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1. 发明授权

US4546010A Process for producing an electrically conductive layer on the surface of a solid-body electrolyte, and electrically conductive layer 失效
标题翻译：在固体电解质表面上制造导电层的方法和导电层
公开(公告)号：US4546010A
公开(公告)日：1985-10-08
申请号：US578679
申请日：1984-02-09
申请人： Eric Killer , Gunther Scherer , Samuel Stucki
发明人： Eric Killer , Gunther Scherer , Samuel Stucki
IPC分类号： C08J5/22 , C25B9/10 , C25B13/08 , H01M4/92 , H01M8/1004 , C25B11/00
CPC分类号： H01M4/928 , C25B9/10 , H01M8/1004 , H01M2300/0082 , Y02P70/56
摘要： An electrically conductive layer on a solid-body electrolyte (1) is produced by swelling and impregnating an organic ion exchange material (2) with a metal salt solution, drying, converting the metal ions in a gas stream to finely distributed particles (3) which are in electrical contact with one another, renewed swelling in a solvent, converting into a brushable paste and applying same to the surface of the solid-body electrolyte and drying. Preferred embodiment: solid-body electrolyte (1) and ion exchange material (2) made of polymers containing sulphonic acids; and conductive particles (3) made of platinum metals or oxides thereof, in particular ruthenium as electrocatalyst.
摘要翻译：通过用金属盐溶液溶胀和浸渍有机离子交换材料（2）来制造固体电解质（1）上的导电层，干燥，将气流中的金属离子转化成细分散的颗粒（3）它们彼此电接触，在溶剂中更新溶胀，转化成可刷涂糊剂并将其施加到固体电解质的表面并干燥。优选实施方案：固体电解质（1）和由含有磺酸的聚合物制成的离子交换材料（2）和由铂金属或其氧化物制成的导电颗粒（3），特别是钌作为电催化剂。

2. 发明授权

US4597846A Depassivation layer on an electrode of an electrochemical cell 失效
标题翻译：电化学电池电极上的钝化层
公开(公告)号：US4597846A
公开(公告)日：1986-07-01
申请号：US625232
申请日：1984-06-27
申请人： Eric Killer , Gunther Scherer
发明人： Eric Killer , Gunther Scherer
IPC分类号： C25B11/03 , B05D1/28 , C25B11/00 , C25B11/04 , C25B11/10 , H01M4/66 , C25B1/34
CPC分类号： B05D1/28 , C25B11/00 , C25B11/0484
摘要： A depassivation layer is produced on an electrode for an electrochemical cell by applying one or more layers of a metal salt solution, containing the elements to be applied, to the substrate (1) which is to be coated and is in the form of a porous plate, by means of rolling an elastic roller (2) over the substrate, with the insertion of a solution carrier (3) in the form of felt or paper, and then drying the layer and subjecting it to a chemical/thermal treatment in air (heat treatment at 450.degree. C.). Good depassivation layers with a relatively small noble metal content can be produced in this way. The depassivation layer which, in the form of a homogeneous film, is at least partially coherent contains, as a finely divided, sub-microscopic mixture, electronically conductive sub-oxides/oxides of the substrate (1) in addition to noble metals/noble metal oxides, and it can also contain further components, such as SnO.sub.2.
摘要翻译：在用于电化学电池的电极上，通过将一层或多层含有待涂覆的元素的金属盐溶液施加到待涂覆的基底（1）上并且呈多孔的形式，产生钝化层通过在基体上滚动弹性辊（2），将溶液载体（3）插入毡或纸的形式，然后干燥该层并在空气中进行化学/热处理（在450℃下进行热处理）。可以以这种方式生产具有相当小的贵金属含量的良好的钝化层。以平均膜的形式至少部分相干的去钝化层除了贵金属/贵金属之外还含有作为细碎的亚微观混合物的基板（1）的电子导电子氧化物/氧化物金属氧化物，并且还可以含有其它组分，例如SnO 2。

3. 发明授权

US06375832B1 Fuel synthesis 失效
标题翻译：燃料合成
公开(公告)号：US06375832B1
公开(公告)日：2002-04-23
申请号：US09532082
申请日：2000-03-21
申请人： Baldur Eliasson , Eric Killer , Chang-Jun Liu
发明人： Baldur Eliasson , Eric Killer , Chang-Jun Liu
IPC分类号： C10G3504
CPC分类号： C01B3/342 , B01J19/088 , B01J2219/0875 , B01J2219/0877 , B01J2219/0892 , C07C2/862 , C07C2529/65 , C07C2529/70
摘要： A method of transforming a normally gaseous composition containing at least one hydrogen source, at least one oxygen source and at least one carbon source into a normally liquid fuel, wherein said gaseous composition consists at least in part of carbon dioxide as said carbon source and said oxygen source, and of methane as said hydrogen source and as a second carbon source; the method comprising the steps of feeding the composition into a reactor including a first electrode means, a second electrode means and at least one layer of a normally solid dielectric material positioned between the first and the second electrode means; submitting the composition within the reactor in the presence of a normally solid catalyst to a dielectric barrier discharge, wherein said normally solid catalyst is a member selected from the group of zeolites, aluminophosphates, silicoaluminophosphates, metalloaluminophosphates and metal oxides containing OH groups; and controlling the dielectric barrier discharge to convert the gaseous composition into the normally liquid fuel.
摘要翻译：将含有至少一个氢源，至少一个氧源和至少一个碳源的常规气态组合物转化成常规液体燃料的方法，其中所述气体组合物至少部分地由至少部分二氧化碳作为所述碳源和所述氧源和甲烷作为所述氢源和作为第二碳源; 该方法包括以下步骤：将组合物进料到反应器中，该反应器包括位于第一和第二电极装置之间的第一电极装置，第二电极装置和至少一层常规固体电介质材料; 在正常固体催化剂存在下将反应器中的组合物提供给介电阻挡放电，其中所述常规固体催化剂是选自沸石，铝磷酸盐，硅铝磷酸盐，金属铝磷酸盐和含有OH基团的金属氧化物的成员; 并控制电介质势垒放电以将气态组合物转化为常规液体燃料。

4. 发明授权

US06326407B1 Hydrocarbon synthesis 失效
标题翻译：烃合成
公开(公告)号：US06326407B1
公开(公告)日：2001-12-04
申请号：US09632798
申请日：2000-08-04
申请人： Baldur Eliasson , Chang-Jun Liu , Eric Killer
发明人： Baldur Eliasson , Chang-Jun Liu , Eric Killer
IPC分类号： C07C2700
CPC分类号： C10G50/00 , B01J19/088 , B01J2219/0809 , B01J2219/083 , B01J2219/0835 , B01J2219/0875 , B01J2219/0892 , C07C2/76 , C07C2529/08 , C07C2529/40 , C07C2529/70 , Y10S585/943
摘要： A method of transforming a normally gaseous composition consisting essentially of methane into a material comprising a major portion, at least, of hydrocarbons containing at least two carbon atoms; the method comprising the steps of feeding the composition into a reactor including a first electrode means, a second electrode means and at least one layer of a normally solid dielectric material positioned between the first and the second electrode means; submitting the composition within the reactor in the presence of a normally solid catalyst to a dielectric barrier discharge; and controlling the dielectric barrier discharge to convert the normally gaseous composition into the material comprising a major portion, at least, of the hydrocarbons containing at least two carbon atoms.
摘要翻译：将基本上由甲烷组成的常规气态组合物转化成至少包含至少两个碳原子的烃的主要部分的材料的方法; 该方法包括以下步骤：将组合物进料到反应器中，该反应器包括位于第一和第二电极装置之间的第一电极装置，第二电极装置和至少一层常规固体电介质材料; 将反应器内的组合物在常规固体催化剂存在下进行介电阻挡放电; 并且控制电介质势垒放电以将正常气态组合物转化成包含至少一种含有至少两个碳原子的烃的主要部分的材料。

5. 发明授权

US6045761A Process and device for the conversion of a greenhouse gas 失效
标题翻译：温室气体转化的工艺和装置
公开(公告)号：US6045761A
公开(公告)日：2000-04-04
申请号：US930915
申请日：1997-10-14
申请人： Alain Bill , Baldur Eliasson , Eric Killer , Ulrich Kogelschatz
发明人： Alain Bill , Baldur Eliasson , Eric Killer , Ulrich Kogelschatz
IPC分类号： B01D53/32 , B01J19/08 , C07C29/50 , C01B21/00 , F01N3/10 , H05F3/00 , F28D8/04
CPC分类号： C07C29/50 , B01D53/32 , B01D53/323 , B01J19/088 , Y02C20/20
摘要： So that fuels can be produced efficiently from an undesirable greenhouse gas, the gas is subjected, together with a catalyst gas, preferably nitrogen or nitrous oxide, and a hydrogen-containing gas or vapour, to a silent electric discharge in a 1st reactor (4). In the process, excited or ionized atoms and/or molecules are formed which are converted, in a catalyst reactor (8) comprising a copper-containing 1st catalyst (8'), to H.sub.2 and possibly CO. Via an expansion valve (9), a liquid (13) separates from a fuel in a liquid vessel (11). Gases escaping from the liquid vessel (11) are passed over a thermal reactor (14) containing a 2nd catalyst (15) and expanded via an expansion valve (16). In a downstream liquid vessel (11') CH.sub.3 OH, for example, separates as the desired liquid fuel (13'). The 1st reactor (4) and the thermal reactor (14) may be combined in a container comprising a plurality of reaction chambers which are parallel to one another.
摘要翻译： PCT No.PCT / CH97 / 00042 Sec。 371日期1997年10月14日第 102（e）日期1997年10月14日PCT 1997年2月11日提交PCT公布。出版物WO97 / 29833 日期1997年8月21日由于燃料可以从不期望的温室气体中有效地生产，所以将气体与催化剂气体，优选氮或一氧化二氮，含氢气体或蒸气一起经受静音放电第一反应堆（4）。在此过程中，形成激发的或离子化的原子和/或分子，其在包含含铜的第一催化剂（8'）的催化剂反应器（8）中转化为H 2，并且可能地经由膨胀阀（9）液体（13）与液体容器（11）中的燃料分离。从液体容器（11）排出的气体通过含有第二催化剂（15）的热反应器（14），并通过膨胀阀（16）膨胀。例如，在下游液体容器（11'）CH3OH中分离为所需的液体燃料（13'）。第一反应器（4）和热反应器（14）可以组合在包括彼此平行的多个反应室的容器中。

6. 发明授权

US4569730A Method for continuous coating of a solid electrolyte with a catalytically active material 失效
标题翻译：用催化活性材料连续涂覆固体电解质的方法
公开(公告)号：US4569730A
公开(公告)日：1986-02-11
申请号：US692521
申请日：1985-01-18
申请人： Eric Killer
发明人： Eric Killer
IPC分类号： C25B9/10 , C25D5/56 , H01M8/1004 , C25D5/04 , C25D17/00
CPC分类号： C25B9/10 , C25D5/56 , H01M8/1004
摘要： A method for continuous coating of a solid electrolyte (3) with a coating comprised of a catalytically active metal, comprising impregnating the solid electrolyte (3) (present in the form of a film comprised of a plastic polymer) with a solution of a metal salt, and electrolyzing the metal salt in a plurality of passes of the solid electrolyte (3) between two rolls (4, 5) which rolls serve as electrodes, in a water bath, wherewith at first the speed of advance of the solid electrolyte film is a relatively high value of 20 to 30 cm/min and then a lower value of 1 to 2 cm/min, and wherewith the linear current density in the line of contact between the rolls (4, 5) and the solid electrolyte (3) is at least 830 mA/cm.
摘要翻译：一种用包含催化活性金属的涂层连续涂覆固体电解质（3）的方法，包括用金属溶液浸渍固体电解质（3）（以塑料聚合物形式的膜形式）盐，并在水浴中在两个辊（4,5）之间的固体电解质（3）的多次通过中电解金属盐，首先将固体电解质膜的前进速度相对较高的值为20〜30cm / min，然后为1〜2cm / min的较低值，并且在辊（4,5）和固体电解质（3）之间的接触线中的线性电流密度）为至少830mA / cm。

7. 发明申请

US20050150643A1 Heat exchanger 审中-公开
标题翻译：热交换器
公开(公告)号：US20050150643A1
公开(公告)日：2005-07-14
申请号：US10512956
申请日：2003-06-18
申请人： Daniel Chartouni , Eric Killer , Christian Ohler
发明人： Daniel Chartouni , Eric Killer , Christian Ohler
IPC分类号： F28F1/40 , F28B1/06 , F28D1/02 , F28D1/04 , F28D1/047 , F28D7/02 , F28D7/10 , F28F21/06 , H01M8/04 , H01M8/10 , F28F13/18
CPC分类号： H01M8/04164 , F28D1/0233 , F28D1/04 , F28D7/026 , F28D7/106 , F28D2001/0273 , F28F2240/00 , Y02P70/56
摘要： The present invention provides a fluid-to-fluid through-the-wall heat exchanger for condensation of a vapour in a primary fluid stream, wherein a flow path (5) of the primary fluid stream is defined by an inner cylinder (1), an outer cylinder (2) arranged concentrically to and surrounding the inner cylinder, and a helical space holder (3) arranged between the inner and the outer cylinder. Additionally, the cylinder surfaces delimiting the primary flow path are made of or coated with corrosion resistant material in order to reduce a contamination of the primary fluid. Compared to other condensers with identical ratings, this heat exchanger shows a smaller flow resistance, resulting in a smaller power demand of the blower or pumps, It is therefore particularly suitable for fuel cell systems where the condensed water has to be recirculated in the system and where purity demands are high and parasitic blower power should be minimal. The manufacturing of such a double envelope cylindrical heat exchanger is particularly simple and cost effective.
摘要翻译：本发明提供一种用于冷凝主要流体流中的蒸气的流体到流体的通过壁的热交换器，其中主流体流的流动路径（5）由内筒（1）限定，与所述内筒同心地配置并围绕所述内筒的外筒（2），以及配置在所述内筒和所述外筒之间的螺旋空间保持架（3）。此外，限定主流路的气缸表面由耐蚀材料制成或涂覆以减少初级流体的污染。与具有相同额定值的其他电容器相比，该热交换器显示较小的流动阻力，导致鼓风机或泵的功率需求较小。因此，特别适用于必须在系统中再循环冷凝水的燃料电池系统，纯度要求高，寄生风扇功率最小。这种双包络圆柱形换热器的制造特别简单且成本有效。

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