland
发明人： Frank Stein , Thomas Krug , Martin Gall , Gabriele Iffland
IPC分类号： C07C2700
CPC分类号： C07C29/149 , C07C2601/14 , C07C31/20 , C07C35/08
摘要： A process for preparing 1,6-hexanediol from a carboxylic acid mixture obtained as by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol with oxygen or oxygen-comprising gases and by aqueous extraction of the reaction mixture and comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols by esterification of the acids and hydrogenation, by a) reacting the mono- and dicarboxylic acids in the aqueous dicarboxylic acid mixture with a low molecular weight alcohol to form the corresponding carboxylic esters, b) conducting a first distillation to remove excess alcohol and low boilers from the esterification mixture obtained, c) conducting a second distillation to separate the bottom product into an ester fraction which is essentially free from 1,4-cyclohexanediols and a fraction which includes at least the larger proportion of the 1,4-cyclohexanediols, d) subjecting the ester fraction essentially free from 1,4-cyclohexanediols to a catalytic hydrogenation, and e) subjecting the hydrogenation effluent to a distillation to recover 1,6-hexanediol in a conventional manner, comprises using an aqueous dicarboxylic acid mixture comprising more than 20 ppm of cobalt and more than 40 ppm of phosphorus in the form of phosphate and passing this aqueous dicarboxylic acid mixture through a cation exchanger and after the esterification of step (a) through an anion exchanger.
摘要翻译：从环己烷氧化成环己酮/环己醇与氧气或含氧气体的副产物得到的羧酸混合物中制备1,6-己二醇的方法，并通过水提取反应混合物，并包含己二酸，6- 羟基己酸和少量的1,4-环己烷二醇通过酸的酯化和氢化，a）使二羧酸二羧酸混合物与低分子量醇反应形成相应的羧酸酯，b）导电从所得到的酯化混合物中除去多余的醇和低沸点物的第一次蒸馏，c）进行第二次蒸馏以将底部产物分离成基本上不含1,4-环己烷二醇的酯馏分和至少包括较大的 1,4-环己烷二醇的比例，d）将基本上不含1,4-环己烷二醇的酯馏分进行催化水解国家和地区）使氢化流出物以常规方式进行蒸馏以回收1,6-己二醇，包括使用包含大于20ppm钴的多余二羧酸混合物和大于40ppm磷酸盐形式的磷，使该含水二羧酸混合物通过阳离子交换剂，并且在步骤（a）通过阴离子交换剂酯化之后。

4. 发明申请

US20120271068A1 REACTION OF GLYCOLALDEHYDE WITH AN AMINATING AGENT 有权
标题翻译：甘氨酸与氨基化剂的反应
公开(公告)号：US20120271068A1
公开(公告)日：2012-10-25
申请号：US13516479
申请日：2010-12-14
申请人： Wolfgang Mägerlein , Johann-Peter Melder , Jörg Pastre , Jan Eberhardt , Thomas Krug , Mirko Kreitschmann
发明人： Wolfgang Mägerlein , Johann-Peter Melder , Jörg Pastre , Jan Eberhardt , Thomas Krug , Mirko Kreitschmann
IPC分类号： C07C213/02
CPC分类号： C07C209/26 , C07C213/00 , C07C215/08 , C07C211/10
摘要： The present invention relates to a process for reacting glycolaldehyde with an aminating agent in the presence of hydrogen and of a catalyst, the catalyst being activated by reducing a catalyst precursor or by reducing a passivated catalyst, which comprises effecting the reaction in the presence of a solvent and contacting the glycolaldehyde with the activated catalyst.
摘要翻译：本发明涉及一种在氢气和催化剂存在下使乙醇醛与胺化剂反应的方法，该催化剂通过还原催化剂前体而被还原或通过还原钝化的催化剂来活化，其包括在存在下进行反应溶剂并使乙醇醛与活化的催化剂接触。

5. 发明授权

US08247580B2 Process for preparing ε-caprolactone 有权
标题翻译：己内酯的制备方法
公开(公告)号：US08247580B2
公开(公告)日：2012-08-21
申请号：US12741383
申请日：2008-10-28
申请人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
发明人： Rolf Pinkos , Gerd-Dieter Tebben , Thomas Krug , Tilman Sirch , Todd C Spengeman , Stephanie A. Bejune , Jeffrey T. Andress , Todd Gasiorowski
IPC分类号： C07D313/00
CPC分类号： C07D313/04
摘要： The present invention provides a process for preparing ε-caprolactone in a purity of more than 99% by cyclizing 6-hydroxycaproic esters in the liquid phase at from 150 to 400° C. and from 1 to 1020 hPa abs., and removing and condensing the compounds which are volatile under cyclization conditions, which comprises thermally treating the remaining bottom product of the cyclization in at least one further reactor, removing and condensing volatile compounds and obtaining ε-caprolactone by distillation from the condensates.
摘要翻译：本发明提供了通过在150至400℃和1至1020hPa绝对压力下使液相中的6-羟基己酸酯环化来制备纯度大于99％的己内酯的方法，冷凝在环化条件下挥发的化合物，其包括在至少一个另外的反应器中热处理剩余的环化的底部产物，除去和冷凝挥发性化合物，并通过从冷凝物蒸馏获得ε-己内酯。

6. 发明授权

US08163139B2 Process for the distillative separation of mixtures comprising monoethylene glycol and diethylentriamine 有权
标题翻译：用于蒸馏分离包含单乙二醇和二乙基三胺的混合物的方法
公开(公告)号：US08163139B2
公开(公告)日：2012-04-24
申请号：US12279372
申请日：2007-02-08
申请人： Karin Pickenäcker , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Gunther van Cauwenberge , Frank-Friedrich Pape
发明人： Karin Pickenäcker , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Gunther van Cauwenberge , Frank-Friedrich Pape
IPC分类号： B01D3/34 , B01D3/00
CPC分类号： C07C209/86 , C07C211/14
摘要： Processes comprising: providing a mixture comprising monoethylene glycol and diethylenetriamine; and subjecting the mixture to extractive distillation with a diethylenetriamine-selective solvent comprising triethylene glycol to provide a first stream comprising monoethylene glycol and a second stream comprising diethylenetriamine; wherein the first stream is substantially free of diethylenetriamine, and wherein the second stream is substantially free of monoethylene glycol.
摘要翻译：方法包括：提供包含单乙二醇和二亚乙基三胺的混合物; 并用包含三甘醇的二亚乙基三胺选择性溶剂对混合物进行萃取蒸馏以提供包含单乙二醇的第一物流和包含二亚乙基三胺的第二物流; 其中所述第一物流基本上不含二亚乙基三胺，并且其中所述第二物流基本上不含单乙二醇。

7. 发明授权

US07754921B2 Shaped body comprising an aluminosilicate and aluminium oxide and process for the continuous preparation of methylamines 有权
标题翻译：包含铝硅酸盐和氧化铝的成形体和用于连续制备甲胺的方法
公开(公告)号：US07754921B2
公开(公告)日：2010-07-13
申请号：US12088743
申请日：2006-09-21
申请人： Marco Bosch , Roderich Röttger , Jan Eberhardt , Thomas Krug , Manfred Julius , Karl-Heínz Roβ , Theodor Weber
发明人： Marco Bosch , Roderich Röttger , Jan Eberhardt , Thomas Krug , Manfred Julius , Karl-Heínz Roβ , Theodor Weber
IPC分类号： C07C209/16 , B01J29/00
CPC分类号： C07C209/16 , B01J21/12 , B01J21/16 , B01J35/002 , B01J35/023 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/109 , B01J35/1095 , B01J37/0009 , B01J37/0018 , C07C211/04
摘要： Shaped body comprising an aluminosilicate and aluminum oxide, wherein the shaped body has a molar Al/Si ratio in the range from 10 to 30 and an at least bimodal pore distribution for pores having a diameter of greater than 1 nm, with the volume of the pores of the shaped body having a diameter of greater than 10 nm corresponding to at least 40% of the total pore volume of the shaped body, process for producing it and process for the continuous preparation of methylamines by reaction of methanol and/or dimethyl ether with ammonia in the presence of a heterogeneous catalyst, wherein the abovementioned shaped bodies are used as catalyst.
摘要翻译：包括铝硅酸盐和氧化铝的成形体，其中成形体的Al / Si摩尔比在10至30的范围内，并且对于具有大于1nm直径的孔的至少双峰孔分布，其体积成形体的孔径大于10nm，对应于成形体的总孔体积的至少40％，其生产方法和通过甲醇和/或二甲醚的反应连续制备甲胺的方法在存在非均相催化剂的情况下使用氨，其中上述成形体用作催化剂。

8. 发明授权

US07714169B2 Continuous preparation of alkylamines 失效
标题翻译：连续制备烷基胺
公开(公告)号：US07714169B2
公开(公告)日：2010-05-11
申请号：US12258563
申请日：2008-10-27
申请人： Marco Bosch , Roderich Röttger , Bernd Stein , Thomas Krug , Johann-Peter Melder , Theodor Weber
发明人： Marco Bosch , Roderich Röttger , Bernd Stein , Thomas Krug , Johann-Peter Melder , Theodor Weber
IPC分类号： C07C209/16
CPC分类号： C07C209/16 , B01J8/0221 , B01J8/0285 , B01J2208/00132 , B01J2208/00353 , B01J2208/0053 , C07C211/04
摘要： In the continuous process for preparing alkylamines by reacting C1-4-alkanols with ammonia in the gas phase in the presence of a shape-selective fixed-bed catalyst in a cooled reactor, the shape-selective fixed-bed catalyst is present in a single contiguous fixed bed in the reactor and tubes through which coolants are passed run within the fixed bed to regulate the temperature of the fixed bed.
摘要翻译：在冷却的反应器中，在形状选择性固定床催化剂存在下，在气相中使C 1-4 - 链烷醇与氨反应制备烷基胺的连续方法中，形状选择性固定床催化剂存在于单一反应器中连续的固定床和冷却剂通过的管通过固定床内以调节固定床的温度。

9. 发明申请

US20090030237A1 METHOD FOR PRODUCING ETHYLENE AMINES AND ETHANOL AMINES BY THE HYDROGENATING AMINATION OF MONOETHYLENE GLYCOL AND AMMONIA IN THE PRESENCE OF A CATALYST 有权
标题翻译：通过催化剂存在下单乙基甘氨酸和氨基甲酸的加氢胺化生产乙烯胺和乙醇胺的方法
公开(公告)号：US20090030237A1
公开(公告)日：2009-01-29
申请号：US12279215
申请日：2007-02-08
申请人： Gunther van Cauwenberge , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Karin Pickenaecker , Frank-Friedrich Pape , Ekkehard Schwab
发明人： Gunther van Cauwenberge , Johann-Peter Melder , Bram Willem Hoffer , Thomas Krug , Karin Pickenaecker , Frank-Friedrich Pape , Ekkehard Schwab
IPC分类号： C07C209/14
CPC分类号： C07C209/16 , C07C211/10 , C07C211/14
摘要： A process for preparing ethylene amines and ethanolamines by hydrogenative amination of monoethylene glycol and ammonia in the presence of a catalyst, wherein a catalyst having an active composition comprising ruthenium and cobalt and no further additional metal of group VIII and also no metal of group IB is used in the form of shaped catalyst bodies which in the case of a spherical shape or rod shape in each case have a diameter of
摘要翻译：一种在催化剂存在下通过单乙酰胺和氨的氢化胺化制备乙烯胺和乙醇胺的方法，其中具有包含钌和钴的活性组合物以及没有另外的另外的第VIII族金属以及也没有IB族金属的催化剂是使用成形催化剂体的形式，在球形或棒状的情况下，每种情况具有<3mm的直径，在颗粒形状的情况下具有<3mm的高度，并且在全部情况下每种情况下的其他几何形状具有等效直径L = 1 / a'<0.70mm，其中a'是每单位体积的外表面积（mms2 / mmp3），并且： $a'=\frac{其中Ap是成形催化剂体的外表面面积（mms2），Vp是（mms2），其中Ap是成形催化剂体的外表面积（mms2），Vp是}{提出了成形催化剂体的体积（mmp3）。}$

10. 发明申请

US20060276649A1 Method for producing ethylene-amines 失效
标题翻译：生产乙烯胺的方法
公开(公告)号：US20060276649A1
公开(公告)日：2006-12-07
申请号：US10566419
申请日：2004-07-15
申请人： Matthias Frauenkron , Thomas Krug , Holger Evers , Johann-Peter Melder , Roderich Rottger , Markus Siegert , Till Gerlach , Jan Nouwen , Ellen Dahlhoff , Christian Miller
发明人： Matthias Frauenkron , Thomas Krug , Holger Evers , Johann-Peter Melder , Roderich Rottger , Markus Siegert , Till Gerlach , Jan Nouwen , Ellen Dahlhoff , Christian Miller
IPC分类号： C07D241/04 , C07C211/13 , C07C211/09
CPC分类号： C07C209/64 , C07C211/14
摘要： Process for the preparation of ethylenamines, in particular diethylenetriamine (DETA), by continuous reaction of ethylenediamine (EDA) in the presence of a heterogeneous catalyst, where the reaction is carried out in a reaction column.
摘要翻译：通过乙二胺（EDA）在多相催化剂存在下连续反应制备乙烯胺，特别是二亚乙基三胺（DETA）的方法，其中反应在反应塔中进行。

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