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1. 发明授权

US07172989B2 Catalytic hydrogenation over rhenium-containing catalysts supported on activated carbon 失效
标题翻译：通过负载在活性炭上的含铼催化剂进行催化氢化
公开(公告)号：US07172989B2
公开(公告)日：2007-02-06
申请号：US11104408
申请日：2005-04-13
申请人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
发明人： Rolf-Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
IPC分类号： B01J23/42 , B01J21/18 , B01J23/36
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated. It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译：在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属活性炭的重量比为0至0.25，并且活性炭已经被非氧化预处理。如果氢气压力不超过25巴，也可制备醚和内酯。在这种情况下，催化剂中的活性炭也可以被非氧化预处理。

2. 发明授权

US07179388B2 Method for removing formic acid from aqueous solutions 失效
标题翻译：从水溶液中除去甲酸的方法
公开(公告)号：US07179388B2
公开(公告)日：2007-02-20
申请号：US10473203
申请日：2002-06-10
申请人： Thomas Nöbel
发明人： Thomas Nöbel
IPC分类号： C02F1/00
CPC分类号： C07C45/33 , C07C29/80 , C07C29/88 , C07C45/85 , C07C2601/14 , C07C49/403 , C07C35/08
摘要： Formic acid is at least partly removed from an aqueous solution comprising formic acid, cyclohexanone and cyclohexanol by decomposition over certain decomposition catalysts.The method is preferably used for processing reaction products from the oxidation of cyclohexane and comprises: (i) extracting a product gas mixture obtained in the oxidation of cyclohexane with an aqueous scrubbing liquid, (ii) separating the aqueous solution obtained in (i) by distillation into an aqueous solution comprising formic acid, cyclohexanone and cyclohexanol together with further minor organic components and a carboxylic acid mixture (iii) removing the formic acid at least partially from the aqueous solution obtained in (ii) by decomposition, and (iv) further processing the aqueous solution obtained in (iii) to give epsilon-caprolactam, or using the aqueous solution obtained in (iii) as scrubbing liquid in (i).
摘要翻译：通过某些分解催化剂的分解，甲酸至少部分地从包含甲酸，环己酮和环己醇的水溶液中除去。该方法优选用于处理来自环己烷氧化的反应产物，并包括：（i）用水洗涤液萃取在环己烷氧化中获得的产物气体混合物，（ii）将（i）中获得的水溶液蒸馏成包含甲酸，环己酮和环己醇的水溶液以及其它少量有机组分和羧酸混合物（iii）至少部分地通过分解从（ii）中获得的水溶液中除去甲酸，和（iv）进一步加工（iii）中得到的水溶液得到ε-己内酰胺，或者使用（ⅲ）中得到的水溶液作为（i）中的洗涤液。

3. 发明授权

US07230141B2 Method for producing toluol derivatives 失效
标题翻译：甲苯衍生物的制备方法
公开(公告)号：US07230141B2
公开(公告)日：2007-06-12
申请号：US10500718
申请日：2003-01-20
申请人： Nils Bottke , Rolf-Hartmuth Fischer , Thomas Nöbel , Markus Rösch
发明人： Nils Bottke , Rolf-Hartmuth Fischer , Thomas Nöbel , Markus Rösch
IPC分类号： C07C41/18 , C07C43/205
CPC分类号： B01J23/8892 , B01J23/002 , B01J23/72 , B01J23/755 , B01J23/885 , B01J23/8898 , B01J2523/00 , C07C2523/72 , C07C2523/75 , C07C2523/755 , B01J2523/17 , B01J2523/31 , B01J2523/68 , B01J2523/847 , B01J2523/12 , B01J2523/51 , B01J2523/72 , B01J2523/845 , B01J2523/41 , B01J2523/48
摘要： A process for preparing toluene derivatives of the formula I, where R1, R2 and R3 independently of one another are hydrogen, halogen, C1–C6-alkyl, hydroxyl or C1–C6-alkoxy, by hydrogenating benzaldehydes and/or benzyl alcohols of the formula II, with hydrogen in the presence of a catalyst, which is described in more detail in the description.
摘要翻译：制备式I的甲苯衍生物的方法，其中R 1，R 2和R 3彼此独立地为氢，卤素， C 1 -C 6 - 烷基，羟基或C 1 -C 6 - 烷氧基，通过氢化苯甲醛和 /或式II的苄醇与催化剂存在下的氢反应，这在描述中有更详细的描述。

4. 发明授权

US06906228B2 Method for catalytic hydrogenation on rhenium-containing active carbon carrier catalysts 失效
标题翻译：用于含铼活性炭载体催化剂的催化氢化方法
公开(公告)号：US06906228B2
公开(公告)日：2005-06-14
申请号：US10220566
申请日：2001-03-01
申请人： Rolf Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
发明人： Rolf Hartmuth Fischer , Rolf Pinkos , Stephan Andreas Schunk , Joachim Wulff-Döring , Frank Stein , Thomas Nöbel , Sylvia Huber
IPC分类号： B01J21/18 , B01J23/656 , B01J23/89 , C07C29/17 , C07C29/136 , C07C29/14 , C07C29/141 , C07C29/143 , C07C29/145 , C07C29/147 , C07C29/149 , C07C29/146 , C07C29/148
CPC分类号： C07C29/177 , B01J21/18 , B01J23/6567 , B01J23/8986 , C07C2601/20 , C07C31/207 , C07C31/20 , C07C31/133
摘要： In a process for preparing alcohols by catalytic hydrogenation of carbonyl compounds over a catalyst comprising rhenium on activated carbon, the catalyst used comprises rhenium (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5, platinum (calculated as metal) in a weight ratio to the activated carbon of from 0.0001 to 0.5 and, if appropriate, at least one further metal selected from among Zn, Cu, Ag, Au, Ni, Fe, Ru, Mn, Cr, Mo, W and V in a weight ratio to the activated carbon of from 0 to 0.25, and the activated carbon has been nonoxidatively pretreated It is also possible to prepare ethers and lactones if the hydrogen pressure is not more than 25 bar. In this case, the activated carbon in the catalyst may also have been nonoxidatively pretreated.
摘要翻译：在通过羰基化合物催化氢化羰基化合物的方法中，所用的催化剂包括铼在活性炭上的催化剂，所用的催化剂包括铼（以金属计）与活性炭的重量比为0.0001至0.5，铂（以金属计算），活性炭的重量比为0.0001〜0.5，如果合适，选自Zn，Cu，Ag，Au，Ni，Fe，Ru，Mn，Cr，Mo，W和V中的至少一种以上的金属活性炭的重量比为0至0.25，并且活性炭未经氧化预处理。如果氢气压力不超过25巴，也可制备醚和内酯。在这种情况下，催化剂中的活性炭也可以被非氧化预处理。

5. 发明授权

US06727395B1 Method for producing hexanediol 失效
标题翻译：己二醇的制备方法
公开(公告)号：US06727395B1
公开(公告)日：2004-04-27
申请号：US10018338
申请日：2001-12-19
申请人： Frank Stein , Thomas Krug , Thomas Nöbel , Harald Rust
发明人： Frank Stein , Thomas Krug , Thomas Nöbel , Harald Rust
IPC分类号： C07C2700
CPC分类号： C07C29/149 , C07C31/20
摘要： A process for preparing 1,6-hexanediol from a carboxylic acid mixture comprising adipic acid, 6-hydroxycaproic acid and small amounts of 1,4-cyclohexanediols which is obtained as by-product in the oxidation of cyclohexane to cyclohexanone/cyclohexanol after water extraction of the reaction mixture followed by extraction with aqueous sodium hydroxide solution, by esterification of the acids and hydrogenation comprises a) liberating the carboxylic acids from the alkaline extract by addition of a mineral acid, b) fractionating the organic phase comprising carboxylic acids to give a distillate comprising the low molecular weight monocarboxylic acids and a residue comprising adipic acid and 6-hydroxycaproic acid, c) reacting the monocarboxylic an dicarboxylic acids present in the aqueous dicarboxylic acid mixture with a low molecular weight alcohol to give the corresponding carboxylic esters, d) freeing the esterification mixture obtained of excess alcohol and low boilers in a first distillation step, e) fractionating the bottom product in a second distillation step to give an ester fraction essentially free of 1,4-cyclohexanediols and a fraction comprising at least the major part of the 1,4-cyclohexanediols, f) catalytically hydrogenating the ester fraction which is essentially free of 1,4-cyclohexanediols and g) isolating 1,6-hexanediol from the hydrogenation product in a manner known per se in a final distillation step.
摘要翻译：从包含己二酸，6-羟基己酸和少量1,4-环己二醇的羧酸混合物制备1,6-己二醇的方法，其在水提取后在环己烷氧化成环己酮/环己醇时作为副产物获得的反应混合物，然后用氢氧化钠水溶液萃取，通过酸的酯化和氢化反应，包括a）通过加入无机酸从碱性提取物中释放出羧酸，b）将包含羧酸的有机相分馏得到馏出物包括低分子量单羧酸和包含己二酸和6-羟基己酸的残基，c）使一元羧酸与二羧酸混合物中存在的二羧酸与低分子量醇反应，得到相应的羧酸酯，d）释放在第一馏出物中获得过量酒精和低锅炉的酯化混合物 e步骤，e）在第二蒸馏步骤中分馏底部产物，得到基本上不含1,4-环己烷二醇的酯馏分和至少包含大部分1,4-环己烷二醇的馏分，f）催化氢化酯基本上不含1,4-环己烷二醇的馏分，和g）在最终蒸馏步骤中以本身已知的方式从氢化产物中分离出1,6-己二醇。

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