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1. 发明授权

US08313544B2 Process for the synthetic generation of methane 有权
标题翻译：甲烷合成生成工艺
公开(公告)号：US08313544B2
公开(公告)日：2012-11-20
申请号：US10589158
申请日：2005-01-24
申请人： Martin Seemann , Serge Biollaz , Samuel Stucki
发明人： Martin Seemann , Serge Biollaz , Samuel Stucki
IPC分类号： B23K35/38
CPC分类号： C07C1/046 , C07C1/043 , C07C2523/755 , C07C9/04
摘要： In a process for the synthetic generation of methane from a feed gas mixture, a feed gas mixture including carbon monoxide, hydrogen, water vapor, CO2, volatile hydrocarbons comprising C2 and higher, unsaturated C2 components and aromatic hydrocarbons in the range of 1 to 10 vol % is provided. The feed gas mixture is contacted with a fluidized bed catalyst having catalyst particles having a catalytic active component selected from the group consisting of a metal, a metal compound and combinations thereof. The contacting occurs at an elevated temperature in the range of 250 to 450° C., a feed gas pressure in the range of 0.8 to 70 bar, a gas hourly space velocity of 1000 to 50000 h−1, and a concentration of H2/CO in the gas mixture in the range of 0.25 to 5.
摘要翻译：在从进料气体混合物合成生成甲烷的方法中，包括一氧化碳，氢气，水蒸汽，CO 2，包含C2和更高级别的不饱和C2组分和芳族烃的挥发性烃的进料气体混合物的范围为1至10 提供vol％。进料气体混合物与具有催化剂颗粒的流化床催化剂接触，催化剂颗粒具有选自金属，金属化合物及其组合的催化活性组分。接触在250至450℃的升高的温度，0.8至70巴的进料气体压力，1000至50000h -1的气时空速和H 2 / CO在气体混合物中的范围为0.25至5。

2. 发明授权

US4546010A Process for producing an electrically conductive layer on the surface of a solid-body electrolyte, and electrically conductive layer 失效
标题翻译：在固体电解质表面上制造导电层的方法和导电层
公开(公告)号：US4546010A
公开(公告)日：1985-10-08
申请号：US578679
申请日：1984-02-09
申请人： Eric Killer , Gunther Scherer , Samuel Stucki
发明人： Eric Killer , Gunther Scherer , Samuel Stucki
IPC分类号： C08J5/22 , C25B9/10 , C25B13/08 , H01M4/92 , H01M8/1004 , C25B11/00
CPC分类号： H01M4/928 , C25B9/10 , H01M8/1004 , H01M2300/0082 , Y02P70/56
摘要： An electrically conductive layer on a solid-body electrolyte (1) is produced by swelling and impregnating an organic ion exchange material (2) with a metal salt solution, drying, converting the metal ions in a gas stream to finely distributed particles (3) which are in electrical contact with one another, renewed swelling in a solvent, converting into a brushable paste and applying same to the surface of the solid-body electrolyte and drying. Preferred embodiment: solid-body electrolyte (1) and ion exchange material (2) made of polymers containing sulphonic acids; and conductive particles (3) made of platinum metals or oxides thereof, in particular ruthenium as electrocatalyst.
摘要翻译：通过用金属盐溶液溶胀和浸渍有机离子交换材料（2）来制造固体电解质（1）上的导电层，干燥，将气流中的金属离子转化成细分散的颗粒（3）它们彼此电接触，在溶剂中更新溶胀，转化成可刷涂糊剂并将其施加到固体电解质的表面并干燥。优选实施方案：固体电解质（1）和由含有磺酸的聚合物制成的离子交换材料（2）和由铂金属或其氧化物制成的导电颗粒（3），特别是钌作为电催化剂。

3. 发明授权

US4836929A Process for breaking down organic substances and/or microbes in pretreated feed water for high-purity water recirculation systems 失效
标题翻译：用于分解用于高纯度水循环系统的预处理进料水中的有机物质和/或微生物的方法
公开(公告)号：US4836929A
公开(公告)日：1989-06-06
申请号：US165902
申请日：1988-03-09
申请人： Hans Baumann , Samuel Stucki
发明人： Hans Baumann , Samuel Stucki
IPC分类号： C02F1/20 , C02F1/32 , C02F1/42 , C02F1/44 , C02F1/46 , C02F1/467 , C02F1/50 , C02F1/58 , C02F1/70 , C02F1/78 , C02F9/00
CPC分类号： C02F1/4672 , C02F1/20 , C02F1/32 , C02F1/441 , C02F1/444 , C02F2001/427 , C02F2101/30 , C02F2103/04 , C02F2201/46115 , C02F2201/4612 , C02F2201/4618 , C02F2201/782 , C02F2303/04 , C02F2303/18
摘要： A process for breaking down organic substances and/or microbes in pretreated feed water for high-purity recirculation systems using ozone which is generated in the anode space (5) of an electrochemical cell (3) and treated with ultraviolet rays and/or with H.sub.2 (8) generated in the cathode space (6) of the same cell (3) or H.sub.2 (20) supplied from outside. The latter is used to reduce elementary oxygen in any form to harmless water. Post treatment via mixed bed (14) and filter (15). Possibility of feeding back water (19) downstream of the receiver (17). No harmful reaction products.
摘要翻译：一种在预处理的给水中分解用于使用臭氧的高纯度再循环系统中的有机物质和/或微生物的方法，其在电化学电池（3）的阳极空间（5）中产生并用紫外线和/或用H2处理（8）在同一电池（3）的阴极空间（6）或从外部供应的H2（20）中产生。后者用于将任何形式的基本氧还原成无害水。通过混床（14）和过滤器（15）进行后处理。将接收器（17）下游的水（19）送回的可能性。无有害反应产物。

4. 发明授权

US4759849A Process and a device for the treatment, by means of ozone, of feed water for reverse osmosis 失效
标题翻译：方法和用于通过臭氧处理用于反渗透的给水的装置
公开(公告)号：US4759849A
公开(公告)日：1988-07-26
申请号：US24006
申请日：1987-03-10
申请人： Hans Baumann , Hans-Peter Klein , Samuel Stucki
发明人： Hans Baumann , Hans-Peter Klein , Samuel Stucki
IPC分类号： C02F1/44 , B01D61/04 , C02F1/00 , C02F1/46 , C02F1/467 , C02F1/78 , B01D13/00
CPC分类号： C02F1/78 , B01D61/025 , B01D61/04 , B01D61/08 , C02F1/4672 , B01D2311/02 , B01D2311/04 , B01D2311/06 , C02F2301/043
摘要： The feed water for a reverse osmosis device (7) is treated, by means of ozone, by being passed through a mixing vessel (4), in which the charging with ozone is carried out, a direct contact time container (5), and a residual-ozone destruction vessel (6) into the reverse osmosis device (7). At the permeate outlet (9) of the latter, part of the stream is branched off and fed, for charging with ozone, into an electrolysis cell (2) which is provided with a solid electrolyte, and fed back into the mixing vessel (4).
摘要翻译：用于反渗透装置（7）的给水通过臭氧通过穿过其中进行充满臭氧的混合容器（4），直接接触时间容器（5）和将残留臭氧破坏容器（6）装入反渗透装置（7）中。在后者的渗透物出口（9）处，部分流体被分出并进料，以便与臭氧一起加入到具有固体电解质的电解槽（2）中，反馈到混合容器（4））。

5. 发明授权

US4619753A Bipolar plate for an apparatus with a stacked configuration, said apparatus comprised of a plurality of electrochemical cells with solid electrolyte; and method of manufacturing said plate 失效
标题翻译：用于具有堆叠构型的装置的双极板，所述装置由具有固体电解质的多个电化学电池组成; 以及制造所述板的方法
公开(公告)号：US4619753A
公开(公告)日：1986-10-28
申请号：US692522
申请日：1985-01-18
申请人： Hans-Jorg Christen , Hubert Devantay , Claude Schellenberg , Gunther Scherer , Samuel Stucki
发明人： Hans-Jorg Christen , Hubert Devantay , Claude Schellenberg , Gunther Scherer , Samuel Stucki
IPC分类号： C25B9/18 , H01M8/0204 , H01M8/0206 , H01M8/0213 , H01M8/0226 , H01M8/0228 , H01M8/0232 , B65D85/18 , H01M4/88
CPC分类号： H01M8/0204 , C25B9/18 , H01M8/0206 , H01M8/0213 , H01M8/0226 , H01M8/0228 , H01M8/0232 , Y02P70/56
摘要： A bipolar plate for an apparatus having a stacked configuration, said apparatus comprised of a plurality of electrochemical cells and employing a solid electrolyte, said bipolar plate comprised of a porous titanium plate (1) having a parallel groove structure (3), said bipolar plate further comprised of a non-porous, solid titanium plate (2) strongly welded to plate (1) at contact loci (4), wherewith channels (5) are present, and said bipolar plate further comprised of a surface layer or coating (6) comprised of a material which is a catalyst for electrolytic reactions. A method of manufacturing the subject bipolar plate, comprising the following: Powder metallurgical manufacture of the porous titanium plate (1), and bonding of plate (1) to the solid titanium plate (2) by sintering. Further development of the bipolar plate by applying a non-porous, solid graphite and PVF composite plate (7) with a parallel groove structure (8), and further applying a porous graphite and PVF composite plate (10), wherewith channels (9) are present. Combining of the plates by hot pressing, sintering, or adhesive bonding, to form a compact, mechanically strong electrically conducting whole.
摘要翻译：一种用于具有层叠结构的装置的双极板，所述装置包括多个电化学电池并使用固体电解质，所述双极板由具有平行凹槽结构（3）的多孔钛板（1）组成，所述双极板还包括在接触轨道（4）处强烈焊接到板（1）的无孔固体钛板（2），其中存在通道（5），并且所述双极板还包括表面层或涂层（6 ）由作为电解反应催化剂的材料组成。一种制造本发明的双极板的方法，包括以下步骤：多孔钛板（1）的粉末冶金制造，以及通过烧结将板（1）与固体钛板（2）结合。通过使用具有平行槽结构（8）的无孔固体石墨和PVF复合板（7）进一步开发双极板，并进一步施加多孔石墨和PVF复合板（10），其中通道（9）存在。通过热压，烧结或粘合剂结合板，以形成紧凑的机械强度导电整体。

6. 发明授权

US4427504A Process for the continuous production of nitric oxide (NO) 失效
标题翻译：连续生产一氧化氮（NO）的方法
公开(公告)号：US4427504A
公开(公告)日：1984-01-24
申请号：US344034
申请日：1982-01-29
申请人： Samuel Stucki
发明人： Samuel Stucki
IPC分类号： C25B1/00 , C25B1/04 , C25B1/12
CPC分类号： C25B1/00 , C25B1/04 , Y02E60/366 , Y02P20/129 , Y10S423/11
摘要： Nitric oxide is prepared by the oxidation of ammonia produced by the Haber-Bosch synthesis technique by (a) vaporizing and heating water to superheated steam; (b) electrolyzing the superheated steam in a high temperature electrolysis cell to oxygen and hydrogen; (c) reacting said hydrogen with atmospheric nitrogen thereby forming ammonia by the Haber-Bosch process; and (d) oxidizing said ammonia to nitric oxide and water vapor in the anode of said electrolytic cell with the oxygen produced by said electrolysis.
摘要翻译：通过（a）将水蒸发并加热至过热蒸汽，通过由Haber-Bosch合成技术生产的氨的氧化制备一氧化氮; （b）将高温电解池中的过热蒸汽电解为氧和氢; （c）使所述氢气与大气氮反应，由Haber-Bosch工艺形成氨; 和（d）用所述电解产生的氧将所述氨氧化成所述电解池的阳极中的一氧化氮和水蒸汽。

7. 发明申请

US20160040308A1 ELECTROLYSIS CELL AND METHOD FOR OPERATING AN ELECTROLYSIS CELL 有权
标题翻译：电解质细胞和操作电解质细胞的方法
公开(公告)号：US20160040308A1
公开(公告)日：2016-02-11
申请号：US14807515
申请日：2015-07-23
申请人： Samuel Stucki , Dirk SCHULZE
发明人： Samuel Stucki , Dirk SCHULZE
IPC分类号： C25B9/08 , C25B1/20 , C25B1/18 , C25B1/10 , C25B15/02
CPC分类号： C25B9/08 , C25B1/10 , C25B1/18 , C25B1/20 , C25B15/02 , Y02E60/366
摘要： An electrolysis cell, having an anode, a cathode, and a membrane that is situated between the anode and the cathode and contacts the anode via an anode contact area and contacts the cathode via a cathode contact area, wherein the cathode contact area is greater than the anode contact area, the membrane has a surface oriented toward the cathode that is greater than the cathode contact area, and the electrolysis cell has cathodically polarized surfaces that are in direct contact with the electrically conductive water. This invention also relates to a method for operating an electrolysis cell in natural water and a use of such an electrolysis cell for disinfecting water are also proposed.
摘要翻译：一种电解槽，其具有位于阳极和阴极之间的阳极，阴极和膜，并经由阳极接触区域接触阳极，并通过阴极接触区与阴极接触，其中阴极接触面积大于阳极接触区域，膜具有朝向阴极的表面，其大于阴极接触面积，并且电解池具有与导电水直接接触的阴极极化表面。本发明还涉及在天然水中操作电解槽的方法以及这种电解槽用于消毒水的用途。

8. 发明申请

US20090126274A1 Process for Generating Methane and/or Methane Hydrate From Biomass 有权
标题翻译：从生物质产生甲烷和/或甲烷水合物的方法
公开(公告)号：US20090126274A1
公开(公告)日：2009-05-21
申请号：US11992812
申请日：2006-06-19
申请人： Frederic Vogel , Thanh-Binh Truong , Samuel Stucki , Maurice Waldner
发明人： Frederic Vogel , Thanh-Binh Truong , Samuel Stucki , Maurice Waldner
IPC分类号： C12P5/00
CPC分类号： B09B3/00 , C02F11/04 , C02F11/08 , C05F3/00 , C05G1/00 , C10J3/00 , C10J3/78 , C10J2200/06 , C10J2300/0916 , C10J2300/0959 , C10J2300/0979 , C10L3/08 , C10L5/44 , Y02A40/205 , Y02E50/10 , Y02E50/30 , Y02E50/343 , Y02P20/145 , Y02P20/52 , Y02P20/544 , Y02W30/47
摘要： To generate methane from biomass, a biomass pulp is produced from the biomass with a desired dry mass content being set, and the biomass pulp is placed under pressure. The biomass pulp is heated under pressure in order to liquefy the solid organic components of the biomass pulp. The pressurized and heated biomass pulp is heated further to at least the critical temperature of the biomass pulp. Solids precipitated under pressure and increased temperature are separated from the fluid phase. At least a part of the remaining fluid phase is gasified under pressure and increased temperature by means of a reactor to form a methane-rich gas.
摘要翻译：为了从生物质产生甲烷，从生物质产生生物质纸浆，其中所需的干质量含量被设定，生物质纸浆被置于压力下。在压力下加热生物质纸浆以使生物质纸浆的固体有机成分液化。将加压和加热的生物质纸浆进一步加热至至少生物质纸浆的临界温度。在压力下沉淀的固体和升高的温度与流体相分离。剩余流体相的至少一部分通过反应器在压力和升高的温度下气化以形成富含甲烷的气体。

9. 发明申请

US20070299288A1 Process for the Synthetic Generation of Methane 有权
标题翻译：甲烷合成生成工艺
公开(公告)号：US20070299288A1
公开(公告)日：2007-12-27
申请号：US10589158
申请日：2005-01-24
申请人： Martin Seemann , Serge Biollaz , Samuel Stucki
发明人： Martin Seemann , Serge Biollaz , Samuel Stucki
IPC分类号： C07C1/10
CPC分类号： C07C1/046 , C07C1/043 , C07C2523/755 , C07C9/04
摘要： In a process for the synthetic generation of methane from a feed gas mixture, a feed gas mixture including carbon monoxide, hydrogen, water vapor, CO2, volatile hydrocarbons comprising C2 and higher, unsaturated C2 components and aromatic hydrocarbons in the range of 1 to 10 vol % is provided. The feed gas mixture is contacted with a fluidized bed catalyst having catalyst particles having a catalytic active component selected from the group consisting of a metal, a metal compound and combinations thereof. The contacting occurs at an elevated temperature in the range of 250 to 450° C., a feed gas pressure in the range of 0.8 to 70 bar, a gas hourly space velocity of 1000 to 50000 h−1, and a concentration of H2/CO in the gas mixture in the range of 0.25 to 5.
摘要翻译：在从进料气体混合物合成生成甲烷的方法中，包括一氧化碳，氢气，水蒸气，CO 2的进料气体混合物，包含C 2 H 2的挥发性烃，并且提供更高的不饱和C 2 H 2成分和1至10体积％范围内的芳族烃。进料气体混合物与具有催化剂颗粒的流化床催化剂接触，催化剂颗粒具有选自金属，金属化合物及其组合的催化活性组分。接触在250至450℃的升高的温度，0.8至70巴的进料气体压力，1000至50000小时-1的气时空速下进行。，气体混合物中的H 2 H 2 / CO浓度在0.25〜5的范围内。

10. 发明授权

US4416747A Process for the synthetic production of ozone by electrolysis and use thereof 失效
标题翻译：通过电解合成生产臭氧的方法及其用途
公开(公告)号：US4416747A
公开(公告)日：1983-11-22
申请号：US373107
申请日：1982-04-29
申请人： Anton Menth , Samuel Stucki
发明人： Anton Menth , Samuel Stucki
IPC分类号： C01B13/10 , C02F1/461 , C02F1/467 , C02F1/78 , C25B1/13 , C25B1/02
CPC分类号： C25B1/13 , C01B13/10 , C02F1/4672 , C02F1/78 , C02F2001/46128 , C02F2001/46133 , C02F2001/46152 , C02F2201/46115 , C02F2201/782
摘要： Electrolytic production of ozone by a process wherein an oxygen-saturated mixture of water and oxygen, or air, is led along both sides of a solid electrolyte (1), which acts as an ion-exchange membrane and carries coatings (2,3) of electrically conductive materials, both on the cathode side and on the anode side, ozone being evolved, in addition to oxygen, on the anode side and, on the cathode side, the evolution of hydrogen being suppressed by the depolarizing effect of the oxygen which is entrained in the water stream, and merely water being formed. The electrolysis is carried out under an increased pressure.Individual electrolysis cell bounded by bipolar plates (6), and comprising a solid electrolyte (1), provided, in each case, with a surface coating (2,3), and centrally located between current-collectors (4) and adjoining open metallic structures (5). A plurality of individual cells integrated together between end plates (7), electrically connected in series and hydrodynamically connected in parallel, combined to form a block.Use in water-treatment, and as a component of chemical processes (oxidation processes).
摘要翻译：通过其中氧和氧的氧饱和的混合物或空气的氧饱和的电解生产通过用作离子交换膜并承载涂层（2,3）的固体电解质（1）的两侧引导，的导电材料，在阴极侧和阳极侧，在阳极侧除了氧之外还产生臭氧，在阴极侧，通过氧的去极化效应抑制氢的释放被夹带在水流中，仅形成水。电解在增压下进行。由双极板（6）界定并且包括固体电解质（1）的单个电解槽，在每种情况下都具有表面涂层（2,3），并且位于集电体（4）和邻接的开放金属结构（5）。在串联电连接并并联流体动力连接的端板（7）之间集成在一起的多个单个电池组合在一起形成一块。用于水处理和作为化学过程（氧化过程）的组成部分。

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