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    • 2. 发明授权
    • High-power radiation source
    • 大功率辐射源
    • US4983881A
    • 1991-01-08
    • US295743
    • 1989-01-11
    • Baldur EliassonUlrich Kogelschatz
    • Baldur EliassonUlrich Kogelschatz
    • H01J65/00H01J65/04
    • H01J65/046
    • The high-power radiation source for visible light includes a discharge space (4) bounded by dielectrics (1, 10) and filled with a noble gas or gas mixture. Adjacent to the dielectrics (1,10) are luminescent coatings (5,11). Both the dielectric (1,10) and the electrode (6,12) situated on the surfaces of the dielectrics facing away from the discharge space (4) are transparent to the radiation generated by the dark electrical discharges. In this way, a large-area radiation source with high efficiency is provided which can be operated with high electrical power densities of up to 50 kW/m.sup.2 of active electrode surface.
    • 用于可见光的高功率辐射源包括由电介质(1,10)限定并填充惰性气体或气体混合物的放电空间(4)。 与电介质(1,10)相邻的是发光涂层(5,11)。 位于电介质背离放电空间(4)的表面上的电介质(1,10)和电极(6,12)对于由暗放电产生的辐射是透明的。 以这种方式,提供了高效率的大面积辐射源,其可以以高达50kW / m 2的有效电极表面的高功率密度进行操作。
    • 3. 发明授权
    • Dielectric barrier discharge cracking
    • 介质阻隔放电开裂
    • US06284105B1
    • 2001-09-04
    • US09583742
    • 2000-05-31
    • Baldur EliassonChang-Jun Liu
    • Baldur EliassonChang-Jun Liu
    • B01J1908
    • B01J19/088C02F2201/003C10G15/12
    • A method of cracking a hydrocarbon composition having a normal boiling range beginning at a temperature of at least about 200° C., includes the steps of providing the hydrocarbon composition in a reactor including a first electrode mechanism, a second electrode mechanism and at least one layer of a normally solid dielectric material positioned between the first and the second electrode mechanisms. The hydrocarbon composition within the reactor is exposed to a dielectric barrier discharge, and the dielectric barrier discharge is controlled to convert the hydrocarbon composition into products having normal boiling points of below about 200° C.
    • 一种在至少约200℃的温度下开始具有正常沸程的烃组合物的方法包括以下步骤:将烃组合物提供在包括第一电极机构,第二电极机构和至少一个 位于第一和第二电极机构之间的常规固体电介质材料层。 将反应器内的烃组合物暴露于电介质阻挡放电,并且控制电介质阻挡放电以将烃组合物转化为具有低于约200℃的正常沸点的产物。
    • 4. 发明授权
    • Process and device for the conversion of a greenhouse gas
    • 温室气体转化的工艺和装置
    • US6045761A
    • 2000-04-04
    • US930915
    • 1997-10-14
    • Alain BillBaldur EliassonEric KillerUlrich Kogelschatz
    • Alain BillBaldur EliassonEric KillerUlrich Kogelschatz
    • B01D53/32B01J19/08C07C29/50C01B21/00F01N3/10H05F3/00F28D8/04
    • C07C29/50B01D53/32B01D53/323B01J19/088Y02C20/20
    • So that fuels can be produced efficiently from an undesirable greenhouse gas, the gas is subjected, together with a catalyst gas, preferably nitrogen or nitrous oxide, and a hydrogen-containing gas or vapour, to a silent electric discharge in a 1st reactor (4). In the process, excited or ionized atoms and/or molecules are formed which are converted, in a catalyst reactor (8) comprising a copper-containing 1st catalyst (8'), to H.sub.2 and possibly CO. Via an expansion valve (9), a liquid (13) separates from a fuel in a liquid vessel (11). Gases escaping from the liquid vessel (11) are passed over a thermal reactor (14) containing a 2nd catalyst (15) and expanded via an expansion valve (16). In a downstream liquid vessel (11') CH.sub.3 OH, for example, separates as the desired liquid fuel (13'). The 1st reactor (4) and the thermal reactor (14) may be combined in a container comprising a plurality of reaction chambers which are parallel to one another.
    • PCT No.PCT / CH97 / 00042 Sec。 371日期1997年10月14日第 102(e)日期1997年10月14日PCT 1997年2月11日提交PCT公布。 出版物WO97 / 29833 日期1997年8月21日由于燃料可以从不期望的温室气体中有效地生产,所以将气体与催化剂气体,优选氮或一氧化二氮,含氢气体或蒸气一起经受静音放电 第一反应堆(4)。 在此过程中,形成激发的或离子化的原子和/或分子,其在包含含铜的第一催化剂(8')的催化剂反应器(8)中转化为H 2,并且可能地经由膨胀阀(9) 液体(13)与液体容器(11)中的燃料分离。 从液体容器(11)排出的气体通过含有第二催化剂(15)的热反应器(14),并通过膨胀阀(16)膨胀。 例如,在下游液体容器(11')CH3OH中分离为所需的液体燃料(13')。 第一反应器(4)和热反应器(14)可以组合在包括彼此平行的多个反应室的容器中。
    • 6. 发明授权
    • Discharge reactor and uses thereof
    • 放电反应器及其用途
    • US6136278A
    • 2000-10-24
    • US144971
    • 1998-09-01
    • Baldur EliassonUlrich Kogelschatz
    • Baldur EliassonUlrich Kogelschatz
    • B01J19/08C01B3/34C01B3/38C01B13/11C07C29/152C07C29/154
    • B01J19/087B01J19/088C01B13/11C01B3/342C01B3/38C07C29/152C07C29/154B01J2219/0809B01J2219/0883C01B2201/32C01B2201/34C01B2203/0238C01B2203/0861C01B2203/1041C01B2203/1052C01B2203/1076C01B2203/1241Y02P20/142Y02P20/52
    • In an electrical discharge reactor for facilitating chemical reactions, power consumption and yield of chemical reactions are optimized, and heat dissipation is improved, by filling an interspace between a first electrode (1) and a second electrode (2) of the discharge reactor with a block (4) of rigid, open-pored dielectric material. The material preferably has a porosity of 80-90%. The skeleton of the block can consist of glass, quartz or ceramic. The diameter of the pores in the block, in which micro-discharges occur, represents an effective gap width that is critical for the progress of the silent discharge. The diameter of the pores can, for example, be between 0.05 millimeters and 0.2 millimeters to optimize power consumption. As a safeguard against breakdown, a barrier layer (5) of a nonconductive, solid material can be provided between the electrodes (1, 2). To facilitate a reaction of CO.sub.2 and H.sub.2 to form methanol and water, or to facilitate a reaction of CO.sub.2 and CH.sub.4 to form synthesis gas, the skeleton of the block can be coated with a suitable catalyst. The catalyst can include, for example, Cu and ZrO.sub.2, or Cu and ZnO, or nickel compounds.
    • 在用于促进​​化学反应的放电反应器中,优化了功率消耗和化学反应的产率,并且通过在放电反应器的第一电极(1)和第二电极(2)之间填充空隙,从而改善了散热, 块(4)的刚性,开孔电介质材料。 该材料的孔隙率优选为80-90%。 块的骨架可以由玻璃,石英或陶瓷组成。 发生微量放电的块中的孔的直径表示对静音放电的进展至关重要的有效间隙宽度。 孔的直径例如可以在0.05毫米和0.2毫米之间以优化功率消耗。 作为防止击穿的保障,可以在电极(1,2)之间设置非导电固体材料的阻挡层(5)。 为了促进CO 2和H 2反应形成甲醇和水,或促进CO 2和CH 4反应形成合成气,可以用合适的催化剂涂覆嵌段的骨架。 催化剂可以包括例如Cu和ZrO 2,或Cu和ZnO或镍化合物。
    • 10. 发明授权
    • Fuel synthesis
    • 燃料合成
    • US06375832B1
    • 2002-04-23
    • US09532082
    • 2000-03-21
    • Baldur EliassonEric KillerChang-Jun Liu
    • Baldur EliassonEric KillerChang-Jun Liu
    • C10G3504
    • C01B3/342B01J19/088B01J2219/0875B01J2219/0877B01J2219/0892C07C2/862C07C2529/65C07C2529/70
    • A method of transforming a normally gaseous composition containing at least one hydrogen source, at least one oxygen source and at least one carbon source into a normally liquid fuel, wherein said gaseous composition consists at least in part of carbon dioxide as said carbon source and said oxygen source, and of methane as said hydrogen source and as a second carbon source; the method comprising the steps of feeding the composition into a reactor including a first electrode means, a second electrode means and at least one layer of a normally solid dielectric material positioned between the first and the second electrode means; submitting the composition within the reactor in the presence of a normally solid catalyst to a dielectric barrier discharge, wherein said normally solid catalyst is a member selected from the group of zeolites, aluminophosphates, silicoaluminophosphates, metalloaluminophosphates and metal oxides containing OH groups; and controlling the dielectric barrier discharge to convert the gaseous composition into the normally liquid fuel.
    • 将含有至少一个氢源,至少一个氧源和至少一个碳源的常规气态组合物转化成常规液体燃料的方法,其中所述气体组合物至少部分地由至少部分二氧化碳作为所述碳源和所述 氧源和甲烷作为所述氢源和作为第二碳源; 该方法包括以下步骤:将组合物进料到反应器中,该反应器包括位于第一和第二电极装置之间的第一电极装置,第二电极装置和至少一层常规固体电介质材料; 在正常固体催化剂存在下将反应器中的组合物提供给介电阻挡放电,其中所述常规固体催化剂是选自沸石,铝磷酸盐,硅铝磷酸盐,金属铝磷酸盐和含有OH基团的金属氧化物的成员; 并控制电介质势垒放电以将气态组合物转化为常规液体燃料。