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1. 发明申请

US20100063209A1 DEGRADABLE THIOL-ENE POLYMERS 有权
标题翻译：可降解的THIOL-ENE聚合物
公开(公告)号：US20100063209A1
公开(公告)日：2010-03-11
申请号：US12556640
申请日：2009-09-10
申请人： Christopher Bowman , Kristi Anseth , Bilge Hacioglu , Charlie Nuttleman
发明人： Christopher Bowman , Kristi Anseth , Bilge Hacioglu , Charlie Nuttleman
IPC分类号： C08F116/06 , C08G75/00 , C08G63/688 , C08G59/14 , C08G64/00 , C08F251/00 , C08G73/10
CPC分类号： C08L89/00 , A01N25/04 , A61K47/34 , A61L27/16 , A61L27/18 , A61L27/38 , A61L27/52 , A61L27/54 , A61L2300/62 , C05G3/0029 , C05G3/0076 , C08G75/045 , C08G81/00 , C08G81/027 , C08G2261/126 , C08J3/075 , C08J2329/04 , C08J2367/04 , C08J2371/02 , C08L71/02 , C08L81/02 , C08L2205/05 , Y10S524/916 , Y10S525/936 , C08L83/00 , C08L2666/22
摘要： A thiol-ene polymeric material is disclosed. The material is produced by the photopolymerization of reactants having thiol and olefin moieties. The material can incorporate encapsulated components, including cells. Additionally, the material can be derivatized by reacting the polymeric material with components such as proteins.
摘要翻译：公开了一种硫醇烯聚合物材料。该材料通过具有硫醇和烯烃部分的反应物的光聚合产生。该材料可以包含包封的组分，包括细胞。此外，可以通过使聚合物材料与诸如蛋白质的组分反应来衍生该材料。

2. 发明授权

US07288608B2 Degradable thiol-ene polymers 有权
标题翻译：可降解的硫醇聚合物
公开(公告)号：US07288608B2
公开(公告)日：2007-10-30
申请号：US10269916
申请日：2002-10-10
申请人： Christopher Bowman , Kristi Anseth , Bilge Hacioglu , Charlie Nuttelman
发明人： Christopher Bowman , Kristi Anseth , Bilge Hacioglu , Charlie Nuttelman
IPC分类号： C08G81/00
CPC分类号： C08L89/00 , A01N25/04 , A61K47/34 , A61L27/16 , A61L27/18 , A61L27/38 , A61L27/52 , A61L27/54 , A61L2300/62 , C05G3/0029 , C05G3/0076 , C08G75/045 , C08G81/00 , C08G81/027 , C08G2261/126 , C08J3/075 , C08J2329/04 , C08J2367/04 , C08J2371/02 , C08L71/02 , C08L81/02 , C08L2205/05 , Y10S524/916 , Y10S525/936 , C08L83/00 , C08L2666/22
摘要： A thiol-ene polymeric material is disclosed. The material is produced by the photopolymerization of reactants having thiol and olefin moieties. The material can incorporate encapsulated components, including cells. Additionally, the material can be derivatized by reacting the polymeric material with components such as proteins.
摘要翻译：公开了一种硫醇烯聚合物材料。该材料通过具有硫醇和烯烃部分的反应物的光聚合产生。该材料可以包含包封的组分，包括细胞。此外，可以通过使聚合物材料与诸如蛋白质的组分反应来衍生该材料。

3. 发明申请

US20080070786A1 Degradable Thiol-ene Polymers 审中-公开
标题翻译：可降解硫醇烯聚合物
公开(公告)号：US20080070786A1
公开(公告)日：2008-03-20
申请号：US11858062
申请日：2007-09-19
申请人： Christopher Bowman , Kristi Anseth , Bilge Hacioglu , Charlie Nuttelman
发明人： Christopher Bowman , Kristi Anseth , Bilge Hacioglu , Charlie Nuttelman
IPC分类号： C08G75/00 , A01N25/28 , C12N11/04 , A61K47/30
CPC分类号： C08G75/045 , A01N25/04 , A61K47/34 , A61L27/16 , A61L27/18 , A61L27/38 , A61L27/52 , A61L27/54 , A61L2300/62 , C05G3/0029 , C05G3/0076 , C08G81/00 , C08G81/025 , C08G81/027 , C08G2261/126 , C08J3/075 , C08J2329/04 , C08J2367/04 , C08J2371/02 , C08L71/02 , C08L81/02 , C08L89/00 , C08L2205/05 , Y10S524/916 , Y10S525/936 , C08L83/00 , C08L2666/22
摘要： A thiol-ene polymeric material is disclosed. The material is produced by the photopolymerization of reactants having thiol and olefin moieties. The material can incorporate encapsulated components, including cells. Additionally, the material can be derivatized by reacting the polymeric material with components such as proteins.
摘要翻译：公开了一种硫醇烯聚合物材料。该材料通过具有硫醇和烯烃部分的反应物的光聚合产生。该材料可以包含包封的组分，包括细胞。此外，可以通过使聚合物材料与诸如蛋白质的组分反应来衍生该材料。

4. 发明申请

US20140038826A1 COVALENTLY CROSS LINKED HYDROGELS AND METHODS OF MAKING AND USING SAME 审中-公开
标题翻译：共同的交联水合物及其制备方法和使用方法
公开(公告)号：US20140038826A1
公开(公告)日：2014-02-06
申请号：US13981885
申请日：2012-01-27
申请人： Kristi Anseth , Ben Fairbanks , Christopher Bowman
发明人： Kristi Anseth , Ben Fairbanks , Christopher Bowman
IPC分类号： A61L27/22 , A61L27/18 , A61L27/52
CPC分类号： A61L27/18 , A61L27/22 , A61L27/52 , A61L27/54 , A61L2430/02 , A61L2430/06 , A61L2430/34 , C08F38/00 , C08G75/045 , C08G75/12 , C08J3/075 , C08J2300/16 , C08J2300/20 , C08J2371/02 , C08L81/02 , C08L101/02 , C08L101/16 , C12N5/0068
摘要： A thiol-yne polymeric material and methods for producing said polymers are disclosed. The material is produced by the radically mediated polymerization of monomers having alkyne and thiol functional groups. The alkyne moiety, internal or terminal, may react with one or two thiols. Degradable monomers may be used to form degradable polymers.
摘要翻译：公开了一种硫醇聚合物材料及其制备方法。该材料通过具有炔和硫醇官能团的单体的自由基介导的聚合产生。内部或末端的炔基部分可与一个或两个硫醇反应。可降解单体可用于形成可降解聚合物。

5. 发明授权

US08519086B2 Degradable thiol-ene polymers 有权
公开(公告)号：US08519086B2
公开(公告)日：2013-08-27
申请号：US12556640
申请日：2009-09-10
申请人： Christopher Bowman , Kristi Anseth , Blige Hacioglu , Charlie Nuttelman
发明人： Christopher Bowman , Kristi Anseth , Blige Hacioglu , Charlie Nuttelman
IPC分类号： C08G75/04 , C08G81/00
CPC分类号： C08L89/00 , A01N25/04 , A61K47/34 , A61L27/16 , A61L27/18 , A61L27/38 , A61L27/52 , A61L27/54 , A61L2300/62 , C05G3/0029 , C05G3/0076 , C08G75/045 , C08G81/00 , C08G81/027 , C08G2261/126 , C08J3/075 , C08J2329/04 , C08J2367/04 , C08J2371/02 , C08L71/02 , C08L81/02 , C08L2205/05 , Y10S524/916 , Y10S525/936 , C08L83/00 , C08L2666/22
摘要： A thiol-ene polymeric material is disclosed. The material is produced by the photopolymerization of reactants having thiol and olefin moieties. The material can incorporate encapsulated components, including cells. Additionally, the material can be derivatized by reacting the polymeric material with components such as proteins.

6. 发明申请

US20060066006A1 Fabrication of 3d photopolymeric devices 审中-公开
标题翻译： 3d光聚合器件的制造
公开(公告)号：US20060066006A1
公开(公告)日：2006-03-30
申请号：US10521635
申请日：2003-07-21
申请人： K. Haraldsson , J Hutchison , Christopher Bowman , Kristi Anseth
发明人： K. Haraldsson , J Hutchison , Christopher Bowman , Kristi Anseth
IPC分类号： B29C35/08 , B29C41/02 , B29C41/22
CPC分类号： B82Y10/00 , B82Y40/00 , G03F7/0002 , G03F7/0035 , G03F7/0037 , G03F7/2014
摘要： A process and apparatus for making polymeric layers. A layer of liquid (20) including a photopolymerizable precursor is formed between a substrate (17) and a photomask (12). A reaction chamber is formed by a base (15), side walls (16) and photomask (12) polymerizes one or more regions of the liquid layer (20) to form a polymeric layer.
摘要翻译：用于制备聚合物层的方法和设备。在基板（17）和光掩模（12）之间形成包含可光聚合的前体的液体层（20）。反应室由基底（15）形成，侧壁（16）和光掩模（12）聚合液体层（20）的一个或多个区域以形成聚合物层。

7. 发明授权

US07354706B2 Use of photopolymerization for amplification and detection of a molecular recognition event 失效
标题翻译：使用光聚合进行扩增和检测分子识别事件
公开(公告)号：US07354706B2
公开(公告)日：2008-04-08
申请号：US11372485
申请日：2006-03-09
申请人： Kathy L. Rowlen , John W. Birks , Christopher Bowman , Hadley Sikes , Ryan Hansen , Robert Kuchta
发明人： Kathy L. Rowlen , John W. Birks , Christopher Bowman , Hadley Sikes , Ryan Hansen , Robert Kuchta
IPC分类号： C12Q1/68 , C12Q1/70 , G01N33/53
CPC分类号： C12Q1/6816 , C12Q2565/401
摘要： The invention provides methods to detect molecular recognition events. The invention also provides methods to detect the presence of or identify a target species based on its interaction with one or more probe species. The methods of the invention are based on amplification of the signal due to each molecular recognition event. The amplification is achieved through photopolymerization, with the polymer formed being associated with the molecular recognition event. In an embodiment, a fluorescent polymer, a magnetic polymer, a radioactive polymer or an electrically conducting polymer can form the basis of detection and amplification. In another embodiment, a polymer gel swollen with a fluorescent solution, a magnetic solution, a radioactive solution or an electrically conducting solution can form the basis of detection and amplification. In another embodiment, sufficient polymer forms to be detectable by visual inspection.
摘要翻译：本发明提供检测分子识别事件的方法。本发明还提供了基于其与一种或多种探针物种的相互作用来检测靶物种的存在或鉴定目的物种的方法。本发明的方法基于由于每个分子识别事件引起的信号的放大。通过光聚合实现扩增，形成的聚合物与分子识别事件相关联。在一个实施方案中，荧光聚合物，磁性聚合物，放射性聚合物或导电聚合物可以形成检测和扩增的基础。在另一个实施方案中，用荧光溶液，磁性溶液，放射性溶液或导电溶液溶胀的聚合物凝胶可以形成检测和扩增的基础。在另一个实施方案中，足够的聚合物形式可通过目视检查来检测。

8. 发明申请

US20070082966A1 Novel photopolymers and use in dental restorative materials 有权
标题翻译：新型光聚合物和用于牙科修复材料
公开(公告)号：US20070082966A1
公开(公告)日：2007-04-12
申请号：US10576635
申请日：2004-10-22
申请人： Christopher Bowman , Hui Lu , Jeffrey Stansbury
发明人： Christopher Bowman , Hui Lu , Jeffrey Stansbury
IPC分类号： C08F2/50
CPC分类号： C08G75/045 , A61C13/08 , A61C13/087 , A61K6/083 , C08F2/50 , G03F7/0275 , C08L33/00
摘要： Photopolymerizable polymer composites based on dimethacrylate systems have been increasingly utilized as dental restorative materials. One of the biggest drawbacks of current dental resin systems is the volume shrinkage and shrinkage induced stresses that arise during the polymerization. Other major problems include incomplete double bond conversion and insufficient wear resistance. This invention involves the development of an entirely novel approach to the photopolymerization process that utilizes thiol-ene systems as low shrinkage and ultra-low shrinkage stress dental restorative materials. Compared with the traditional dimethacrylate dental resins, these novel photopolymerizations have demonstrated a dramatically decreased volume shrinkage, extremely rapid polymerization, abilities to photopolymerize ultrathick materials and achieve much higher conversion, lack of oxygen inhibition and ultra-low shrinkage stress due to low volume shrinkage and drastically delayed gel point conversion. These polymers have thus shown outstanding suitability as dental restorative materials.
摘要翻译：基于二甲基丙烯酸酯体系的可光聚合聚合物复合材料越来越多地用作牙科修复材料。现有牙科树脂系统的最大缺点之一是在聚合期间产生的体积收缩和收缩诱导的应力。其他主要问题包括不完全双键转化和耐磨性不足。本发明涉及开发一种全新的光聚合方法，其利用硫醇系统作为低收缩和超低收缩应力牙科修复材料。与传统的二甲基丙烯酸酯牙科树脂相比，这些新型光聚合已经显示体积收缩率显着降低，聚合极快，光聚合超薄材料的能力，并且由于低体积收缩而实现了更高的转化率，缺少氧抑制和超低收缩应力，急剧延迟凝胶点转化。因此，这些聚合物显示出作为牙科修复材料的突出的适用性。

9. 发明申请

US20060286570A1 Use of photopolymerization for amplification and detection of a molecular recognition event 失效
标题翻译：使用光聚合扩增和检测分子识别事件
公开(公告)号：US20060286570A1
公开(公告)日：2006-12-21
申请号：US11372485
申请日：2006-03-09
申请人： Kathy Rowlen , John Birks , Christopher Bowman , Hadley Sikes , Ryan Hansen , Robert Kuchta
发明人： Kathy Rowlen , John Birks , Christopher Bowman , Hadley Sikes , Ryan Hansen , Robert Kuchta
IPC分类号： C12Q1/70 , C12Q1/68
CPC分类号： C12Q1/6816 , C12Q2565/401
摘要： The invention provides methods to detect molecular recognition events. The invention also provides methods to detect the presence of or identify a target species based on its interaction with one or more probe species. The methods of the invention are based on amplification of the signal due to each molecular recognition event. The amplification is achieved through photopolymerization, with the polymer formed being associated with the molecular recognition event. In an embodiment, a fluorescent polymer, a magnetic polymer, a radioactive polymer or an electrically conducting polymer can form the basis of detection and amplification. In another embodiment, a polymer gel swollen with a fluorescent solution, a magnetic solution, a radioactive solution or an electrically conducting solution can form the basis of detection and amplification. In another embodiment, sufficient polymer forms to be detectable by visual inspection.
摘要翻译：本发明提供检测分子识别事件的方法。本发明还提供了基于其与一种或多种探针物种的相互作用来检测靶物种的存在或鉴定目的物种的方法。本发明的方法基于由于每个分子识别事件引起的信号的放大。通过光聚合实现扩增，形成的聚合物与分子识别事件相关联。在一个实施方案中，荧光聚合物，磁性聚合物，放射性聚合物或导电聚合物可以形成检测和扩增的基础。在另一个实施方案中，用荧光溶液，磁性溶液，放射性溶液或导电溶液溶胀的聚合物凝胶可以形成检测和扩增的基础。在另一个实施方案中，足够的聚合物形式可通过目视检查来检测。

10. 发明授权

US09044902B2 Radio frequency magnetic field responsive polymer composites 有权
标题翻译：射频磁场响应聚合物复合材料
公开(公告)号：US09044902B2
公开(公告)日：2015-06-02
申请号：US13303782
申请日：2011-11-23
申请人： Christopher Bowman , Brian Adzima , Christopher Kloxin
发明人： Christopher Bowman , Brian Adzima , Christopher Kloxin
IPC分类号： C08K3/22 , B29C73/16 , B29C73/18 , B29C35/02 , C09J5/06 , B29C65/36 , B29C65/76 , B29C65/00 , B29K105/20 , B29C35/08
CPC分类号： B29C73/16 , B29C35/0272 , B29C65/02 , B29C65/3612 , B29C65/368 , B29C65/76 , B29C66/0242 , B29C66/721 , B29C66/7212 , B29C66/72141 , B29C66/72143 , B29C66/73756 , B29C66/91216 , B29C66/91315 , B29C66/91411 , B29C66/91445 , B29C66/91651 , B29C66/919 , B29C66/9192 , B29C66/91921 , B29C73/18 , B29C2035/0861 , B29K2105/203 , C08K3/22 , C08K2003/2251 , C08K2201/01 , C09J5/06 , C09J2205/31 , C09J2400/226 , B29K2307/04 , B29K2309/08
摘要： The invention includes a composite material comprising magnetic field responsive particles distributed in a reversibly crosslinked polymer, wherein the reversibly crosslinked polymer includes thermally reversible bonds. In one embodiment, exposing the composite material to an electromagnetic field allows for crack-healing, remolding and/or bonding of the material.
摘要翻译：本发明包括包含分布在可逆交联的聚合物中的磁场响应颗粒的复合材料，其中可逆交联的聚合物包括热可逆键。在一个实施例中，将复合材料暴露于电磁场允许材料的裂纹愈合，重塑和/或粘合。

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